LUMINOUS PAINT.

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The sun is evidently going out of fashion, and is more and more excluded from “good society” as our modern substitute for civilization advances. “Serve him right!” many will say, for behaving so badly during the last two summers. The old saw, which says something about “early to bed and early to rise” is forgotten: we take “luncheon” at dinner-time, dine at supper-time, make “morning” calls and go to “morning” concerts, etc., late in the afternoon, say “Good morning” until 6 or 7 P.M.; and thus, by sleeping through the bright hours of the morning, and waking up fully only a little before sunset, the demand for artificial light becomes almost overwhelming. Not only do we require this during a longer period each day, but we insist upon more and more, and still more yet, during that period.

The rushlight of our forefathers was superseded by an exotic luxury, the big-flame candle made of Russian tallow, with a wick of Transatlantic cotton. Presently this luxurious innovation was superseded by the “mould candle;” the dip was consigned to the kitchen, and the bloated aristocrats of the period indulged in a pair of candlesticks, alarming their grandmothers by the extravagance of burning two candles on one table. Presently the mould candle was snuffed out by the composite; then came the translucent pearly paraffin candle, gas light, solar lamps, moderator lamps, and paraffin lamps. Even these, with their brilliant white flame from a single wick, are now insufficient, and we have duplex and even triplex wicks to satisfy our demand for glaring mockeries of the departed sun.

Some are still living who remember the oil lamps in Cheapside and Piccadilly, and the excitement caused by the brilliancy of the new gas lamps; but now we are dissatisfied with these, and demand electric lights for common thoroughfares, or some extravagant combination of concentric or multiplex gas-jets to rival it.

The latest novelty is a device to render darkness visible by capturing the sunbeams during the day, holding them as prisoners until after sunset, and then setting them free in the night. The principle is not a new discovery; the novelty lies in the application and some improvements of detail. In the “Boy’s Own Book,” or “Endless Amusement,” of thirty or forty years ago, are descriptions of “Canton’s phosphorus,” or “solar phosphori,” and recipes for making them. Burnt oyster-shells or oyster-shells burnt with sulphur, was one of these.

Various other methods of effecting combination between lime or baryta with sulphur are described in old books, the result being the formation of more or less of what modern chemists call calcium sulphide and barium sulphide (or otherwise sulphide of calcium or sulphide of barium). These compounds, when exposed to the sun, are mysteriously acted upon by the solar rays, and put into such a condition that their atoms or molecules, or whatever else constitutes their substance, are set in motion—in that sort of motion which communicates to the surrounding medium the wavy tremor which agitates our optic nerve and produces the sensation of light.

Until lately, this property has served no other purpose than puzzling philosophers, and amusing that class of boys who burn their fingers, spoil their clothes, and make holes in their mothers’ table-covers, with sulphuric acid, nitric acid, and other noxious chemicals. The first idea of turning it to practical account was that of making a sort of enamel of one or the other of these sulphides, and using it as a coating for clock-faces. A surface thus coated and exposed to the light during the day becomes faintly luminous at night.

Anybody desirous of seeing the sort of light which it emits, may do so very easily by purchasing an unwashed smelt from the fishmonger, and allowing it to dry with its natural slime upon it, then looking at it in the dark. A sole or almost any other fish will answer the purpose, but I name the smelt from having found it the most reliable in the course of my own experiments. It emits a dull, ghostly light, with very little penetrating power, which shows the shape of the fish, but casts no perceptible light on objects around.

Thus the phosphorescent parish-clock face, with non-phosphorescent figures and hands, would look like a pale ghost of the moon with dark figures round it, and dark hands stretching across, by which the time of the night might possibly be discovered there or thereabouts. This invention has already appeared in a great many paragraphs, but, hitherto, upon very few clock-faces.

Recently it has assumed a more ambitions form—patented, of course. The patentees claim an improved phosphorescent powder, which is capable of being worked up with the medium of paints and varnishes, and thus applied, not merely to clock-faces, but to the whole of the walls and ceilings of any apartment. In this case the faintness of the light will be in some degree compensated by the extent of phosphorescent surface, and it is just possible that the sum total of the light emitted from walls and ceiling may be nearly equal to that of one mould candle. If so, it will have some value as a means of lighting powder magazines and places for storage of inflammable compounds. It is stated that one of the London Dock companies is about to use it for its spirit vaults; also that the Admiralty has already tried the paint at Whitehall, and has ordered two compartments of the Comus to be painted with it, in order to test its capability of lighting the dark regions of ironclad ships.

This application can, however, only be limited to those parts which receive a fair amount of light during the day, for unless the composition first receives light, it is not able afterwards to emit it, and this emission or phosphorescence only continues a few hours after the daylight has passed away; five or six hours is the time stated.

A theatrical manager is said to be negotiating for the exclusive right to employ this weird illumination for scenic purposes. The sepulchre scene in “Robert le Diable,” or the incantation in “Der Freischutz,” or “The Sorcerer,” might be made especially effective by its ghostly aid. The name-plates of streets, and buoys at sea might be advantageously coated with such a composition; and many other uses suggest themselves.

There are rival inventors, as a matter of course. The French patentees claim the use of cuttle-fish bones, various sea-shells, etc., mixed with pure lime, sulphur, and calcined sea-salt, besides sulphides of calcium, barium, strontium, uranium, magnesium, or aluminium. They also add phosphorus itself, though for what purpose is questionable, seeing that this substance is only luminous during the course of its oxidation or slow combustion, and after this has ended the resultant phosphoric acid is no more luminous than linseed oil or turpentine. An admixture of phosphorus might temporarily increase the luminosity of a sample, but any conclusions based upon this would be quite delusive. They also assert that electrical discharges passed through the paint increase its luminosity. According to some enthusiasts, electricity is to do everything; but these ladies and gentlemen omit to calculate the cost of rousing and feeding this omnipotent giant. In this case electrical machinery for stimulating the paint for anything outside of lecture-table experiments or theatrical and other sensational displays, would be a commercial absurdity.

The Americans, of course, are re-inventing in this direction, but Mr. Edison has not yet appeared on the luminous-paint scene. If he does we shall doubtless hear of something very brilliant, even though we never see it. In the meantime we may safely hope that this application of an old scientific plaything to useful purposes may become of considerable utility, as it evidently opens a wide field for further investigation and progressive improvement, by the application of the enlarged powers which modern science places at the disposal of ingenious inventors. We hope, for the sake of all concerned, that it will not fall into the hands of professional prospectus manufacturers and joint-stock-company mongers, and that the story of its triumphs will be told without any newspaper exaggerations. Since the above was written—in February, 1880—I have tested this luminous paint (Balmain’s patent). Practically, I find it unsatisfactory. In the first place, its endurance is far shorter than is stated. It begins to fade almost immediately the light is withdrawn, and in the course of an hour or two it is, for all practical use—though not absolutely—extinguished. Besides this it emits a very unpleasant odor painfully resembling sewage and sulphureted hydrogen. This is doubtless due to the sulphur compound, but is, I have no doubt, quite harmless in spite of its suggestions.


                                                                                                                                                                                                                                                                                                           

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