ACETYLENE FROM IODOFORM.

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P. CAZENEUVE publishes in the Comptes Rendus a new method for the preparation of acetylene, which consists in mixing iodoform intimately with moist and finely divided silver. An abundant evolution of acetylene takes place without heating. The reaction is represented by the following formula: 2CHI3 + 6Ag = C2H2 + 6 AgI. The decomposition of the iodoform is hastened if the silver is mixed with finely divided copper, such as can be obtained by precipitating it from its sulphate by means of zinc.

Cazeneuve also observed that most metals which have any affinity for iodine will decompose iodoform in the presence of water, forming acetylene and an iodide of the metal. By the use of zinc he obtained a liquid having a pleasant ethereal odor, and a gas mixture that contained besides acetylene an iodine compound which burned with a purple-edged, fawn-colored flame.


                                                                                                                                                                                                                                                                                                           

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