SILICON, called also silicium, may be obtained by burning potassium in silicated fluoric gas. The product of the combustion is a brown cinder, which, on being thrown into water, disengages hydrogen with violence, and lets fall a dark liver-brown powder, upon which water exercises no action. This matter is silicon mixed with a salt of difficult solution, which is composed of fluorine, potassium, and silicon. This salt may, however, be removed by a great deal of washing. The further details of this curious subject will be given in my forthcoming system of chemistry.

SILK MANUFACTURE. (Fabrique de soie, Fr.; Seidenfabrik, Germ.) This may be divided into two branches: 1. the production of raw silk; 2. its filature and preparation in the mill, for the purposes of the weaver and other textile artisans. The threads, as spun by the silkworm, and wound up in its cocoon, are all twins, in consequence of the twin orifice in the nose of the insect through which they are projected. These two threads are laid parallel to each other, and are glued more or less evenly together by a kind of glossy varnish, which also envelopes them, constituting nearly 25 per cent. of their weight. Each ultimate filament measures about ¹/₂₀₀₀ of an inch in average fine silk, and the pair measures of course fully ¹/₁₀₀₀ of an inch. In the raw silk, as imported from Italy, France, China, &c., several of these twin filaments are slightly twisted and agglutinated to form one thread, called a single.

The specific gravity of silk is 1·300, water being 1·000. It is by far the most tenacious or the strongest of all textile fibres, a thread of it of a certain diameter being nearly three times stronger than a thread of flax, and twice stronger than hemp. Some varieties of silk are perfectly white, but the general colour in the native state is a golden yellow.

The production of silk was unknown in Europe till the sixth century, when two monks, who brought some eggs of the silkworm from China or India to Constantinople, were encouraged to breed the insect, and cultivate its cocoons, by the Emperor Justinian. Several silk manufactures were in consequence established in Athens, Thebes, and Corinth, not only for rearing the worm upon mulberry-leaves, but for unwinding its cocoons, for twisting their filaments into stronger threads, and weaving these into robes. The Venetians having then and long afterwards intimate commercial relations with the Greek empire, supplied the whole of western Europe with silk goods, and derived great riches from the trade.

About 1130, Roger II., king of Sicily, set up a silk manufacture at Palermo, and another in Calabria, conducted by artisans whom he had seized and carried off as prisoners of war in his expedition to the Holy Land. From these countries, the silk industry soon spread throughout Italy. It seems to have been introduced into Spain at a very early period, by the Moors, particularly in Murcia, Cordova, and Granada. The last town, indeed, possessed a flourishing silk trade when it was taken by Ferdinand in the 15th century. The French having been supplied with workmen from Milan, commenced, in 1521, the silk manufacture; but it was not till 1564 that they began successfully to produce the silk itself, when Traucat, a working gardener at Nismes, formed the first nursery of white mulberry-trees, and with such success, that in a few years he was enabled to propagate them over many of the southern provinces of France. Prior to this time, some French noblemen, on their return from the conquest of Naples, had introduced a few silkworms with the mulberry into Dauphiny; but the business had not prospered in their hands. The mulberry plantations were greatly encouraged by Henry IV.; and since then they have been the source of most beneficial employment to the French people. James I. was most solicitous to introduce the breeding of silkworms into England, and in a speech from the throne he earnestly recommended his subjects to plant mulberry-trees; but he totally failed in the project. This country does not seem to be well adapted for this species of husbandry, on account of the great prevalence of blighting east winds during the months of April and May, when the worms require a plentiful supply of mulberry-leaves. The manufacture of silk goods, however, made great progress during that king’s peaceful and pompous reign. In 1629 it had become so considerable in London, that the silk-throwsters of the city and suburbs were formed into a public corporation. So early as 1661 they employed 40,000 persons. The revocation of the edict of Nantes, in 1685, contributed in a remarkable manner to the increase of the English silk trade, by the influx of a large colony of skilful French weavers, who settled in Spitalfields. The great silk-throwing mill mounted at Derby, in 1719, also served to promote the extension of this branch of manufacture; for soon afterwards, in the year 1730, the English silk goods bore a higher price in Italy than those made by the Italians, according to the testimony of Keysler.

Till the year 1826, however, our silk manufactures in general laboured under very grievous fiscal burdens. Foreign organzine, or twisted raw silk, paid an import duty of 14s. 7¹/₂d. per pound; raw Bengal silk, 4s.; and that from other places, 5s. 7¹/₂d. Mr. Huskisson introduced a bill at that time, reducing the duty on organzine to 5s., and the duty on other raw silk to 3d. per pound. The total prohibition of the import of French manufactured silks, which gave rise to so much contraband trade, was also converted into a duty of 30 per cent. ad valorem. During the reign of the prohibitory system, when our silk weavers had no variety of patterns to imitate, and no adequate stimulus to excel, on account of the monopoly which they possessed in the home market, the inferiority of their productions was a subject of constant pride and congratulation among the Lyonnais; and accordingly the English could not stand their competition any where. At that time, the disadvantage on English silk goods, compared to French, was estimated in foreign markets at 40 per cent.; of late years it certainly does not exceed 20, notwithstanding the many peculiar facilities which France enjoys for this her favourite staple.

The silkworm, called by entomologists PhalÆna bombyx mori, is, like its kindred species, subject to four metamorphoses. The egg, fostered by the genial warmth of spring, sends forth a caterpillar, which, in its progressive enlargement, casts its skin either three or four times, according to the variety of the insect. Having acquired its full size in the course of 25 or 30 days, and ceasing to eat during the remainder of its life, it begins to discharge a viscid secretion, in the form of pulpy twin filaments, from its nose, which harden in the air. These threads are instinctively coiled into an ovoid nest round itself, called a cocoon, which serves as a defence against living enemies and changes of temperature. Here it soon changes into the chrysalis or nymph state, in which it lies swaddled, as it were, for about 15 or 20 days. Then it bursts its cearments, and comes forth furnished with appropriate wings, antennÆ, and feet, for living in its new element, the atmosphere. The male and the female moths couple together at this time, and terminate their union by a speedy death, their whole existence being limited to two months. The cocoons are completely formed in the course of three or four days; the finest being reserved as seed worms. From these cocoons, after an interval of 18 or 20 days, the moth makes its appearance, perforating its tomb by knocking with its head against one end of the cocoon, after softening it with saliva, and thus rendering the filaments more easily torn asunder by its claws. Such moths or aurelias are collected and placed upon a piece of soft cloth, where they couple and lay their eggs.

The eggs, or grains as they are usually termed, are enveloped in a liquid which causes them to adhere to the piece of cloth or paper on which the female lays them. From this glue they are readily freed, by dipping them in cold water, and wiping them dry. They are best preserved in the ovum state at a temperature of about 55° F. If the heat of spring advances rapidly in April, it must not be suffered to act on the eggs, otherwise it might hatch the caterpillars long before the mulberry has sent forth its leaves to nourish them. Another reason for keeping back their incubation is, that they may be hatched together in large broods, and not by small numbers in succession. The eggs are made up into small packets, of an ounce, or somewhat more, which in the south of France are generally attached to the girdles of the women during the day, and placed under their pillows at night. They are, of course, carefully examined from time to time. In large establishments, they are placed in an appropriate stove-room, where they are exposed to a temperature gradually increased till it reaches the 86th degree of Fahrenheit’s scale, which term it must not exceed. Aided by this heat, nature completes her mysterious work of incubation in eight or ten days. The teeming eggs are now covered with a sheet of paper pierced with numerous holes, about one-twelfth of an inch in diameter. Through these apertures the new-hatched worms creep upwards instinctively, to get at the tender mulberry leaves strewed over the paper.

The nursery where the worms are reared, is called by the French a magnaniÈre; it ought to be a well-aired chamber, free from damp, excess of cold or heat, rats and other vermin. It should be ventilated occasionally, to purify the atmosphere from the noisome emanations produced by the excrements of the caterpillars and the decayed leaves. The scaffolding of the wicker-work shelves should be substantial; and they should be from 15 to 18 inches apart. A separate small apartment should be allotted to the sickly worms. Immediately before each moulting, the appetite of the worms begins to flag; it ceases altogether at that period of cutaneous metamorphosis, but revives speedily after the skin is fairly cast, because the internal parts of the animal are thereby allowed freely to develop themselves. At the end of the second age, the worms are half an inch long; and should then be transferred from the small room in which they were first hatched, into the proper apartment where they are to be brought to maturity and set to spin their balls. On occasion of changing their abode, they must be well cleansed from the litter, laid upon beds of fresh leaves, and supplied with an abundance of food every six hours in succession. In shifting their bed, a piece of network being laid over the wicker plates, and covered with leaves, the worms will creep up over them; when they may be transferred in a body upon the net. The litter, as well as the sickly worms, may thus be readily removed, without handling a single healthy one. After the third age, they may be fed with entire leaves; because they are now exceedingly voracious, and must not be subsequently stinted in their diet. The exposure of chloride of lime, spread thin upon plates, to the air of the magnaniÈre, has been found useful in counteracting the tendency which sometimes appears of an epidemic disease among the silkworms, from the fetid exhalations of the dead and dying.

When they have ceased to eat, either in the fourth or fifth age, agreeably to the variety of the bombyx, and when they display the spinning instinct by crawling up among the twigs of heath, &c., they are not long of beginning to construct their cocoons, by throwing the thread in different directions, so as to form the floss, filoselle, or outer open network, which constitutes the bourre or silk for carding and spinning.

The cocoons destined for filature, must not be allowed to remain for many days with the worms alive within them; for should the chrysalis have leisure to grow mature or come out, the filaments at one end would be cut through, and thus lose almost all their value. It is therefore necessary to extinguish the life of the animal by heat, which is done either by exposing the cocoons for a few days to sunshine, by placing them in a hot oven, or in the steam of boiling water. A heat of 202° F. is sufficient for effecting this purpose, and it may be best administered by plunging tin cases filled with the cocoons into water heated to that pitch.

80 pounds French (88 Eng.) of cocoons, are the average produce from one ounce of eggs, or 100 from one ounce and a quarter; but M. Folzer of Alsace obtained no less than 165 pounds. The silk obtained from a cocoon is from 750 to 1150 feet long. The varnish by which the coils are glued slightly together, is soluble in warm water.

The silk husbandry, as it may be called, is completed in France within six weeks from the end of April, and thus affords the most rapid of agricultural returns, requiring merely the advance of a little capital for the purchase of the leaf. In buying up cocoons, and in the filature, indeed, capital may be often laid out to great advantage. The most hazardous period in the process of breeding the worms, is at the third and fourth moulting; for upon the 6th day of the third age, and the seventh day of the fourth, they in general eat nothing at all. On the first day of the fourth age, the worms proceeding from one ounce of eggs will, according to Bonafons, consume upon an average twenty-three pounds and a quarter of mulberry leaves; on the first of the fifth age, they will consume forty-two pounds; and on the sixth day of the same age, they acquire their maximum voracity, devouring no less than 223 pounds. From this date their appetite continually decreases, till on the tenth day of this age they consume only fifty-six pounds. The space which they occupy upon the wicker tables, being at their birth only nine feet square, becomes eventually 239 feet. In general the more food they consume, the more silk will they produce.

A mulberry-tree is valued, in Provence, at from 6d. to 10d.; it is planted out of the nursery at four years of age; it is begun to be stripped in the fifth year, and affords an increasing crop of leaves till the twentieth. It yields from 1 cwt. to 30 cwt. of leaves, according to its magnitude and mode of cultivation. One ounce of silkworm eggs is worth in France about 2¹/₂ francs; it requires for its due development into cocoons about 15 cwt. of mulberry leaves, which cost upon an average 3 francs per cwt. in a favourable season. One ounce of eggs is calculated, as I have said, to produce from 80 to 100 pounds of cocoons, of the value of 1 fr. 52 centimes per pound, or 125 francs in whole. About 8 pounds of reeled raw silk, worth 18 francs a pound, are obtained from these 100 pounds of cocoons.

There are three denominations of raw silk; viz., organzine, trame (shute or tram), and floss. Organzine serves for the warp of the best silk stuffs, and is considerably twisted; tram is made usually from inferior silk, and is very slightly twisted, in order that it may spread more, and cover better in the weft; floss, or bourre, consists of the shorter broken silk, which is carded and spun like cotton. Organzine and trame may contain from 3 to 30 twin filaments of the worm; the former possesses a double twist, the component filaments being first twisted in one direction, and the compound thread in the opposite; the latter receives merely a slender single twist. Each twin filament gradually diminishes in thickness and strength, from the surface of the cocoon, where the animal begins its work in a state of vigour, to the centre, where it finishes it, in a state of debility and exhaustion; because it can receive no food from the moment of its beginning to spin by spouting forth its silky substance. The winder is attentive to this progressive attenuation, and introduces the commencement of some cocoons to compensate for the termination of others. The quality of raw silk depends, therefore, very much upon the skill and care bestowed upon its filature. The softest and purest water should be used in the cocoon kettle.

The quality of the raw silk is determined by first winding off 400 ells of it, equal to 475 metres, round a drum one ell in circumference, and then weighing that length. The weight is expressed in grains, 24 of which constitute one denier; 24 deniers constitute one ounce; and 16 ounces make one pound, poids de marc. This is the Lyons rule for valuing silk. The weight of a thread of raw silk 400 ells long, is two grains and a half, when five twin filaments have been reeled and associated together.

Raw silk is so absorbent of moisture, that it may be increased ten per cent. in weight by this means. This property has led to falsifications; which are detected by enclosing weighed portions of the suspected silk in a wire-cloth cage, and exposing it to a stove-heat of about 78° F. for 24 hours, with a current of air. The loss of weight which it thereby undergoes, demonstrates the amount of the fraud. There is an office in Lyons called the Condition, where this assay is made, and by the report of which the silk is bought and sold. The law in France requires, that all the silk tried by the Condition must be worked up into fabrics in that country.

In the Journal of the Asiatic Society of Bengal, for January, 1837, there are two very valuable papers upon silkworms; the first, upon those of Assam, by Mr. Thomas Hugon, stationed at Nowgong; the second by Dr. Heifer, upon those which are indigenous to India. Besides the Bombyx mori, the Doctor enumerates the following seven species, formerly unknown:—1. The wild silkworm of the central provinces, a moth not larger than the Bombyx mori. 2. The Joree silkworm of Assam, Bombyx religiosÆ, which spins a cocoon of a fine filament, with much lustre. It lives upon the pipul tree (Ficus religiosa), which abounds in India, and ought therefore to be turned to account in breeding this valuable moth. 3. Saturnia silhetica, which inhabits the cassia mountains in Silhet and Dacca, where its large cocoons are spun into silk. 4. A still larger Saturnia, one of the greatest moths in existence, measuring ten inches from the one end of the wing to the other; observed by Mr. Grant, in Chirra Punjee. 5. Saturnia paphia, or the Tusseh silkworm, is the most common of the native species, and furnishes the cloth usually worn by Europeans in India. It has not hitherto been domesticated, but millions of its cocoons are annually collected in the jungles, and brought to the silk factories near Calcutta and Bhagelpur. It feeds most commonly on the hair-tree (Zizyphus jujuba), but it prefers the Terminalia alata, or Assam tree, and the Bombax heptaphyllum. It is called Koutkuri mooga, in Assam. 6. Another Saturnia, from the neighbourhood of Comercolly. 7. Saturnia assamensis, with a cocoon of a yellow-brown colour, different from all others, called mooga, in Assam; which, although it can be reared in houses, thrives best in the open air upon trees, of which seven different kinds afford it food. The Mazankoory mooga, which feeds on the Adakoory tree, produces a fine silk, which is nearly white, and fetches 50 per cent. more than the fawn-coloured. The trees of the first year’s growth produce by far the most valuable cocoons. The mooga which inhabits the soom-tree, is found principally in the forests of the plains, and in the villages. The tree grows to a large size, and yields three crops of leaves in the year. The silk is of a light fawn colour, and ranks next in value to the Mazankoory. There are generally five breeds of mooga worms in the year; 1. in January and February; 2. in May and June; 3. in June and July; 4. in August and September; 5. in October and November; the first and last being the most valuable.

The Assamese select for breeding, such cocoons only as have been begun to be formed in the largest number on the same day, usually the second or third after the commencement; those which contain males being distinguishable by a more pointed end. They are put in a closed basket suspended from the roof; the moths, as they come forth, having room to move about, after a day, the females (known only by their large body) are taken out, and tied to small wisps of thatching-straw, selected always from over the hearth, its darkened colour being thought more acceptable to the insect. If out of a batch, there should be but few males, the wisps with the females tied to them are exposed outside at night; and the males thrown away in the neighbourhood find their way to them. These wisps are hung upon a string tied across the roof, to keep them from vermin. The eggs laid after the first three days are said to produce weak worms. The wisps are taken out morning and evening, and exposed to the sunshine, and in ten days after being laid, a few of them are hatched. The wisps being then hung up to the tree, the young worms find their way to the leaves. The ants, whose bite is fatal to the worm in its early stages, are destroyed by rubbing the trunk of the tree with molasses, and tying dead fish and toads to it, to attract these rapacious insects in large numbers, when they are destroyed with fire; a process which needs to be repeated several times. The ground under the trees is also well cleared, to render it easy to pick up and replace the worms which fall down. They are prevented from coming to the ground by tying fresh plantain-leaves round the trunk, over whose slippery surface they cannot crawl; and they are transferred from exhausted trees to fresh ones, on bamboo platters tied to long poles. The worms require to be constantly watched and protected from the depredations of both day and night birds, as well as rats and other vermin. During their moultings, they remain on the branches; but when about beginning to spin, they come down the trunk, and being stopped by the plantain-leaves, are there collected in baskets, which are afterwards put under bunches of dry leaves, suspended from the roof, into which the worms crawl, and form their cocoons—several being clustered together: this accident, due to the practice of crowding the worms together, which is most injudicious, rendering it impossible to wind off their silk in continuous threads, as in the filatures of Italy, France, and even Bengal. The silk is, therefore, spun like flax, instead of being unwound in single filaments. After four days the proper cocoons are selected for the next breed, and the rest are uncoiled. The total duration of a breed varies from 60 to 70 days; divided into the following periods:—

On being tapped with the finger, the body renders a hollow sound; the quality of which shows whether they have come down for want of leaves on the tree, or from their having ceased feeding.

As the chrysalis is not soon killed by exposure to the sun, the cocoons are put on stages, covered up with leaves, and exposed to the hot air from grass burned under them; they are next boiled for about an hour in a solution of the potash, made from incinerated rice-stalks; then taken out, and laid on cloth folded over them to keep them warm. The floss being removed by hand, they are then thrown into a basin of hot water to be unwound; which is done in a very rude and wasteful way.

The plantations for the mooga silkworm in Lower Assam, amount to 5000 acres, besides what the forests contain; and yield 1500 maunds of 84 lbs. each per annum. Upper Assam is more productive.

The cocoon of the Koutkuri mooga is of the size of a fowl’s egg. It is a wild species, and affords filaments much valued for fishing-lines. See Silkworm Gut.

8. The Arrindy, or Eria worm, and moth, is reared over a great part of Hindustan, but entirely within doors. It is fed principally on the Hera, or Palma christi leaves, and gives sometimes 12 broods of spun silk in the course of a year. It affords a fibre which looks rough at first; but when woven, becomes soft and silky, after repeated washings. The poorest people are clothed with stuff made of it, which is so durable as to descend from mother to daughter. The cocoons are put in a closed basket, and hung up in the house, out of reach of rats and insects. When the moths come forth, they are allowed to move about in the basket for twenty-four hours; after which the females are tied to long reeds or canes, twenty or twenty-five to each, and these are hung up in the house. The eggs that are laid the first three days, amounting to about 200, alone are kept; they are tied up in a cloth, and suspended to the roof till a few begin to hatch. These eggs are white, and of the size of turnip-seed. When a few of the worms are hatched, the cloths are put on small bamboo platters hung up in the house, in which they are fed with tender leaves. After the second moulting, they are removed to bunches of leaves suspended above the ground, beneath which a mat is laid to receive them when they fall. When they cease to feed, they are thrown into baskets full of dry leaves, among which they form their cocoons, two or three being often found joined together. Upon this injudicious practice I have already animadverted.

9. The Saturnia trifenestrata, has a yellow cocoon of a remarkably silky lustre. It lives on the soom-tree in Assam, but seems not to be much used.

The mechanism of the silk filature, as lately improved in France, is very ingenious. Figs. 973. and 974. exhibit it in plan and longitudinal view. a is an oblong copper basin containing water heated by a stove or by steam. It is usually divided by transverse partitions into several compartments, containing 20 cocoons, of which there are 5 in one group, as shown in the figure. b, b, are wires with hooks or eyelets at their ends, through which the filaments run, apart, and are kept from ravelling. c, c, the points where the filaments cross and rub each other, on purpose to clean their surfaces. d, is a spiral groove, working upon a pin point, to give the traverse motion alternately to right and left, whereby the thread is spread evenly over the surface of the reel e. f, f, are the pulleys, which by means of cords transmit the rotatory movement of the cylinder d, to the reel e. g, is a friction lever or tumbler, for lightening or slackening the endless cord, in the act of starting or stopping the winding operation. Every apartment of a large filature contains usually a series of such reels as the above, all driven by one prime mover; each of which, however, may by means of the tumbling lever be stopped at pleasure. The reeler is careful to remove any slight adhesions, by the application of a brush in the progress of her work.

The expense of reeling the excellent Cevennes silk is only 3 francs and 50 centimes per Alais pound; from 4 to 5 cocoons going to one thread. That pound is 92 hundredths of our avoirdupois pound. In Italy, the cost of reeling silk is much higher, being 7 Italian livres per pound, when 3 to 4 cocoons go to the formation of one thread; and 6 livres when there are from 4 to 5 cocoons. The first of these raw silks will have a titre of 20 to 24 deniers; the last, of 24 to 28. If 5 to 6 cocoons go to one thread, the titre will be from 26 to 32 deniers, according to the quality of the cocoons. The Italian livre is worth 7¹/₂d. English. The woman employed at the kettle receives one livre and five sous per day; and the girl who turns the reel, gets thirteen sous a day; both receiving board and lodging in addition. In June, July, and August, they work 16 hours a day, and then they wind a rubo or ten pounds weight of cocoons, which yield from 1-5th to 1-6th of silk, when the quality is good. The whole expenses amount to from 6 to 7 livres upon every ten pounds of cocoons; which is about 2s. 8d. per English pound of raw silk.

The raw silk, as imported into this country in hanks from the filatures, requires to be regularly wound upon bobbins, doubled, twisted, and reeled in our silk-mills. These processes are called throwing silk, and their proprietors are called silk throwsters; terms probably derived from the appearance of swinging or tossing which the silk threads exhibit during their rapid movements among the machinery of the mills.

A representation of a French mill for throwing silk, is given in the Dictionnaire Technologique, under the article Moulinage de Soie. But it is a most awkward, operose, and defective piece of machinery, quite unworthy of being presented to my readers. It was in Manchester that throwing-mills received the grand improvement upon the antient Italian plan, which had been originally introduced into this country by Sir Thomas Lombe, and erected at Derby. That improvement is chiefly due to the eminent factory engineers, Messrs. Fairbairn and Lillie, who transferred to silk the elegant mechanism of the throstle, so well known in the cotton trade. Still, throughout the silk districts of France the throwing mills are generally small, not many of them turning off more than 1000 pounds of organzine per annum, and not involving 5000l. of capital. The average price of throwing organzine in that country, where the throwster is not answerable for loss, is 7 francs; of throwing trame, from 4 fr. to 5 fr. (per kilogramme?) Where the throwster is accountable for loss, the price is from 10 fr. to 11 fr. for organzine, and from 6 to 7 for trame. In Italy, throwing adds 3s. 9d. to the price of raw silk, upon an average. I should imagine, from the perfection and speed of the silk-throwing machinery in this country, as about to be described, that the cost of converting a pound of raw silk either into organzine or trame must be considerably under any of the above sums.

SILK-THROWING MILL.

The first process to which the silk is subjected, is winding the skeins, as imported, off upon bobbins. The mechanism which effects this winding off and on, is technically called the engine, or swift. The bobbins to which the silk is transferred, are wooden cylinders, of such thickness as may not injure the silk by sudden flexure, and which may also receive a great length of thread without having their diameter materially increased, or their surface velocity changed. Fig. 975. is an end view of the silk-throwing machine, or engine, in which the two large hexagonal reels, called swifts, are seen in section, as well as the table between them, to which the bobbins and impelling mechanism are attached. The skeins are put upon these reels, from which the silk is gradually unwound by the traction of the revolving bobbins. One principal object of attention, is to distribute the thread over the length of the bobbin-cylinder in a spiral or oblique direction, so that the end of the slender semi-transparent thread may be readily found when it breaks. As the bobbins revolve with uniform velocity, they would soon wind on too fast, were their diameters so small at first as to become greatly thicker when they are filled. They are therefore made large, are not covered thick, but are frequently changed. The motion is communicated to that end of the engine shown in the figure.

The wooden table A, shown here in cross section, is sometimes of great length, extending 20 feet, or more, according to the size of the apartment. Upon this the skeins are laid out. It is supported by the two strong slanting legs B, B, to which the bearings of the light reel C are made fast. These reels are called swifts, apparently by the same etymological casuistry as lucus À non lucendo; for they turn with reluctant and irregular slowness; yet they do their work much quicker than any of the old apparatus, and in this respect may deserve their name. At every eighth or tenth leg there is a projecting horizontal piece D, which carries at its end another horizontal bar a, called the knee rail, at right angles to the former. This protects the slender reels or swifts from the knees of the operatives.

These swifts have a strong wooden shaft b, with an iron axis passing longitudinally through it, round which they revolve, in brass bearings fixed near to the middle of the legs B. Upon the middle of the shaft b, a loose ring is hung, shown under c, in fig. 976., to which a light weight d, is suspended, for imparting friction to the reel, and thus preventing it from turning round, unless it be drawn with a gentle force, such as the traction of the thread in the act of winding upon the bobbin.

Fig. 976. is a front view of the engine. B, B, are the legs, placed at their appropriate distances (scale 1¹/₂ inch to the foot); C, C, are the swifts. By comparing figs. 975. and 976., the structure of the swifts will be fully understood. From the wooden shaft b, six slender wooden (or iron) spokes e, e, proceed, at equal angles to each other; which are bound together by a cord f, near their free ends, upon the transverse line f of which cord, the silk thread is wound, in a hexagonal form; due tension being given to the circumferential cords, by sliding them out from the centre. Slender wooden rods are set between each pair of spokes, to stay them, and to keep the cord tight. E is one of the two horizontal shafts, placed upon each side of the engine, to which are affixed a number of light iron pulleys g, g (shown on a double scale in fig. 977.) These serve, by friction, to drive the bobbins which rest upon their peripheries.

To the table A, fig. 975., are screwed the light cast-iron slot-bearings I, I, wherein the horizontal spindles or skewers rest, upon which the bobbins revolve. The spindles (see F, fig. 981.) carry upon one end a little wooden pulley h, whereby they press and revolve upon the larger driving pulleys g, of the shaft E. These pulleys are called stars by our workmen. The other ends of the spindles, or skewers, are cut into screws, for attaching the swivel nuts i (fig. 981.), by which the bobbins K, K, are made fast to their respective spindles. Besides the slots, above described, in which the spindles rest when their friction pulleys h, are in contact with the moving stars g, there is another set of slots in the bearings, into which the ends of the spindles may be occasionally laid, so as to be above the line of contact of the rubbing periphery of the star g, in case the thread of any bobbin breaks. Whenever the girl has mended the thread, she replaces the bobbin-spindle in its deeper slot-bearings, thereby bringing its pulley once more into contact with the star, and causing it to revolve.

G is a long ruler or bar of wood, which is supported upon every eighth or twelfth leg B, B. (The figure being, for convenience of the page, contracted in length, shows it at every sixth leg.) To the edge of that bar the smooth glass rods k, are made fast, over which the threads glide from the swifts, in their way to the bobbins. H is the guide bar, which has a slow traverse or seesaw motion, sliding in slots at the top of the legs B, where they support the bars G. Upon the guide bar H, the guide pieces l, l, are made fast. These consist of two narrow, thin, upright plates of iron, placed endwise together, their contiguous edges being smooth, parallel, and capable of approximation to any degree by a screw, so as to increase or diminish at pleasure the ordinary width of the vertical slit that separates them. Through this slit the silk thread must pass, and, if rough or knotty, will be either cleaned or broken; in the latter case, it is neatly mended by the attendant girl.

The motions of the various parts of the engine are given as follows. Upon the end of the machine, represented in fig. 975., there are attached to the shafts E (fig. 976.), the bevel wheels 1 and 2, which are set in motion by the bevel wheels 3 and 4, respectively. These latter wheels are fixed upon the shaft m, fig. 975. m is moved by the main steam shaft which runs parallel to it, and at the same height, through the length of the engine apartment, so as to drive the whole range of the machines. 5 is a loose wheel or pulley upon the shaft m, working in geer with a wheel upon the steam shaft, and which may be connected by the clutch n, through the hand lever or geering rod o (figs. 975. and 976.), when the engine is to be set at work. 6 is a spur wheel upon the shaft m, by which the stud wheel 7, is driven, in order to give the traverse motion to the guide bar H. This wheel is represented, with its appendages, in double size, figs. 979. and 980., with its boss upon a stud p, secured to the bracket q. In an eccentric hole of the same boss, another stud r, revolves, upon which the little wheel s, is fixed. This wheel s, is in geer with a pinion cut upon the end of the fixed stud p; and upon it is screwed the little crank t, whose collar is connected by two rods u (figs. 975. and 976.), to a cross-piece v, which unites the two arms w, that are fixed upon the guide bar H, on both sides of the machine. By the revolution of wheel 7, the wheel s will cause the pinion of the fixed stud p to turn round. If that wheel bear to the pinion the proportion of 4 to 1, then the wheel s will make, at each revolution of the wheel 7, one-fourth of a revolution; whereby the crank t will also rotate through one-fourth of a turn, so as to be brought nearer to the centre of the stud, and to draw the guide bar so much less to one side of its mean position. At the next revolution of wheel 7, the crank t will move through another quadrant, and come still nearer to the central position, drawing the guide bars still less aside, and therefore causing the bobbins to wind on more thread in their middle than towards their ends. The contrary effect would ensue, were the guide bars moved by a single or simple crank. After four revolutions of the wheel 7, the crank t will stand once more as shown in fig. 980., having moved the bar H through the whole extent of its traverse. The bobbins, when filled, have the appearance represented in fig. 982.; the thread having been laid on the mall the time in diagonal lines, so as never to coincide with each other.

Doubling is the next operation of the silk throwster. In this process, the threads of two or three of the bobbins, filled as above, are wound together in contact upon a single bobbin. An ingenious device is here employed to stop the winding-on the moment that one of these parallel threads happens to break. Instead of the swifts or reels, a creel is here mounted for receiving the bobbins from the former machine, two or three being placed in one line over each other, according as the threads are to be doubled or trebled. Though this machine is in many respects like the engine, it has some additional parts, whereby the bobbins are set at rest, as above mentioned, when one of the doubling threads gets broken.

Fig. 983. is an end view, from which it will be perceived that the machine is, like the preceding, a double one, with two working sides.

Fig. 984. is a front view of a considerable portion of the machine.

Fig. 985. shows part of a cross section, to explain minutely the mode of winding upon a single bobbin.

Fig. 986. is the plan of the parts shown in fig. 985.; these two figures being drawn to double the scale of figs. 983. and 984.

A, A, figs. 983. and 984. are the end frames, connected at their tops by a wooden stretcher, or bar-beam, a, which extends through the whole length of the machine; this bar is shown also in figs. 985. and 986.

B, B, are the creels upon each side of the machine, or bobbin bearers, resting upon wooden beams or boards, made fast to the arms or brackets C, about the middle of the frames A.

D, D, are two horizontal iron shafts, which pervade the whole machine, and carry a series of light movable pulleys, called stars, c, c, (figs. 985, 986.) which serve to drive the bobbins E, E, whose fixed pulleys rest upon their peripheries, and are therefore turned simply by friction. These bobbins are screwed by swivel nuts e, e, upon spindles, as in the silk engine. Besides the small friction pulley or boss, d, seen best in fig. 986., by which they rest upon the star pulleys c, c, a little ratchet wheel f, is attached to the other end of each bobbin. This is also shown by itself at f, in fig. 987.

The spindles with their bobbins revolve in two slot-bearings F, F, fig. 986., screwed to the bar-beam a, which is supported by two or three intermediate upright frames, such as A'. The slot-bearings F, have also a second slot, in which the spindle with the bobbin is laid at rest, out of contact of the star wheel, while its broken thread is being mended. G is the guide bar (to which the cleaner slit pieces g, g, are attached), for making the thread traverse to the right and the left, for its proper distribution over the surface of the bobbin. The guide bar of the doubling machine is moved with a slower traverse than in the engine; otherwise, in consequence of the different obliquities of the paths, the single threads would be readily broken, h, h, is a pair of smooth rods of iron or brass, placed parallel to each of the two sides of the machine, and made fast to the standards H, H, which are screwed to brackets projecting from the frames A, A'. Over these rods the silk threads glide, in their passage to the guide wires g, g, and the bobbins E, E.

I, I, is the lever board upon each side of the machine, upon which the slight brass bearings or fulcrums i, i, one for each bobbin in the creel, are made fast. This board bears the balance-lever k, l, with the fullers n, n, n, which act as dexterous fingers, and stop the bobbin from winding-on the instant a thread may chance to break. The levers k, l, swing upon a fine wire axis, which passes through their props i, i, their arms being shaped rectangularly, as shown at k, k', fig. 986. The arm l, being heavier than the arm k, naturally rests upon the ridge bar m, of the lever board I. n, n, n, are three wires, resting at one of their ends upon the axis of the fulcrum i, i, and having each of their other hooked ends suspended by one of the silk threads, as it passes over the front steel rod h, and under h'. These faller wires, or stop fingers, are guided truly in their up-and-down motions with the thread, by a cleaner-plate o, having a vertical slit in its middle. Hence, whenever any thread happens to break, in its way to a winding-on bobbin E, the wire n, which hung by its eyelet end to that thread, as it passed through between the steel rods in the line of h, h', falls upon the lighter arm of the balance lever k, l, weighs down that arm k, consequently jerks up the arm l, which pitches its tip or end into one of the three notches of the ratchet or catch wheel f (figs. 986. and 987.), fixed to the end of the bobbin. Thus its motion is instantaneously arrested, till the girl has had leisure to mend the thread, when she again hangs up the faller wire n, and restores the lever k, l, to its horizontal position. If, meanwhile, she took occasion to remove the winding bobbin out of the sunk slot-bearing, where pulley d touches the star wheel c, into the right-hand upper slot of repose, she must now shift it into its slot of rotation.

The motions are given to the doubling machine in a very simple way. Upon the end of the framing, represented in fig. 983., the shafts D, D, bear two spur wheels 1 and 2, which work into each other. To the wheel 1, is attached the bevel wheel 3, driven by another bevel wheel 4 (fig. 984.), fixed to a shaft that extends the whole length of the apartment, and serves, therefore, to drive a whole range of machines. The wheel 4 may be put in geer with the shaft, by a clutch and geer-handle, as in the silk engine, and thereby it drives two shafts, by the one transmitting its movement to the other.

The traverse motion of the guide bar G, is effected as follows:—Upon one of the shafts D, there is a bevel wheel 5, driving the bevel wheel 6, upon the top of the upright shaft p (fig. 984., to the right of the middle); whence the motion is transmitted to the horizontal shaft q, below, by means of the bevel wheels 7 and 8. Upon this shaft q, there is a heart-wheel r, working against a roller which is fixed to the end of the lever s, whose fulcrum is at t, fig. 983. The other end of the lever s, is connected by two rods (shown by dotted lines in fig. 984.) to a brass piece which joins the arms u (fig. 984.), of the guide bars G. To the same cross piece a cord is attached, which goes over a roller v, and suspends a weight w, by means of which the lever s, is pressed into contact with the heart-wheel r. The fulcrum t, of the lever s, is a shaft which is turned somewhat eccentric, and has a very slow rotatory motion. Thus the guide bar, after each traverse, necessarily winds the silk in variable lines, to the side of the preceding threads.

The motion is given to this shaft in the following way. Upon the horizontal shaft q, there is a bevel wheel g (figs. 983. and 984.), which drives the wheel 10 upon the shaft x; on whose upper end, the worm y works in the wheel 11, made fast to the said eccentric shaft t; round which the lever s, swings or oscillates, causing the guide bars to traverse.

The spinning silk-mill.—The machine which twists the silk threads, either in their single or doubled state, is called the spinning mill. When the raw singles are first twisted in one direction, next doubled, and then twisted together in the opposite direction, an exceedingly wiry, compact thread, is produced, called organzine. In the spinning mill, either the singles or the doubled silk, while being unwound from one set of bobbins, and wound upon another set, is subjected to a regular twisting operation; in which process the thread is conducted as usual through guides, and coiled diagonally upon the bobbins by a proper mechanism.

Fig. 988. exhibits an end view of the spinning mill; in which four working lines are shown; two tiers upon each side, one above the other. Some spinning mills have three working tiers upon each side; but as the highest tier must be reached by a ladder or platform, this construction is considered by many to be injudicious.

Fig. 989. is a front view, where, as in the former figure, the two working lines are shown.

Fig. 990. is a cross section of a part of the machine, to illustrate the construction and play of the working parts; figs. 996, 997. are other views of fig. 990.

Fig. 991. shows a single part of the machine, by which the bobbins are made to revolve.

Figs. 992. and 993. show a different mode of giving the traverse to the guide bars, than that represented in fig. 990.

Figs. 994. and 995. show the shape of the full bobbins, produced by the action of these two different traverse motions.

The upper part of the machine being exactly the same as the under part, it will be sufficient to explain the construction and operation of one of them.

A, A, are the end upright frames or standards, between which are two or three intermediate standards, according to the length of the machine. They are all connected at their sides by beams B and C, which extend the whole length of the machines. D, D, are the spindles, whose top bearings a, a, are made fast to the beams B, and their bottoms turn in hard brass steps, fixed to the bar C. These two bars together are called, by the workmen, the spindle box. The standards A, A, are bound with cross bars N, N.

c, c, are the wharves or whorls, turned by a band from the horizontal tin cylinder in the lines of E, E, fig. 988., lying in the middle line between the two parallel rows of spindles D, D. F, F, are the bobbins containing the untwisted doubled silk, which are simply pressed down upon the taper end of the spindles. d, d, are little flyers, or forked wings of wire, attached to washers of wood, which revolve loose upon the tops of the said bobbins F, and round the spindles. One of the wings is sometimes bent upwards, to serve as a guide to the silk, as shown by dotted lines in fig. 990. e, e, are pieces of wood pressed upon the tops of the spindles, to prevent the flyers from starting off by the centrifugal force. G, are horizontal shafts bearing a number of little spur wheels f, f. H, are slot-bearings, similar to those of the doubling-machine, which are fixed to the end and middle frames. In these slots, the light square cast-iron shafts or spindles g, fig. 989., are laid, on whose end the spur wheel h is cast; and when the shaft g lies in the front slot of its bearing, it is in geer with the wheel f, upon the shaft G; but when it is laid in the back slot, it is out of geer, and at rest. See F, F, fig. 986.

Upon these little cast-iron shafts or spindles g, fig. 991., the bobbins or blocks I, are thrust, for receiving, by winding-on, the twisted or spun silk. These blocks are made of a large diameter, in order that the silk fibres may not be too much bent; and they are but slightly filled, at each successive charge, lest, by increasing their diameter too much, they should produce too rapid an increase in the rate of winding, with proportional diminution in the twist, and risk of stretching or tearing the silk. They are therefore the more frequently changed. K, K, are the guide bars, with the guides i, i, through which the silk passes, being drawn by the revolving bobbins I, and delivered or laid on by the flyers d, d, from the rotatory twisting-bobbins F. The operation of the machine is therefore simple, and the motions are given to the parts in a manner equally so.

Upon the shaft of the tin cylinder or drum, exterior to the frame, the usual fast and loose pulleys, or riggers, L, L', are mounted, for driving the whole machine. These riggers are often called steam-pulleys by the workmen, from their being connected by bands with the steam-driven shaft of the factory. In order to allow the riggers upon the shafts of the upper and the under drums to be driven from the same pulley upon the main shaft, the axis of the under drum is prolonged at L, L, and supported at its end, directly from the floor, by an upright bearing. Upon the shafts of the tin cylinders there is also a fly-wheel M, to equalize the motion. Upon the other ends of these shafts, namely at the end of the spinning-mill, represented in fig. 988., the pinions 1 are fixed, which drive the wheels 3, by means of the intermediate or carrier wheel 2; called also the plate wheel, from its being hollowed somewhat like a trencher. 1, is called the change-pinion, because it is changed for another, of a different size and different number of teeth, when a change in the velocity of wheels 2 and 3 is to be made. To allow a greater or smaller pinion to be applied at 1, the wheel 2 is mounted upon a stud k, which is movable in a slot concentric with the axis of the wheel 3. This slot is a branch from the cross bar N. The smaller the change-pinion is, the nearer will the stud k approach to the vertical line joining the centres of wheels 1 and 3; and the more slowly will the plate wheel 2 be driven. To the spur wheel 3, a bevel wheel 4, is fixed, with which the other also revolves loose upon a stud. The bevel wheel 5, upon the shaft l, is driven by the bevel wheel 4; and it communicates motion, by the bevel wheels 6 and 7, to each of the horizontal shafts G, G, extending along the upper and under tiers of the machine. At the left-hand side of the top part of fig. 988. the two wheels 6 and 7 are omitted, on purpose to show the bearings of the shaft G, as also the slot-bearings for carrying the shafts or skewers of the bobbins.

If it be desired to communicate twist in the opposite direction to that which would be given by the actual arrangement of the wheels, it is necessary merely to transpose the carrier wheel 2, from its present position on the right hand of pinion 1, to the left of it, and to drive the tin cylinder by a crossed or close strap, instead of a straight or open one.

The traverse motion of the guide is given here in a similar way to that of the engine, (fig. 975.) Near one of the middle or cross-frames of the machine (see fig. 990.) the wheel f, in geer with a spur wheel h, upon one of the block-shafts, drives also a spur wheel m, that revolves upon a stud, to which wheel is fixed a bevel wheel n, in geer with the bevel wheel o. To wheel o, the same mechanism is attached as was described under figs. 979. and 980., and which is here marked with the same letters.

To the crank-knob r, fig. 990., a rod x, is attached, which moves or traverses the guide bar belonging to that part of the machine; to each machine one such apparatus is fitted. In figs. 992. and 993. another mode of traversing the guide bar is shown, which is generally used for the coarser qualities of silk. Near to one of the middle frames, one of the wheels f, in geer with the spur wheel m, and the bevel wheel n, both revolving on one stud, gives motion also to the wheel o, fixed upon a shaft a', at whose other end the elliptical wheel b' is fixed, which drives a second elliptical wheel c', in such a way that the larger diameter of the one plays in geer with the smaller diameter of the other; the teeth being so cut as to take into each other in all positions. The crank-piece d' is screwed upon the face of the wheel c', at such a distance from its centre as may be necessary to give the desired length of traverse motion to the guide bar for laying the silk spirally upon the blocks. The purpose of the elliptical wheel is to modify the simple crank motion, which would wind on more silk at the ends of the bobbins than in their middle, and to effect an equality of winding-on over the whole surface of the blocks. In fig. 993. the elliptical wheels are shown in front, to illustrate their mode of operating upon each other. Fig. 994. is a block filled by the motion of the eccentric, fig. 900.; and fig. 995. is a block filled by the elliptical mechanism. As the length of the motions of the bar in the latter construction remains the same during the whole operation, the silk, as it is wound on the blocks, will slide over the edges, and thereby produce the flat ends of the barrel in fig. 995. The conical ends of the block (fig. 994.) are produced by the continually shortened motions of the guide bar, as the stud approaches, in its sun-and-planet rotation, nearer to the general centre.

Figs. 996, 997. are two different views of the differential mechanism described under fig. 990.

The bent wire x, fig. 990., is called the guider iron. It is attached at one end to the pivot of the sun-and-planet wheel-work t, s, o, and at the other to the guide bar f, f, fig. 989. The silk threads pass through the guides, as already explained. By the motion communicated to the guide bar (guider), the diamond pattern is produced, as shown in fig. 994.

THE SILK AUTOMATIC REEL.

In this machine, the silk is unwound from the blocks of the throwing-mill, and formed into hanks for the market. The blocks being of a large size, would be productive of much friction, if made to revolve upon skewers thrust through them, and would cause frequent breakage of the silk. They are, therefore, set with their axes upright upon a board, and the silk is drawn from their surface, just as the weft is from a cop in the shuttle. On this account the previous winding-on must be executed in a very regular manner; and preferably as represented in fig. 994.

Fig. 998. is a front view of the reel; little more than one-half of it being shown. Fig. 999. is an end view. Here the steam-pulleys are omitted, for fear of obstructing the view of the more essential parts. A, A, are the two end framings, connected by mahogany stretchers, which form the table B, for receiving the bobbins C, C, which are sometimes weighted at top with a lump of lead, to prevent their tumbling. D is the reel, consisting of four long laths of wood, which are fixed upon iron frames, attached to an octagonal wooden shaft. The arm which sustains one of these laths is capable of being bent inwards, by loosening a tightening hook, so as to permit the hanks, when finished, to be taken off, as in every common reel.

The machine consists of two equal parts, coupled together at a, to facilitate the removal of the silk from either half of the reel; the attendant first lifting the one part, and then the other. E is the guide bar, which by a traverse motion causes the silk to be wound on in a cross direction. b and c are the wire guides, and d are little levers lying upon the cloth-covered guide bar E. The silk in its way from the block to the reel, passes under these levers, by which it is cleaned from loose fibres.

On the other end of the shaft of the reel, the spur wheel 1 is fixed, which derives motion from wheel 2, attached to the shaft of the steam-pulley F. Upon the same shaft there is a bevel wheel 3, which impels the wheel 4 upon the shaft e; to whose end a plate is attached, to which the crank f is screwed, in such a way as to give the proper length of traverse motion to the guide bar E, connected to that crank or eccentric stud by the jointed rod g. Upon the shaft of the steam-pulleys F, there is a worm or endless screw, to the left of f, fig. 999., which works in a wheel 5; attached to the short upright shaft h (fig. 998.). At the end of h, there is another worm, which works in a wheel 6; at whose circumference there is a stud i, which strikes once at every revolution against an arm attached to a bell, seen to the left of G; thus announcing to the reel-tenter that a measured length of silk has been wound upon her reel. e is a rod or handle, by which the fork l, with the strap, may be moved upon the fast or loose pulley, so as to set on or arrest the motion at pleasure.

Throwsters submit their silk to scouring and steaming processes. They soak the hanks, as imported, in lukewarm soap-water in a tub; but the bobbins of the twisted single silk from the spinning mill are enclosed within a wooden chest, and exposed to the opening action of steam for about ten minutes. They are then immersed in a cistern of warm water, from which they are transferred to the doubling frame.

The wages of the workpeople in the silk-throwing mills of Italy are about one half of their wages in Manchester; but this difference is much more than counterbalanced by the protecting duty of 2s. 10d. a pound upon thrown silk, and the superior machinery of our mills. In 1832, there was a power equal to 342 horses engaged in the silk-throwing mills of Manchester; and of about 100 in the mills of Derby. The power employed in the other silk mills of England and Scotland has not been recorded.

There is a peculiar kind of silk called marabout, containing generally three threads, made from the white Novi raw silk. From its whiteness, it takes the most lively and delicate colours without the discharge of its gum. After being made into tram by the single twist upon the spinning mill, it is reeled into hanks, and sent to the dyer without further preparation. After being dyed, the throwster re-winds and re-twists it upon the spinning mill, in order to give it the whipcord hardness which constitutes the peculiar feature of marabout. The cost of the raw Novi silk is 19s. 6d. a pound; of throwing it into tram, 2s. 6d.; of dyeing, 2s.; of re-winding and re-twisting, after it has been dyed, about 5s.; of waste, 2s., or 10 per cent.; the total of which sum is 31s.; being the price of one pound of marabout in 1832.

An Estimate of the Annual Quantities of Silk produced or exported from the several Countries in the World, exhibiting also the Countries to which exported.

Note.—These estimates exclude the silk manufactured in Italy.

The declared value of the silk manufactures exported from the United Kingdom in 1836, was 917,822l.; and in 1837, only 494,569. The deficit in the last year was owing to the commercial crisis in the United States; which country took, the preceding year, our silk goods to the value of 524,301l.

SILVERING, is the art of covering the surfaces of bodies with a thin film of silver. When silver leaf is to be applied, the methods prescribed for gold leaf are suitable. Among the metals, copper or brass are those on which the silverer most commonly operates. Iron is seldom silvered; but the processes for both metals are essentially the same.

The principal steps of this operation are the following:—

1. The smoothing down the sharp edges, and polishing the surface of the copper; called Émorfiler by the French artists.

2. The annealing; or, making the piece to be silvered redhot, and then plunging it in very dilute nitric acid, till it be bright and clean.

3. Pumicing; or, clearing up the surface with pumice-stone and water.

4. The warming, to such a degree merely as, when it touches water, it may make a slight hissing sound; in which state it is dipped in the very weak aquafortis, whereby it acquires minute insensible asperities, sufficient to retain the silver leaves that are to be applied.

5. The hatching. When these small asperities are inadequate for giving due solidity to the silvering, the plane surfaces must be hatched all over with a graving tool; but the chased surfaces need not be touched.

6. The bluing, consists in heating the piece till its copper or brass colour changes to blue. In heating, they are placed in hot tools made of iron, called mandrins in France.

7. The charging, the workman’s term for silvering. This operation consists in placing the silver leaves on the heated piece, and fixing them to its surface by burnishers of steel, of various forms. The workman begins by applying the leaves double. Should any part darken in the heating, it must be cleared up by the scratch-brush.

The silverer always works two pieces at once; so that he may heat the one, while burnishing the other. After applying two silver leaves, he must heat up the piece to the same degree as at first, and he then fixes on with the burnisher four additional leaves of silver; and he goes on charging in the same way, 4 or 6 leaves at a time, till he has applied, one over another, 30, 40, 50, or 60 leaves, according to the desired solidity of the silvering. He then burnishes down with great pressure and address, till he has given the surface a uniform silvery aspect.

Silvering by the precipitated chloride of silver.—The white curd obtained by adding a solution of common salt to one of nitrate of silver, is to be well washed and dried. One part of this powder is to be mixed with 3 parts of good pearlash, one of washed whiting, and one and a half of sea salt. After clearing the surface of the brass, it is to be rubbed with a bit of soft leather, or cork moistened with water, and dipped in the above powder. After the silvering, it should be thoroughly washed with water, dried, and immediately varnished. Some use a mixture of 1 part of the silver precipitate, with 10 of cream of tartar, and this mixture also answers very well.

Others give a coating of silver by applying with friction, in the moistened state, a mixture of 1 part of silver-powder precipitated by copper, 2 parts of cream of tartar, and as much common salt. The piece must be immediately washed in tepid water very faintly alkalized, then in slightly warm pure water, and finally wiped dry before the fire. See Plated Manufacture.

The inferior kinds of plated buttons get their silver coating in the following way:—

2 ounces of chloride of silver are mixed up with 1 ounce of corrosive sublimate, 3 pounds of common salt, and 3 pounds of sulphate of zinc, with water, into a paste. The buttons being cleaned, are smeared over with that mixture, and exposed to a moderate degree of heat, which is eventually raised nearly to redness, so as to expel the mercury from the amalgam, formed by the reaction of the horn silver and the corrosive sublimate. The copper button thus acquires a silvery surface, which is brightened by clearing and burnishing.

Leather is silvered by applying a coat of parchment size, or spirit varnish, to the surface, and then the silver leaf, with pressure.

SIMILOR, is a golden-coloured variety of brass.

SINGEING OF WEBS. The old furnace for singeing cotton goods is represented in longitudinal section, fig. 1030., and in a transverse one in fig. 1031. a is the fire-door; b, the grate; c, the ash-pit; d, a flue, 6 inches broad, and 2¹/₂ high, over which a hollow semi-cylindrical mass of cast iron e, is laid, one inch thick at the sides, and 2¹/₂ thick at the top curvature. The flame passes along the fire-flue d, into a side opening f, in the chimney. The goods are swept swiftly over this ignited piece of iron, with considerable friction, by means of a wooden roller, and a swing frame for raising them at any moment out of contact.

In some shops, semi-cylinders of copper, three quarters of an inch thick, have been substituted for those of iron, in singeing goods prior to bleaching them. The former last three months, and do 1500 pieces with one ton of coal; while the latter, which are an inch and a half thick, wear out in a week, and do no more than from 500 to 600 pieces with the same weight of fuel.

In the early part of the year 1818, Mr. Samuel Hall enrolled the specification of a patent for removing the downy fibres of the cotton thread from the interstices of bobbin-net lace, or muslins, which he effected by singeing the lace with the flame of a gas-burner. The second patent granted to Mr. Hall, in April, 1823, is for an improvement in the above process; viz., causing a strong current of air to draw the flame of the gas through the interstices of the lace, as it passes over the burner, by means of an aperture in a tube placed immediately above the row of gas-jets, which tube communicates with an air-pump or exhauster.

Fig. 1032. shows the construction of the apparatus complete, and manner in which it operates; a, a, is a gas-pipe, supplied by an ordinary gasometer; from this pipe, several small ones extend upwards to the long burner b, b. This burner is a horizontal tube, perforated with many small holes on the upper side, through which, as jets, the gas passes; and when it is ignited, the bobbin-net lace, or other material intended to be singed, is extended and drawn rapidly over the flame, by means of rollers, which are not shown in the figure.

The simple burning of the gas, even with a draught chimney, as in the former specification, is found not to be at all times efficacious; the patentee, therefore, now introduces a hollow tube c, c, with a slit or opening, immediately over the row of burners; and this tube, by means of the pipes d, d, d, communicates with the pipe e, e, e, which leads to the exhausting apparatus.

This exhausting apparatus consists of two tanks, f and g, nearly filled with water, and two inverted boxes or vessels, h and i, which are suspended by rods to the vibrating beam k; each of the boxes is furnished with a valve opening upwards; l, l, are pipes extending from the horizontal part of the pipe e, up into the boxes or vessels h and i, which pipes have valves at their tops, also opening upward. When the vessel h descends, the water in the tank forces out the air contained within the vessel at the valve m; but when that vessel rises again, the valve m being closed, the air is drawn from the pipe e, through the pipe l. The same takes place in the vessel i, from which the air in its descent is expelled through the valve n, and, in its ascent, draws the air through the pipe l, from the pipe e. By these means, a partial exhaustion is effected in the pipe e, e, and the tube c, c; to supply which, the air rushes with considerable force through the long opening of the tube c, c, and carries with it the flame of the gas-burners. The bobbin-net lace, or other goods, being now drawn over the flame between the burner b, b, and the exhausted tube c, c, by means of rollers, as above said, the flame of the gas is forced through the interstices of the fabric, and all the fine filaments and loose fibres of the thread are burnt off, without damaging the substance of the goods.

To adjust the draught from the gas-burners, there are stopcocks introduced into several of the pipes d; and to regulate the action of the exhausting apparatus, an air vessel o, is suspended by a cord or chain passing over pulleys, and balanced by a weight p. There is also a scraper introduced into the tube c, which is made, by any convenient contrivance, to revolve and slide backwards and forwards, for the purpose of removing any light matter that may arise from the goods singed, and which would otherwise obstruct the air passage. Two of these draught tubes c, may be adapted and united to the exhausting apparatus, when a double row of burners is employed, and the inclination of the flame may be directed upwards, downwards, or sideways, according to the position of the slit in the draft tube, by which means any description of goods may, if required, be singed on both sides at one operation.

The greater part of the bobbin-net lace made in England, is sent to Mr. Hall’s works, at Basford, near Nottingham, to be singed; and at a reduction of price truly wonderful. He receives now only one farthing for what he originally was paid one shilling.

SKIN (Peau, Fr.; Haut, Germ.); the external membrane of animal bodies, consists of three layers: 1. the epidermis, scarf-skin, (Oberhaut, Germ.); 2. the vascular organ, or papillary body, which performs the secretions; and 3. the true skin, (Lederhaut, Germ.), of which leather is made. The skin proper, or dermoid substance, is a tissue of innumerable very delicate fibres, crossing each other in every possible direction, with small orifices between them, which are larger on its internal than on its external surface. The conical channels thus produced, are not straight, but oblique, and filled with cellular membrane; they receive vessels and nerves which pass out through the skin (cutis vera), and are distributed upon the secretory organ. The fibrous texture of the skin is composed of the same animal matter as the serous membranes, the cartilages, and the cellular tissue; the whole possessing the property of dissolving in boiling water, and being, thereby, converted into glue. See Glue, Leather, and Tan.

SLAG (Laitier, Fr.; Schlacke, Germ.); is the vitreous mass which covers the fused metals in the smelting-hearths. In the iron-works it is commonly called cinder. Slags consist, in general, of bi-silicates of lime and magnesia, along with the oxides of iron and other metals; being analogous in composition, and having the same crystalline form as the mineral, pyroxene. See Copper and Iron.

SLATES (Ardoises, Fr.: Schiefern, Germ.) The substances belonging to this class may be distributed into the following species:—

• 1. Mica-slate, occasionally used for covering houses.
• 2. Clay-slate, the proper roofing-slate.
• 3. Whet-slate.
• 4. Polishing-slate.
• 5. Drawing-slate, or black chalk.
• 6. Adhesive slate.
• 7. Bituminous shale.
• 8. Slate-clay.

1. Mica-slate.—This is a mountain rock of vast continuity and extent, of a schistose texture, composed of the minerals mica and quartz, the mica being generally predominant.

2. Clay-slate.—This substance is closely connected with mica; so that uninterrupted transitions may be found between these two rocks in many mountain chains. It is a simple schistose mass, of a bluish-gray or grayish-black colour, of various shades, and a shining, somewhat pearly internal lustre on the faces, but of a dead colour in the cross fracture.

Clay-slate is extensively distributed in Great Britain. It skirts the Highlands of Scotland, from Lochlomond by Callender, Comrie, and Dunkeld; resting on, and gradually passing into mica-slate throughout the whole of that territory. Roofing-slate occurs, on the western side of England, in the counties of Cornwall and Devon; in various parts of North Wales and Anglesea; in the north-east parts of Yorkshire, near Ingleton, and in Swaledale; as also in the counties of Cumberland and Westmorland. It is likewise met with in the county of Wicklow and other mountainous districts of Ireland.

All the best beds of roofing-slate improve in quality as they lie deeper under the surface; near to which, indeed, they have little value.

A good roofing-slate should split readily into thin even laminÆ; it should not be absorbent of water either on its face or endwise, a property evinced by its not increasing perceptibly in weight after immersion in water; and it should be sound, compact, and not apt to disintegrate in the air. The slate raised at Eisdale, on the west coast of Argyllshire, is very durable.

Cleaving and dressing of the slates.—The splitter begins by dividing the block, cut lengthwise, to a proper size, which he rests on end, and steadies between his knees. He uses a mallet and a chisel, which he introduces into the stone in a direction parallel to the folia. By this means he reduces it into several manageable pieces, and he gives to each the requisite length, by cutting cross grooves on the flat face, and then striking the slab with the chisel. It is afterwards split into thinner sections, by finer chisels dexterously applied to the edges. The slate is then dressed to the proper shape, by being laid on a block of wood, and having its projecting parts at the ends and sides cut off with a species of hatchet or chopping-knife. It deserves to be noticed, that blocks of slate may lose their property of divisibility into thin laminÆ. This happens from long exposure to the air, after they have been quarried. The workmen say, then, that they have lost their waters. For this reason, the number of splitters ought to be always proportioned to the number of block-hewers. Frost renders the blocks more fissile; but a supervening thaw renders them quite refractory. A new frost restores the faculty of splitting, though not to the same degree; and the workmen therefore avail themselves of it without delay. A succession of frosts and thaws renders the quarried blocks quite intractable.

3. Whet-slate, or Turkey hone, is a slaty rock, containing a great proportion of quartz, in which the component particles, the same as in clay-slate and mica-slate, but in different proportions, are so very small as to be indiscernible.

4. Polishing slate. Colour, cream-yellow, in alternate stripes; massive; composition impalpable; principal fracture, slaty, thin, and straight; cross fracture, fine earthy; feels fine, but meagre; adheres little, if at all, to the tongue; is very soft, passing into friable; specific gravity in the dry state, 0·6; when imbued with moisture, 1·9. It is supposed to have been formed from the ashes of burnt coal. It is found at Planitz, near Zwickau, and at Kutschlin near Bilin in Bohemia.

5. Drawing-slate, or black chalk; has a grayish-black colour; is very soft, sectile, easily broken, and adheres slightly to the tongue; spec. grav. 2·11. The streak is glistening. It occurs in beds in primitive and transition clay-slate; also in secondary formations, as in the coal-measures of most countries. It is used in crayon drawing. Its trace upon paper is regular and black. The best kinds are found in Spain, Italy, and France. Some good black chalk occurs also in Caernarvonshire and in the island of Islay.

6. Adhesive slate, has a light greenish-gray colour, is easily broken or exfoliated, has a shining streak, adheres strongly to the tongue, and absorbs water rapidly, with the emission of air-bubbles and a crackling sound.

7. Bituminous shale, is a species of soft, sectile slate-clay, much impregnated with bitumen, which occurs in the coal-measures.

8. Slate-clay, has a gray or grayish-yellow colour; is massive, with a dull glimmering lustre from spangles of mica interspersed. Its slaty fracture approaches at times to earthy; fragments, tabular; soft, sectile, and very frangible; specific gravity, 2·6. It adheres to the tongue, and crumbles down when immersed for some time in water. It is found as an alternating bed in the coal-measures. (See the sections of the strata under Pitcoal.) When breathed upon, it emits a strong argillaceous odour. When free from lime and iron, it forms an excellent material for making refractory fire-bricks, being an infusible compound of alumina and silica; one of the best examples of which is the schist known by the name of Stourbridge clay.

SMALL WARES, is the name given in this country to textile articles of the tape kind, narrow bindings of cotton, linen, silk, or woollen fabric; plaited sash cord, braid, &c. Tapes are woven upon a loom like that for weaving ribbons, which is now generally driven by mechanical power. Messrs. Worthington and Mulliner obtained a patent, in June, 1825, for improvements in such a loom, which have answered the purposes of their large factory in Manchester very well; and in May, 1831, Mr. Whitehead, of the same town, patented certain improvements in the manufacture of small wares. The objects of the latter patent are, the regular taking up of the tape or cloth, as it is woven, a greater facility of varying the vibration of the lay, together with the saving of room required for a range of looms to stand in.[55] See Braiding Machine.

SMALT, see Azure and Cobalt.

Imported for home consumption in 1834, 162,232 lbs.; in 1835, 96,649; in 1836, 79,531; duty, 4d. per lb.

SMELTING, is the operation by which the ores of iron, copper, lead, &c., are reduced to the metallic state. See Metallurgy, Ores, and the respective metals.

SOAP (Savon, Fr.; Seife, Germ.); is a chemical compound, of saponified fats or oils with potash or soda, prepared for the purposes of washing linen, &c. Fatty matters, when subjected to the action of alkaline lyes, undergo a remarkable change, being converted into three different acids, called stearic, margaric, and oleic; and it is these acids, in fact, which combine with the bases, in definite proportions, to form compounds analogous to the neutro-saline. Some chemical writers describe under the title soap, every compound which may result from the union of fats with the various earths and metallic oxides—a latitude of nomenclature which common language cannot recognise, and which would perplex the manufacturer.

Soaps are distinguished into two great classes, according to their consistence; the hard and the soft; the former being produced by the action of soda upon fats, the latter by that of potash. The nature of the fats contributes also somewhat to the consistence of soaps; thus tallow, which contains much stearine and margarine, forms with potash a more consistent soap than liquid oils will do, which consist chiefly of oleine. The drying oils, such as those of linseed and poppy, produce the softest soaps.

1. Of the manufacture of hard soap.—The fat of this soap, in the northern countries of Europe, is usually tallow, and in the southern, coarse olive oil. Different species of grease are saponified by soda, with different degrees of facility; among oils, the olive, sweet almond, rapeseed, and castor oil; and among solid fats, tallow, bone grease, and butter, are most easily saponified. According to the practice of the United Kingdom, six or seven days are required to complete the formation of a pan of hard soap, and a day or two more for settling the impurities, if it contains rosin. From 12 to 13 cwt. of tallow are estimated to produce one ton of good soap. Some years ago, in many manufactories the tallow used to be saponified with potash lyes, and the resulting soft soap was converted, in the course of the process, into hard soap, by the introduction of muriate of soda, or weak kelp lyes, in sufficient quantity to furnish the proper quantity of soda by the reaction of the potash upon the neutral salts. But the high price of potash, and the diminished price as well improved quality of the crude sodas, have led to their general adoption in soap-works. The soda-ash used by the soap-boiler, contains in general about 36 per cent. of real soda, in the state of dry carbonate, mixed with muriate of soda, and more or less undecomposed sulphate. I have met lately with soda-ash, made from sulphate of soda, in which the materials had been so ill worked, and so imperfectly decomposed, as to contain 16 per cent. of sulphate, a circumstance equally disgraceful, as it was ruinous to the soda manufacturer. The barillas from Spain and Teneriffe contain from 18 to 24 per cent. of real soda. The alkali in both states is employed in England; barilla being supposed by many to yield a finer white or curd soap, on account of its freedom from sulphur.

The crude soda of either kind being ground, is to be stratified with lime in cylindrical cast-iron vats, from 6 to 7 feet wide, and from 4 to 5 feet deep; the lowest layer consisting, of course, of unslaked or shell quicklime. The vats have a false bottom, perforated with holes, and a lateral tubulure under it, closed commonly with a wooden plug, similar to the Épine of the French soap pans, by which the lyes trickle off clear and caustic, after infiltration through the beds of lime. The quantity of lime must be proportional to the carbonic acid in the soda.

Upon 1 ton of tallow put into the soap pan, about 200 gallons of soda lye, of specific gravity 1·040, being poured, heat is applied, and after a very gentle ebullition of about 4 hours, the fat will be found to be completely saponified, by the test of the spatula, trowel, or pallet knife; for the fluid lye will be seen to separate at once upon the steel blade, from the soapy paste. Such lyes, if composed of pure caustic soda, would contain 4 per cent. of alkali; but from the presence of neutro-saline matter, they seldom contain so much as 2 per cent.; in fact, a gallon may be estimated to contain not more than 2 ounces; so that 200 gallons contain 25 pounds of real soda. The fire being withdrawn from the soap pan, the mass is allowed to cool during one hour, or a little more, after which the spent lyes, which are not at all alkaline, are run off by a spigot below, or pumped off above, by a pump set into the pan. A second similar charge of lye is now introduced into the pan, and a similar boiling process is renewed. Three such boils may be given in the course of one day’s work, by an active soap-maker. Next day the same routine is resumed with somewhat stronger lyes, and so progressively, till, towards the sixth day, the lye may have the density of 1·160, and will be found to contain 6 per cent. of real soda.[56] Were the lye a solution of pure caustic soda, it would contain at this density no less than 14³/₄ per cent. of alkali. The neutro-saline matter present in the spent lye is essential to the proper granulation and separation of the saponaceous compound; for otherwise the watery menstruum would dilute and even liquefy the soap. Supposing 12¹/₂ cwt. of tallow to yield upon an average 20 cwt. of hard soap, then 20 cwt. of tallow will produce 32 cwt.; and as its average contents in soda are 6 per cent., these 32 cwt. should require 1·52 cwt. of real soda for their production. If barilla at 20 per cent. be the alkali employed, then 7·6 cwt. of barilla must be consumed in the said process. If the alkali be soda-ash of 40 per cent., half the weight will of course suffice. I have reason to believe that there is great waste of alkali incurred in many soap-works, as 6 cwt. of soda-ash, of at least 30 per cent., is often expended in making 1 ton of soap, being 50 per cent. more than really enters into the composition of the soap.

The barillas always contain a small proportion of potash, to which their peculiar value, in making a less brittle or more plastic hard soap than the factitious sodas, may with great probability be ascribed. Chemistry affords many analogies, especially in mineral waters, where salts, apparently incompatible, co-exist in dilute solutions. We may thus conceive how a small quantity of stearate or oleate of potash may resist the decomposing action of the soda salts. The same modification of the consistence of hard soap may, however, be always more conveniently produced by a proper admixture of oleine with stearine.

Soda which contains sulphurets is preferred for making the mottled or marbled soap, whereas the desulphuretted soda makes the best white curd soap. Mottling is usually given in the London soap-works, by introducing into the nearly finished soap in the pan a certain quantity of the strong lye of crude soda, through the rose spout of a watering-can. The dense sulphuretted liquor, in descending through the pasty mass, causes the marbled appearance. In France a small quantity of solution of sulphate of iron is added during the boiling of the soap, or rather with the first service of the lyes. The alkali seizes the acid of the sulphate, and sets the protoxide of iron free, to mingle with the paste, to absorb more or less oxygen, and to produce thereby a variety of tints. A portion of oxide combines also with the stearine to form a metallic soap. When the oxide passes into the red state, it gives the tint called manteau Isabelle. As soon as the mottler has broken the paste, and made it pervious in all directions, he ceases to push his rake from right to left, but only plunges it perpendicularly, till he reaches the lye; then he raises it suddenly in a vertical line, making it act like the stroke of a piston in a pump, whereby he lifts some of the lye, and spreads it over the surface of the paste. In its subsequent descent through the numerous fissures and channels, on its way to the bottom of the pan, the coloured lye impregnates the soapy particles in various forms and degrees, whence a varied marbling results.

Three pounds of olive oil afford five pounds of marbled Marseilles soap of good quality, and only four pounds four ounces of white soap; showing that more water is retained by the former than the latter. Oil of grains, as linseed and rapeseed, do not afford so solid a soda soap as oil of olives; but tallow affords a still harder soap with soda. Some of the best Windsor soap made in London contains one part of olive oil (gallipoli) for every nine parts of tallow. Much of the English hard soap is made with kitchen and bone fat, of a very coarse quality; the washing of the numerous successive lyes, however, purifies the foul fats, and deprives them of their offensive smell in a great degree. It is common now at Marseilles to mix ten per cent. of the oil of grains with olive oil; for which purpose a large proportion of the oils extracted from seeds in the mills of the Department du Nord is sent to Marseilles; but five per cent. of poppy-seed oil, mixed with tallow, renders the soap made with the mixture stringy and unfit for washing; because the two species of fat refuse to amalgamate.

The affinity between the stearine of tallow and the alkali, is so great that a soap may be speedily made from them in the cold. If we melt tallow at the lowest possible temperature, and let it cool to the fixing point, then add to it half its weight of caustic lye, at 36° B., agitating meanwhile incessantly with a pallet knife, we shall perceive, at the end of some hours of contact, the mixture suddenly acquire a very solid consistence, and at the same moment assume a marked elevation of temperature, proving the phenomenon to be due to chemical attraction. In some trials of this kind, the thermometer has risen from 54° to 140° F.

According to recent experiments made in Marseilles, 100 pounds of olive oil take, for their conversion into soap, 54 pounds of crude soda, of 36 per cent. alkaline strength. One part of lime is employed for rendering three parts of the soda caustic. The richer the oil is in stearine, the more dilute should be the lye used in the saponification; and vice vers when it abounds in oleine. For oil of the former kind, the first lyes added have a density of from 8° to 9° B.; but for the latter kind, the density is from 10° to 11°. When four parts of olive oil are mixed with one part of poppy, rape, or linseed oil, as is now the general practice at Marseilles, then for such a mixture the first lyes have usually a specific gravity of from 20° to 25°, the second from 10° to 15°, and the third from 4° to 5°, constituting a great difference from the practice in Great Britain, where the weaker lyes are generally employed at the commencement. The chief reason for this practice is, however, to be found in the more complete causticity of the weak than of the strong lyes, according to the slovenly way in which most of our soap-boilers prepare them. Indeed, one very extensive manufacturer of soap in London assured me that the lyes should not be caustic; an extraordinary assertion, upon which no comment need be made. In common cases, I would recommend the first combination of the ingredients to be made with somewhat weak, but perfectly caustic lye, and when the saponification is fairly established, to introduce the stronger lye.

In a Marseilles soap-house, there are four lye-vats in each set: No. 1. is the fresh vat, into which the fresh alkali and lime are introduced; No. 2. is called the avanÇaire, being one step in advance; No. 3. is the small avanÇaire, being two steps in advance, and therefore containing weaker liquor; No. 4. is called the water vat, because it receives the water directly.

Into No. 3. the moderately exhausted or somewhat spent lyes are thrown. From No. 3. the lye is run or pumped into No. 2., to be strengthened; and in like manner from No. 3. into No. 1. Upon the lime paste in No. 4., which has been taken from No. 3., water is poured; the lye thus obtained is poured upon the paste of No. 3., which has been taken from No. 2. No. 3. is twice lixiviated; and No. 2., once. The receiver under No. 1. has four compartments; into No. 1. of which the first and strongest lye is run; into No. 2. the second lye; into No. 3. the third lye; and into No. 4. the fourth lye, which is so weak as to be used for lixiviation, instead of water; (pour d’avances).

The lime of vat No. 4., when exhausted, is emptied out of the window near to which it stands; in which case the water is poured upon the contents of No. 3.; and upon No. 2. the somewhat spent lyes.

No. 1. is now the avanÇaire of No. 4; because this has become, in its turn, the fresh vat, into which the fresh soda and quicklime are put. The lye discharged from No. 3. comes, in this case, upon No. 2.; and after being run through it, is thrown upon No. 1.

144 pounds of oil yield at Marseilles, upon an average, not more than from 240 to 244 pounds of soap; or 100 pounds yield about 168; so that in making 100 pounds of soap, at this rate nearly 60 pounds of oil are consumed.

OF YELLOW OR ROSIN SOAP.

Rosin, although very soluble in alkaline menstrua, is not however susceptible, like fats, of being transformed into an acid, and will not of course saponify, or form a proper soap by itself. The more caustic the alkali, the less consistence has the resinous compound which is made with it. Hence fat of some kind, in considerable proportion, must be used along with the rosin, the minimum being equal parts; and then the soap is far from being good. As alkaline matter cannot be neutralized by rosin, it preserves its peculiar acrimony in a soap poor in fat, and is ready to act too powerfully upon woollen and all other animal fibres to which it is applied. It is said that rancid tallow serves to mask the strong odour of rosin in soap, more than any oil or other species of fat. From what we have just said, it is obviously needless to make the rosin used for yellow soaps pass through all the stages of the saponifying process; nor would this indeed be proper, as a portion of the rosin would be carried away, and wasted with the spent lyes. The best mode of proceeding, therefore, is first of all to make the hard soap in the usual manner, and at the last service or charge of lye, namely, when this ceases to be absorbed, and preserves in the boiling-pan its entire causticity, to add the proportion of rosin intended for the soap. In order to facilitate the solution of the rosin in the soap, it should be reduced to coarse powder, and well incorporated by stirring with the rake. The proportion of rosin is usually from one-third to one-fourth the weight of the tallow. The boil must be kept up for some time with an excess of caustic lye; and when the paste is found, on cooling a sample of it, to acquire a solid consistence, and when diffused in a little water, not to leave a resinous varnish on the skin, we may consider the soap to be finished. We next proceed to draw off the superfluous lyes, and to purify the paste. For this purpose, a quantity of lyes at 80° B. being poured in, the mass is heated, worked well with a rake, then allowed to settle, and drained of its lyes. A second service of lyes, at 4° B., is now introduced, and finally one at 2°; after each of which, there is the usual agitation and period of repose. The pan being now skimmed, and the scum removed for another operation, the soap is laded off by hand-pails into its frame-moulds. A little palm oil is usually employed in the manufacture of yellow soap, in order to correct the flavour of the rosin, and brighten the colour. This soap, when well made, ought to be of a fine wax-yellow hue, be transparent upon the edges of the bars, dissolve readily in water, and afford, even with hard pump-water, an excellent lather.

The frame-moulds for hard soap are composed of strong wooden bars, made into the form of a parallelogram, which are piled over each other, and bound together by screwed iron rods, that pass down through them. A square well is thus formed, which in large soap factories is sometimes 10 feet deep, and capable of containing a couple of tons of soap.

Mr. Sheridan some time since obtained a patent for combining silicate of soda with hard soap, by triturating them together in the hot and pasty state with a crutch in an iron pan. In this way from 10 to 30 per cent. of the silicate may be introduced. Such soap possesses very powerful detergent qualities, but it is apt to feel hard and be somewhat gritty in use. The silicated soda is prepared by boiling ground flints in a strong caustic lye, till the specific gravity of the compound rises to nearly double the density of water. It then contains about 35 grains of silica, and 46 of soda-hydrate, in 100 grains[57].

Hard soap, after remaining two days in the frames, is at first divided horizontally into parallel tablets, 3 or 4 inches thick, by a brass wire; and these tablets are again cut vertically into oblong nearly square bars, called wedges in Scotland.

The soap-pans used in the United Kingdom are made of cast iron, and in three separate pieces joined together by iron-rust cement. The following is their general form:—The two upper frusta of cones are called curbs; the third, or undermost, is the pan, to which alone the heat is applied, and which, if it gets cracked in the course of boiling, may easily be lifted up within the conical pieces, by attaching chains or cords for raising it, without disturbing the masonry, in which the curbs are firmly set. The surface of the hemispherical pan at the bottom, is in general about one-tenth part of the surface of the conical sides.

The white ordinary tallow soap of the London manufacturers, called curd soap, consists, by my experiments, of—fat, 52; soda, 6; water, 42; = 100. Nine-tenths of the fat, at least, is tallow.

I have examined several other soaps, and have found their composition somewhat different.

The foreign Castile soap of the apothecary has a specific gravity of 1·0705, and consists of—

English imitation of Castile soap, spec. grav. 0·9669, consists of—

A perfumer’s white soap was found to consist of—

Glasgow white soap—

Glasgow brown rosin soap—

A London cocoa-nut oil soap was found to consist of—

This remarkable soap was sufficiently solid; but it dissolved in hot water with extreme facility. It is called marine soap, because it washes linen with sea water.

A poppy-nut-oil hard soap consisted of—

The soap known in France by the name of soap in tables consists, according to M. Thenard’s analysis, of—

M. D’Arcet states the analysis of Marseilles soap at—

SOFT SOAP.

The principal difference between soaps with base of soda, and soaps with base of potash, depends upon their mode of combination with water. The former absorb a large quantity of it, and become solid; they are chemical hydrates. The others experience a much feebler cohesive attraction; but they retain much more water in a state of mere mixture.

Three parts of fat afford, in general, fully five parts of soda soap, well dried in the open air; but three parts of fat or oil will afford from six to seven parts of potash soap of moderate consistence. This feebler cohesive force renders it apt to deliquesce, especially if there be a small excess of the alkali. It is, therefore, impossible to separate it from the lyes; and the washing or relargage, practised on the hard-soap process, is inadmissible in the soft. Perhaps, however, this concentration or abstraction of water might be effected by using dense lyes of muriate of potash. Those of muriate or sulphate of soda change the potash into a soda soap, by double decomposition. From its superior solubility, more alkaline reaction, and lower price, potash soap is preferred for many purposes, and especially for scouring woollen yarns and stuffs.

Soft soaps are usually made in this country with whale, seal, olive, and linseed oils, and a certain quantity of tallow; on the continent, with the oils of hempseed, sesame, rapeseed, linseed, poppy-seed, and colza; or with mixtures of several of these oils. When tallow is added, as in Great Britain, the object is to produce white and somewhat solid grains of stearic soap in the transparent mass, called figging, because the soap then resembles the granular texture of a fig.

The potash lyes should be made perfectly caustic, and of at least two different strengths; the weakest being of specific gravity 1·05; and the strongest, 1·20, or even 1·25. Being made from the potashes of commerce, which contain seldom more than 60 per cent., and often less, of real alkali, the lyes correspond in specific gravity to double their alkaline strength; that is to say, a solution of pure potash, of the same density, would be fully twice as strong. The following is the process followed by respectable manufacturers of soft soap (savon vert, being naturally or artificially green,) upon the continent.

A portion of the oil being poured into the pan, and heated to nearly the boiling point of water, a certain quantity of the weaker lye is introduced; the fire being kept up so as to bring the mixture to a boiling state. Then some more oil and lye are added alternately, till the whole quantity of oil destined for the pan is introduced. The ebullition is kept up in the gentlest manner possible, and some stronger lye is occasionally added, till the workman judges the saponification to be perfect. The boiling becomes progressively less tumultuous, the frothy mass subsides, the paste grows transparent, and it gradually thickens. The operation is considered to be finished when the paste ceases to affect the tongue with an acrid pungency, when all milkiness and opacity disappear, and when a little of the soap placed to cool upon a glass-plate, assumes the proper consistency.

A peculiar phenomenon may be remarked in the cooling, which affords a good criterion of the quality of the soap. When there is formed around the little patch, an opaque zone, a fraction of an inch broad, this is supposed to indicate complete saponification, and is called the strength; when it is absent, the soap is said to want its strength. When this zone soon vanishes after being distinctly seen, the soap is said to have false strength. When it occurs in the best form, the soap is perfect, and may be secured in that state by removing the fire, and then adding some good soap of a previous round, to cool it down, and prevent further change by evaporation.

200 pounds of oil require for their saponification—72 pounds of American potash of moderate quality, in lyes at 15° B.; and the product is 460 pounds of well-boiled soap.

If hempseed oil have not been employed, the soap will have a yellow colour, instead of the green, so much in request on the continent. This tint is then given by the addition of a little indigo. This dye-stuff is reduced to fine powder, and boiled for some hours in a considerable quantity of water, till the stick with which the water is stirred, presents, on withdrawing it, a gilded pellicle over its whole surface. The indigo paste diffused through the liquid, is now ready to be incorporated with the soap in the pan, before it stiffens by cooling.

M. Thenard states the composition of soft soap at—potash 9·5, + oil 44·0, + water 46·5, = 100.

Good soft soap of London manufacture, yielded to me—potash 8·5, + oil and tallow 45, + water 46·5.

Belgian soft or green soap afforded me—potash 7, + oil 36, + water 57, = 100.

Scotch soft soap, being analyzed, gave me—potash 8, + oil and tallow 47, + water 45.

Another well-made soap—potash 9, + oil and fat 34, + water 57.

A rapeseed-oil soft soap, from Scotland, consisted of—potash 10, + oil 51·66, + water 38·33.

An olive-oil (gallipoli) soft soap, from ditto, contained—potash with a good deal of carbonic acid 10, oil 48, water 42, = 100.

A semi-hard soap, from Verviers, for fulling woollen cloth, called savon Économique, consisted of, potash 11·5, + fat (solid) 62, + water 26·5, = 100.

The following is a common process, in Scotland, by which good soft soap is made:—

273 gallons of whale or cod oil, and 4 cwt. of tallow, are put into the soap-pan, with 250 gallons of lye from American potash, of such alkaline strength that 1 gallon contains 6600 grains of real potash. Heat being applied to the bottom pan, the mixture froths up very much as it approaches the boiling temperature, but is prevented from boiling over by being beat down on the surface, within the iron curb or crib which surmounts the cauldron. Should it soon subside into a doughy-looking paste, we may infer that the lye has been too strong. Its proper appearance is that of a thin glue. We should now introduce about 42 gallons of a stronger lye, equivalent to 8700 gr. of potash per gallon; and after a short interval, an additional 42 gallons; and thus successively till nearly 600 such gallons have been added in the whole. After suitable boiling to saponify the fats, the proper quality of soap will be obtained, amounting in quantity to 100 firkins of 64 pounds each, from the above quantity of materials.

It is generally supposed, and I believe it to be true, from my own numerous experiments upon the subject, that it is a more difficult and delicate operation to make a fine soft soap of glassy transparency, interspersed with the figged granulations of stearate of potash, than to make hard soap of any kind.

Soft soap is made in Belgium as follows:—For a boil of 18 or 20 tons, of 100 kilogrammes each, there is employed for the lyes—1500 pounds of American potashes, and 500 to 600 pounds of quicklime.

The lye is prepared cold in cisterns of hewn stone, of which there are usually five in a range. The first contains the materials nearly exhausted of their alkali; and the last the potash in its entire state. The lye run off from the first, is transferred into the second; that of the second into the third; and so on to the fifth.

In conducting the empatage of the soap, they put into the pan, on the eve of the boiling-day, six aimes (one ohm, = 30 gallons imperial,) of oil of colza, in summer, but a mixture of that oil with linseed oil in winter, along with two aimes of potash lye at 13° B., and leave the mixture without heat during eight hours. After applying the fire, they continue to boil gently till the materials cease to swell up with the heat; after which, lye of 16° or 17° must be introduced successively, in quantities of one quarter of an aime after another, till from 2 to 4 aimes be used. The boil is finished by pouring some lye of 20° B., so that the whole quantity may amount to 9¹/₂ aimes.

It is considered that the operation will be successful, if from the time of kindling the fire till the finish of the boil, only five hours elapse. In order to prevent the soap from boiling over, a wheel is kept revolving in the pan. The operative considers the soap to be finished, when it can no longer be drawn out into threads between the finger and thumb. He determines if it contains an excess of alkali, by taking a sample out during the boil, which he puts into a tin dish; where if it gets covered with a skin, he pours fresh oil into the pan, and continues the boil till the soap be perfect. No wonder the Belgian soap is bad, amid such groping in the dark, without one ray of science!

SOFT TOILET SOAPS.

The soft fancy toilet soaps are divisible into two classes: 1. good potash soap, coloured and scented in various ways, forms the basis of the Naples and other ordinary soft soaps of the perfumer; 2. pearl soap (savon nacrÉ), which differs from the other both in physical aspect and in mode of preparation.

Ordinary soft Toilet Soap.—Its manufacture being conducted on the principles already laid down, presents no difficulty to a man of ordinary skill and experience; the only point to be strictly attended to, is the degree of evaporation, so as to obtain soap always of uniform consistence. The fat generally preferred is good hog’s lard; of which 30 pounds are to be mixed with 45 pounds of a caustic lye marking 17° on BaumÉ’s scale; the temperature is to be gradually raised to ebullition, but the boil must not be kept up too long or too briskly, till after the empatage or saponification is completed, and the whole of the lye intimately combined with the fatty particles; after this, the evaporation of the water may be pushed pretty quickly, by a steady boil, till copious vapours cease to rise. This criterion is observed when the paste has become too stiff to be stirred freely. The soap should have a dazzling snowy whiteness, provided the lard has been well refined, by being previously triturated in a mortar, melted by a steam heat, and then strained. The lard soap so prepared, is semi-solid, and preserves always the same appearance. If the paste is not sufficiently boiled, however, it will show the circumstance very soon; for in a few days the soap will become gluey and stringy, like a tenacious mass of birdlime. This defect may not only be easily avoided, but easily remedied, by subjecting the paste to an adequate evaporation. Such soaps are in great request for shaving, and are most convenient in use, especially for travellers. Hence their sale has become very considerable.

Pearl soft Soap.—It is only a few years since the process for making this elegant soap became known in France. It differs little from the preceding, and owes its beautiful aspect merely to minute manipulations, about to be described. Weigh out 20 pounds of purified hog’s lard on the one hand; and 10 pounds of potash lye at 36° B. on the other. Put the lard into a porcelain capsule, gently heated upon a sand-bath, stirring it constantly with a wooden spatula; and when it is half melted, and has a milky appearance, pour into it only one-half of the lye, still stirring, and keeping up the same temperature, with as little variation as possible. While the saponification advances gradually, we shall perceive, after an hour, some fat floating on the surface, like a film of oil, and at the same time the soapy granulations falling to the bottom. We must then add the second portion of the lye; whereon the granulations immediately disappear and the paste is formed. After conducting this operation during four hours, the paste becomes so stiff and compact, that it cannot be stirred; and must then be lightly beaten. At this time the capsule must be transferred from the sand-bath into a basin of warm water, and allowed to cool very slowly.

The soap, though completely made, has yet no pearly appearance. This physical property is developed only by pounding it strongly in a marble mortar; whereby all its particles, which seemed previously separated, combine to form a homogeneous paste. The perfume given to it, is always essence of bitter almonds; on which account the soap is called almond cream, crÈme d’amandes.

HARD SOAPS FOR THE TOILET.

The soaps prepared for the perfumer, are distinguished into different species, according to the fat which forms their basis. Thus there is soap of tallow, of hog’s lard, of oil of olives, of almonds, and palm oil.

It is from the combination of these different sorts, mingled in various proportions, and perfumed agreeably to the taste of the consumer, that we owe the vast number of toilet soaps sold under so many fantastic names. One sort is rarely scented by itself, as a mixture of several is generally preferred; in which respect every perfumer has his peculiar secret. Some toilet soaps, however, require the employment of one kind more than of another.

Formerly the Windsor soap was made in France, wholly with mutton suet; and it was accordingly of inferior value. Now, by mixing some olive oil or lard with the suet, a very good Windsor soap is produced. I have already stated, that the fat of the London Windsor is, nine parts of good ox tallow, and one of olive oil. A soap made entirely with oil and soda, does not afford so good a lather as when it contains a considerable proportion of tallow.

The soaps made with palm oil are much used; when well made, they are of excellent quality, and ought to enter largely into all the coloured sorts. They naturally possess the odour of violets.

The soaps made with oil of almonds are very beautiful, and preserve the agreeable smell of their perfume; but being expensive, are introduced sparingly into the mixtures by most manufacturers.

Some perfumers are in the habit of making what may be called extempore soaps, employing lyes at 36° BaumÉ in their formation. This method, however, ought never to be adopted by any person who prefers quality to beauty of appearance. Such soap is, indeed, admirably white, glistening, contains no more water than is necessary to its constitution, and may therefore be sold the day after it is made. But it has counterbalancing disadvantages. It becomes soon very hard, is difficultly soluble in water, and, if not made with tallow, does not lather well. Hog’s lard is very commonly used, for making that soap. Twenty kilogrammes of the fat are taken, to ten kilogrammes of soda lye, at 36° B. (specific gravity 1·324); as soon as the former is nearly fluid, 5 kilogrammes of the lye are introduced, and the mixture is continually agitated during an hour with a wooden spatula. The temperature should never be raised above 150° Fahr. at the commencement of the operation; at the end of one hour, 5 other kilogrammes of lye are to be added, with careful regulation of the heat. The paste thus formed by the union of the fat and alkali, ought to be perfectly homogeneous, and should increase in consistence every hour, till it becomes firm enough to be poured into the frame; during which transfer, the essential oils destined to scent it, should be introduced. Next day the soap is hard enough; nor does it differ in appearance from ordinary soap, only it requires prompt manipulation to be cut into bars and cakes; for when neglected a day or two, it may become too brittle for that purpose, and too hard to take the impression of the stamps in relief. Such an article gets the name of little-pan soap, on account of the small quantity in which it is usually manufactured. Hard soap, made in the common way, is, on the contrary, called large-pan soap. This extemporaneous compound is now seldom or never made by respectable manufacturers. In making Windsor soap, the admixture of olive oil is advantageous; because, being richer in oleine than suet, it saponifies less readily than it, and thus favours the formation of a more perfect neutral combination. When the soap cuts, or parts from the lye, when the paste becomes clotty, or, in the language of the operative, when the grain makes its appearance, the fire should be immediately withdrawn, that the impurities may be allowed to subside. This part of the operation lasts 12 hours at least; after which, the soap, still hot, becomes altogether fluid and perfectly neutral.

For every 1000 pounds of the paste, there must be introduced 9 pounds of essences, mingled in the following proportions:—6 pounds of essence of carui; 1¹/₂ ditto lavender (finest); 1¹/₂ ditto rosemary.

The mixture must be well stirred, in order to get completely saturated with the perfumes; and this may be readily done without at all touching or stirring up the subjacent lyes; in the course of two hours, the soap may be transferred into the ordinary frames. In twenty-four hours, the mass is usually solidified enough for cutting into bars and cakes, ready to be stamped for sale.

The above method of scenting Windsor soap is practised only in the largest establishments; in the smaller, the soap is pailed out of the soap-pans, into a pan provided with a steam case or jacket, and there mixed with the essential oils, by means of appropriate heat and agitation.

The most fashionable toilet soaps are, the rose, the bouquet, the cinnamon, the orange-flower, the musk, and the bitter almond or peach blossom.

Soap À la rose.—This is made of the following ingredients: 30 pounds of olive-oil soap; 20 of good tallow soap.

Toilet soaps must be reduced to thin shavings, by means of a plane, with its under face turned up, so that the bars may be slid along it. These shavings must be put into an untinned copper pan, which is surrounded by a water-bath, or steam. If the soap be old and hard, 5 pounds of water must be added to them; but it is preferable to take fresh-made soaps, which may melt without addition, as soap some time kept does not readily form a homogeneous paste. The fusion is commonly completed in an hour, or thereby, the heat being applied at 212° F., to accelerate the progress, and prevent the dissolution of the constituent water of the soap. For this purpose the interior pan may be covered. Whenever the mass is sufficiently liquefied, 1¹/₂ ounces of finely ground vermillion are to be introduced, and thoroughly mixed, after which the heat may be taken off the pan; when the following perfumes may be added with due trituration:—3 ounces of essence of rose; 1 ditto cloves; 1 ditto cinnamon; 2¹/₂ ditto bergamot; = 7¹/₂.

The scented soap being put into the frames, speedily consolidates. Some recommend to pass the finished fused soap through a tammy cloth, in order to free it from all clots and impurities; a very proper precaution in the act of transferring it to the frame. If the preceding instructions be observed, we obtain a soap perfect in every point of view; possessing a delicious fragrance, equally rich and agreeable, a beautiful roseate hue, and the softest detergent qualities, which keeping cannot impair. Such a soap has, in fact, been known to retain every property in perfection during four or five years. When the essential oils are particularly volatile, they should not be added to the soap till its temperature has fallen to about 140° Fahr.; but in this case a more careful trituration is required. The economy is, however, ill bestowed; for the cakes made of such cooler soap, are never so homogeneous and glossy.

Soap au bouquet.—30 pounds of good tallow soap; 4 ounces of essence of bergamot; oil of cloves, sassafras, and thyme, 1 ounce each; neroli, ¹/₂ ounce. The colour is given with 7 ounces of brown ochre.

Cinnamon Soap.—30 pounds of good tallow soap; 20 ditto of palm-oil soap. Perfumes:—7 ounces of essence of cinnamon; 1¹/₄ ditto sassafras; 1¹/₄ ditto bergamot. Colour:—1 pound of yellow ochre.

Orange-flower Soap.—30 pounds of good tallow soap; 20 ditto palm-oil soap. Perfumes:—7¹/₂ ounces essence of Portugal; 7¹/₂ ditto amber. Colour:—9¹/₂ ounces, consisting of 8¹/₄ of a yellow-green pigment, and 1¹/₄ of red lead.

Musk Soap.—30 pounds of good tallow soap; 20 ditto palm-oil soap. Perfumes:—Powder of cloves, of pale roses, gilliflower, each 4¹/₂ ounces; essence of bergamot, and essence of musk, each 3¹/₂ ounces. Colour:—4 ounces of brown ochre, or Spanish brown.

Bitter Almond Soap.—Is made by compounding, with 50 pounds of the best white soap, 10 ounces of the essence of bitter almonds.

LIGHT SOAPS.

The apparatus employed for making these soaps, is a copper pan, heated by a water-bath; in the bottom of the pan there is a step, to receive the lower end of a vertical shaft, to which arms or paddles are attached, for producing constant agitation, by causing them to revolve among the liquefied mass. Into a pan so mounted, 50 pounds of a good oil soap of any kind are put (for a tallow soap does not become frothy enough), and melted by proper heat, with the addition of 3 or 4 pounds of water. By the rapid rotation of the machine, an abundant thick lather is produced, beginning first at the bottom, and creeping gradually upwards to the top of the pan, when the operation should be stopped; the soap having by this time doubled its volume. It must now be pailed off into the frame, allowed to cool, and then cut into cakes. Such soap is exceedingly pleasant at the wash-stand, feeling very soft upon the skin, affording a copious thick lather, and dissolving with the greatest ease.

TRANSPARENT SOAPS.

These soaps were for a long time manufactured only in England, where the process was kept a profound secret. They are now made every where.

Equal parts of tallow soap, made perfectly dry, and spirit of wine, are to be put into a copper still, which is plunged in a water-bath, and furnished with its capital and refrigeratory. The heat applied to effect the solution should be as slight as possible, to avoid evaporating too much of the alcohol. The solution being effected, must be suffered to settle; and after a few hours’ repose, the clear supernatant liquid is drawn off into tin frames, of the form desired for the cakes of soap. These bars do not acquire their proper degree of transparency till after a few weeks’ exposure to dry air. They are now planed, and subjected to the proper mechanical treatment for making cakes of any form. The soap is coloured with strong alcoholic solution of archil for the rose tint, and of turmeric for the deep yellow. Transparent soaps, however pleasing to the eye, are always of indifferent quality; they are never so detergent as ordinary soaps, and they eventually acquire a disagreeable smell.

SODA, Caustic soda (Hydrate de soude, Fr.; Aetznatron, Germ.); is an alkaline substance, used in chemical researches, in bleaching, and in the manufacture of soap. It is prepared by boiling a solution of crystallized carbonate of soda in 4 or 5 parts of water, with half its weight of recently slaked and sifted lime. At the end of half an hour, the vessel of iron, porcelain, or preferably silver, may be removed from the fire, and covered carefully, till the calcareous matter has settled into a solid magma at the bottom. The clear supernatant lye may be then decanted into bottles for use in the liquid state, or evaporated, out of contact of air, till it assumes an oily appearance, then poured upon an iron or marble slab, broken into pieces, and put up in phials secured with greased stoppers or corks.

Caustic soda is a white brittle mass, of a fibrous texture, a specific gravity of 1·536, melting at a heat under redness, having a most corrosive taste and action upon animal matters, dissolving readily in both water and alcohol, attracting carbonic acid when exposed to the atmosphere, but hardly any water, and falling thereby into an efflorescent carbonate; it forms soaps with tallow, oils, wax, rosin; dissolves wool, hair, silk, horn, alumina, silica, sulphur, and some metallic sulphurets. It consists of 77·66 soda, and 22·34 water. A solution of caustic soda affords no precipitate with solution of chloride of platinum, or tartaric acid, as a solution of caustic potash never fails to do.

The following Table of the quantity of Caustic Soda contained in Lyes of different densities, has been given by Richter:—

Soda free from water, can be obtained only by the combustion of sodium, which see.

SODA, CARBONATE OF (Kohlensaures natron, Germ.): is the soda of commerce in various states, either crystallized, in lumps, or in a crude powder called soda-ash. It exists in small quantities in certain mineral waters; as, for example, in those of Seltzer, Seydschutz, Carlsbad, and the volcanic springs of Iceland, especially the Geyser; it frequently occurs as an efflorescence in slender needles upon damp walls, being produced by the action of the lime upon the sea salt present in the mortar. The mineral soda is the sesquicarbonate, to be afterwards described.

Of manufactured soda, the variety most antiently known is barilla, the incinerated ash of the Salsola soda. This plant is cultivated with great care by the Spaniards, especially in the vicinity of Alicant. The seed is sown in light low soils, which are embanked towards the sea shore, and furnished with sluices, for admitting an occasional overflow of salt water. When the plants are ripe, the crop is cut down and dried; the seeds are rubbed out and preserved; the rest of the plant is burned in rude furnaces, at a temperature just sufficient to cause the ashes to enter into a state of semi-fusion, so as to concrete on cooling into cellular masses moderately compact. The most valuable variety of this article is called sweet barilla. It has a grayish-blue colour and gets covered with a saline efflorescence when exposed for some time to the air. It is hard and difficult to break; when applied to the tongue, it excites a pungent alkaline taste.

I have analyzed many varieties of barilla. Their average quantity of free or alkalimetrical soda, is about 17 per cent.; though several contain only 14 parts in the hundred, and a few upwards of 20. This soda is chiefly a carbonate, with a little sulphuret and sulphite; and is mixed with sulphate and muriate of soda, carbonate of lime, vegetable carbon, &c.

Another mode of manufacturing crude soda, is by burning sea-weed into kelp. Formerly very large revenues were derived by the proprietors of the shores of the Scottish islands and Highlands, from the incineration of sea-weed by their tenants, who usually paid their rents in kelp; but since the tax has been taken off salt, and the manufacture of a crude soda from it has been generally established, the price of kelp has fallen extremely low.

The crystals of soda-carbonate, as well as the soda-ash of British commerce, are now made altogether by the decomposition of sea salt.

SODA MANUFACTURE.

The manufacture divides itself into three branches:—1. The conversion of sea salt, or chloride of sodium, into sulphate of soda. 2. The decomposition of this sulphate into crude soda, called black balls by the workmen. 3. The purification of these balls, either into a dry white soda-ash or into crystals.

1. The preparation of the sulphate of soda.—Figs. 1033, 1034, 1035. represent the furnace for converting the muriate of soda into the sulphate. The furnace must be built interiorly of the most refractory fire-bricks, such as are used for glasshouses, but of the ordinary brick size; except the bridges C, G, N, which should be formed of one mass, such as what is called a Welsh lump. A is the ash-pit; B, the grate; C, the first bridge, between the fire and the first calcining hearth, D, D; F, F, is its roof; G, the second bridge, between the calcining hearth and the decomposing hearth I, I, I; the roof of which is K, K. This hearth I, I, is lined with a lead square pan, 5 or 6 inches deep, sloped at the back opening, in fig. 1035., marked M'; which deficient part of the upright side is filled up with two bricks placed one over the other, as shown at m, m, fig. 1034., and luted with clay, to confine the semi-liquid mass in the pan, I, I. Some manufacturers make this pan 8 inches deep, and line its bottom and sides with bricks or siliceous sandstone, to protect the lead from the corrosive action of the acid. There are others who consider this precaution troublesome, as the points of the pan which become leaky are thereby concealed. In the roof of the decomposing hearth, one or two syphon funnels R, of lead, are inserted when the charge of acid (sulphuric) is to be poured down upon the salt in I, I, to save the risk of any annoyance from the fumes of the muriatic acid. O, O, is a chimney filled with round flint nodules, which are kept continually moist by the trickling of a streamlet of water upon the topmost layer. The muriatic gas meeting this descending film of water upon so extensive a surface, becomes absorbed, and runs out below in a liquid form. When the acid is required in a somewhat concentrated state, this chimney should be made both high and capacious. Such a plan, moreover, is very valuable for abating the nuisance caused by the disengagement of the muriatic acid gas; which is otherwise apt to sterilize the surrounding vegetation.

A fire being kindled in the grate B, figs. 1033. and 1034., 3 cwt. of salt in powder are to be thrown by a shovel into the pan I, through the door M, fig. 1035., or m, m, fig. 1034. Two hundred weight and a half of oil of vitriol, of specific gravity 1·844 having been diluted with from 25 to 30 per cent. of water, and well mixed, or 3 cwts. at 56° BaumÉ, are to be slowly poured in by the funnel, and diffused among the muriate of soda, by an occasional stir with an iron rake cased with sheet lead. Fumes of muriatic acid will now plentifully escape, and, passing up the condensing-shaft O, will flow down in the form of liquid spirit of salt, and escape by the stoneware stopcock P, into the pipe of a sunk cistern. The fire having been steadily kept up at a moderate degree, the chemical reaction will be tolerably complete in the course of two hours; but as this is relative to the nature of the fuel, and the draught of the furnace, no very precise rule in point of time can be laid down; but it is sufficient for this stage of the process, when the fumes cease to be very dense and copious, as may be ascertained by opening the door M, and looking in, or by the appearance at the top of the shaft O. Over the door M', in the opposite side of the decomposing hearth, fig. 1035., there must be an arch or hood terminating in a small chimney, 15 or 20 feet high, for the ascent of the muriatic vapours, when the charge is drawn or run out of the hearth, and allowed to fall into a square shallow iron tray, placed on the ground at the back of the furnace. For this discharge, the two bricks which serve as stoppers to that orifice, must be unluted and removed.

As soon as that charge is taken out, (the fire being meanwhile checked by opening the door T, fig. 1034., and shutting partially the ash-pit opening at A,) a fresh charge must be introduced as above described. The nearly decomposed saline matter during the second charging of the hearth I, will have grown cool and concrete. It must be shovelled into the calcining hearth D, D, fig. 1033., by the back door Q, fig. 1035., where it will receive a higher degree of heat; and, by the expulsion of the remaining part of the muriatic acid, it will become a perfect sulphate of soda. It should be finally brought into a state of semi-fusion. When a sample of it, taken out on the end of the rake or trowel-shaped scraper, emits no fumes, the conversion is accomplished.

From 3 cwts. of common salt, or muriate of soda, rather more than 3¹/₂ cwts. of perfect sulphate should be obtained, quite free from metallic impurity.

The next step is the conversion of the sulphate into a crude soda.

One of the most improved soda furnaces is that, employed in a few factories, represented in figs. 1036, 1037, and 1038. In the section fig. 1037., there are two hearths in one furnace, the one elevated above the level of the other by the thickness of a brick, or about 3 inches. A is the preparatory shelf, where the mixture to be decomposed is first laid in order to be thoroughly heated, so that when transferred to the lower or decomposing hearth B, it may not essentially chill it, and throw back the operation. C is the fire-bridge, and D is the grate. In the horizontal section, or ground plan, fig. 1038., we see an opening in the front corresponding to each hearth. This is a door, as shown in the side view or elevation of the furnace, fig. 1036.; and each door is shut by an iron square frame filled with a fire-tile or bricks, and suspended by a chain over a pulley fixed in any convenient place. See Pitcoal, coking of, p. 1041. The workman, on pushing up the door lightly, makes it rise, because there is a counterweight at the other end of each chain, which balances the weight of the frame and bricks. In the ground plan, only one smoke-flue is shown; and this construction is preferred by many manufacturers; but others choose to have two flues, one from each shoulder, as at a, b; which two flues afterwards unite in one vertical chimney, from 25 to 40 feet high; because the draught of a soda-furnace must be very sharp. Having sufficiently explained the construction of this improved furnace, I shall now proceed to describe the mode of making soda with it.

The materials with which the sulphate is decomposed into a rough carbonate of soda, are chalk or ground limestone, and ground coal or charcoal. The proportions in which these three substances are mixed, influence in a remarkable degree the success of the decomposing process. I have known a false proportion introduced, and persevered in, at a factory, with the most prejudicial effect to the product; the soda-ash produced, being in a small quantity relatively to the sulphate employed, and being much charged with sulphur. After very numerous trials which I have made on the great scale, and many inquiries at the most successful soda-works, both in this country and abroad, I am warranted to offer the following proportions as the most profitable:—

Sulphate of soda, 100 parts: carbonate of lime (chalk or limestone), from 110 to 120 parts; if pure, 110; if a little impure or damp, 120: pit coal, 50 parts.

These materials must be separately ground by an edge-stone mill, and sifted into a tolerably fine powder. They must be then very carefully mixed. Attention to these particulars is of no little importance to the success of the soda process.

One hundred parts or pounds of sulphate of soda are equivalent to 75 parts of carbonate, and when skilfully decomposed, will generally yield fully 70 pounds. A charge for the decomposing furnace with the preparatory shelf should not exceed 200 lbs., or perhaps 180; therefore if 75 pounds of ground sulphate of soda, with 80 pounds of chalk or limestone (ground), and 37 pounds of ground coal; be well mixed, they will constitute one charge. This charge must be shovelled in upon the hearth A, or shelf of preparation, (fig. 1037.); and whenever it has become hot (the furnace having been previously brought to bright ignition), it is to be transferred to the decomposing hearth or laboratory B, by an iron tool, shaped exactly like an oar, called the spreader. This tool has the flattened part from 2 to 3 feet long, and the round part, for laying hold of and working by, from 6 to 7 feet long. Two other tools are used; one, a rake, bent down like a garden hoe at the end; and another, a small shovel, consisting of a long iron rod terminated with a piece of iron plate, about 6 inches long, 4 broad, sharpened and tipped with steel, for cleaning the bottom of the hearth from adhering cakes or crusts. Whenever the charge is shoved by the sliding motion of the oar down upon the working hearth, a fresh charge should be thrown into the preparation shelf, and evenly spread over its surface.

The hot and partially carbonized charge being also evenly spread upon the hearth B, is to be left untouched for about ten minutes, during which time it becomes ignited, and begins to fuse upon the surface. A view may be taken of it through a peep-hole in the door, which should be shut immediately, in order to prevent the reduction of the temperature. When the mass is seen to be in a state of incipient fusion, the workman takes the oar and turns it over breadth by breadth in regular layers, till he has reversed the position of the whole mass, placing on the surface the particles which were formerly in contact with the hearth. Having done this, he immediately shuts the door, and lets the whole get another decomposing heat. After five or six minutes, jets of flame begin to issue from various parts of the pasty-consistenced mass. Now is the time to incorporate the materials together, turning and spreading by the oar, gathering them together by the rake, and then distributing them on the reverse part of the hearth; that is, the oar should transfer to the part next the fire-bridge the portion of the mass lying next the shelf, and vice versÂ. The dexterous management of this transposition characterizes a good soda-furnacer. A little practice and instruction will render this operation easy to a robust clever workman. After this transposition, incorporation, and spreading, the door may be shut again for a few minutes, to raise the heat for the finishing off. Lastly, the rake must be dexterously employed to mix, shift, spread, and incorporate. The jets, called candles, are very numerous, and bright at first; and whenever they begin to fade, the mass must be raked out into cast-iron moulds, placed under the door of the laboratory to receive the ignited paste.

One batch being thus worked off, the other, which has lain undisturbed on the shelf, is to be shoved down from A to B, and spread equally upon it, in order to be treated as above described. A third batch is then to be placed on the shelf.

The article thus obtained should contain at least 22 per cent. of real soda, equivalent to 37 per cent. of dry carbonate, or to 100 of crystals. A skilful workman can turn out a batch in from three quarters of an hour to an hour, producing a perfect carbonate, which yields on solution an almost colourless liquid, nearly destitute of sulphur, and containing hardly any decomposed sulphate.

In some soda-works, where the decomposing furnace is very large, and is charged with a ton of materials at a time, it takes two men to work it, and from five to six hours to complete a batch. Having superintended the operation of the above-described small furnace, and examined its products, I feel warranted to recommend its adoption.

The following materials and products show the average state of this soda process:—

But these products necessarily vary with the skill of the workman.

In another manufactory the following proportions are used:—Six stones, of 14 lbs. each, of dry ground sulphate of soda, are mixed with 3 of chalk and 3 of coal. This mixture, weighing 1¹/₂ cwt., forms a batch, which is spread upon the preparation shelf of the furnace (figs. 1037. and 1038.), as above described, and gradually heated to incipient ignition. It is then swept forwards to the lower area B, by the iron oar, and spread evenly by the rake. Whenever it begins to soften under the rising heat of the laboratory (the side doors being meanwhile shut), the mass must be laboriously turned over and incorporated; the small shovel, or paddle, being employed to transfer, by the interchange of small portions at a time, in rapid but orderly succession, the whole materials from the colder to the hotter, and from the hotter to the colder parts of the hearth. The process of working one batch takes about an hour, during the first half of which period it remains upon the preparation shelf. The average weight of the finished ball is 1 cwt., and its contents in alkalimetrical soda are 33 pounds.

Where the acidulous sulphate of iron from pyrites may be had at a cheap rate, it has been long ago employed, as at Hurlett in Scotland, instead of sulphuric acid, for decomposing the chloride of sodium. Mr. Turner’s process of preparing soda, by decomposing sea salt with litharge and quicklime, has been long abandoned, the resulting patent yellow, or sub-chloride of lead, having a very limited sale.

2. The extraction of pure soda from the crude article.—The black balls must be broken into fragments, and thrown into large square iron cisterns, furnished with false bottoms of wooden spars; when the cisterns are nearly full of these lumps, water is pumped in upon them, till they are all covered. After a few days, the lixiviation is effected, and the lye is drawn off either by a syphon or by a plug-hole near the bottom of the cistern, and run into evaporating vessels. These may be of two kinds. The surface-evaporating furnace, shown in fig. 1039., is a very admirable invention for economizing vessels, lime, and fuel. The grate A, and fireplace, are separated from the evaporating laboratory D, by a double fire-bridge B, C, having an interstitial space in the middle, to arrest the communication of a melting or igniting heat towards the lead-lined cistern D. This cistern may be 8, 10, or 20 feet long, according to the magnitude of the soda-work, and 4 feet or more wide. Its depth should be about 4 feet. It consists of sheet lead, of about 6 pounds weight to the square foot, and it is lined with one layer of bricks, set in roman or hydraulic cement, both along the bottom and up the sides and ends. The lead comes up to the top of C, and the liquor, or lye, may be filled in to nearly that height. Things being thus arranged, a fire is kindled upon the grate A; the flame and hot air sweep along the surface of the liquor, raise its temperature there rapidly to the boiling point, and carry off the watery parts in vapour up the chimney E, which should be 15 or 20 feet high, to command a good draught. But, indeed, it will be most economical to build one high capacious chimney stalk, as is now done at Glasgow, Manchester, and Newcastle, and to lead the flues of the several furnaces above described into it. In this evaporating furnace the heavier and stronger lye goes to the bottom, as well as the impurities, where they remain undisturbed. Whenever the liquor has attained to the density of 1·3, or thereby, it is pumped up into evaporating cast-iron pans, of a flattened somewhat hemispherical shape, and evaporated to dryness while being diligently stirred with an iron rake and iron scraper.

This alkali gets partially carbonated by the above surface-evaporating furnace, and is an excellent article.

When pure carbonate is wanted, that dry mass must be mixed with its own bulk of ground coal, sawdust, or charcoal, and thrown into a reverberatory furnace, like fig. 1038., but with the sole all upon one level. Here it must be exposed to a heat not exceeding 650° or 700° F.; that is, a little above the melting heat of lead; the only object being to volatilize the sulphur present in the mass, and carbonate the alkali. Now, it has been found, that if the heat be raised to distinct redness, the sulphur will not go off, but will continue in intimate union with the soda. This process is called calking, and the furnace is called a calker furnace. It may be six or eight feet long, and four or five feet broad in the hearth, and requires only one door in its side, with a hanging iron frame filled with a fire-tile or bricks, as above described.

This carbonating process may be performed upon several cwts. of the impure soda, mixed with sawdust, at a time. It takes three or four hours to finish the desulphuration; and it must be carefully turned over by the oar and the rake, in order to burn the coal into carbonic acid, and to present the carbonic acid to the particles of caustic soda diffused through the mass, so that it may combine with them.

When the blue flames cease, and the saline matters become white, in the midst of the coaly matter, the batch may be considered as completed. It is raked out, and when cooled, lixiviated in great iron cisterns with false bottoms, covered with mats. The watery solution being drawn off clear by a plug-hole, is evaporated either to dryness, in hemispherical cast-iron pans, as above described, or only to such a strength that it shows a pellicle upon its surface, when it may be run off into crystallizing cisterns of cast iron, or lead-lined wooden cisterns. The above dry carbonate is the best article for the glass manufacture.

Crystallized carbonate of soda, contains 62³/₄ per cent. of water. The crystals are colourless transparent rhomboids, which readily effloresce in the air, and melt in their own water of crystallization. On decanting the liquid from the fused mass, it is found that one part of the salt has given up its water of crystallization to another. By evaporation of that fluid, crystals containing one-fifth less water than the common carbonate are obtained. These do not effloresce in the air.

Mineral soda, the sesquicarbonate, (Anderthalb kohlensaures natron, Germ.); is found in the province of Sukena, in Africa, between Tripoli and Fezzan. It forms a stratum no more than an inch thick, just below the surface of the soil. Its texture is striated crystalline, like fibrous gypsum. Several hundred tons of it are collected annually, which are chiefly consumed in Africa. This species of soda does not effloresce like the Egyptian, or the manufactured soda crystals, owing to its peculiar state of composition and density. It was analyzed by Klaproth, under its native name of trona, and was found to consist, in 100 parts, of—soda, 37; carbonic acid, 38; sulphate of soda, 2·5; water, 22·5, in 100.

This soda is, therefore, composed of—3 atoms of carbonic acid, associated with 2 atoms of soda, and 4 of water; while our commercial soda crystals are composed of—1 atom of carbonic acid, 1 atom of soda, and 10 atoms of water.

There are six natron lakes in Egypt. They are situated in a barren valley, called Bahr-bela-ma, about thirty miles to the west of the Delta.

There are natron lakes also in Hungary, which afford in summer a white saline efflorescent crust of carbonate of soda, mixed with a little sulphate.

There are several soda lakes in Mexico, especially to the north of Zacatecas, as also in many other provinces. In Columbia, 48 English miles from Merida, mineral soda is extracted from the earth in great abundance, under the name of urao.

Bicarbonate of soda (Doppelt kohlensaures natron, Germ.); is prepared, like bicarbonate of potassa, by transmitting carbonic acid gas through a cold saturated solution of pure carbonate of soda, till crystalline crusts be formed. The bicarbonate may also be obtained in four-sided tables grouped together. It has an alkaline taste and reaction upon litmus paper, dissolves in 13 parts of cold water, and is converted by boiling water into the sesquicarbonate, with the disengagement of one fourth of its carbonic acid. It consists of—37 of soda, 52·35 carbonic acid, and 10·65 water.

SODA-WATER, is the name given to water containing a minute quantity of soda, and highly charged with carbonic acid gas, whereby it acquires a sparkling appearance, an agreeable pungent taste, an exhilarating quality, and certain medicinal powers. It constitutes a considerable object of manufacture in this kingdom. The following figure represents, I understand, the best system of apparatus for preparing it. A very dilute solution of soda is put into the globular vessel H, and the carbonic acid gas is forced into it from the gasometer E, by means of the powerful pump-work, as will be understood from the subjoined explanation.

The same apparatus may serve for making any species of aerated water, in imitation of any natural spring. All that is necessary for this purpose, is to put into the cistern Q, the neutro-saline matter, earths, metallic oxides, pure water, &c., each in due proportion, according to the most accredited analysis of the mineral water to be imitated, to agitate that mixture, to suck it into the condenser H, through the pipe R, and then to impregnate it to the due degree, by pumping in the appropriate gas, previously contained in the gasometer F.

Thus, to make Seltzer water, for each 12 pounds troy, = 69,120 grains, or 1 gallon imperial very nearly, take 55 grains of dry carbonate of soda, 17 of carbonate of lime, 18 of carbonate of magnesia, 3¹/₂ of subphosphate of alumina, 3 of chloride of potassium, 155 of chloride of sodium, and 3 of finely precipitated silica. Put these materials into the cistern Q, and charge the gasometer F with 353 cubic inches of carbonic acid gas. Then work the machine by the handle of the wheel X, as explained below, and regulate the introduction of the liquid and the gas in aliquot portions; for example, if the condenser H admits half a gallon of water at a time, that quantity of liquid should be charged with 176 cubic inches of the gas, being one half of the whole quantity. The sulphuretted mineral waters may be imitated in like manner, by taking the proportions of their constituents, as given in Table II. of Waters, Mineral.

IMPROVED SODA-WATER APPARATUS, AS MADE BY MR. HAYWARD TYLER, OF MILTON STREET.

Fig. 1040. front view of the soda-water machine. Fig. 1041. end view of the same.

A, lead generator, for making the gas. B, lead pot, for holding sulphuric acid. C, handle for moving the agitator of the receiver, which stirs up the ingredients in the lead generator. a, cap and screw, for charging the lead pot with sulphuric acid. b, swivel-joint, which is movable, for occasionally throwing in portions of sulphuric acid for generating gas. c, stuffing-box for agitator. d, large cap and screw, for charging the lead generator with whiting and water. e, cap and screw, for emptying contents of ditto. D, lead pipe, to convey the gas from the lead generator to gasometer. E, wood tub, filled with water, for gasometer to work in. F, copper gasometer. G, strong iron frame, for gasometer and tub to stand on, firmly fixed together by three wrought-iron rods, f, f. g, g, two pulleys, for carrying rope and counterbalance weight h, for balancing copper gasometer. i, cock for discharging atmospheric air contained in the gasometer before making the gas. k, cock for occasionally emptying the water out of the tub. l, union joint, to which is fixed a copper pipe, passing through the water in the tub, to deliver the gas as generated into the copper gasometer. m, another union joint, with a similar copper pipe, passing through the water in the tub, and projecting two or three inches above the surface of the water, to convey the gas from the copper gasometer to the soda-water machine. H, H, condenser for aerating the soda-water. I, safety valve. K, K, bottling valve. L, bottling nipple. M, M, soda-water pump. N, valve-piece. O, O, piston of the pump. P, pipe for conducting gas from the gasometer to pump. Q, copper pan for holding the solution of soda. R, copper pipe for conducting the solution of soda to the force pump. S, S, two cocks for regulating the admission of the solution and gas to the pump. T, copper pipe through which the soda-water is forced to the condenser. U, pinion wheel, to give motion to the agitator revolving inside the condenser. V, V, wheel for driving ditto. W, W, cast-iron frame for carrying machinery. X, X, cast-iron fly-wheel. Z, wrought-iron crank. Y, Z, Z, wood stools and curb, upon which the whole of the machinery is fixed.

SODIUM, the metallic basis of soda, is obtained by processes similar to those by which potassium is procured. By fusing hydrate of soda with a little hydrate of potassa, a mixture is obtained, which yields more readily than soda by itself to the decomposing action of iron-turnings at a high heat, in a bent gun-barrel. The portion of potassium produced, may be got rid of, by digesting the alloy for a few days in some naphtha or oil of turpentine contained in an open vessel. The sodium remains at the bottom of the liquid. Pure sodium may, however, be prepared at once, by subjecting incinerated tartrate of soda to heat in the apparatus of Brunner, described under Potassium. It is white, like silver; softer and more malleable than any other metal, and may be readily reduced into very thin leaves. It preserves its malleability till it approaches the melting point. Its specific gravity is 0·970. It softens at the temperature of 122° F., and at 200° it is perfectly fluid; but it will not rise in vapour until heated to nearly the melting point of glass. In the air it oxidizes slowly, and gets covered with a crust of soda; but it does not take fire till it is made nearly red-hot; and then it emits brilliant scintillations. When thrown upon water, it is rapidly oxidized, but without kindling, like potassium. If a drop of water be thrown upon it, it becomes so hot by the chemical action as to take fire. There are three oxides of sodium; 1. the suboxide; 2. the oxide, or the basis of common soda; and, 3. the suroxide; the last being formed when sodium is heated to redness upon a plate of silver.

SOLDERING (Souder, Fr.; LÖthen, Germ.); is the process of uniting the surfaces of metals, by the intervention of a more fusible metal, which being melted upon each surface, serves, partly by chemical attraction, and partly by cohesive force, to bind them together. The metals thus united may be either the same or dissimilar; but the uniting metal must always have an affinity for both. Solders must be, therefore, selected in reference to their appropriate metals. Thus tin-plates are soldered with an alloy consisting of from 1 to 2 parts of tin, with 1 of lead; pewter is soldered with a more fusible alloy, containing a certain proportion of bismuth added to the lead and tin; iron, copper, and brass are soldered with spelter, an alloy of zinc and copper, in nearly equal parts; silver, sometimes with pure tin, but generally with silver-solder, an alloy consisting of 5 parts of silver, 6 of brass, and 2 of zinc; zinc and lead, with an alloy of from 1 to 2 parts of lead with 1 of tin; platinum, with fine gold; gold, with an alloy of silver and gold, or of copper and gold; &c.

In all soldering processes, the following conditions must be observed: 1. the surfaces to be united must be entirely free from oxide, bright, smooth, and level; 2. the contact of air must be excluded during the soldering, because it is apt to oxidize one or other of the surfaces, and thus to prevent the formation of an alloy at the points of union. This exclusion of air is effected in various ways. The locksmith encases in loam the objects of iron, or brass, that he wishes to subject to a soldering heat; the silversmith and brazier mix their respective solders with moistened borax powder; the coppersmith and tinman apply sal ammoniac, rosin, or both, to the cleaned metallic surfaces, before using the soldering-iron to fuse them together with the tin alloy. The strong solder of the coppersmith consists of 8 parts of brass and 1 of zinc; the latter being added to the former, previously brought into a state of fusion. The crucible must be immediately covered up for two minutes till the combination be completed. The melted alloy is to be then poured out upon a bundle of twigs held over a tub of water, into which it falls in granulations. An alloy of 3 parts of copper and 1 of zinc forms a still stronger solder for the coppersmiths. When several parts are to be soldered successively upon the same piece, the more fusible alloys, containing more zinc, should be used first. A softer solder for coppersmiths is made with 6 parts of brass, 1 of tin, and 1 of zinc; the tin being first added to the melted brass, then the zinc; and the whole well incorporated by stirring.

The edges of sheet lead for sulphuric acid chambers, and its concentration pans, are joined together by melted lead itself, because any solder containing tin would soon be corroded. With this view, the two edges being placed in contact, are flattened down into a long wooden groove, and secured in their situation by a few brass pins driven into the wood. The surfaces are next brightened with a triangular scraper, rubbed over with candle grease, and then covered with a stream of hot melted lead. The riband of lead thus applied is finally equalized by being brought into partial fusion with the plumber’s conical iron heated to redness; the contact of air being prevented by sprinkling rosin over the surface. The sheets of lead are thus burned together, in the language of the workmen.

SOOT (Noir de fumÉe, Suie, Fr.; Rus, Flatterrus, Germ.); is the pulverulent charcoal condensed from the smoke of wood or coal fuel. A watery infusion of the former is said to be antiseptic, probably from its containing some creosote.

The soot of pitcoal has not been analyzed with any minuteness. It contains some sulphate and carbonate of ammonia, along with bituminous matter.

SORBIC ACID, is the same with malic acid; which see.

SOY, is a liquid condiment, or sauce, imported chiefly from China. It is prepared with a species of white haricots, wheat flour, common salt, and water; in the proportions respectively of 50, 60, 50, and 250 pounds. The haricots are washed, and boiled in water till they become so soft as to yield to the fingers. They are then laid in a flat dish to cool, and kneaded along with the flour, a little of the hot water of the decoction being added from time to time. This dough is next spread an inch or an inch and a half thick upon the flat vessel (made of thin staves of bamboo), and when it becomes hot and mouldy, in two or three days, the cover is raised upon bits of stick, to give free access of air. If a rancid odour is exhaled, and the mass grows green, the process goes on well; but if it grows black, it must be more freely exposed to the air. As soon as all the surface is covered with green mouldiness, which usually happens in eight or ten days, the cover is removed, and the matter is placed in the sunshine for several days. When it has become as hard as a stone, it is cut into small fragments, thrown into an earthen vessel, and covered with the 250 pounds of water having the salt dissolved in it. The whole is stirred together, and the height at which the water stands is noted. The vessel being placed in the sun, its contents are stirred up every morning and evening; and a cover is applied at night, to keep it warm and exclude rain. The more powerful the sun, the sooner the soy will be completed; but it generally requires two or three of the hottest summer months. As the mass diminishes by evaporation, well water is added; and the digestion is continued till the salt water has dissolved the whole of the flour and the haricots; after which the vessel is left in the sun for a few days, as the good quality of the soy depends on the completeness of the solution, which is promoted by regular stirring. When it has at length assumed an oily appearance, it is poured into bags, and strained. The clear black liquid is the soy, ready for use. It is not boiled, but is put up into bottles, which must be carefully corked. Genuine soy was made in this way at Canton, by Michael de Grubbens. See Memoirs of Academy of Sciences of Stockholm for 1803.

SPECIFIC GRAVITY, designates the relative weights of different bodies under the same bulk; thus a cubic foot of water weighs 1000 ounces avoirdupois; a cubic foot of coal, 1350; a cubic foot of cast iron, 7280; a cubic foot of silver, 10,400; and a cubic foot of pure gold, 19,200; numbers which represent the specific gravities of the respective substances, compared to water = 1·000. See Alloy.

SPERMACETI; the Cetine of Chevreul. In certain species of the cachalot whale, as the Physeter macrocephalus, tursio, microps, and orthodon, as also the Delphinus edentulus, the fat of some parts of their bodies contains a peculiar kind of stearine, called spermaceti. The oil obtained from cavities in the bones of the cranium of the above cetaceÆ is the richest in this kind of stearine. This being thrown into great filter-bags, the spermaceti oil passes through, and is subsequently purified by the addition of a small quantity of potash lye, which precipitates certain matters by neutralizing the acid that held them in solution. The solid which remains on the filter is next squeezed in bags, by means of a horizontal hydraulic press encased in steam, then digested with a weak potash lye, in order to dissolve out any oil which may continue to adhere to it, washed with water, finally dissolved in a tub by the agency of steam, laded into tin pans, and allowed slowly to concrete into a white semi-transparent brittle lamellar crystalline mass, which forms elegant candles.

At 60° its specific gravity is 0·943. It melts at 112·5°; 100 parts of alcohol at 0·821 dissolve 3¹/₂ of it, of which 0·9 are deposited on cooling. Warm ether dissolves it in very large quantities. It is soluble also in the fat of volatile oils; and if the solutions have been saturated while hot, the greater part of the spermaceti crystallizes on cooling. When this substance has been purified by digesting alcohol upon it repeatedly, what remains is the cetine of Chevreul, or pure spermaceti. Its melting point has now become 116° F., and its boiling point 616° F., at which it distils without alteration. Caustic alkaline lyes saponify it with difficulty.

SPIRIT OF AMMONIA, is, properly speaking, alcohol combined with ammonia gas; but the term is often applied to water of ammonia.

SPIRITS, VINOUS. This subject has been fully discussed in the articles Alcohol, Distillation, and Fermentation. I have shown that the progressive increase of alcohol in the wash tends progressively to prevent the conversion of the wort into spirit, or checks the fermenting process, though a great deal of fermentable matter remains unchanged. Mr. Sheridan has sought to remove this obstacle to the thorough transmutation of saccharine matter into alcohol, by drawing off the spirit as it is formed. For this purpose he ferments his wash in close tuns, connected with a powerful air-pump worked by machinery, thus continually removing the carbonic acid as it is formed, and maintaining a diminished pressure under which the alcohol readily distils at a temperature of 120° or 130° F. He finds that this degree of heat is not injurious to the fermentation, provided that it be communicated by the air of a stove-room, and not by water or steam pipes traversing the liquid, which would inevitably scald or seeth the particles in succession, and thereby extinguish the fermenting principle.

By the above ingenious plan, Mr. Sheridan tells me he has obtained 28 gallons of proof spirit from a quarter of grain, instead of the average product 21, being an increase of 25 per cent. The experiment was tried upon a considerable scale at Messrs. Currie’s great distillery near London; but could not be established as a mode of manufacture, on account of the excise laws, which prohibit the distillers from carrying on the two processes of fermentation and distillation at the same time.

SPIRIT OF WINE; Alcohol.

SPONGE (Eponge, Fr.; Schwamm, Germ.); is a cellular fibrous tissue produced by small animals, almost imperceptible, called polypi by naturalists, which live in the sea. This tissue is said to be covered in its recent state with a kind of semi-fluid thin coat of animal jelly, susceptible of a slight contraction or trembling on being touched; which is the only symptom of vitality displayed by the sponge. After death, this jelly disappears, and leaves merely the sponge; formed by the combination of a multitude of small capillary tubes, capable of receiving water in their interior, and of becoming thereby distended. Sponges occur attached to stones at the bottom of the sea; and abound particularly upon the shores of the islands in the Grecian Archipelago. Although analogous in their origin to coral, sponges are quite different in their nature; the former being composed almost entirely of carbonate of lime; while the latter are formed of the same elements as animal matters, and afford, on distillation, a considerable quantity of ammonia.

Dilute sulphuric acid has been recommended for bleaching sponges, after the calcareous impurities have been removed by muriatic acid. Chlorine water answers better.

SPOON MANUFACTURE. See Stamping of Metals.

STAINED GLASS. When certain metallic oxides or chlorides, ground up with proper fluxes, are painted upon glass, their colours fuse into its surface at a moderate heat, and make durable pictures, which are frequently employed in ornamenting the windows of churches as well as of other public and private buildings. The colours of stained glass are all transparent, and are therefore to be viewed only by transmitted light. Many metallic pigments, which afford a fine effect when applied cold on canvas or paper, are so changed by vitreous fusion as to be quite inapplicable to painting in stained glass.

The glass proper for receiving these vitrifying pigments, should be colourless, uniform, and difficult of fusion; for which reason crown glass, made with little alkali, or with kelp, is preferred. When the design is too large to be contained on a single pane, several are fitted together, and fixed in a bed of soft cement while painting, and then taken asunder to be separately subjected to the fire. In arranging the glass pieces, care must be taken to distribute the joinings so that the lead frame-work may interfere as little as possible with the effect.

A design must be drawn upon paper, and placed beneath the plate of glass; though the artist cannot regulate his tints directly by his pallet, but by specimens of the colours producible from his pallet pigments after they are fired. The upper side of the glass being sponged over with gum-water, affords, when dry, a surface proper for receiving the colours, without the risk of their running irregularly, as they would be apt to do, on the slippery glass. The artist first draws on the plate, with a fine pencil, all the traces which mark the great outlines and shades of the figures. This is usually done in black, or, at least, some strong colour, such as brown, blue, green, or red. In laying on these, the painter is guided by the same principles as the engraver, when he produces the effect of light and shade by dots, lines, or hatches; and he employs that colour to produce the shades, which will harmonize best with the colour which is to be afterwards applied; but for the deeper shades, black is in general used. When this is finished, the whole picture will be represented in lines or hatches similar to an engraving finished up to the highest effect possible; and afterwards, when it is dry, the vitrifying colours are laid on by means of larger hair pencils; their selection being regulated by the burnt specimen tints. When he finds it necessary to lay two colours adjoining, which are apt to run together in the kiln, he must apply one of them to the back of the glass. But the few principal colours to be presently mentioned, are all fast colours, which do not run, except the yellow, which must therefore be laid on the opposite side. After colouring, the artist proceeds to bring out the lighter effects by taking off the colour in the proper place, with a goose quill cut like a pen without a slit. By working this upon the glass, he removes the colour from the parts where the lights should be the strongest; such as the hair, eyes, the reflection of bright surfaces and light parts of draperies. The blank pen may be employed either to make the lights by lines, or hatches and dots, as is most suitable to the subject.

By the metallic preparations now laid upon it, the glass is made ready for being fired, in order to fix and bring out the proper colours. The furnace or kiln best adapted for this purpose, is similar to that used by enamellers. See Enamel, and the Glaze-kiln; under Pottery. It consists of a muffle or arch of fire-clay or pottery, so set over a fireplace, and so surrounded by flues, as to receive a very considerable heat within, in the most equable and regular manner; otherwise some parts of the glass will be melted; while, on others, the superficial film of colours will remain unvitrified. The mouth of the muffle, and the entry for introducing fuel to the fire, should be on opposite sides, to prevent as much as possible the admission of dust into the muffle, whose mouth should be closed with double folding-doors of iron, furnished with small peep-holes, to allow the artist to watch the progress of the staining, and to withdraw small trial slips of glass, painted with the principal tints used in the picture.

The muffle must be made of very refractory fire-clay, flat at its bottom, and only 5 or 6 inches high, with such an arched top as may make the roof strong, and so close on all sides as to exclude entirely the smoke and flame. On the bottom of the muffle a smooth bed of sifted lime, freed from water, about half an inch thick, must be prepared for receiving the pane of glass. Sometimes several plates of glass are laid over each other with a layer of dry pulverulent lime between each. The fire is now lighted, and most gradually raised, lest the glass should be broken; and after it has attained to its full heat, it must be kept up for 3 or 4 hours, more or less, according to the indications of the trial slips; the yellow colour being principally watched, as it is found to be the best criterion of the state of the others. When the colours are properly burnt in, the fire is suffered to die away, so as to anneal the glass.

STAINED-GLASS PIGMENTS.

Flesh colour.—Take an ounce of red lead, two ounces of red enamel (Venetian glass enamel, from alum and copperas calcined together), grind them to fine powder, and work this up with spirits (alcohol) upon a hard stone. When slightly baked, this produces a fine flesh colour.

Black colour.—Take 14¹/₂ ounces of smithy scales of iron, mix them with two ounces of white glass (crystal), an ounce of antimony, and half an ounce of manganese; pound and grind these ingredients together with strong vinegar. A brilliant black may also be obtained by a mixture of cobalt blue with the oxides of manganese and iron. Another black is made from three parts of crystal glass, two parts of oxide of copper, and one of (glass of) antimony worked up together, as above.

Brown colour.—An ounce of white glass or enamel, half an ounce of good manganese; ground together.

Red, rose, and brown colours, are made from peroxide of iron, prepared by nitric acid. The flux consists of borax, sand, and minium in small quantity.

Red colour, may be likewise obtained from one ounce of red chalk pounded, mixed with two ounces of white hard enamel, and a little peroxide of copper.

A red, may also be composed of rust of iron, glass of antimony, yellow glass of lead, such as is used by potters (or litharge), each in equal quantity; to which a little sulphuret of silver is added. This composition, well ground, produces a very fine red colour on glass. When protoxide of copper is used to stain glass, it assumes a bright red or green colour, according as the glass is more or less heated in the furnace, the former corresponding to the orange protoxide, the latter having the copper in the state of peroxide.

Bistres and brown reds, may be obtained by mixtures of manganese, orange oxide of copper, and the oxide of iron called umber, in different proportions. They must be previously fused with vitreous solvents.

Green colour.—Two ounces of brass calcined into an oxide, two ounces of minium, and eight ounces of white sand; reduce them to a fine powder, which is to be enclosed in a well luted crucible, and heated strongly in an air-furnace for an hour. When the mixture is cold, grind it in a brass mortar. Green may, however, be advantageously produced by a yellow on one side, and a blue on the other. Oxide of chrome has been also employed to stain glass green.

A fine yellow colour.—Take fine silver laminated thin, dissolve in nitric acid, dilute with abundance of water, and precipitate with solution of sea salt. Mix this chloride of silver, in a dry powder, with three times its weight of pipe-clay well burnt and pounded. The back of the glass pane is to be painted with this powder; for when painted on the face, it is apt to run into the other colours.

Another yellow can be made by mixing sulphuret of silver with glass of antimony, and yellow ochre previously calcined to a red-brown tint. Work all these powders together, and paint on the back of the glass. Or silver laminÆ melted with sulphur, and glass of antimony, thrown into cold water, and afterwards ground to powder, afford a yellow.

A pale yellow may be made with the powder resulting from brass, sulphur, and glass of antimony, calcined together in a crucible, till they cease to smoke; and then mixed with a little burnt yellow ochre.

The fine yellow of M. Merand, is prepared from chloride of silver, oxide of zinc, white-clay, and rust of iron. This mixture, simply ground, is applied on the glass.

Orange colour.—Take 1 part of silver powder, as precipitated from the nitrate of that metal by plates of copper, and washed; mix it with 1 part of red ochre and 1 of yellow, by careful trituration; grind into a thin pap with oil of turpentine or lavender, and apply this with a brush, dry, and burn in.

In the Philosophical Magazine, of December, 1836, the anonymous author of an ingenious essay, “On the Art of Glass-painting,” says, that if a large proportion of ochre has been employed with the silver, the stain is yellow; if a small proportion, it is orange-coloured; and by repeated exposure to the fire, without any additional colouring-matter, the orange may be converted into red; but this conversion requires a nice management of the heat. Artists often make use of panes coloured throughout their substance in the glass-house pots, because the perfect transparency of such glass gives a brilliancy of effect, which enamel painting, always more or less opaque, cannot rival. It was to a glass of this kind that the old glass-painters owed their splendid red. This is, in fact, the only point in which the modern and antient processes differ; and this is the only part of the art which was ever really lost. Instead of blowing plates of solid red, the old glass-makers (like those of Bohemia, for some time back,) used to flash a thin layer of brilliant red over a substratum of colourless glass; by gathering a lump of the latter upon the end of their iron rod in one pot, covering it with a layer of the former in another pot, then blowing out the two together into a globe or cylinder, to be opened into circular tables, or into rectangular plates. The elegant art of tinging glass red by protoxide of copper, and flashing it on common crown glass, has become general within these few years.

That gold melted with flint glass stains it purple, was originally discovered and practised, as a profitable secret, by Kunckel. Gold has been recently used at Birmingham for giving a beautiful rose-colour to scent bottles. The proportion of gold should be very small, and the heat very great, to produce a good effect. The glass must contain either the oxide of lead, bismuth, zinc, or antimony; for crown glass will take no colour from gold. Glass combined with this metal, when removed from the crucible is generally of a pale rose-colour; nay, sometimes is as colourless as water, and does not assume its ruby colour till it has been exposed to a low red heat, either under a muffle or at the lamp. This operation must be nicely regulated; because a slight excess of fire destroys the colour, leaving the glass of a dingy brown, but with a blue (green?) transparency, like that of gold leaf. It is metallic gold which gives the colour; and, indeed, the oxide is too easily reduced, not to be converted into the metal by the intense heat which is necessarily required.

Upon the kindred art of painting in enamel, Mr. A. Essex has published an interesting paper in the same journal, for June, 1837, in which he says that the antient ruby glass, on being exposed to the heat of a glass-kiln, preserves its colour unimpaired, while the modern suffers considerable injury, and in some cases becomes almost black. Hence the latter cannot be painted upon, as the heat required to fix the fresh colour would destroy the beauty of the original basis. To obviate this difficulty, the artist paints upon a piece of plain glass the tints and shadows necessary for blending the rich ruby glow with the other parts of his picture, leaving those parts untouched where he wishes the ruby to appear in undiminished brilliancy, and fixes the ruby glass in the picture behind the painted piece, so that in such parts, the window is double-glazed. Mr. Essex employs, as did the late Mr. Muss, chrome oxide alone for greens; and he rejects the use of iron and manganese in his enamel colours.

Coloured transparent glass is applied as enamel in silver and gold bijouterie, previously bright-cut in the metal with the graver or the rose-engine. The cuts, reflecting the rays of light from their numerous surfaces, exhibit through the glass, richly stained with gold, silver, copper, cobalt, &c., a gorgeous play of prismatic colours, varied with every change of aspect. When the enamel is to be painted on, it should be made opalescent by oxide of arsenic, in order to produce the most agreeable effect.

The artist in enamel has obtained from modern chemistry, preparations of the metals platinum, uranium, and chromium, which furnish four of the richest and most useful colours of his palette. Oxide of platinum produces a substantive rich brown, formerly unknown in enamel painting; a beautiful transparent tint, which no intensity or repetition of firing can injure. Colours proper for enamel painting, he says, are not to be purchased; those sold for the purpose, are adapted only for painting upon china. The constituents of the green enamel used by his brother, Mr. W. Essex, are, silica, borax, oxide of lead, and oxide of chrome.

Mr. Essex’s enamelling furnace is a cubic space of about 12 inches, and contains a fire-clay muffle, without either bottom or back, which is surrounded with coke, except in front. The entire draught of air which supplies the furnace, passes through the muffle; the plates and paintings being placed on a thin slab, made of tempered fire-clay, technically termed planche, which rests on the bed of coke-fuel. As the greatest heat is at the back of the muffle, the picture must be turned round while in the fire, by means of a pair of spring tongs. The above furnace serves for objects up to five inches in diameter; but for larger works a different furnace is required, for the description of which I must refer to the original paper.

Relatively to the receipts for enamel colours, and for staining and gilding on glass, for which twenty guineas were voted by the Society for the Encouragement of Arts, in the session of 1817, to Mr. R. Wynn, Mr. A. Essex says, in p. 446. of his essay—“the unfortunate artist who shall attempt to make colours for the purpose of painting in enamel from these receipts, will assuredly find, to his disappointment, that they are utterly useless.” In page 449. he institutes a comparison between Mr. Wynn’s complex farrago for green, as published in the Transactions of the Society, with the simple receipt of his brother, as given above. It is a remarkable circumstance, that not one of our enamel artists, during a period of twenty years, should have denounced the fallacy of these receipts, and the folly of sanctioning imposture by a public reward. Should Mr. Essex’s animadversions be just, the well-intentioned Society in the Adelphi may, from the negligence of its committee, come to merit the sobriquet, “For the Discouragement of Arts.”

STAMPING OF METALS. The following ingenious machine for manufacturing metal spoons, forks, and other articles, was made the subject of a patent by Jonathan Hayne, of Clerkenwell, in May, 1833. He employs a stamping-machine with dies, in which the hammer is raised to a height between guides, and is let fall by a trigger. He prefers fixing the protuberant or relief portion of the die to the stationary block or bed of the stamping-machine, and the counterpart or intaglio to the falling hammer or ram.

The peculiar feature of improvement in this manufacture consists in producing the spoon, ladle, or fork perfect at one blow in the stamping-machine, and requiring no further manipulation of shaping, but simply trimming off the barb or fin, and polishing the surface, to render the article perfect and finished.

Heretofore, in employing a stamping-machine, or fly-press, for manufacturing spoons, ladles, and forks, it has been the practice to give the impressions to the handles, and to the bowls or prongs, by distinct operations of different dies, and after having so partially produced the pattern upon the article, the handles had to be bent and formed by the operations of filing and hammering.

By his improved form of dies, which, having curved surfaces and bevelled edges, allow of no parts of the faces of the die and counter-die to come into contact, he is enabled to produce considerable elevations of pattern and form, and to bring up the article perfect at one blow, with only a slight barb or fin upon its edge.

In the accompanying drawings, fig. 1042. is the lower or bed die for producing a spoon, seen edgewise; fig. 1043. is the face of the upper or counter-die, corresponding; fig. 1044. is a section, taken through the middle of the pair of dies, showing the space in which the metal is pressed to form the spoon.

To manufacture spoons, ladles, or forks according to his improved process, he first forges out the ingot into flat pieces, of the shape and dimensions of the die of the intended article; and if a spoon or ladle is to be made, gives a slight degree of concavity to the bowl part; but, if necessary, bends the back, in order that it may lie more steadily, and bend more accurately, upon the lower die; if a fork, he cuts or otherwise removes portions of the metal at those parts which will intervene between the prongs; and, having thus produced the rude embryo of the intended article, scrapes its entire surface clean and free from oxidation-scale or fire-strain, when it is ready to be introduced into the stamping-machine.

He now fixes the lower die in the bed of the stamping-machine, shown at a, a, in the elevations figs. 1045. and 1046., and fixes, in the hammer b, the upper or counter-die c, accurately adjusting them both, so that they may correspond exactly when brought together. He then places the rudely-formed article above described upon the lower die, and having drawn up the hammer to a sufficient elevation by a windlass and rope, or other ordinary means, lets go the trigger, and allows the hammer with the counter-die to fall upon the under die, on which the article is placed; when, by the blow thus given to the metal, the true and perfect figure and pattern of the spoon, ladle, or fork is produced, and which, as before said, will only require the removal of the slight edging of barb or fin, with polishing, to finish it.

On striking the blow, in the operation of stamping the article, the hammer will recoil and fly up some distance, and if allowed to fall again with reiterated blows, would injure both the article and the dies; therefore, to avoid this inconvenience, he causes the hammer on recoiling to be caught by a pair of palls locking into racks on the face of the standards, seen in figs. 1045. and 1046. In fig. 1045. the hammer b, of the stamping-machine, is seen raised and suspended by a rope attached to a pair of jointed hooks or holders d, d, the lower ends of which pass into eyes e, e, extending from the top of the hammer. When the lever or trigger t is drawn forward, as in fig. 1046., the two inclined planes g, g, on the axle h, press the two legs of the holders d, d, inward, and cause their hooks or lower ends to be withdrawn from the eyes e, e, when the hammer instantly falls, and brings the dies together: such is the ordinary construction of the stamping-machine.

On the hammer falling from a considerable elevation, the violence of the blow causes it to recoil and bound upwards, as before mentioned; it therefore becomes necessary to catch the hammer when it has rebounded, in order to prevent the dies coming again together; this is done by the following mechanism:—

Two latch levers i, i, are connected by joints to the upper part of the hammer, and two pall levers k, k, turning upon pins, are mounted in the bridge l, affixed to the hammer. Two springs m, m, act against the lower arms of these levers, and press them outwards, for the purpose of throwing the palls at the lower ends of the levers into the teeth of the ratchet racks n, n, fixed on the sides of the upright standards.

Previously to raising the hammer, the upper ends of the pall levers k, are drawn back, and the latches i, being brought down upon them, as in fig. 1045., the levers k are confined, and their palls prevented from striking into the side racks; but as the hammer falls, the ends of the latches i strike upon the fingers o, o, fixed to the side standards, and liberate the palls, the lower ends of which, when the hammer rebounds, after stamping, catch into the teeth of the racks, as in fig. 1046., and thereby prevent the hammer from again descending.

STARCH; (Amidon, Fecule, Fr.; StÄrke, Germ.); is a white pulverulent substance, composed of microscopic spheroids, which are bags containing the amylaceous matter. It exists in a great many different plants, and varies merely in the form and size of its microscopic particles; as found in some plants, it consists of spherical particles ¹/₁₀₀₀ of an inch in diameter; and in others, of ovoid particles, of ¹/₃₀₀ or ¹/₄₀₀ of an inch. It occurs, 1. in the seeds of all the acotyledinous plants, among which are the several species of corns, and those of other gramineÆ; 2. in the round perennial tap roots, which shoot up an annual stem; in the tuberose roots, such as potatos, the Convolvulus batatas and edulis, the Helianthus tuberosus, the Jatropha manihot, &c., which contain a great quantity of it; 3. in the stems of several monocotyledinous plants, especially of the palm tribe, whence sago comes; but it is very rarely found in the stems and branches of the dicotyledinous plants; 4. it occurs in many species of lichen. Three kinds of starch have been distinguished by chemists; that of wheat, that called inuline, and lichen starch. These three agree in being insoluble in cold water, alcohol, ether, and oils, and in being converted into sugar by either dilute sulphuric acid or diastase. The main difference between them consists in their habitudes with water and iodine. The first forms with hot water a mucilaginous solution, which constitutes, when cold, the paste of the laundress, and is tinged blue by iodine; the second forms a granular precipitate, when its solution in boiling-hot water is suffered to cool, which is tinged yellow by iodine; the third affords, by cooling the concentrated solution, a gelatinous mass, with a clear liquor floating over it, that contains little starch. Its jelly becomes brown-gray with iodine.

1. Ordinary starch.—This may be extracted from the following grains:—wheat, rye, barley, oats, buckwheat, rice, maize, millet, spelt; from the siliquose seeds, as peas, beans, lentiles, &c.; from tuberous and tap roots, as those of the potato, the orchis, manioc; arrowroot, batata, &c. Different kinds of corn yield very variable quantities of starch. Wheat differs in this respect, according to the varieties of the plant, as well as the soil, manure, season, and climate. See Bread.

Wheat partly damaged by long keeping in granaries, may be employed for the manufacture of starch, as this constituent suffers less injury than the gluten; and it may be used either in the ground or unground state.

1. With unground wheat.—The wheat being sifted clean, is to be put into cisterns, covered with soft water, and left to steep till it becomes swollen and so soft as to be easily crushed between the fingers. It is now to be taken out, and immersed in clear water of a temperature equal to that of malting-barley, whence it is to be transferred into bags, which are placed in a wooden chest containing some water, and exposed to strong pressure. The water rendered milky by the starch being drawn off by a tap, fresh water is poured in, and the pressure is repeated. Instead of putting the swollen grain into bags, some prefer to grind it under vertical edge-stones, or between a pair of horizontal rollers, and then to lay it in a cistern, and separate the starchy liquor by elutriation with successive quantities of water well stirred up with it. The residuary matter in the sacks or cisterns contains much vegetable albumen and gluten, along with the husks; when exposed to fermentation, it affords a small quantity of starch of rather inferior quality.

The above milky liquor, obtained by expression or elutriation, is run into large cisterns, where it deposits its starch in layers successively less and less dense; the uppermost containing a considerable proportion of gluten. The supernatant liquor being drawn off, and fresh water poured on it, the whole must be well stirred up, allowed again to settle, and the surface-liquor again withdrawn. This washing should be repeated as long as the water takes any perceptible colour. As the first turbid liquor contains a mixture of gluten, sugar, gum, albumen, &c., it ferments readily, and produces a certain portion of vinegar, which helps to dissolve out the rest of the mingled gluten, and thus to bleach the starch. It is, in fact, by the action of this fermented or soured water, and repeated washing, that it is purified. After the last deposition and decantation, there appears on the surface of the starch a thin layer of a slimy mixture of gluten and albumen, which, being scraped off, serves for feeding pigs or oxen; underneath will be found a starch of good quality. The layers of different sorts are then taken up with a wooden shovel, transferred into separate cisterns, where they are agitated with water, and passed through fine sieves. After this pap is once more well settled, the clear water is drawn off, the starchy mass is taken out, and laid on linen cloths in wicker baskets, to drain and become partially dry. When sufficiently firm, it is cut into pieces, which are spread upon other cloths, and thoroughly desiccated in a proper drying-room, which in winter is heated by stoves. The upper surface of the starch is generally scraped, to remove any dusty matter, and the resulting powder is sold in that state. Wheat yields, upon an average, only from 35 to 40 per cent. of good starch. It should afford more by skilful management.

2. In this country, wheat crushed between iron rollers is laid to steep in as much water as will wet it thoroughly; in four or five days the mixture ferments, soon afterwards settles, and is ready to be washed out with a quantity of water into the proper fermenting vats. The common time allowed for the steep, is from 14 to 20 days. The next process consists in removing the stuff from the vats into a stout round basket set across a back below a pump. One or two men keep going round the basket, stirring up the stuff with strong wooden shovels, while another keeps pumping water, till all the farina is completely washed from the bran. Whenever the subjacent back is filled, the liquor is taken out and strained through hair sieves into square frames or cisterns, where it is allowed to settle for 24 hours; after which the water is run off from the deposited starch by plug taps at different levels in the side. The thin stuff, called slimes, upon the surface of the starch, is removed by a tray of a peculiar form. Fresh water is now introduced, and the whole being well mixed by proper agitation, is then poured upon fine silk sieves. What passes through is allowed to settle for 24 hours; the liquor being withdrawn, and then the slimes, as before, more water is again poured in, with agitation, when the mixture is again thrown upon the silk sieve. The milky liquor is now suffered to rest for several days, 4 or 5, till the starch becomes settled pretty firmly at the bottom of the square cistern. If the starch is to have the blue tint, called Poland, fine smalt must be mixed in the liquor of the last sieve, in the proportion of 2 or 3 lbs. to the cwt. A considerable portion of these slimes may, by good management, be worked up into starch by elutriation and straining.

The starch is now fit for boxing, by shovelling the cleaned deposit into wooden chests, about 4 feet long, 12 inches broad, and 6 inches deep, perforated throughout, and lined with thin canvas. When it is drained and dried into a compact mass, it is turned out by inverting the chests upon a clean table, where it is broken into pieces 4 or 5 inches square, by laying a ruler underneath the cake, and giving its surface a cut with a knife, after which the slightest pressure with the hand will make the fracture. These pieces are set upon half-burned bricks, which by their porous capillarity imbibe the moisture of the starch, so that its under surface may not become hard and horny. When sufficiently dried upon the bricks, it is put into a stove (which resembles that of a sugar refinery), and left there till tolerably dry. It is now removed to a table, when all the sides are carefully scraped with a knife; it is next packed up in the papers in which it is sold; these packages are returned into the stove, and subjected to a gentle heat during some days; a point which requires to be skilfully regulated.

Mr. Samuel Hall obtained a patent for bleaching starch by chloride of lime in 1821. Chlorine water would probably be preferable, and might prove useful in operating upon damaged wheat.

The sour water of the starch manufacture contains, according to Vauquelin, acetic acid, acetate of ammonia, alcohol, phosphate of lime, and gluten.

During the drying, starch splits into small prismatic columns, of considerable regularity. When kept dry, it remains unaltered for a very long period. When it is heated to a certain degree in water, the envelopes of its spheroidal particles burst, and the farina forms a mucilaginous emulsion, magma, or paste. When this apparent solution is evaporated to dryness, a brittle horny-looking substance is obtained, quite different in aspect from starch, but similar in chemical habitudes. When the moist paste is exposed for 2 or 3 months to the air in summer, the starch is converted into sugar to the amount of one-third or one-half of its weight, into gum, and gelatinous starch called amidine by De Saussure, with occasionally a resinous matter. This curious change goes on even in close vessels.

Starch from potatos.—From the following table of analyses, it appears that potatos contain from 24 to 30 per cent. of dry substance:—

Manufacture of potato starch.—The potatos are first washed in a cylindrical cage formed of wooden spars, made to revolve upon a horizontal axis, in a trough filled with water to the level of the axis. They are then reduced to a pulp by a rasping machine, similar to that represented in figs. 1047, 1048., where a is a wooden drum covered with sheet-iron, roughened outside with numerous prominences, made by punching out holes from the opposite side. It is turned by a winch fixed upon each end of the shaft. The drum is enclosed in a square wooden box, to prevent the potato-mash from being scattered about. The hopper b is attached to the upper frame, has its bottom concentric with the rasp-drum, and nearly in contact with it. The pulp chest c is made to slide out, so as when full to be readily replaced by another. The two slanting boards d, d, conduct the pulp into it. A moderate stream of water should be made to play into the hopper upon the potatos, to prevent the surface of the rasp from getting foul with fibrous matter. Two men, with one for a relay, will rasp, with such a machine, from 2¹/₂ to 3 tons of potatos in 12 hours.

The potato pulp must be now elutriated upon a fine wire or hair sieve, which is set upon a frame in the mouth of a large vat, while water is made to flow upon it from a spout with many jets. The pulp meanwhile must be stirred and kneaded by the hand, or by a mechanical brush-agitator, till almost nothing but fibrous particles are left upon the sieve. These, however, generally retain about 5 per cent. of starch, which cannot be separated in this way. This parenchyma should therefore be subjected to a separate rasping upon another cylinder. The water turbid with starch is allowed to settle for some time in a back; the supernatant liquor is then run by a cock into a second back, and after some time into a third, whereby the whole starch will be precipitated. The finest powder collects in the last vessel. The starch thus obtained, containing 33 per cent. of water, may be used either in the moist state, under the name of green fecula, for various purposes, as for the preparation of dextrine, and starch syrup; or it may be preserved under a thin layer of water, which must be renewed from time to time, to prevent fermentation; or lastly, it may be taken out and dried.

In trials made with St. Etienne’s rasp and starch machinery, in Paris, which was driven by two horses, nearly 18 cwt. of potatos were put through all the requisite operations in one hour, including the pumping of the water. The product in starch amounted to from 17 to 18 per cent. of the potatos. The quicker the process of potato-starch making, the better is its quality.

Starch from certain foreign plants.—1. From the pith of the sago palm. See Sago.

2. From the roots of the Maranta arundinacea, of Jamaica, the Bahamas, and other West India islands, the powder called arrow-root is obtained, by a process analogous to that for making potato starch.

3. From the root of the Manioc, which also grows in the West Indies, as well as in Africa, the cassava is procured, by a similar process. The juice of this plant is poisonous, from which the wholesome starch is deposited. When dried with stirring upon hot iron plates, it agglomerates into small lumps, called tapioca; being a gummy fecula.

The characters of the different varieties of starch can be learnt only from microscopic observation; by which means also their sophistication or admixture may be readily ascertained.

Starch, from whatever source obtained, is a white soft powder, which feels crispy, like flowers of sulphur, when pressed between the fingers; it is destitute of taste and smell, unchangeable in the atmosphere, and has a specific gravity of 1·53. I have already described the particles as spheroids enclosed in a membrane. The potato contains some of the largest, and the millet the smallest. Potato starch consists of truncated ovoids, varying in size from ¹/₃₀₀ to ¹/₃₀₀₀ of an inch; arrow-root, of ovoids varying in size from ¹/₈₀₀ to ¹/₂₀₀₀ of an inch; flower starch, of insulated globules about ¹/₁₀₀₀ of an inch; cassava, of similar globules assembled in groups. These measurements I have made with a good achromatic microscope, and a divided glass-slip micrometer of Tully.

For the saccharine changes which starch undergoes by the action of diastase, see Fermentation.

Lichenine, a species of starch obtained from Iceland moss (Cetraria islandica), as well as inuline, from elecampane (Inula Helenium), are rather objects of chemical curiosity, than of manufactures.

There is a kind of starch made in order to be converted into gum for the calico-printer. This conversion having been first made upon the great scale in this country, has occasioned the product to be called British gum. The following is the process pursued in a large and well conducted establishment near Manchester. A range of four wooden cisterns, each about 7 or 8 feet square, and 4 feet deep, is provided. Into each of them 2000 gallons of water being introduced, 12¹/₂ loads of flour are stirred in. This mixture is set to ferment upon old leaven left at the bottom of the backs, during 2 or 3 days. The contents are then stirred up, and pumped off into 3 stone cisterns, 7 feet square and 4 feet deep; as much water being added, with agitation, as will fill the cisterns to the brim. In the course of 24 hours the starch forms a firm deposit at the bottom; and the water is then syphoned off. The gluten is next scraped from the surface, and the starch is transferred into wooden boxes pierced with holes, which may be lined with coarse cloth, or not, at the pleasure of the operator.

The starch, cut into cubical masses, is put into iron trays, and set to dry in a large apartment, two stories high, heated by a horizontal cylinder of cast-iron traversed by the flame of a furnace. The drying occupies two days. It is now ready for conversion into gum, for which purpose it is put into oblong trays of sheet iron, and heated to the temperature of 300° F. in a cast-iron oven, which holds four of these trays. Here it concretes into irregular semi-transparent yellow-brown lumps, which are ground into fine flour between mill-stones, and in this state brought to the market. In this roasted starch, the vesicles being burst, their contents become soluble in cold water. British gum is not convertible into sugar, as starch is, by the action of dilute sulphuric acid; nor into mucic acid, by nitric acid; but into the oxalic; and it is tinged purple-red by iodine. It is composed, in 100 parts, of 35·7 carbon, 6·2 hydrogen, and 58·1 oxygen; while starch is composed of, 43·5 carbon, 6·8 hydrogen, and 49·7 oxygen.

To prove whether starch be quite free from gluten, or whether it be mixed with any wheat flour, diffuse 12 grains of it through six ounces of water, heat the mixture to boiling, stirring it meanwhile with a glass slip. If the starch be pure, no froth will be seen upon the surface of the pasty fluid; or if any be produced during the stirring, it will immediately subside after it; but if the smallest portion of gluten be present, much froth will be permanently formed, which may be raised by stirring into the appearance of soap-suds.

STEAM, is the vapour of hot water; the discussion of which belongs to chemistry, physics, and engineering. Certain practical applications of the subject will be found in the article Evaporation.

STEARIC ACID, improperly called Stearine (TalgsaÜre, Germ.), is the solid constituent of fatty substances, as of tallow and olive oil, converted into a crystalline mass by saponification with alkaline matter, and abstraction of the alkali by an acid. By this process, fats are convertible into three acids, called Stearic, Margaric, and Oleic; the first two being solid, and the last liquid. The stearine, of which factitious wax candles are made, consists of the stearic and margaric acids combined. These can be separated from each other only by the agency of alcohol, which holds the margaric acid in solution after it has deposited the stearic in crystals. Pure stearic acid is prepared, according to its discoverer, Chevreul, in the following way:—Make a soap, by boiling a solution of potash and mutton-suet in the proper equivalent proportions (see Soap); dissolve one part of that soap in 6 parts of hot water, then add to the solution 40 or 50 parts of cold water, and set the whole into a place whose temperature is about 52° Fahrenheit. A substance falls to the bottom, possessed of pearly lustre, consisting of the bi-stearate and bi-margarate of potash; which is to be drained and washed upon a filter. The filtered liquor is to be evaporated, and mixed with the small quantity of acid necessary to saturate the alkali left free by the precipitation of the above bi-salts. On adding water to it afterwards, the liquor affords a fresh quantity of bi-stearate and bi-margarate. By repeating this operation with precaution, we finally arrive at a point when the solution contains no more of these solid acids, but only the oleic. The precipitated bi-salts are to be washed and dissolved in hot alcohol, of specific gravity 0·820, of which they require about 24 times their weight. During the cooling of the solution, the bi-stearate falls down, while the greater part of the bi-margarate, and the remainder of the oleate, remain dissolved. By once more dissolving in alcohol, and crystallizing, the bi-stearate will be obtained alone; as may be proved by decomposing a little of it in water at a boiling heat, with muriatic acid, letting it cool, washing the stearic acid obtained, and exposing it to heat, when, if pure, it will not fuse in water under the 158th degree of Fahrenheit’s scale. If it melts at a lower heat, it contains more or less margaric acid. The purified bi-stearate being decomposed by boiling in water along with any acid, as the muriatic, the disengaged stearic acid is to be washed by melting in water, then cooled and dried.

Stearic acid, prepared by the above process, contains combined water, from which it cannot be freed. It is insipid and inodorous. After being melted by heat, it solidifies at the temperature of 158° Fahrenheit, and affects the form of white brilliant needles grouped together. It is insoluble in water, but dissolves in all proportions in boiling anhydrous alcohol, and on cooling to 122°, crystallizes therefrom, in pearly plates; but if the concentrated solution be quickly cooled to 112°, it forms a crystalline mass. A dilute solution affords the acid crystallized in large white brilliant scales. It dissolves in its own weight of boiling ether of 0·727, and crystallizes on cooling in beautiful scales, of changing colours. It distils over in vacuo without alteration; but if the retort contains a little atmospheric air, a small portion of the acid is decomposed during the distillation; while the greater part passes over unchanged, but slightly tinged brown, and mixed with traces of empyreumatic oil. When heated in the open air, and kindled, stearic acid burns like wax. It contains 3·4 per cent. of water, from which it may be freed by combining it with oxide of lead. When this anhydrous acid is subjected to ultimate analysis, it is found to consist of—80 of carbon, 12·5 hydrogen, and 7·5 oxygen, in 100 parts. Stearic acid displaces, at a boiling heat in water, carbonic acid from its combinations with the bases; but in operating upon an alkaline carbonate, a portion of the stearic acid is dissolved in the liquor before the carbonic acid is expelled. This decomposition is founded upon the principle, that the stearic acid transforms the salt into a bicarbonate, which is decomposed by the ebullition.

Stearic acid put into a strong watery infusion of litmus, has no action upon it in the cold; but when hot, the acid combines with the alkali of the litmus, and changes its blue colour to red; so that it has sufficient energy to abstract from the concentrated tincture all the alkali required for its neutralization. If we dissolve bi-stearate of potash in weak alcohol, and pour litmus water, drop by drop, into the solution, this will become red, because the litmus will give up its alkali to a portion of the bi-stearate, and will convert it into neutral stearate. If we now add cold water, the reddened mixture will resume its blue tint, and will deposit bi-stearate of potash in small spangles. In order that the alcoholic solution of the bi-stearate may redden the litmus, the alcohol should not be very strong.

From the composition of stearate of potash, the atomic weight of the acid appears to be 106·6; hydrogen being 1; for 18 : 48× 2 ? 100 : 533·3 = 5 atoms of acid.

From the stearate of soda, it appears to be 104; and from that of lime, 102. The stearate of lead, by Chevreul, gives 109 for the atomic weight of the acid.

The margaric and oleic acids seem to have the same neutralizing power, and the same atomic weight.

The preceding numbers will serve to regulate the manufacture of stearic acid for the purpose of making candles. Potash and soda were first prescribed for saponifying fat, as may be seen in M. Gay Lussac’s patent, under the article Candle; and were it not for the cost of these articles, they are undoubtedly preferable to all others in a chemical point of view. Of late years lime has been had recourse to, with perfect success, and has become subservient to a great improvement in candle-making. The stearine block now made by many London houses, though containing not more than 2 or 3 per cent. of wax, is hardly to be distinguished from the purified produce of the bee. The first process is to boil the fat with quicklime and water in a large tub, by means of perforated steam pipes distributed over its bottom. From the above statements we see that about 11 parts of dry lime are fully equivalent to 100 of stearine and oleine mixed: but as the lime is in the state of hydrate, 14 parts of it will be required when it is perfectly pure; in the ordinary state, however, as made from average good limestone, 16 parts may be allowed. After a vigorous ebullition of 3 or 4 hours, the combination is pretty complete. The stearate being allowed to cool to such a degree as to allow of its being handled, becomes a concrete mass, which must be dug out with a spade, and transferred into a contiguous tub, in order to be decomposed with the equivalent quantity of sulphuric acid diluted with water, and also heated with steam. Four parts of concentrated acid will be sufficient to neutralize three parts of slaked lime. The saponified fat now liberated from the lime, which is thrown down to the bottom of the tub in the state of sulphate, is skimmed off the surface of the watery menstruum into a third contiguous tub, where it is washed with water and steam.

The washed mixture of stearic, margaric, and oleic acids, is next cooled in tin pans; then shaved by large knives, fixed on the face of a fly-wheel, called a tallow cutter, preparatory to its being subjected in canvas or caya bags to the action of a powerful hydraulic press. Here a large portion of the oleic acid is expelled, carrying with it a little of the margaric. The pressed cakes are now subjected to the action of water and steam once more, after which the supernatant stearic acid is run off, and cooled in moulds. The cakes are then ground by a rotatory rasping-machine to a sort of mealy powder, which is put into canvas bags, and subjected to the joint action of steam and pressure in a horizontal hydraulic press of a peculiar construction, somewhat similar to that which has been long used in London for pressing spermaceti. The cakes of stearic acid thus freed completely from the margaric and oleic acids, are subjected to a final cleansing in a tub with steam, and then melted into hemispherical masses called blocks. When these blocks are broken, they display a highly crystalline texture, which would render them unfit for making candles. This texture is therefore broken down or comminuted by fusing the stearine in a plated copper pan, along with one thousandth part of pulverized arsenious acid, after which it is ready to be cast into candles in appropriate moulds. See Candle.

STEARINE COLD PRESS. The cold hydraulic press, as mounted by Messrs. Maudslay and Field, for squeezing out the oleic acid from saponified fat, or the oleine from coco-nut lard, is represented in plan in fig. 1051.; in side view of pump in fig. 1052.; and in elevation, fig. 1053.; where the same letters refer to like objects.

A, A, are two hydraulic presses; B the frame; C, the cylinder; D, the piston or ram; E, the follower; F, the recess in the bottom to receive the oil; G, twilled woollen bags with the material to be pressed, having a thin plate of wrought iron between each; H, apertures for the discharge of the oil; I, cistern in which the pumps are fixed; K, framing for machinery to work in; L, two pumps, large and small, to inject the water into the cylinders; M, a frame containing three double branches; N, three branches, each having two stops or plugs, by which the action of one of the pumps may be intercepted from, or communicated to, one or both of the presses; the large pump is worked at the beginning of the operation, and the small one towards the end; by these branches, one or both presses may be discharged when the operation is finished; O, two pipes from the pumps to the branches; P, pipe to return the water from the cylinders to the cisterns; Q, pipes leading from the pumps through the branches to the cylinders; R, conical drum, fixed upon the main shaft Y, driven by the steam-engine of the factory; S, a like conical drum to work the pumps; T, a narrow leather strap to communicate the motion from R to S; U, a long screw bearing a nut, which works along the whole length of the drum; V, the fork or guide for moving the strap T; W, W, two hanging bearings to carry the drum S; X, a pulley on the spindle of the drum S; Y, the main shaft; Z, fly-wheel with groove on the edge, driven by the pulley X; on the axis of S, is a double crank, which works the two pumps L. a, is a pulley on the end of the long screw U; an endless cord passes twice round this pulley, and under a pulley fixed in the weight b; by laying hold of both sides of his cord, and raising or lowering it, the forked guide V, and the leather strap T, are moved backwards or forwards, by means of the nut fixed in the guide, so as to accelerate or retard at pleasure the speed of the working of the pumps; c, is a piece of iron, with a long slit, in which a pin, attached to the fork V, travels, to keep it in the vertical position.

STEATITE (Soapstone; Craie de BrianÇon, Fr.; Speckstein, Germ.); is a mineral of the magnesian family. It has a grayish-white or greenish-white colour, often marked with dendritic delineations, and occurs massive, as also in various supposititious crystalline forms; it has a dull or fatty lustre; a coarse splintery fracture, with translucent edges; a shining streak; it writes feebly; is soft, and easily cut with a knife; but somewhat tough; does not adhere to the tongue; feels very greasy; infusible before the blowpipe; specific gravity from 2·6 to 2·8. It consists of—silica, 44; magnesia, 44; alumina, 2; iron, 7·3; manganese, 1·5; chrome, 2; with a trace of lime. It is found frequently in small contemporaneous veins that traverse serpentine in all directions, as at Portsoy, in Shetland, in the limestone of Icolmkiln, in the serpentine of Cornwall, in Anglesey, in Saxony, Bavaria (at Bayruth), Hungary, &c. It is used in the manufacture of porcelain. It makes the biscuit semi-transparent, but rather brittle, and apt to crack with slight changes of heat. It is employed for polishing serpentine, marble, gypseous alabaster, and mirror glass; as the basis of cosmetic powders; as an ingredient in anti-attrition pastes; it is dusted in powder upon the inside of boots, to make the feet glide easily into them; when rubbed upon grease-spots in silk and woollen clothes, it removes the stains by absorption; it enters into the composition of certain crayons, and is used itself for making traces upon glass, silk, &c. The spotted steatite, cut into cameos and calcined, assumes an onyx aspect. Soft steatite forms excellent stoppers for the chemical apparatus used in distilling or subliming corrosive vapours. Lamellar steatite is Talc.

STEEL (Acier, Fr.; Stahl, Germ.); as a carburet of iron, has already been considered under that metal. I shall treat in this article more particularly of its manufacture and technical relations.

1. Steel of cementation, bar or blistered steel.—With the exception of the Ulverstone charcoal iron, no bars are manufactured in Great Britain capable of conversion into steel at all approaching in quality to that made from the Madras, Swedish, and Russian irons, so largely imported for that purpose. The first rank is assigned to the Swedish iron stamped with a circle enclosing the letter L (hence called hoop L); which fetches the high price of 36l. 10s. per ton, while excellent English coke-iron may be had for one-fifth of the price. The other Swedish irons are sold at a much lower rate, though said to be manufactured in the same way; and therefore the superiority of the Dannemora iron must be owing to some peculiarity in the ore from which it is smelted. The steel recently made in the Indian steel-works at Chelsea, from Mr. Heath’s Madras iron, rivals that from the hoop L.

The Sheffield furnace for making bar or blistered steel, called the furnace of cementation, is represented in fig. 1054. in a cross section, and in fig. 1055. in a ground plan. The hearth of this oblong quadrangular furnace, is divided by a grate into two parts, upon each side of which there is a chest a, called a trough, made of fire-clay, or fire-tiles. The breadth of the grate varies according to the quality of the fuel. b, b, are air-holes; c, c, flues leading to the chimney d, d. To aid the draught of the smoke and the flame, an opening e, is made in the middle of the flat arch of the furnace. In one of its shorter sides (ends), there are orifices f, f, through which the long bars of iron may be put in and taken out; g, is the door by which the steel-maker enters, in filling or emptying the trough; h, is a proof hole, at which small samples of the steel, in the act of its conversion, may be drawn out. The furnace is built under a conical hood or chimney, from 30 to 50 feet high, for aiding the draught, and carrying off the smoke.

The two chests are built of fire-stone grit. They are 8, 10, or even 15 feet long, and from 26 to 36 inches in width and depth; the lower and smaller they are, the more uniform will the quality of the steel be. A great breadth and height of trough are incompatible with equability of the cementing temperature. The sides are a few inches thick. The space between them is at least a foot wide. They should never rest directly upon the sole of the furnace, but must have their bottom freely played upon by the flame, as well as the sides and top. The degree of heat is regulated by openings in the arch, or upon the long sides of the furnace, which lead to the chimney; as also by the greater or less quantity of air admitted below the grate, as in glass-house furnaces.

The cement consists of ground charcoal (sometimes of soot), mixed with one-tenth of ashes, and some common salt; the charcoal of hard wood being preferred. Ground coke is inadmissible, on account of the sulphur, silica, and clay which it generally contains. Possibly the salt serves to vitrify the particles of silica in the charcoal, and thus to prevent their entering into combination with the steel. As for the ashes, it is difficult to discover their use. The best steel may be made without their presence. The bottom of the trough being covered with two inches of the powder of cementation, the bars are laid along in it, upon their narrow edge, the side bar being one inch from the trough, and the rest being from ¹/₂ to ³/₄ of an inch apart. Above this first layer of iron bars, fully half an inch depth of the powder is spread, then a new series of bars is stratified, and so on till the trough is filled within six inches of the top. This space is partially filled with old cement powder, and is covered with refractory damp sand. Sometimes the trough is filled to the surface with the old cement, and then closely covered with fire-tiles. The bars should never be allowed to touch each other, or the trough. The fire must be carefully urged from 2 to 4 days, till it acquires the temperature of 100° Wedgewood; which must be steadily maintained during the 4, 6, 8, or 10 days requisite for the cementation; a period dependent on the size of the furnace, and which is determined by the examination of the proof pieces, taken out from time to time.

In the front or remote end of the furnace, fig. 1054., a door is left in the outer building, corresponding to a similar one in the end of the interior vault, through which the workman enters for charging the furnace with charcoal and iron bars, as also for taking out the steel after the conversion. Small openings are likewise made in the ends of the chests, through which the extremities of a few bars are left projecting, so that they may be pulled out and examined, through small doors opposite to them in the exterior walls. These tap holes, as they are called, should be placed near the centre of the end stones of the chests, that the bars may indicate the average state of the process. The joinings of the fire-stones are secured with a finely ground Stourbridge clay.

The interval between the two chests (in furnaces containing two, for many have only one,) being covered with an iron platform, the workman stands on it, and sifts a layer of charcoal on the bottom of the chests evenly, about half an inch thick; he then lays a row of bars, cut to the proper length, over the charcoal, about an inch from each other; he next sifts on a second stratum of charcoal-dust, which, as it must serve for the bars above, as well as below, is made an inch thick; thus, he continues to stratify, till the chest be filled within two inches of the top; and he covers the whole with the earthy detritus found at the bottom of grindstone troughs, or any convenient fire-loam. It is obvious that the second series of bars should correspond vertically with the interstices between the first series, and so in succession. The trial-rods are left longer than the others, and their projecting ends are encrusted with fire-clay, or imbedded in sand. The iron platform being removed, and all the openings into the vault closed, the fire is lighted, and very gradually increased, to avoid every risk of cracking the gritstone by too sudden a change of temperature; and the ignition being finally raised to about 100° Wedgewood, but not higher, for fear of melting the metal, must be maintained at a uniform pitch, till the iron have absorbed the desired quantity of carbon, and have been converted as highly as the manufacturer intends for his peculiar object. From six to eight days may be reckoned a sufficient period for the production of steel of moderate hardness, and fit for tilting into shear steel. A softer steel, for saws and springs, takes a shorter period; and a harder steel, for fabricating chisels used in cutting iron, will need longer exposure to the ignited charcoal. But, for a few purposes, such as the bits for boring cast iron, the bars are exposed to two or three successive processes of cementation, and are hence said to be twice or thrice converted into steels. The higher the heat of the furnace, the quicker is the process of conversion.

The furnace being suffered to cool, the workman enters it again, and hands out the steel bars, which being covered with blisters, from the formation and bursting of vesicles on the surface filled with gaseous carbon, is called blistered steel. This steel is very irregular in its interior texture, has a white colour, like frosted silver, and displays crystalline angles and facettes, which are larger the further the cementation has been urged, or the greater the dose of carbon. The central particles are always smaller than those near the surface of the bar.

In such a furnace as the above, twelve tons of bar iron may be converted at a charge. But other furnaces are constructed with one chest, which receives six or eight tons at a time; the small furnaces, however, consume more fuel in proportion than the larger.

The absorption and action of the carbonaceous matter, to the amount of about a half per cent., occasions fissures and cavities in the substance of the blistered bars, which render the steel unfit for any useful purpose in tool-making, till it be condensed and rendered uniform by the operation of tilting, under a powerful hammer driven by machinery. See Iron.[59]

The heads of the tilt-hammers for steel weigh from one and a half to two hundred pounds. Those in the neighbourhood of Sheffield are much simpler than the one referred to in the note. They are worked by a small water-wheel, on whose axis is another wheel, bearing a great number of cams or wipers on its circumference, which strike the tail of the hammer in rapid succession, raise its head, and then let it fall smartly on the hot metal rod, dexterously presented on its several parts to the anvil beneath it, by the workman. The machinery is adapted to produce from 300 to 400 blows per minute; which on this plan requires an undue and wasteful velocity of the float-boards. Were an intermediate toothed wheel substituted between the water-wheel and the wiper-wheel, so that while the former made one turn, the latter might make three, a much smaller force of water would do the work. The anvils of the tilt-hammer are placed nearly on a level with the floor of the mill-house; and the workman sits in a fosse, dug on purpose, in a direction perpendicular to the line of the helve, on a board suspended from the roof of the building by a couple of iron rods. On this swinging seat, he can advance or retire with the least impulse of his feet, pushing forward the steel bar, or drawing it back with equal rapidity and convenience.

At a small distance from each tilt, stands the forge-hearth, for heating the steel. The bellows for blowing the fire are placed above-head, and are worked by a small crank fixed on the end of the axis of the wheel, the air being conveyed by a copper pipe down to the nozzle. Each workman at the tilt has two boys in attendance, to serve him with hot rods, and to take them away after they are hammered. In small rods, the bright ignition originally given at the forge soon declines to darkness; but the rapid impulsions of the tilt revive the redness again in all the points near the hammer; so that the rod, skilfully handled by the workman, progressively ignites where it advances to the strokes. Personal inspection alone can communicate an adequate idea of the precision and celerity with which a rude steel rod is stretched and fashioned into an even, smooth, and sharp-edged prism, under the operation of the tilt-hammer. The heat may be clearly referred to the prodigious friction among the particles of so cohesive a metal, when they are made to slide so rapidly over each other in every direction during the elongation and squaring of the rod.

2. Shear steel derives its name from the accidental circumstance of the shears for dressing woollen cloth being usually forged from it. It is made by binding into a bundle, with a slender steel rod, four parallel bars of blistered steel, previously broken into lengths of about 18 inches, including a fifth of double length, whose projecting end may serve as a handle. This faggot, as it is called, is then heated in the forge-hearth to a good welding heat, being sprinkled over with sand to form a protecting film of iron slag, carried forthwith to the tilt, and notched down on both sides to unite all the bars together, and close up every internal flaw or fissure. The mass being again heated, and the binding rings knocked off, is drawn out into a uniform rod of the size required. Manufacturers of cutlery are in the habit of purchasing the blistered bars at the conversion furnaces, and sending them to tilt-mills to have them drawn out to the proper size, which is done at regular prices to the trade; from 5 to 8 per cent. discount being allowed on the rude bars for waste in the tilting. The metal is rendered so compact by the welding and hammering, as to become susceptible of a much finer polish than blistered steel can take; while the uniformity of its body, tenacity, and malleability are at the same time much increased; by which properties it becomes well adapted for making table knives and powerful springs, such as those of gun-locks. The steel is also softened down by this process, probably from the expulsion of a portion of its carbon during the welding and subsequent heats; and if these be frequently or awkwardly applied, it may pass back into common iron.

3. Cast steel is made by melting, in the best fire-clay crucibles, blistered steel, broken down into small pieces of convenient size for packing; and as some carbon is always dissipated in the fusion, a somewhat highly converted steel is used for this purpose. The furnace is a square prismatic cavity, lined with fire-bricks, 12 inches in each side, and 24 deep, with a flue immediately under the cover, 3¹/₂ inches by 6, for conducting the smoke into an adjoining chimney of considerable height. In some establishments a dozen such furnaces are constructed in one or two ranges, their tops being on a level with the floor of the laboratory, as in brass-foundries, for enabling the workmen more conveniently to inspect, and lift out, the crucibles with tongs. The ash-pits terminate in a subterraneous passage, which supplies the grate with a current of cool air, and serves for emptying out the ashes. The crucible, stands of course, on a sole-piece of baked fire-clay; and its mouth is closed with a well-fitted lid. Sometimes a little bottle-glass, or blast-furnace slag, is put into the crucible, above the steel pieces, to form a vitreous coating, that may thoroughly exclude the air from oxidizing the metal. The fuel employed in the cast-steel furnace is a dense coke, brilliant and sonorous, broken into pieces about the size of an egg, one good charge of which is sufficient. The tongs are furnished at the fire end with a pair of concave jaws, for embracing the curvature of the crucible, and lifting it out whenever the fusion is complete. The lid is then removed, the slag or scoriÆ cleared away, and the liquid metal poured into cast-iron octagonal or rectangular moulds, during which it throws out brilliant scintillations.

Cast-steel works much harder under the hammer than shear steel and will not, in its usual state, bear much more than a cherry-red heat without becoming brittle; nor can it bear the fatigue incident to the welding operation. It may, however, be firmly welded to iron, through the intervention of a thin film of vitreous boracic acid, at a moderate degree of ignition. Cast steel, indeed, made from a less carburetted bar steel, would be susceptible of welding and hammering at a higher temperature; but it would require a very high heat for its preparation in the crucible.

Iron may be very elegantly plated with cast steel, by pouring the liquid metal from the crucible into a mould containing a bar of iron polished on one face. In this circumstance the adhesion is so perfect as to admit of the two metals being rolled out together; and in this way the chisels of planes and other tools may be made, at a moderate rate and of excellent quality, the cutting-edge being formed in the steel side. Such instruments combine the toughness of iron with the hardness of steel.

For correcting the too high carbonization of steel, or equalizing the too highly converted exterior of a bar with the softer steel of the interior, the metal requires merely to be imbedded, at a cementing heat, in oxide of iron or manganese; the oxygen of which soon abstracts the injurious excess of carbon, so that the outer layers may be even converted into soft iron, while the axis continues steely; because the decarbonizing advances far more rapidly than the carbonizing.

Fig. 1056. represents the mould for making crucibles for the cast-steel works. M, M, is a solid block of wood, to support the two-handled outside mould N, N. This being rammed full of the proper clay dough or compost (see Crucible), the inner mould is to be then pressed vertically into it, till it reaches the bottom P, being directed and facilitated in its descent by the point K. A cord passes through O, by which the inner mould is suspended over a pulley, and guided in its motions.

When a plate of polished steel is exposed to a progressive heat, it takes the following colours in succession: 1. a faint yellow; 2. a pale straw-colour; 3. a full yellow; 4. a brown yellow; 5. a brown with purple spots; 6. a purple; 7. a bright blue; 8. a full blue; 9. a dark blue, verging on black; after which the approach to ignition supersedes all these colours. If the steel plate has been previously hardened by being dipped in cold water or mercury when red-hot, then those successive shades indicate or correspond to successive degrees of softening or tempering. Thus, No. 1. suits the hard temper of a lancet, which requires the finest edge, but little strength of metal; No. 2. a little softer, for razors and surgeons’ amputating instruments; No. 3. somewhat more toughness, for penknives; No. 4. for cold chisels and shears for cutting iron; No. 5. for axes and plane-irons; No. 6. for table knives and cloth shears; No. 7. for swords and watch springs; No. 8. for small fine saws and daggers; No. 9. for large saws, whose teeth need to be set with pliers, and sharpened with a file. After ignition, if the steel be very slowly cooled, it becomes exceedingly soft, and fit for the engraver’s purposes. Hardened steel may be tempered to the desired pitch, by plunging it in metallic baths heated to the proper thermometric degree, as follows: for No. 1. 430° Fahr.; No. 2. 450°; No. 3. 470°; No. 4. 490°; No. 5. 510°; No. 6. 530°; No. 7. 550°; No. 8. 560°; No. 9. 600°.

Small steel tools are most frequently tempered, after hardening, by covering their surface with a thin coat of tallow, and heating them in the flame of a candle till the tallow diffuses a faint smoke, and then thrusting them into the cold tallow. Rinman long ago defined steel to be any kind of iron which, when heated to redness, and then plunged in cold water, becomes harder. But several kinds of cast iron are susceptible of such hardening. Every malleable and flexible iron, however, which may be hardened in that way, is a steel. Moreover, steel may be distinguished from pure iron by its giving a dark-gray spot when a drop of dilute nitric acid is let fall on its surface, while iron affords a green one. Exposed to the air, steel rusts less rapidly than iron; and the more highly carburetted, the more slowly does it rust, and the blacker is the spot left by an acid.

After hardening, steel seems to be quite a different body; even its granular texture becomes coarser or finer according to the degree of heat to which it was raised; it grows so hard as to scratch glass, and resist the keenest file, while it turns exceedingly brittle. When a slowly cooled steel rod is forged and filed, it becomes capable of affording agreeable and harmonious sounds by its vibrations; but hard-tempered steel affords only dull deafened tones, like those emitted by a cracked instrument.

The good quality of steel is shown by its being homogeneous; being easily worked at the forge; by its hardening and tempering well; by its resisting or overcoming forces; and by its elasticity. To ascertain the first point, the surface should be ground and polished on the wheel; when its lustre and texture will appear. The second test requires a skilful workman to give it a heat suitable to its nature and state of conversion. The size and colour of the grain are best shown by taking a bar forged into a razor form; hardening and tempering it; and then breaking off the thin edge in successive bits with a hammer and anvil. If it had been fully ignited only at the end, then, after the hardening, it will display, on fracture, a succession in the aspect of its grains from that extremity to the other; as they are whiter and larger at the former than the latter. The other qualities become manifest on filing the steel; using it as a chisel for cutting iron; or bending it under a heavy weight.

Much interest was excited a few years back by the experiments of Messrs. Stodart and Faraday on the alloys of steel with silver, platinum, rhodium, and iridium. Steel refuses to take up in fusion more than one five-hundreth part of silver; but with this minute quantity of alloy, it is said to bear a harder temper, without losing its tenacity. When pure iron is substituted for steel, the alloys so formed are much less subject to oxidation in damp air than before. With three per cent. of iridium and osmium, an alloy was obtained which had the property of tempering like steel, and of remaining clean and bright, in circumstances when simple iron became covered with rust. “Upon the whole,” says the editor of the Quarterly Journal of Science, giving a report of these experiments in his 14th volume, p. 378, “though we consider these researches upon the alloys of steel as very interesting, we are not sanguine as to their important influence upon the improvement of the manufacture of cutlery, and suspect that a bar of the best ordinary steel, selected with precaution, and most carefully forged, wrought, and tempered, under the immediate inspection of the master, would afford cutting instruments as perfect and excellent as those composed of wootz, or of the alloys.”

Case-hardening of iron, is a process for converting a thin film of the outer surface into steel, while the interior remains as before. Fine keys are generally finished in this way. See Case-hardening.

So great is the affinity of iron for carbon, that, in certain circumstances, it will absorb it from carburetted hydrogen, or coal-gas, and thus become converted into steel. On this principle, Mr. Macintosh of Glasgow obtained a patent for making steel. His furnace consists of one cylinder of bricks built concentrically within another. The bars of iron are suspended in the innermost, from the top; a stream of purified coal-gas circulates freely round them, entering below and escaping slowly above, while the bars are maintained in a state of bright ignition by a fire burning in the annular space between the cylinders. The steel so produced is of excellent quality; but the process does not seem to be so economical as the ordinary cementation with charcoal powder.

Damasking of steel, is the art of giving to sabre blades a variety of figures in the style of watering. See Damascus Blades.

Several explanations have been offered of the change in the constitution of steel, which accompanies the tempering operation; but none of them seems quite satisfactory. It seems to be probable that the ultimate molecules are thrown by the sudden cooling into a constrained state, so that their poles are not allowed to take the position of strongest attraction and greatest proximity; and hence the mass becomes hard, brittle, and somewhat less dense. An analogous condition may be justly imputed to hastily cooled glass, which, like hardened steel, requires to be annealed by a subsequent nicely graduated heat, under the influence of which the particles assume the position of repose, and constitute a denser, softer, and more tenacious body. The more sudden the cooling of ignited steel, the more unnatural and constrained will be the distribution of its particles, and also the more refractory, an effect produced by plunging it into cold mercury. This excess of hardness is removed in any required degree by judicious annealing or tempering. The state of the carbon present in the steel may also be modified by the rate of refrigeration, as Mr. Karsten and M. BrÉant conceive happens with cast iron and the damask metal. If the uniform distribution and combination of the carbon through the mass, determine the peculiarity of white cast iron, which is a hard and brittle substance, and if its transition to the dark-gray and softer cast metal be effected by a partial formation of plumbago during slow cooling, why may not something similar be supposed to occur with steel, an analogous compound?

Mr. Oldham, printing engineer of the Bank of England, who has had great experience in the treatment of steel for dies and mills, says that, for hardening it, the fire should never be heated above the redness of sealing-wax, and kept at that pitch for a sufficient time. On taking it out, he hardens it by plunging it, not in water, but in olive oil, or rather naphtha, previously heated to 200° F. It is kept immersed only till the ebullition ceases, then instantly transferred into cold spring water, and kept there till quite cold. By this treatment the tools come out perfectly clean, and as hard as it is possible to make cast-steel, while they are perfectly free from cracks, flaws, or twist. Large tools are readily brought down in temper by being suspended in the red-hot muffle till they show a straw-colour; but for small tools, he prefers plunging them in the oil heated to 400 degrees; and leaves them in till they become cold.Mr. Oldham softens his steel dies by exposing them to ignition for the requisite time, imbedded in a mixture of chalk and charcoal.

“The common mode of softening steel,” says Mr. Baynes, “is to put it into an iron case, surrounded with a paste made of lime, cow’s gall, and a little nitre and water; then to expose the case to a slow fire, which is gradually increased to a considerable heat, and afterwards allowed to go out, when the steel is found to be soft and ready for the engraver.”[60]

Indian steel, or wootz.—The wootz ore consists of the magnetic oxide of iron, united with quartz, in proportions which do not seem to differ much, being generally about 42 of quartz and 58 of magnetic oxide. Its grains are of various size, down to a sandy texture. The natives prepare it for smelting by pounding the ore, and winnowing away the stony matrix, a task at which the Hindoo females are very dexterous. The manner in which iron ore is smelted and converted into wootz or Indian steel, by the natives at the present day, is probably the very same that was practised by them at the time of the invasion of Alexander; and it is a uniform process, from the Himalaya mountains to Cape Comorin. The furnace or bloomery in which the ore is smelted, is from 4 to 5 feet high; it is somewhat pear-shaped, being about 2 feet wide at bottom, and one foot at top; it is built entirely of clay, so that a couple of men can finish its erection in a few hours, and have it ready for use the next day. There is an opening in front about a foot or more in height, which is built up with clay at the commencement, and broken down at the end, of each smelting operation. The bellows are usually made of a goat’s skin, which has been stripped from the animal without ripping open the part covering the belly. The apertures at the legs are tied up, and a nozzle of bamboo is fastened in the opening formed by the neck. The orifice of the tail is enlarged and distended by two slips of bamboo. These are grasped in the hand, and kept close together in making the stroke for the blast; in the returning stroke they are separated to admit the air. By working a bellows of this kind with each hand, making alternate strokes, a pretty uniform blast is produced. The bamboo nozzles of the bellows are inserted into tubes of clay, which pass into the furnace at the bottom corners of the temporary wall in front. The furnace is filled with charcoal, and a lighted coal being introduced before the nozzles, the mass in the interior is soon kindled. As soon as this is accomplished, a small portion of the ore, previously moistened with water, to prevent it from running through the charcoal, but without any flux whatever, is laid on the top of the coals, and covered with charcoal to fill up the furnace.

In this manner ore and fuel are supplied; and the bellows are urged for 3 or 4 hours, when the process is stopped; and the temporary wall in front being broken down, the bloom is removed by a pair of tongs from the bottom of the furnace. It is then beaten with a wooden mallet, to separate as much of the scoriÆ as possible from it, and, while still red-hot, it is cut through the middle, but not separated, in order merely to show the quality of the interior of the mass. In this state it is sold to the blacksmiths, who make it into bar iron. The proportion of such iron made by the natives from 100 parts of ore, is about 15 parts. In converting the iron into steel, the natives cut it into pieces, to enable it to pack better in the crucible, which is formed of refractory clay, mixed with a large quantity of charred husk of rice. It is seldom charged with more than a pound of iron, which is put in with a proper weight of dried wood chopped small, and both are covered with one or two green leaves; the proportions being in general 10 parts of iron to 1 of wood and leaves. The mouth of the crucible is then stopped with a handful of tempered clay, rammed in very closely, to exclude the air. The wood preferred is the Cassia auriculata, and the leaf that of the Asclepias gigantea, or the Convolvulus laurifolius. As soon as the clay plugs of the crucibles are dry, from 20 to 24 of them are built up in the form of an arch, in a small blast furnace; they are kept covered with charcoal, and subjected to heat urged by a blast for about two hours and a half, when the process is considered to be complete. The crucibles being now taken out of the furnace and allowed to cool, are broken, and the steel is found in the form of a cake, rounded by the bottom of the crucible. When the fusion has been perfect, the top of the cake is covered with striÆ, radiating from the centre, and is free from holes and rough projections; but if the fusion has been imperfect, the surface of the cake has a honeycomb appearance, with projecting lumps of malleable iron. On an average, four out of five cakes are more or less defective. These imperfections have been tried to be corrected in London by re-melting the cakes, and running them into ingots; but it is obvious, that when the cakes consist partially of malleable iron and of unreduced oxide, simple fusion cannot convert them into good steel. When care is taken, however, to select only such cakes as are perfect, to re-melt them thoroughly, and tilt them carefully into rods, an article has been produced which possesses all the requisites of fine steel in an eminent degree. In the Supplement to the EncyclopÆdia Britannica, article Cutlery, the late Mr. Stodart, of the Strand, a very competent judge, has declared “that for the purposes of fine cutlery, it is infinitely superior to the best English cast steel.”

The natives prepare the cakes for being drawn into bars by annealing them for several hours in a small charcoal furnace, actuated by bellows; the current of air being made to play upon the cakes while turned over before it; whereby a portion of the combined carbon is probably dissipated, and the steel is softened; without which operation the cakes would break in the attempt to draw them. They are drawn by a hammer of a few pounds weight.

The natives weld two pieces of cast steel, by giving to each a sloping face, jagged all over with a small chisel; then applying them with some calcined borax between, and tying them together with a wire, they are brought to a full red heat, and united by a few smart blows of a hammer.

The ordinary bar iron of Sweden and England, when converted by cementation into steel, exhibits upon its surface numerous small warty points, but few or no distinct vesicular eruptions; whereas the Dannemora and the Ulverston steels present, all over the surface of the bars, well raised blisters, upwards of three-eighths of an inch in diameter horizontally, but somewhat flattened at top. Iron of an inferior description, when highly converted in the cementing-chest, becomes gray on the outer edges of the fracture; while that of Dannemora acquires a silvery colour and lustre on the edges, with crystalline facets within. The highly converted steel is used for tools that require to be made very hard; the slightly converted, for softer and more elastic articles, such as springs and sword blades.

STILL (Alambic, Fr.; Blase, Germ.); is a chemical apparatus, for vaporizing liquids by heat in one part, called the cucurbit, and condensing the vapours into liquids in another part, called the refrigeratory; the general purpose of both combined being to separate the more volatile fluid particles from the less volatile. In its simplest form, it consists of a retort and a receiver, or of a pear-shaped matrass and a capital, furnished with a slanting tube for conducting away the condensed vapours in drops; whence the term still, from the Latin verb stillare, to drop. Its chief employment in this country being to eliminate alcohol, of greater or less strength, from fermented wash, I shall devote this article to a description of the stills best adapted to the manufacture of British spirits, referring to chemical authors[62] for those fitted for peculiar objects.

In respect of rapidity and extent of work, stills had attained to an extraordinary pitch of perfection in Scotland about thirty years ago, when legislative wisdom thought fit to levy the spirits duty, per annum, from each distiller, according to the capacity of his still. It having been shown, in a report presented to the House of Commons in 1799, that an 80-gallon still could be worked off in eight minutes, this fact was made the basis of a new fiscal law, on the supposition that the maximum of velocity had been reached. But, instigated by the hopes of enormous gains at the expense of the revenue, the distillers soon contrived to do the same thing in three minutes, by means of broad-bottomed shallow stills, with stirring-chains, and lofty capitals. In the year 1815, that preposterous law, which encouraged fraud and deteriorated the manufacture, was repealed. The whiskey duties having been since levied, independently of the capacity of the still, upon the quantity produced, such rapid operations have been abandoned, and processes of economy in fuel, and purity in product, have been sought after.

One of the greatest improvements in modern distilleries, is completing the analysis of crude spirit at one operation. Chemists had been long familiar with the contrivance of Woulfe, for impregnating with gaseous matter, water contained in a range of bottles; but they had not thought of applying that plan to distillation, when Edouard Adam, an illiterate workman of Montpellier, after hearing accidentally a chemical lecture upon that apparatus, bethought himself of converting it into a still. He caused the boiling-hot vapours to chase the spirits successively out of one bottle into another, so as to obtain in the successive vessels alcohol of any desired strength and purity, “at one and the same heat.” He obtained a patent for this invention in 1801, and was soon afterwards enabled, by his success on the small scale, to set up in his native city a magnificent distillery, which excited the admiration of all the practical chemists of that day. In November, 1805, he obtained a certificate of certain improvements for extracting from wine, at one process, the whole of its alcohol. Adam was so overjoyed, after making his first experiments, that he ran about the streets of Montpellier, telling every body of the surprising results of his invention. Several competitors soon entered the lists with him, especially Solimani, professor of chemistry in that city, and Isaac Berard, distiller in the department of Gard; who, having contrived other forms of continuous stills, divided the profits with the first inventor.

The principles of spirituous distillation may be stated as follows:—The boiling point of alcohol varies with its density or strength, in conformity with the numbers in the following table:—

See also the table under Alcohol, page 16.

Hence, the lower the temperature of the spirituous vapour which enters the refrigeratory apparatus, the stronger and purer will the condensed spirit be; because the offensive oils, which are present in the wash or wine, are less volatile than alcohol, and are brought over chiefly with the aqueous vapour. A perfect still should, therefore, consist of three distinct members; first, the cucurbit, or kettle; second, the rectifier, for intercepting more or less of the watery and oily particles; and third, the refrigerator, or condenser of the alcoholic vapours.

These principles are illustrated in the construction of the still represented in figs. 1057, 1058, 1059, 1060, 1061.; in which the resources of the most refined French stills are combined with a simplicity and solidity suited to the grain distilleries of the United Kingdom. Three principal objects are obtained by the arrangement here shown; first, the extraction from fermented wort or wine, at one operation, of a spirit of any desired cleanness and strength; second, great economy of time, labour, and fuel; third, freedom from all danger of blowing up or boiling over, by mismanaged firing. When a combination of water, alcohol, and essential oil, in the state of vapour, is passed upwards through a series of winding passages, maintained at a determinate degree of heat, between 170° and 180°, the alcohol alone, in any notable proportion, will retain the elastic form, and will proceed onwards into the refrigeratory tube, in which the said passages terminate; while the water and the oil will be in a great measure condensed, arrested, and thrown back into the body of the still, to be discharged with the effete residuum.

The system of passages or channels, represented in fig. 1058., is so contrived as to bring the mingled vapours which rise from the alembic a, into ample and intimate contact with metallic surfaces, maintained, in a water-bath, at a temperature self-regulated by a heat-governor. See Thermostat.

The neck of the alembic tapers upwards, as shown at b, fig. 1057.; and at c, fig. 1058., it enters the bottom, or ingress vestibule, of the rectifier c, f. f is its top or egress vestibule, which communicates with the bottom one by parallel cases or rectangular channels d, d, d, of which the width is small, compared with the length and height. These cases are open at top and bottom, where they are soldered or riveted into a general frame within the cavity, enclosed by the two covers f, c, which are secured round their edges e, e, e, e, with bolts and packing. Each case is occupied with a numerous series of shelves or trays, placed at small distances over each other, in a horizontal or slightly inclined position, of which a side view is given in fig. 1059., and cross sections at d, d, d, fig. 1058. Each shelf is turned up a little at the two edges, and at one end, but sloped down at the other end, that the liquor admitted at the top may be made to flow slowly backwards and forwards in its descent through the system of shelves or trays, as indicated by the darts and spouts in fig. 1059. The shelves of each case are framed together by two or more vertical metallic rods, which pass down through them, and are fixed to each shelf by solder, or by screw-nuts. By this means, if the cover f, be removed, the sets of shelves may be readily lifted out of the cases and cleaned; for which reason they are called movable.

The intervals i, i, i, fig. 1058., between the cases, are left for the free circulation of the water contained in the bath-vessel g, g; these intervals being considerably narrower than the cases.

Fig. 1060. represents in plan the surface of the rectifying cistern, shown in two different sections in figs. 1058. and 1059. h, k, figs. 1058. and 1060., is the heat-governor, shaped somewhat like a pair of tongs. Each leg is a compound bar, consisting of a flat bar or ruler of steel, and one of brass alloy, riveted facewise together, having their edges up and down. The links, at k, are joined to the free ends of these compound bars, which, receding by increase and approaching by decrease of temperature, act by a lever on the stopcock l, fixed to the pipe of a cold-water back, and are so adjusted by a screw-nut, that whenever the water in the bath vessel g, g, rises above the desired temperature, cold water will be admitted, through the stopcock l, and pipe n, into the bottom of the cistern, and will displace the over-heated water by the overflow-pipe m. Thus a perfect equilibrium of caloric may be maintained, and alcoholic vapour of correspondent uniformity transmitted to the refrigeratory.

Fig. 1061. is the cold condenser, of similar construction to the rectifier, fig. 1058.; only the water cells should be here larger in proportion to the vapour channels d, d. This refrigeratory system will be found very powerful, and it presents the great advantage of permitting its interior to be readily inspected and cleansed. It is best made of laminated tin, hardened with a little copper alloy.

The mode of working the preceding apparatus will be understood by the following instructions. Into the alembic, a, let as much fermented liquor be admitted as will protect its bottom from being injured by the fire, reserving the main body in the charging-back. Whenever the ebullition in the alembic has raised the temperature of the water-bath g, g, to the desired pitch, whether that be 170°, 175°, or 180°, the thermostatic instrument is to be adjusted by its screw-nut, and then the communication with the charging-back is to be opened by moving the index of the stopcock o, over a proper portion of its quadrantal arch. The wash will now descend in a slender equable stream, through the pipe o, f, thence spread into the horizontal tube p, p, and issue from the orifices of distribution, as seen in the figure, into the respective flat trays or spouts. The manner of its progress is seen for one set of trays, in fig. 1059. The direction of the stream in each shelf is evidently the reverse of that in the shelf above and below it; the turned-up end of one shelf corresponding to the discharge slope of its neighbour.

By diffusing the cool wash or wine in a thin film over such an ample range of surfaces, the constant tendency of the bath to exceed the proper limit of temperature is counteracted to the utmost, without waste of time or fuel; for the wash itself, in transitu, becomes boiling-hot, and experiences a powerful steam distillation. By this arrangement a very moderate influx of cold water, through the thermostatic stopcock, suffices to temper the bath; such an extensive vaporization of the wash producing a far more powerful refrigerant influence than its simple heating to ebullition. It deserves to be remarked, that the maximum distillatory effect, or the bringing over the greatest quantity of pure spirits in the least time, and with the least labour and fuel, is here accomplished without the least steam pressure in the alembic; for the passages are all pervious to the vapour; whereas, in almost every wash-still heretofore contrived for similar purposes, the spirituous vapours must force their way through successive layers of liquid, the total pressure produced by which causes undue elevation of temperature, and obstruction to the process. Whatever supplementary refrigeration of the vapours in their passage through the bath may be deemed proper, will be administered by the thermostatic regulator.

Towards the end of the process, after all the wash has entered the alembic, it may be sometimes desirable, for the sake of despatch, to modify the thermostat, by its adjusting-screw, so that the bath may take a higher temperature, and allow the residuary feints to run rapidly over, into a separate cistern. This weak fluid may be pumped back into the alembic, as the preliminary charge of a fresh operation.

The above plan of a water-bath regulated by the thermostat, may be used simply as a rectifying cistern, without transmitting the spirit or wash down through it. The series of shelves will cause the vapours from the still to impinge against a most extensive system of metallic surfaces, maintained at a steady temperature, whereby their watery and crude constituents will be condensed and thrown back, while their fine alcoholic particles will proceed forwards to the refrigeratory. Any ordinary still may be readily converted into this self-rectifying form, by merely interposing the cistern, fig. 1058., between the alembic and the worm-tub. The leading novelty of the present invention is the movable system of shelves or trays, enclosed in metallic cases, separated by water, combined with the thermostatic regulator. By this combination, any quality of spirits may be procured at one step from wash or wine, by an apparatus, simple, strong and easily kept in order.

The empyreumatic taint which spirits are apt to contract from the action of the naked fire on the bottom of the still, may be entirely prevented by the use of a bath of potash lye, p, p, fig. 1057.; for thus a safe and effectual range of temperature, of 300° F., may be conveniently obtained. The still may also be used without the bath vessel.

Mr. D. T. Shears, of Southwark, obtained a patent in March, 1830, for certain improvements and additions to stills, which are ingenious. They are founded upon a previous patent, granted to Joseph Corty, in 1818; a section of whose contrivance is shown in fig. 1062., consisting of a first still a, a second still b, a connecting tube c, from the one end to the other, and the tube d, which leads from the second still-head down through the bent tube e, e, to the lower part of the condensing apparatus.

The original improvements described under Corty’s patent, consisted further, in placing boxes f, f, f, of the condensing apparatus in horizontal positions, and at a distance from each other, in order that the vapour might ascend through them, for the purpose of discharging the spirit by the top tube g, and pipe h, into the worm, in a highly rectified or concentrated state. In each of the boxes f, there is a convex plate or inverted dish i, i, i, and the vapour in rising from the tube e, strikes against the concave or under part of the first dish, and then escapes round its edges, and over its convex surface, to the under part of the second dish, and so on to the top, the condensed part of the vapour flowing down again into the still, and the spirit passing off by the pipe h, at top; and as the process of condensation will be assisted by cooling the vapour as it rises, cold water is made to flow over the tops of the boxes f, from a cock k, and through small channels or tubes on the sides of the boxes, and is ultimately discharged by the pipe l, at bottom.

Fig. 1063. represents a peculiarly shaped tube a, through which the spirit is described as passing after leaving the end of the worm at b, which tube is open to the atmospheric air at z; c, is the passage through which the carbonic acid gas is described as escaping into the vessel of water d.

Now the improvements claimed under the present patent, are exhibited in figs. 1064, 1065, and 1066. Fig. 1064. represents the external appearance of a still, the head of which is made very capacious, to guard against over-boiling by any mismanagement of the fire; fig. 1065. is the same, partly in section. On the top of the still-head is formed the first-described rectifying apparatus, or series of condensing boxes. The vapour from the body of the still filling the head, meets with the first check from the dish or lower vessel i, and after passing under its edges, ascends and strikes against the lower part of the second dish or vessel i, and so on, till it ultimately leaves the still-head by the pipe at top.

This part of the apparatus is slightly altered from the former, by the substitution of hollow convex vessels, instead of the inverted dishes before described, which vessels have rims descending from their under surfaces, for the purpose of retaining the vapour. The cold water, which, as above described, flowed over the tops of the boxes f, for the purpose of cooling them, now flows also through the hollow convex vessels i, within the boxes, and by that means greatly assists the refrigerating process, by which the aqueous parts of the vapour are more readily condensed, and made to fall down and flow back again into the body of the still, while the spirituous parts pass off at top to the worm, in a very high state of rectification.

After the water employed for the refrigeration has passed over all the boxes, and through all the vessels, it is carried off by the pipe m, through the vessel n, called the wash-heater; that is, the vessel in which the wash is placed previous to introducing it into the still. The pipe m, is coiled round in the lower part of the vessel n, in order that the heated water may communicate its caloric to the wash, instead of losing the heat by allowing the water to flow away. After the heated water has made several turns round the wash heater, it passes out at the curved pipe o, which is bent up, in order to keep the coils of the pipe within always full of water.

Instead of the coiled pipe n, last described, the patentee proposes sometimes to pass the hot water into a chamber in a tub or wooden vessel, as at n, in fig. 1061., in which the wash to be heated occupies the upper part of the vessel, and is separated from the lower part by a thin metallic partition.

The swan-neck h, figs. 1064. and 1065., which leads from the head of the still, conducts the spirit from the still through the wash-heater, where it becomes partially cooled, and gives out its heat to the wash; and from thence the spirit passes to the worm tub, and being finally condensed, is passed through a safety tube, as (fig. 1058.) before described, and by the funnel is conducted into the cask below.

Should any spirit rise in the wash-heater during the above operation, it will be carried down to the worm by the neck p, and coiled pipe, and discharged at its lower end; or it may be passed into the still-head, as shown in fig. 1062.

A patent was obtained by Mr. Æneas Coffey, in August, 1830, for a still, which has been since mounted in several distilleries. It is economical in fuel, labour, and time, but is said not to produce a clean spirit, without peculiar attention.

The apparatus is represented in fig. 1067. a, b, c, d, is a sectional view of that part of the still wherein the wash is deprived of its alcohol, and the vapours analyzed. It is described as consisting of a chamber or vessel a, with the vertical chamber b, c, placed above it; the lower half of this chamber is divided into compartments by horizontal plates e, e, e, of thin copper or other metal; each of these plates is turned down at one side, until it nearly touches the plate next underneath it, as shown in the figure; thus leaving a passage throughout the whole of them, by which any liquid falling on the top plate may descend into the next under it, and from that to the third, and so on, from plate to plate, at the alternate ends, until it arrives at the last plate, wherein it falls into the vessel a, by the pipe f; each of these plates is furnished with several light valves, opening upwards, through which any steam or vapour may ascend; it may also be perforated with holes, but they must not be so numerous or so large as to allow of all the steam passing through them without raising the valves; c, is a pipe by which the alcoholic vapour, after it has been analyzed, and has acquired the proper strength, is conducted into the vessel d, which is made perfectly close; the vapour will here be condensed on the surface of the pipe g, g, g; from this chamber it will descend in a liquid state into the pipe h, whence it may be conducted to a worm or refrigerator, to be cooled in the ordinary way; i, is a vessel through which the spent wash flows, after being operated upon in the distilling apparatus, and is discharged in a state of ebullition; j, is a vessel or chamber containing the wash to be distilled. A force pump may be substituted, to force the wash through the pipes k, and distilling apparatus, with the velocity required.

The patentee states that it is requisite the wash should be passed through the pipe k, with sufficient velocity and force, so as to prevent the deposition of sediment in the pipe; the wash in its passage through the pipe k, will gradually become increased in temperature as it passes through the spent wash in the chamber, and the close vessel d, until it is discharged nearly at the boiling point on the upper plate in the chamber, where it comes in contact with the vapours arising from the vessel a.

It is to be observed, that the wort does not reach the boiling point while in the pipe k, k; to ascertain which, a thermometer is placed on the pipe, and by increasing or diminishing the quantity of wash, its temperature may be regulated. The wash, after being discharged from the pipe k, descends from plate to plate as before mentioned, at which time a supply of steam from a boiler, or generator is admitted into the apparatus, through the pipe.

The lower part of this pipe in the vessel a, is pierced with a number of small holes, so as to spread the steam over the vessel; it then rises upwards, passing through the plate by the small holes and valves, and through the stratum or sheet of wash flowing over them; the wash, as it descends, gives out a portion of its alcohol to the steam, as it passes over every plate, until it is entirely deprived of its spirit, which it will generally do by the time it arrives at the 7th or 8th plate; but it is better to employ a greater number, to guard against accidents or neglect.

A small steam pipe rises from the chamber a, with its upper end opening into the box or chamber; into this chamber the end of a worm projects from the cistern of cold water; the steam rising up the pipe is nearly all condensed in the worm, and flows back into the chamber a, by the pipe. The small portion of the steam uncondensed, is allowed to escape at the upper end of the worm, and the flame of a small lamp or taper is to be constantly kept over the orifice; when, should the least quantity of alcohol descend with the wash into the chamber a, it will rise with the steam through the pipe and worm, and immediately take fire from the flame of the lamp or taper, thereby warning the attendant to increase the supply of steam or diminish the quantity of wash, as may seem necessary.

I shall conclude this article with a description of the cheap still which is commonly employed by the chemists in Berlin for rectifying alcohol. a, is the ash-pit; b, the fireplace; c, c, the flues, which go spirally round the sides of the cucurbit d; e, the capital, made of block tin, and furnished with a brass edge, which fits tight to a corresponding edge on the mouth of d; f, f, the slanting pipes of the capital; g, the oval refrigeratory, made of copper; h, the water-gauge glass tube; i, a stopcock for emptying the vessel; k, do., for drawing off the hot water from the surface; l, tube for the supply of cold water. A double cylinder of tin is placed in the refrigeratory, of which the outer one m, m, stands upon three feet, and is furnished with a discharge pipe n. The inner one o, o, which is open above, receives cold water through the pipe p, and lets the warm water flow off through the short tube q, into the refrigeratory. In the narrow space between the two cylinders, the vapours proceeding from the capital are condensed, and pass off in the liquid state through n. The refrigeratory is made oval, in order to receive two condensers alongside of each other in the line of the longer axis; though only one, and that in the middle, is represented in the figure.

STOCKING MANUFACTURE. See Hosiery.

STONE, is earthy matter, condensed into so hard a state as to yield only to the blows of a hammer, and therefore well adapted to the purposes of building. Such was the care of the antients to provide strong and durable materials for their public edifices, that but for the desolating hands of modern barbarians, in peace and in war, most of the temples and other public monuments of Greece and of Rome would have remained perfect at the present day, uninjured by the elements during 2000 years. The contrast, in this respect, of the works of modern architects, especially in Great Britain, is very humiliating to those who boast so loudly of social advancement; for there is scarcely a public building of recent date, which will be in existence one thousand years hence. Many of the most splendid works of modern architecture are hastening to decay, in what may be justly called the very infancy of their existence, if compared with the date of those erected in antient Italy, Greece, and Egypt. This is remarkably the case with the three bridges of London, Westminster, and Blackfriars; the foundations of which began to perish most visibly in the very lifetime of their constructors. Every stone intended for a durable edifice, ought to be tested as to its durability, by immersion in a saturated solution of sulphate of soda, and exposure during some days to the air. The crystallization which ensues in its interior, will cause the same disintegration of its substance which frost would occasion in a series of years.

STONE, ARTIFICIAL, for statuary and other decorations of architecture, has been made for several years with singular success at Berlin, by Mr. Feilner. His materials are nearly the same with those of English pottery; and the plastic mass is fashioned either in moulds, or by hand. His kilns, which are peculiar in form, and economical in fuel, deserve to be generally known. Figs. 1069. and 1070. represent his round kiln; fig. 1069. being an oblique section in the line A, B, C, of fig. 1070., which is a ground plan in the line D, a, b, E, of fig. 1069. The inner circular space c, covered with the elliptical arch, is filled with the figures to be baked, set upon brick supports. The hearth is a few feet above the ground; and there are steps before the door d, for the workmen to mount by, in charging the kiln. The fire is applied on the four sides under the hearth. The flame of each passes along the straight flues f i, f i, and f k. In the second annular flue g, g, as also in the third l, l, the flame of each fire is kept apart, being separated from the adjoining, by the stones h and m. In the fourth flue n, the flames again come together, as also in o, and ascend by the middle opening. Besides this large orifice, there are several small holes, p, p, in the hearth over the above flues, to lead the flames from the other points into contact with the various articles. There are also channels q, q, in the sides, enclosed by thin walls r, to promote the equable distribution of the heat; and these are placed right over the first fire-flues e. The partitions r, are perforated with many holes, through which, as well as from their tops, the flame may be directed inwards and downwards; s are the vents for carrying off the flames into the upper space u, which is usually left empty. These vents can be closed by iron damper-plates, pushed in through the side-slits of the dome. t, t, are peep-holes, for observing the state of ignition in the furnace; but they are most commonly bricked up. Fig. 1071. is a vertical section, and fig. 1072. a plan, of an excellent kiln for baking clay to a stony consistence, for the above purpose, or for burning fire-bricks. A, is the lower; B, the middle; C, the upper kiln; and D, the hood, terminating in the chimney E. a, a, is the ash-pit; b, b, the vault for raking out the ashes; it is covered with an iron door c. d, is the peep-hole, filled with a clay stopper; e, is the fireplace; f, f, a vent in the middle of each arch; g, g, flues at the sides of the arches, situated between the two fireplaces; h, i, k, are apertures for introducing the articles to be baked; l, a grate for the fire in the uppermost kiln; m, the ash-pit; n, the fire-door; o, openings through which the flames of a second fire are thrown in. At first, only the ground kiln A, is fired, with cleft billets of pine-wood, introduced at the opening e; when this is finished, the second is fired; and then the third, in like manner. This kiln is very like the porcelain kiln of SÈvres, and is employed in many places for baking stoneware.

Mr. Keene obtained a patent, about a year ago, for making a factitious stone-paste in the following way:—He dissolves one pound of alum in a gallon of water, and in this solution he soaks 84 pounds of gypsum calcined in small lumps. He exposes these lumps in the open air for about eight days, till they become apparently dry, and then calcines them in an oven at a dull-red heat. The waste heat of a coke oven is well adapted for this purpose. (See Pitcoal, coking of.) These lumps, being ground and sifted, afford a fine powder, which, when made up into a paste with the proper quantity of water, forms the petrifying ground. The mass soon concretes, and after being brushed over with a thin layer of the petrifying paste, may be polished with pumice, &c., in the usual way. It then affords a body of great compactness and durability. If half a pound of copperas be added to the solution of the alum, the gypsum paste, treated as above, has a fine cream or yellow colour. This stone stands the weather well.

STONEWARE. (Fayence, Fr.; Steingut, Germ.) See Pottery.

STORAX, STYRAX, flows from the twigs and the trunk of the Liquidambar styraciflua, a tree which grows in Louisiana, Virginia, and Mexico. Liquidamber, as this resin is also called, is a brown or ash-gray substance, of the consistence of turpentine, which dries up rapidly, has an agreeable smell, like benzoin, and a bitterish, sharp, burning taste. It dissolves in four parts of alcohol, and affords 1·4 per cent. of benzoic acid.

STOVE (PoËle, CalorifÈre, Fr.; Ofen, Germ.); is a fireplace, more or less close, for warming apartments. When it allows the burning coals to be seen, it is called a stove-grate. Hitherto stoves have rarely been had recourse to in this country for heating our sitting-rooms; the cheerful blaze and ventilation of an open fire being generally preferred. But last winter, by its inclemency, gave birth to a vast multitude of projects for increasing warmth and economizing fuel, many of them eminently insalubrious, by preventing due renewal of the air, and by the introduction of noxious fumes into it. When coke is burned very slowly in an iron box, the carbonic acid gas which is generated, being half as heavy again as the atmospherical air, cannot ascend in the chimney at the temperature of 300° F.; but regurgitates into the apartment through every pore of the stove, and poisons the atmosphere. The large stoneware stoves of France and Germany are free from this vice; because, being fed with fuel from the outside, they cannot produce a reflux of carbonic acid into the apartment, when their draught becomes feeble, as inevitably results from the obscurely burning stoves which have the doors of the fireplace and ash-pit immediately above the hearth-stone.

I have recently performed some careful experiments upon this subject, and find that when the fuel is burning so slowly in the stove as not to heat the iron surface above the 250th or 300th degree of Fahr., there is a constant deflux of carbonic acid gas from the ash-pit into the room. This noxious emanation is most easily evinced by applying the beak of a matrass, containing a little Goulard’s extract (solution of subacetate of lead), to a round hole in the door of the ash-pit of a stove in this languid state of combustion. In a few seconds the liquid will become milky, by the reception of carbonic acid gas. I shall be happy to afford ocular demonstration of this fact to any incredulous votary of the pseudo-economical, anti-ventilation, stoves now so much in vogue. There is no mode in which the health and life of a person can be placed in more insidious jeopardy, than by sitting in a room with its chimney closed up with such a choke-damp-vomiting stove.

That fuel may be consumed by an obscure species of combustion, with the emission of very little heat, was clearly shown in Sir H. Davy’s Researches on Flame. “The facts detailed on insensible combustion,” says he, “explain why so much more heat is obtained from fuel when it is burned quickly, than slowly; and they show that, in all cases, the temperature of the acting bodies should be kept as high as possible; not only because the general increment of heat is greater, but likewise because those combinations are prevented, which, at lower temperatures, take place without any considerable production of heat. These facts likewise indicate the source of the great error into which experimenters have fallen, in estimating the heat given out in the combustion of charcoal; and they indicate methods by which the temperature may be increased, and the limits to certain methods.” These conclusions are placed in a strong practical light by the following simple experiments:—I set upon the top orifice of a small cylindrical stove, a hemispherical copper pan, containing six pounds of water, at 60° F., and burned briskly under it 3¹/₂ pounds of coke in an hour; at the end of which time, 4¹/₂ pounds of water were boiled off. On burning the same weight of coke slowly in the same furnace, surmounted by the same pan, in the course of 12 hours, little more than one-half the quantity of water was exhaled. Yet, in the first case, the aerial products of combustion swept so rapidly over the bottom of the pan, as to communicate to it not more than one-fourth of the effective heat which might have been obtained by one of the plans described in the article Evaporation; while, in the second case, these products moved at least 12 times more slowly across the bottom of the pan, and ought therefore to have been so much the more effective in evaporation, had they possessed the same power or quantity of heat.

Stoves, when properly constructed, may be employed both safely and advantageously to heat entrance-halls upon the ground story of a house; but care should be taken not to vitiate the air by passing it over ignited surfaces, as is the case with most of the patent stoves now foisted upon the public. Fig. 1073. exhibits a vertical section of a stove which has been recommended for power and economy; but it is highly objectionable, as being apt to scorch the air. The flame of the fire A, circulates round the horizontal pipes of cast iron, b b, c c, d d, e e, which receive the external air at the orifice b, and conduct it up through the series, till it issues highly heated at K, L, and may be thence conducted wherever it is wanted. The smoke escapes through the chimney B. This stove has evidently two prominent faults; first, it heats the air-pipes very unequally, and the undermost far too much; secondly, the air, by the time it has ascended through the zigzag range to the pipe e e, will be nearly of the same temperature with it, and will therefore abstract none of its heat. Thus the upper pipes, if there be several in the range, will be quite inoperative, wasting their warmth upon the sooty air.

Fig. 1074. exhibits a transverse vertical section of a far more economical and powerful stove, in which the above evils are avoided. The products of combustion of the fire A, rise up between two brick walls, so as to play upon the bed of tiles B, where, after communicating a moderate heat to the series of slanting pipes whose areas are represented by the small circles a, a, they turn to the right and left, and circulate round the successive rows of pipes b b, c c, d d, e e, and finally escape at the bottom by the flues g, g, pursuing a somewhat similar path to that of the burned air among a bench of gas-light retorts. It is known, that two-thirds of the fuel have been saved in the gas-works by this distribution of the furnace. For the purpose of heating apartments, the great object is to supply a vast body of genial air; and, therefore, merely such a moderate fire should be kept up in A, as will suffice to warm all the pipes pretty equably to the temperature of 220° Fahr.; and, indeed, as they are laid with a slight slope, are open to the air at their under ends, and terminate at the upper in a common main pipe or tunnel, they can hardly be rendered very hot by any intemperance of firing. I can safely recommend this stove to my readers. If the tubes be made of stoneware, its construction will cost very little; and they may be made of any size, and multiplied so as to carry off the whole effective heat of the fuel, leaving merely so much of it in the burned air, as to waft it fairly up the chimney.

I shall conclude this article by a short extract of a paper which was read before the Royal Society, on the 16th of June, 1836, upon warming and ventilating apartments; a subject to which my mind had been particularly turned at that time, by the Directors of the Customs Fund of Life Assurance, on account of the very general state of indisposition and disease prevailing among those of their officers (nearly 100 in number) engaged on duty in the Long Room of the Custom House, London.

“The symptoms of disorder experienced by the several gentlemen (about twenty in number), whom I examined, out of a great many who were indisposed, were of a very uniform character. The following is the result of my researches:—

“A sense of tension or fulness of the head, with occasional flushings of the countenance, throbbing of the temples, and vertigo, followed, not unfrequently, with a confusion of ideas, very disagreeable to officers occupied with important and sometimes intricate calculations. A few are affected with unpleasant perspiration on their sides. The whole of them complain of a remarkable coldness and languor in their extremities, more especially the legs and feet, which has become habitual, denoting languid circulation in these parts, which requires to be counteracted by the application of warm flannels on going to bed. The pulse is, in many instances, more feeble, frequent, sharp, and irritable, than it ought to be, according to the natural constitution of the individuals. The sensations in the head occasionally rise to such a height, notwithstanding the most temperate regimen of life, as to require cupping, and at other times depletory remedies. Costiveness, though not a uniform, is yet a prevailing symptom.

“The sameness of the above ailments, in upwards of one hundred gentlemen, at very various periods of life, and of various temperaments, indicates clearly sameness in the cause.

“The temperature of the air in the Long Room ranged, in the three days of my experimental inquiry, from 62° to 64° of Fahrenheit’s scale; and in the Examiner’s Room it was about 60°, being kept somewhat lower by the occasional shutting of the hot-air valve, which is here placed under the control of the gentlemen; whereas that of the Long Room is designed to be regulated in the sunk story, by the fireman of the stove, who seems sufficiently careful to maintain an equable temperature amidst all the vicissitudes of our winter weather. Upon the 7th of January, the temperature of the open air was 50°; and on the 11th it was only 35°; yet upon both days the thermometer in the Long Room indicated the same heat, of from 62° to 64°.

“The hot air discharged from the two cylindrical stove-tunnels into the Long Room was at 90° upon the 7th, and at 110° upon the 11th. This air is diluted, however, and disguised, by admixture with a column of cold air, before it is allowed to escape. The air, on the contrary, which heats the Examiner’s Room, undergoes no such mollification, and comes forth at once in an ardent blast of fully 170°; not unlike the simoom of the desert, as described by travellers. Had a similar nuisance, on the greater scale, existed in the Long Room, it could not have been endured by the merchants and other visitors on business: but the disguise of an evil is a very different thing from its removal. The direct air of the stove, as it enters the Examiner’s Room, possesses, in an eminent degree, the disagreeable smell and flavour imparted to air by the action of red-hot iron; and, in spite of every attention on the part of the fireman to sweep the stove apparatus from time to time, it carries along with it abundance of burned dusty particles.

“The leading characteristic of the air in these two rooms, is its dryness and disagreeable smell. In the Long Room, upon the 11th, the air indicated, by Daniell’s hygrometer, 70 per cent. of dryness, while the external atmosphere was nearly saturated with moisture. The thermometer connected with the dark bulb of that instrument stood at 30° when dew began to be deposited upon it; while the thermometer in the air stood at 64°. In the court behind the Custom-house, the external air being at 35°, dew was deposited on the dark bulb of the hygrometer by a depression of only 3°; whereas in the Long Room, on the same day, a depression of 34° was required to produce that deposition. Air, in such a dry state, would evaporate 0·44 in. depth of water from a cistern in the course of twenty-four hours; and its influence on the cutaneous exhalents must be proportionably great.

“As cast iron always contains, beside the metal itself, more or less carbon, sulphur, phosphorus, or even arsenic, it is possible that the smell of air passed over it in an incandescent state, may be owing to some of these impregnations; for a quantity of noxious effluvia, inappreciably small, is capable of affecting not only the olfactory nerves, but the pulmonary organs. I endeavoured to test the air as it issued from the valve in the Examiner’s Room, by presenting to it pieces of white paper moistened with a solution of nitrate of silver, and perceived a slight darkening to take place, as if by sulphurous fumes. White paper, moistened with sulphuretted hydrogen water, was not in the least discoloured. The faint impression on the first test paper, may be, probably, ascribed to sulphurous fumes, proceeding from the ignition of the myriads of animal and vegetable matters which constantly float in the atmosphere, as may be seen in the sunbeam admitted into a dark chamber: to this cause, likewise, the offensive smell of air, transmitted over red-hot iron, may in some measure be attributed, as well as to the hydrogen resulting from the decomposition of aqueous vapour, always present in our atmosphere in abundance; especially close to the banks of the Thames, below London Bridge.

“When a column of air sweeps furiously across the burning deserts of Africa and Arabia, constituting the phenomenon called simoom by the natives, the air becomes not only very hot and dry, but highly electrical, as is evinced by lightning and thunder. Dry sands, devoid of vegetation, cannot be conceived to communicate any noxious gas or vapour to the atmosphere, like the malaria of marshes, called miasmata: it is, hence, highly probable that the blast of the simoom owes its deadly malignity, in reference to animal as well as vegetable life, simply to extreme heat, dryness, and electrical disturbance. Similar conditions, though on a smaller scale, exist in what is called the bell, or cockle, apparatus for heating the Long Room and the Examiner’s apartment in the Custom-house. It consists of a series of inverted, hollow, flattened pyramids of cast iron, with an oblong base, rather small in their dimensions, to do their work sufficiently in cold weather, when moderately heated. The inside of the pyramids is exposed to the flames of coke furnaces, which heat them frequently to incandescence, while currents of cold air are directed to their exterior surfaces by numerous sheet-iron channels. The incandescence of these pyramids, or bells, as they are vulgarly called, was proved by pieces of paper taking fire when I laid them on the summits. Again, since air becomes electrical when it is rapidly blown upon the surfaces of certain bodies, it occurred to me that the air which escapes into the Examiner’s Room might be in this predicament. It certainly excites the sensation of a cobweb playing round the head, which is well known to all who are familiar with electrical machines. To determine this point, I presented a condensing gold-leaf electrometer to the said current of hot air, and obtained faint divergence with negative electricity. The electricity must be impaired in its tension, however, in consequence of the air escaping through an iron grating, and striking against the flat iron valves, both of which tend to restore the electric equilibrium. The air blast, moreover, by being diffused round the glass of the condenser apparatus, would somewhat mask the appearances. Were it worth while, an apparatus might be readily constructed for determining this point, without any such sources of fallacy. The influence of an atmosphere charged with electricity in exciting headache and confusion of thought in many persons, is universally known.

“The fetid burned odour of the stove air, and its excessive avidity for moisture, are of themselves, however, sufficient causes of the general indisposition produced among the gentlemen who are permanently exposed to it in the discharge of their public duties.

“From there being nearly a vacuum, as to aqueous vapour, in the said air, while there is nearly a plenum in the external atmosphere round about the Custom-house, the vicissitudes of feeling in those who have occasion to go out and in frequently, must be highly detrimental to health. The permanent action of an artificial desiccated air on the animal economy may be stated as follows:—

“The living body is continually emitting a transpirable matter, the quantity of which, in a grown up man, will depend partly on the activity of the cutaneous exhalents, and partly on the relative dryness or moisture of the circumambient medium. Its average amount, in common circumstances, has been estimated at 20 ounces in twenty-four hours.

“When plunged in a very dry air, the insensible perspiration will be increased; and, as it is a true evaporation or gasefaction, it will generate cold proportionably to its amount. Those parts of the body which are most insulated in the air, and furthest from the heart, such as the extremities, will feel this refrigerating influence most powerfully. Hence the coldness of the hands and feet, so generally felt by the inmates of the apartment, though its temperature be at or above 60°. The brain, being screened by the skull from this evaporating influence, will remain relatively hot, and will get surcharged, besides, with the fluids which are repelled from the extremities by the condensation, or contraction, of the blood-vessels, caused by cold. Hence the affections of the head, such as tension, and its dangerous consequences. If sensible perspiration happen, from debility, to break forth from a system previously relaxed, and plunged into dry air, so attractive of vapour, it will be of the kind called a cold clammy sweat on the sides and back, as experienced by many inmates of the Long Room.

“Such, in my humble apprehension, is a rationale of the phenomena observed at the Custom-house. Similar effects have resulted from hot-air stoves of a similar kind in many other situations.

“After the most mature physical and medical investigation, I am of opinion that the circumstances above specified cannot act permanently upon human beings, without impairing their constitutions, and reducing the value of their lives. The Directors of the Customs Fund are therefore justified in their apprehensions, ‘that the mode of heating the Long Room is injurious to the health of persons employed therein, and that it must unduly shorten the duration of life.’

“It may be admitted, as a general principle, that the comfort of sedentary individuals, occupying large apartments during the winter months, cannot be adequately secured by the mere influx of hot air from separate stove-rooms: it requires the genial influence of radiating surfaces in the apartments themselves, such as of open fires, of pipes, or other vessels filled with hot water or steam. The clothing of our bodies, exposed to such radiation in a pure, fresh, somewhat cool and bracing air, absorbs a much more agreeable warmth than it could acquire by being merely immersed in an atmosphere heated even to 62° Fahr., like that of the Long Room. In the former predicament, the lungs are supplied with a relatively dense air, say at 52° Fahr.; while the external surface of the body or the clothing is maintained at, perhaps, 70° or 75°. This distinctive circumstance has not, I believe, been hitherto duly considered by the stove doctors, each intent on puffing his own pecuniary interest; but it is obviously one of great importance, and which the English people would do well to keep in view; because it is owing to our domestic apartments being heated by open fires, and our factories by steam pipes, that the health of our population, and the expectation of life among all orders in this country, are so much better than in France and Germany, where hot-air stoves, neither agreeable nor inoffensive, and in endless variety of form, are generally employed.

“In conclusion, I take leave to state to you my firm conviction that the only method of warming your Long Room and subsidiary apartments, combining salubrity, safety, and economy, with convenience in erection and durable comfort in use, is by a series of steam pipes laid along the floor, at the line of the desk partitions, in suitable lengths, with small arched junction-pipes rising over the several doorways, to keep the passages clear, and at the same time to allow a free expansion and contraction in the pipes, thereby providing for the permanent soundness of the joints.”

It would not be difficult to construct a stove or stove-grate which should combine economy and comfort of warming an apartment, with briskness of combustion and durability of the fire, without any noxious deflux of carbonic acid. See Chimney.

STRAW-HAT MANUFACTURE. The mode of preparing the Tuscany or Italian straw, is by pulling the bearded wheat while the ear is in a soft milky state, the corn having been sown very close, and of consequence produced in a thin, short, and dwindled condition. The straw, with its ears and roots, is spread out thinly upon the ground in fine hot weather, for three or four days or more, in order to dry the sap; it is then tied up in bundles and stacked, for the purpose of enabling the heat of the mow to drive off any remaining moisture. It is important to keep the ends of the straw air-tight, in order to retain the pith, and prevent its gummy particles from passing off by evaporation.

After the straw has been about a month in the mow, it is removed to a meadow and spread out, that the dew may act upon it, together with the sun and air, and promote the bleaching, it being necessary frequently to turn the straw while this process is going on. The first process of bleaching being complete, the lower joint and root is pulled from the straw, leaving the upper part fit for use, which is then sorted according to qualities; and after being submitted to the action of steam, for the purpose of extracting its colour, and then to a fumigation of sulphur, to complete the bleaching, the straws are in a condition to be platted or woven into hats and bonnets, and are in that state imported into England in bundles, the dried ears of the wheat being still on the straw.

Straw may be easily bleached by a solution of chloride of lime, and also by sulphuring. For the latter purpose, a cask open at both ends, with its seams papered, is to be set upright a few inches from the ground, having a hoop nailed to its inside, about six inches beneath the top, to support another hoop with a net stretched across it, upon which the straw is to be laid in successive handfuls loosely crossing each other. The cask having been covered with a tight overlapping lid, stuffed with lists of cloth, a brazier of burning charcoal is to be inserted within the bottom, and an iron dish containing pieces of brimstone is to be put upon the brazier. The brimstone soon takes fire, and fills the cask with sulphurous acid gas, whereby the straw gets bleached in the course of three or four hours. Care should be taken to prevent such a violent combustion of the sulphur as might cause black burned spots, for these cannot be afterwards removed. The straw, after being aired and softened by spreading it upon the grass for a night, is ready to be split, preparatory to dyeing. Blue is given by a boiling-hot solution of indigo in sulphuric acid, called Saxon blue, diluted to the desired shade; yellow, by decoction of turmeric; red, by boiling hanks of coarse scarlet wool in a bath of weak alum water, containing the straw; or directly, by cochineal, salt of tin, and tartar. Brazil wood and archil are also employed for dyeing straw. For the other colours, see their respective titles in this Dictionary.

STRETCHING MACHINE. Cotton goods and other textile fabrics, either white or printed, are prepared for the market by being stretched in a proper machine, which lays all their warp and woof yarns in truly parallel positions. A very ingenious and effective mechanism of this kind was made the subject of a patent by Mr. Samuel Morand, of Manchester, in April, 1834, which serves to extend the width of calico pieces, or of other cloths woven of cotton, wool, silk, or flax, after they have become shrunk in the processes of bleaching, dyeing, &c. I regret that the limits of this volume will not admit of its description. The specification of the patent is published in Newton’s Journal, for December, 1835.

STRONTIA, one of the alkaline earths, of which strontium is the metallic basis, occurs in a crystalline state, as a carbonate, in the lead mines of Strontian in Argyleshire, whence its name. The sulphate is found crystallized near Bristol, and in several other parts of the world; but strontitic minerals are rather rare. The pure earth is prepared exactly like baryta, from either the carbonate or the sulphate. It is a grayish-white powder, infusible in the furnace, of a specific gravity approaching that of baryta, having an acrid, burning taste, but not so corrosive as baryta, though sharper than lime. It becomes hot when moistened, and slakes into a pulverulent hydrate, dissolves in 150 parts of water at 60°, and in much less at the boiling point, forming an alkaline solution called strontia water, which deposits crystals in four-sided tables as it cools. These contain 68 per cent. of water, are soluble in 52 parts of water at 60°, and in about 2 parts of boiling water; when heated they part with 53 parts of water, but retain the other 15 parts, even at a red heat. The dry earth consists of 84·55 of base, and 15·45 of oxygen. It is readily distinguished from baryta, by its inferior solubility, and by its soluble salts giving a red tinge to flame, while those of baryta give a yellow tinge. Fluosilicic acid and iodate of soda precipitate the salts of the latter earth, but not those of the former. The compounds of strontia are not poisonous, like those of baryta. The only preparation of strontia used in the arts is the Nitrate, which see.

STRYCHNIA, is an alkaline base, extracted from the Strychnos nux vomica, Strychnos ignatia, and the Upas tiente; which has been employed in medicine by some of the poison doctors, but is of no use in any of the arts. When introduced into the stomach, strychnia acts with fearful energy, causing lock-jaw immediately, and the death of the animal in a very short time. Half a grain, blown into the throat of a rabbit, proves fatal in five minutes.

STUCCO. See Gypsum.

SUBERIC ACID, is prepared by digesting grated cork with nitric acid. It forms crystals, which sublime in white vapours when heated.

SUBLIMATE, is any solid matter resulting from condensed vapours, and,

SUBLIMATION, is the process by which the volatile particles are raised by heat, and condensed into a crystalline mass. See Calomel and Sal-ammoniac, for examples.

SUBSALT, is a salt in which the base is not saturated with acid; as subacetate of lead.

SUCCINIC ACID, Acid of amber, (Acide succinique, Fr.; BernsteinsaÜre, Germ.) is obtained by distilling coarsely pounded amber in a retort by itself, with a heat gradually raised; or mixed with one-twelfth of its weight of sulphuric acid, diluted with half its weight of water. The acid which sublimes is to be dissolved in hot water, to be saturated with potassa or soda, boiled with bone black, to remove the foul empyreumatic oily matter, filtered, and precipitated by nitrate of lead, to convert it into an insoluble succinate; which being washed, is to be decomposed by the equivalent quantity of sulphuric acid. Pure succinic acid forms transparent prisms. The succinate of ammonia is an excellent reagent for detecting and separating iron.

SULPHATES, are saline compounds of sulphuric acid with oxidized bases. The minutest quantity of them present in any solution, may be detected by the precipitate, insoluble in nitric or muriatic acid, which they afford with nitrate or muriate of baryta. They are mostly insoluble in alcohol.

SULPHATE OF ALUMINA AND POTASSA, is alum.

SULPHATE OF AMMONIA, is a salt sometimes formed by saturating the ammonia liquor of the gas-works with sulphuric acid; and it is employed for making carbonate of ammonia. See Ammonia and Sal Ammoniac.

SULPHATE OF BARYTA, is the mineral called heavy-spar, which frequently forms the gangue or vein-stone of lead and other metallic ores.

SULPHATE OF COPPER, Roman or Blue Vitriol (Vitriol de Chypre, Fr.; Kupfervitriol, Germ.); is a salt composed of sulphuric acid and oxide of copper, and may be formed by boiling the concentrated acid upon the metal, in an iron pot. It is, however, a natural product of many copper mines, from which it flows out in the form of a blue water, being the result of the infiltration of water over copper pyrites, which has become oxygenated by long exposure to the air in subterranean excavations. The liquid is concentrated by heat in copper vessels, then set aside to crystallize. The salt forms in oblique four-sided tables, of a fine blue colour; has a spec. gravity of 2·104; an acerb, disagreeable, metallic taste; and, when swallowed, it causes violent vomiting. It becomes of a pale dirty blue, and effloresces slightly, on long exposure to the air; when moderately heated, it loses 36 per cent. of water, and falls into a white powder. It dissolves in 4 parts of water, at 60°, and in 2 of boiling water, but not in alcohol; the solution has an acid reaction upon litmus paper. When strongly ignited, the acid flies off, and the black oxide of copper remains. The constituents of crystallized sulphate of copper are—oxide, 31·80; acid, 32·14; and water, 36·06. Its chief employment in this country is in dyeing, and for preparing certain green pigments. See Scheele’s and Schweinfurth Green. In France, the farmers sprinkle a weak solution of it upon their grains and seeds before sowing them, to prevent their being attacked by birds and insects.

SULPHATE OF IRON, Green vitriol, Copperas (Couperose verte, Fr.; Eisenvitriol, Schwefelsaures Eisenoxydul, Germ.); is a crystalline compound of sulphuric acid and protoxide of iron; hence called, by chemists, the protosulphate; consisting of, 26·10 of base, 29·90 of acid, and 44·00 of water, in 100 parts; or of 1 prime equivalent of protoxide, 36, + 1 of acid, 40, + 7 of water, 63, = 139. It may be prepared by dissolving iron to saturation in dilute sulphuric acid, evaporating the solution till a pellicle forms upon its surface, and setting it aside to crystallize. The copperas of commerce is made in a much cheaper way, by stratifying the pyrites found in the coal measures (Vitriolkies and Strahlkies of the Germans), upon a sloping puddled platform of stone, leaving the sulphuret exposed to the weather, till, by the absorption of oxygen, it effloresces, lixiviating with water the supersulphate of iron thus formed, saturating the excess of acid with plates of old iron, then evaporating and crystallizing. The other pyrites, which occurs often crystallized, called by the Germans Schwefelkies or Eisenkies, must be deprived of a part of its sulphur by calcination, before it acquires the property of absorbing oxygen from the atmosphere, and thereby passing from a bisulphuret into a bisulphate. Alum schist very commonly contains vitriolkies, and affords, after being roasted and weather-worn, a considerable quantity of copperas, which must be carefully separated by crystallization from the alum.

This liquor used formerly to be concentrated directly in leaden vessels; but the first stage of the operation is now carried on in stone canals of considerable length, vaulted over with bricks, into which the liquor is admitted, and subjected at the surface to the action of flame and heated air, from a furnace of the reverberatory kind, constructed at one end, and discharging its smoke by a high chimney raised at the other. See Soda Manufacture. Into this oblong trough, resting on dense clay, and rendered tight in the joints by water-cement, old iron is mixed with the liquor, to neutralize the excess of acid generated from the pyrites, as also to correct the tendency to superoxidizement in copperas, which would injure the fine green colour of the crystals. After due concentration and saturation in this surface evaporator, the solution is run off into leaden boilers, where it is brought to the proper density for affording regular crystals, which it does by slow cooling, in stone cisterns.

Copperas forms sea-green, transparent, rhomboidal prisms, which are without smell, but have an astringent, acerb, inky taste; they speedily become yellowish-brown in the air, by peroxidizement of the iron, and effloresce in a warm atmosphere: they dissolve in 1·43 parts of water at 60°, in 0·27 at 190°, and in their own water of crystallization at a higher heat. This salt is extensively used in dyeing black, especially hats, in making ink and prussian blue, for reducing indigo in the blue vat, in the China blue dye, for making the German oil of vitriol, and in many chemical and medicinal preparations.

There is a persulphate and subpersulphate of iron, but they belong to the domain of chemistry. The first may be formed, either by dissolving with heat one part of red oxide of iron (colcothar) in one-and-a-half of concentrated sulphuric acid, or by adding some nitric acid to a boiling-hot solution of copperas. It forms with galls and logwood a very black ink, which is apt to become brown-black. When evaporated to dryness, it appears as a dirty white pulverulent substance, which is soluble in alcohol. It consists, in 100 parts, of 39·42 of red oxide of iron, and 60·58 sulphuric acid.

Hydrated peroxide of iron, prepared by precipitation with alkali from solution of the persulphate, is an excellent antidote against poisoning by arsenic. A French peruquier, who had swallowed two drams of arsenious acid, was, after an interval of twenty minutes, treated with the oxide precipitated from 6 ounces of that salt by caustic potash. It was diffused in 20 quarts of weak syrup, and administered in successive doses. After repeated vomiting and purging, the patient felt no more pain, and was pronounced by the physician to be quite convalescent.

In the copperas and alum works, a very large quantity of ochrey sediment is obtained; which is a peroxide of iron, containing a little sulphuric acid and alumina. This deposit, calcined in reverberatory hearths, becomes of a bright-red colour; and when ground and elutriated, in the same way as is described under white lead, forms a cheap pigment, in very considerable demand, called English red, in the French market.

Colcothar of Vitriol, and Crocus of Mars, are old names for red oxide of iron. This brown-red powder is obtained in its purest state, by calcining dried sulphate of iron in a furnace till all its acid be expelled, and its base become peroxidized. It must be levigated, elutriated, and dried. This powder is employed extensively in the steel manufacture, for giving the finishing lustre to fine articles; it is used by silversmiths under the name of plate powder and rouge; and by the opticians for polishing the specula of reflecting telescopes. Much of the crocus in the market, is made, however, from the copperas and alum sediments, and is greatly inferior to the article prepared by the last process. The finest rouge is made by precipitating the oxide with soda, then washing and calcining the powder.

An excellent powder for applying to razor-strops, is made by igniting together in a crucible equal parts of well-dried copperas and sea salt. The heat must be slowly raised and well regulated, otherwise the materials will boil over in a pasty state, and the product will be in a great measure lost. When well made, out of contact of air, it has the brilliant aspect of plumbago. It has a satiny feel, and is a true fer olegiste, similar in composition to the Elba iron ore. It requires to be ground and elutriated; after which it affords, on drying, an impalpable powder, that may be either rubbed on a strop of smooth buff leather, or mixed up with hog’s-lard or tallow into a stiff cerate.

SULPHATE OF LIME. See Gypsum.

SULPHATE OF MAGNESIA, Epsom Salt (Sel amer, Fr.; Bittersalz, Germ.); exists in sea-water, as also in the waters of SaidschÜtz, Sedlitz, and PÜllna; and in many saline springs, besides Epsom in Surrey, whence it has derived its trivial name, and from which it was first extracted, in the year 1695, and continued to be so, till modern chemistry pointed out cheaper and more abundant sources of this useful purgative salt. The sulphate of magnesia, occasionally found effloresced on the surface of minerals in crystalline filaments, was called haarsalz (hair salt) by the older writers. The bittern of the Scotch sea-salt works is muriate of magnesia, mixed, with a little sulphate of magnesia and chloride of sodium. If the proper decomposing quantity (found by trial) of sulphate of soda be added to it, and the mixed solution be evaporated at the temperature of 122° F., chloride of sodium will form by double affinity, and fall down in cubical crystals; while the solution of sulphate of magnesia which remains, being evaporated to the proper point, will afford regular crystals in four-sided prisms with four-sided acuminations. Or, if bittern be treated in a retort with the equivalent quantity of sulphuric acid, the muriatic acid may be distilled off into a series of Woulfe’s bottles, and the sulphate of magnesia, soda, and lime, will remain in the retort, from which mixture the sulphate of magnesia may be separated by filtration and crystallization.

Magnesian limestone being digested with as much muriatic acid as will dissolve out its lime only, will, after washing, afford, with the equivalent quantity of sulphuric acid, a pure sulphate of magnesia; and this is certainly the simplest and most profitable process for manufacturing this salt upon the great scale. Many prepare it directly, by digesting upon magnesian limestone the equivalent saturating quantity of dilute sulphuric acid. The sulphate of lime being separated by subsidence, the supernatant solution of sulphate of magnesia is evaporated and crystallized.

This salt is composed of, magnesia 16·72, sulphuric acid 32·39, and water 50·89. When free from muriate, it tends to effloresce in the air. It dissolves in 4 parts of water at 32°, in 3 parts at 60°, in 1·4 at 200°, and in its own water of crystallization at a higher heat.

SULPHATE OF MANGANESE, is prepared on the great scale for the calico-printers, by exposing the peroxide of the metal and pitcoal ground together, and made into a paste with sulphuric acid, to a heat of 400° F. On lixiviating the calcined mass, a solution of the salt is obtained, which is to be evaporated and crystallized. It forms pale amethyst-coloured prisms, which have an astringent bitter taste, dissolve in 2¹/₂ parts of water, and consist of, protoxide of manganese 31·93, sulphuric acid 35·87, and water 32·20, in 100 parts.

SULPHATE OF MERCURY, is a white salt which is used in making corrosive sublimate. See Mercury. The subsulphate, called Turbith Mineral, is a pale yellow pigment, and may be prepared by washing the white sulphated peroxide with hot water, which resolves it into the soluble supersulphate, and the insoluble subsulphate, or Turbith. It is poisonous.

SULPHATE OF POTASSA, is obtained by first igniting and then crystallizing the residuum of the distillation of nitric acid from nitre.

SULPHATE OF SODA, is commonly called Glauber’s salt, from the name of the chemist who first prepared it. It is obtained by igniting and then crystallizing the residuum of the distillation of muriatic acid from common salt. It crystallizes in channelled 6-sided prisms. See Soda Manufacture.

SULPHATE OF ZINC, called also White Vitriol, is commonly prepared in the Harz, by washing the calcined and effloresced sulphuret of zinc or blende, on the same principle as green and blue vitriol are obtained from the sulphurets of iron and copper. Pure sulphate of zinc may be made most readily by dissolving the metal in dilute sulphuric acid, evaporating and crystallizing the solution. It forms prismatic crystals, which have an astringent, disagreeable, metallic taste; they effloresce in a dry air, dissolve in 2·3 parts of water at 60°, and consist of—oxide of zinc, 28·29; acid, 28·18; water, 43·53. Sulphate of zinc is used for preparing drying oils for varnishes, and in the reserve or resist pastes of the calico-printer.

SULPHITES, are a class of salts, consisting of sulphurous acid, combined in equivalent proportions with the oxidized bases.

SULPHOSELS, is the name given by Berzelius to a class of salts which may be prepared as follows:—1. Dissolve a salt consisting of an oxide and an acid (an oxisalt), in a very small quantity of water, and pass through the solution a stream of sulphuretted hydrogen, till the salt be entirely decomposed. In this operation, the oxisalt is transformed into a sulphosalt, by the sulphur of the compound gas; while its hydrogen forms water with the oxygen of the saline base. This process is applicable only to the metallic salts; and among these, not to the nitrates, carbonates, or phosphates. 2. Another method of preparing sulphosalts is, to add to a watery solution of sulphuret of potassium, an electro-negative metallic sulphuret, which will dissolve in the liquid till the sulphuret of potassium be saturated. This saline compound is to be employed to effect double decompositions with the oxisalts; that is, to convert the radical of another base, combined with an oxacid, into a sulphosalt. 3. If the electro-negative sulphuret be put in powder into a solution of the hydrosulphuret of potassa, it will dissolve and expel the sulphuretted hydrogen with effervescence; just as carbonic acid is displaced by a stronger acid. For his other three methods of preparing sulphosalts, see his Elements, vol. iii. p. 336, Fr. translation.

SULPHUR; Brimstone (Soufre, Fr.; Schwefel, Germ.); is a simple combustible, solid, non-metallic, of a peculiar yellow colour, very brittle, melting at the temperature of 226° Fahr., and possessing, after it has been fused, a specific gravity of 1·99. When held in a warm hand, a roll of sulphur emits a crackling sound, by the fracture of its interior parts; and when it is rubbed, it emits a peculiar well-known smell, and acquires at the same time negative electricity. When heated to the temperature of 560° F. it takes fire, burns away with a dull blue flame of a suffocating odour, and leaves no residuum. When more strongly heated, sulphur burns with a vivid white flame. It is not affected by air or water.

Sulphur is an abundant product of nature; existing sometimes pure or merely mixed, and at others in intimate chemical combination with oxygen, and various metals, forming sulphates and sulphurets. See Ores of Copper, Iron, Lead, &c., under these metals.

Fig. 1100. represents one of the cast-iron retorts used at Marseilles for refining sulphur, wherein it is melted and converted into vapours, which are led into a large chamber for condensation. The body a, of the retort is an iron pot, 3 feet in diameter outside, 22 inches deep, half an inch thick, which weighs 14 cwt., and receives a charge of 8 cwt. of crude sulphur. The grate is 8 inches under its bottom, whence the flame rises and plays round its sides. A cast-iron capital b, being luted to the pot, and covered with sand, the opening in front is shut with an iron plate. The chamber d, is 23 feet long, 11 feet wide, and 13 feet high, with walls 32 inches thick. In the roof, at each gable, valves or flap-doors, e, 10 inches square, are placed at the bottom of the chimney c. The cords for opening the valves are led down to the side of the furnace. The entrance to the chamber is shut with an iron door. In the wall opposite to the retorts, there are two apertures near the floor, for taking out the sulphur. Each of the two retorts belonging to a chamber is charged with 7¹/₂ or 8 cwts. of sulphur; but one is fired first, and with a gentle heat, lest the brimstone froth should overflow; but when the fumes begin to rise copiously, with a stronger flame. The distillation commences within an hour of kindling the fire, and is completed in six hours. Three hours after putting fire to the first retort, the second is in like manner set in operation.

When the process of distillation is resumed, after having been some time suspended, explosions may be apprehended, from the presence of atmospherical air; to obviate the danger of which, the flap-doors must be opened every 10 minutes; but they should remain closed during the setting of the retorts, and the reflux of sulphurous fumes or acid should be carried off by a draught-hood over the retorts. The distillation is carried on without interruption during the week, the charges being repeated four times in the day. By the third day, the chamber acquires such a degree of heat as to preserve the sulphur in a liquid state; on the sixth, its temperature becoming nearly 300° F., gives the sulphur a dark hue, on which account the furnace is allowed to cool on the Sunday. The fittest distilling temperature is about 248°. The sulphur is drawn off through two iron pipes cast in the iron doors of the orifices on the side of the chamber opposite to the furnace. The iron stoppers being taken out of the mouths of the pipes, the sulphur is allowed to run along an iron spout placed over red-hot charcoal, into the appropriate wooden moulds.

Native sulphur in its pure state is solid, brittle, transparent, yellow, or yellow bordering on green, and of a glassy lustre when newly broken. It occurs frequently in crystalline masses, and sometimes in complete and regular crystals, which are all derivable from the rhomboidal octahedron. The fracture is usually conchoidal and shining. Its specific gravity is 2·072, exceeding somewhat the density of melted sulphur. It possesses a very considerable refractive power; and doubles the images of objects even across two parallel faces. Sulphur, crystallized by artificial means, presents a very remarkable phenomenon; for by varying the processes, crystals are obtained whose forms belong to two different systems of crystallization. The red tint, so common in the crystals of Sicily, and of volcanic districts, has been ascribed by some mineralogists to the presence of realgar, and by others to iron; but Stromeyer has found the sublimed orange-red sulphur of Vulcano, one of the Lipari islands, to result from a natural combination of sulphur and selenium.

It is extracted from the minerals containing it, at Solfatara, by the following process:—

Ten earthen pots, of about a yard in height, and 4¹/₂ gallons imperial in capacity, bulging in the middle, are ranged in a furnace called a gallery; five being set on the one side, and five on the other. These are so distributed in the body of the walls of the gallery, that their belly projects partly without, and partly within, while their top rises out of the vault of the roof. The pots are filled with lumps of the sulphur ore of the size of the fist; their tops are closed with earthenware lids, and from their shoulder proceeds a pipe of about 2 inches diameter, which bends down, and enters into another covered pot, with a hole in its bottom, standing over a tub filled with water. On applying heat to the gallery, the sulphur melts, volatilizes, and runs down in a liquid state into the tubs, where it congeals. When one operation is finished, the pots are re-charged, and the process is repeated.

In Saxony and Bohemia, the sulphurets of iron and copper are introduced into large earthenware pipes, which traverse a furnace-gallery; and the sulphur exhaled flows into pipes filled with cold water, on the outside of the furnace. 900 parts of sulphuret afford from 100 to 150 of sulphur, and a residuum of metallic protosulphuret. See Metallurgy and Copper.

Volcanic sulphur is purer than that extracted from pyrites; and as the latter is commonly mixed with arsenic, and some other metallic impregnations, sulphuric acid made of it would not answer for many purposes of the arts; though a tolerably good sulphuric acid may be made directly from the combustion of pyrites, instead of sulphur, in the lead chambers. The present high price of the Sicilian sulphur is a great encouragement to its extraction from pyrites. It is said that the common English brimstone, such as was extracted from the copper pyrites of the Parys mine of Anglesey, contained fully a fifteenth of residuum, insoluble in boiling oil of turpentine, which was chiefly orpiment; while the fine Sicilian sulphur, now imported in vast quantities by the manufacturers of oil of vitriol, contains not more than 3 per cent. of foreign matter, chiefly earthy, but not at all arsenical.

Sulphur has been known from the most remote antiquity. From its kindling at a moderate temperature, it is employed for readily procuring fire, and lighting by its flame other bodies not so combustible. At Paris, the preparation of sulphur matches constitutes a considerable branch of industry. The sulphurous acid formed by the combustion of sulphur in the atmospheric air, is employed to bleach woollen and silken goods, as also cotton stockings; to disinfect vitiated air, though it is inferior in power to nitric acid vapour and chlorine; to kill mites, moths, and other destructive insects in collections of zoology; and to counteract too rapid fermentation in wine-vats, &c. As the same acid gas has the property of suddenly extinguishing flame, sulphur has been thrown into a chimney on fire, with the best effect; a handful of it being sometimes sufficient. Sulphur is also employed for cementing iron bars in stone; for taking impressions from seals and cameos, for which purpose it is kept previously melted for some time, to give the casts an appearance of bronze. Its principal uses, however, are for the manufactures of vermillion, or cinnabar, gunpowder, and sulphuric acid.

See Metallurgy, page 823, for the description of Gahn’s furnace for extracting sulphur from pyrites.

Pyrites as a bi-sulphuret, consisting of 45·5 parts of iron, and 54·5 of sulphur, may, by proper chemical means, be made to give off one half of its sulphur, or about 27 per cent.; but great care must be taken not to generate sulphurous acid, as is done very wastefully by the Fahlun and the Goslar processes. By the latter, indeed, not more than 1 or 2 parts of sulphur are obtained, by roasting 100 parts of the pyritous ores of the Rammelsberg mines. In these cases, the sulphur is burned, instead of being sublimed. The residuum of the operation, when it is well conducted, is black sulphuret of iron, which may be profitably employed for making copperas. The apparatus for extracting sulphur from pyrites should admit no more air than is barely necessary to promote the sublimation.—Sicily produced last year 70,000 tons of sulphur, and Tuscany 1200; of which Great Britain consumed 46,000; France, 18,000; other places, 6000. In 1820, Great Britain consumed only 5000 tons.

SULPHURATION, is the process by which woollen, silk, and cotton goods are exposed to the vapours of burning sulphur, or to sulphurous acid gas. In the article Straw-hat Manufacture, I have described a simple and cheap apparatus, well adapted to this operation.

Sulphuring-rooms are sometimes constructed upon a great scale, in which blankets, shawls, and woollen clothes may be suspended freely upon poles or cords. The floor should be flagged with a sloping pavement, to favour the drainage of the water that drops down from the moistened cloth. The iron or stoneware vessels, in which the sulphur is burned, are set in the corners of the apartment. They should be increased in number according to the dimensions of the place, and distributed uniformly over it. The windows and the entrance door must be made to shut hermetically close. In the lower part of the door, there should be a small opening, with a sliding shutter, which may be raised or lowered by the mechanism of a cord passing over a pulley.

The aperture by which the sulphurous acid and azotic gases are let off, in order to carry on the combustion, should be somewhat larger than the opening at the bottom. A lofty chimney carries the noxious gases above the building, and diffuses them over a wide space, their ascension being promoted by means of a draught-pipe of iron, connected with an ordinary stove, provided with a valve to close its orifice when not kindled.

When the chamber is to be used, the goods are hung up, and a small fire is made in the draught-stove. The proper quantity of sulphur being next put into the shallow pans, it is kindled, the entrance door is closed, as well as its shutter, while a vent-hole near the ground is opened by drawing its cord, which passes over a pulley. After a few minutes, when the sulphur is fully kindled, that vent-hole must be almost entirely shut, by relaxing the cord; when the whole apparatus is to be let alone for a sufficient time.

The object of the preceding precautions is to prevent the sulphurous acid gas escaping from the chamber by the seams of the principal doorway. This is secured by closing it imperfectly, so that it may admit of the passage of somewhat more air than can enter by the upper seams, and the smallest quantity of fresh air that can support the combustion. The velocity of the current of air may be increased at pleasure, by enlarging the under vent-hole a little, and quickening the fire of the draught-stove.

Before opening the entrance door of the apartment, for the discharge of the goods, a small fire must be lighted in the draught furnace, the vent-hole must be thrown entirely open, and the sliding shutter of the door must be slid up, gradually more and more every quarter of an hour, and finally left wide open for a proper time. By this means the air of the chamber will become soon respirable.

SULPHURETTED HYDROGEN, is a gas, composed of one part of hydrogen and sixteen parts of sulphur, by weight. Its specific gravity is 1·1912, compared to air = 1·0000. It is the active constituent of the sulphureous mineral waters. When breathed, it is very deleterious to animal life; and being nearly twice as dense as air, it may be poured from its generating bottle into cavities; a scheme successfully employed by M. Thenard to destroy rats in their holes.

SULPHURIC ACID, Vitriolic Acid, or Oil of Vitriol (Acid sulfurique, Fr.; SchwefelsaÜre, Germ.). This important product, the agent of many chemical operations, was formerly procured by the distillation of dried sulphate of iron, called green vitriol, whence the corrosive liquid which came over, having an oily consistence, was denominated oil of vitriol. This method has been superseded in Great Britain, France, and most other countries, by the combustion of sulphur along with nitre, in large leaden chambers; but as the former process, which is still practised at Bleyl in Bohemia, and Nordhausen in Saxony, gives birth to some interesting results, I shall describe it briefly.

Into a long horizontal furnace, or gallery of brickwork, a series of earthenware retorts, of a pear shape, is arranged, with curved necks fitted into stoneware bottles or condensers. Each retort is charged with sulphate of iron, which has been previously heated to moderate redness. The first product of the distillation, a slightly acidulous phlegm, is allowed to escape; then the retort and receiver are securely luted together. The fire is now raised, and urged briskly for 36 hours, whereby the strong sulphuric acid is expelled, in the form of heavy white vapours, which condense in the cold receiver into an oily-looking liquid. The latter portions, when received in a separate refrigerator, frequently concrete into a crystalline mass, formerly called glacial oil of vitriol. About 64 pounds of strong acid may be obtained from 600 pounds of copperas. It is brown-coloured; and varies in specific-gravity from 1·842 to 1·896. Its boiling point is so low as 120° Fahr. When re-distilled in a glass retort, into a receiver surrounded with ice, a very moderate heat sends over white fumes, which condense into a soft solid, in silky filaments, like asbestos, tough, and difficult to cut. When this is exposed to the air, it emits copious fumes of sulphuric (not sulphurous) acid. It burns holes in paper as rapidly as a red-hot iron. Dropped in small quantities into water, it excites a hissing noise, like ignited metal; and in larger quantities, it occasions an explosion. By dropping a fragment of it into a poised phial containing water, and stoppering instantly, to prevent the ejection of liquid, by the ebullition which always ensues, I got a dilute acid, containing a known portion of the solid acid, from the specific gravity of which, as well as from its saturating power, I ascertained that the above solid sulphuric acid was truly anhydrous (void of water), consisting of 1 equivalent proportion of sulphur, and 3 of oxygen; or, by weight, of 16 of the former, and 24 of the latter. This acid makes a red solution of indigo.

The production of sulphuric acid from sulphur and nitre may be elegantly illustrated by means of a glass globe with a stoppered hole at its side, and four bent glass tubes inserted into a leaden cap in its upper orifice. The first tube is to be connected with a heated matrass, disengaging sulphurous acid from copper filings and sulphuric acid; the second with a retort, disengaging more slowly deutoxide of azote (nitric oxide) from copper filings and nitric acid; the third with a vessel for furnishing steam in a moderate current towards the end of the process, when no water has been previously admitted into the balloon; the fourth tube may be upright, and terminate in a small funnel. Through the opening in the side of the globe, atmospherical air is to be admitted from time to time, by removing the stopper; after which, the residuary lighter azote may be allowed to escape by the funnel orifice.

The nitric oxide first absorbs oxygen from the air, becomes, in consequence, nitrous acid vapour, which giving up one third of its oxygen to the sulphurous acid, converts this, with the aid of water, into sulphuric acid, while itself returning to the state of nitric oxide, is again qualified to take oxygen from the air, and to transfer it to the sulphurous acid gas; and thus in perpetual rotation. These oxygenating and disoxygenating processes continue until nearly the whole oxygen of the atmospheric air contained in the globe is consumed. Were there little aqueous vapour present, those gases would soon cease to operate upon each other; for though the nitric oxide became nitrous acid, this would oxygenate little of the sulphurous acid, because the three substances would condense into white crystals upon the sides of the balloon, like hoar frost upon a window-pane in winter. These indicate a deficiency of aqueous vapour, and an excess of nitrous acid. On the admission of steam, the crystals disappear, the sulphuric acid is liquefied, the nitrous acid is converted into nitric acid and nitric oxide; the former of which combines with the water, while the latter is converted by the atmospheric oxygen into nitrous acid vapour. A certain quantity of water is therefore requisite to prevent the formation of that crystalline compound, which condenses the nitrous acid, and renders it inoperative in transforming fresh portions of sulphurous acid into sulphuric. On these principles alone is it possible to oxygenate the sulphurous acid, by the nitrous acid resuming and surrendering a dose of oxygen, in perpetual alternation.

It was MM. Clement and Desormes who first had the sagacity to trace these complicated changes. They showed that nitrous acid gas and sulphurous acid gas mixed, react on each other through the intervention of moisture; that there resulted thence a combination of sulphuric acid, deutoxide of azote (nitrous gas), and water; that this crystalline compound was instantly destroyed by more water, with the separation of the sulphuric acid in a liquid state, and the disengagement of nitrous gas; that this gas re-constituted nitrous acid at the expense of the atmospheric oxygen of the leaden chamber, and thus brought matters to their primary condition. From this point, starting again, the particles of sulphur in the sulphurous acid, through the agency of water, became fully oxygenated by the nitrous acid, and fell down in heavy drops of sulphuric acid, while the nitrous gas derived from the nitrous acid, had again recourse to the air for its lost dose of oxygen. This beautiful interchange of the oxygenous principle was found to go on, in their experiments, till either the sulphurous acid, or oxygen in the air, was exhausted.

They verified this proposition, with regard to what occurs in sulphuric acid chambers, by mixing in a crystal globe the three substances, deutoxide of azote, sulphurous acid, and atmospheric air. The immediate production of red vapours indicated the transformation of the deutoxide into nitrous acid gas; and now the introduction of a very little water caused the proper reaction, for opaque vapours rose, which deposited white star-form crystals on the surface of the glass. The gases were once more transparent and colourless; but another addition of water melted these crystals with effervescence, when ruddy vapours appeared. In this manner the phenomena were made to alternate, till the oxygen of the included air was expended, or all the sulphurous acid was converted into sulphuric. The residuary gases were found to be nitrous acid gas, and azote, without sulphurous acid gas; while unctuous sulphuric acid bedewed the inner surface of the globe. Hence, they justly concluded their new theory of the manufacture of oil of vitriol to be demonstrated.

In consequence of their discovery, the manufacture of this acid has received such improvements, that a nearly double product of it may now be obtained from the same weight of materials. Indeed, the economy may be reckoned to be much greater; for one half of the more costly ingredient, the nitre, formerly employed with a given weight of sulphur, suffices at present.

In the manufacture of sulphuric acid upon the great scale, two different systems of working were long prevalent; the intermittent or periodical, and the continuous or uniform. Both were carried on in large leaden chambers. In the former, the chambers were closed during the period of combustion and gaseous combination, but were opened from time to time to introduce fresh atmospheric air. This method is, I believe, generally abandoned now, on account of the difficulties and delays attending it, though it afforded large products in skilful hands. In the latter, a continuous current of air is allowed to enter at the oven in front of the chamber for the combustion of the sulphur, and there is a constant escape of nitrogen gas, with a little sulphurous acid gas, at the remote end of the roof.

Fig. 1101. represents a sulphuric acid chamber, a, a, are the brick or stone pillars upon which it rests; b, b, are the sustaining wooden beams or joists; c, is the chimney for the discharge of the nitrogen; d, is the roof, and e, the sole of the hearth for the combustion of the sulphur; f, is the cylindrical tunnel, or pipe of lead or cast iron, for conducting the gasiform materials into the chamber; g, is the steam-boiler; and h, the steam-pipe. That plan is variously modified, by different oil-of-vitriol makers in this country and in France. Very frequently, the oven e, d, is not situated under the chamber, but is built at the end of it, as at i, and arched over with brick, the crown being 9 inches thick. The pipe f, 18 inches in diameter, is then placed outside of the chamber, being inserted into a brick chimney, and, turning rectangularly, enters it opposite k. The sole of the hearth e, is a thick plate of cast iron (not hollowed as shown in the figure), 5 or 6 feet long, and 3 or 4 broad, with a small fireplace constructed beneath it, whose smoke-flue runs outwards, under the floor, to the side wall of the building. The oven is in this case about 2 feet in height, from the sole to the roof; and it has an iron door, about 12 inches by 15, which slides up and down in a tightly-fitted iron frame. This door is frequently placed in the side of the oven, parallel to the long side of the leaden chamber. A stout collar of lead is bolted to the chamber, where the pipe enters it. At the middle of the side of the chamber, about 2 feet above the ground, a leaden trough is fixed, which serves as a syphon-funnel and water-trap for introducing water to the acid gases.

Several manufacturers divide the chamber into a series of rectangular compartments, by parallel leaden screens, 10 or 12 feet asunder, and allow these compartments to communicate by a narrow opening, or a hole 1 foot square, in the top and bottom of each screen alternately. Thus the fumes, which enter from the chimney-pipe over k, will be forced, by the screen at b, to descend to 1, and pass through the opening there, to get into the second compartment, whence they will escape near the top at 2, thus circulating up and down, so as to occasion a complete agitation and intermixture of their heterogeneous particles. Into the side of the chamber, opposite to the centre of each compartment, a lead pipe enters, and proceeds towards the middle of the area, terminating in a narrow orifice, for discharging a jet of high-pressure steam from a boiler loaded with 40 pounds upon the square inch. This boiler should be placed under a shed exterior to the building. It deserves to be noted, that the incessant tremors produced in this pipe by the escape of the steam, cause the orifice to contract, and eventually to close almost entirely, just as the point of a glass tube does when exposed directly to the flame of a blowpipe. Provision should therefore be made against this event, by the chemical engineer.

Equidistant between the middle point and each end of the chamber, two round holes are cut out in its side, about 16 inches in diameter, and 2 feet from the floor; the sheet lead being folded back over the face of the strong deals which strengthen the chamber in that place. The edges of the holes are bevelled outwards, so as to fit a large conical plug of wood faced with lead, called a man-hole door. One or other of these doors is opened from time to time, to allow the superintendent to inspect the process, or workmen to enter, after the chamber is well ventilated, for the purpose of making repairs. The joists or tie-beams, that bind the rafters of the roof of both the leaden chamber and the house, must be at least 7 inches deep, by 3 broad, and of such length as to have their ends supported upon the outer wall, or the columnar supports of the roof, in case a number of chambers are enclosed together in parallel ranges under a vast shed. These beams, which lie two feet apart, suspend the leaden roof, by means of leaden straps, soldered to its upper surface and edges. The sides of the chamber are sustained by means of similar leaden straps affixed to the wooden posts (uprights), 4 inches broad by 3 thick, placed two or three feet apart along the sides of the chamber; resting on the ground below, and mortised into the tie-beams above. Some chambers rest upon a sand-floor; but they are preferably placed upon wooden joists, supported by pillars stretching over an open area, as shown in the figure, into which the workmen may descend readily, to examine the bottom.

The outlet c, on the top of the chamber, is sometimes joined to a long pipe of lead laid nearly horizontally, with a slight inclination upwards, along the roof, for favouring the condensation and return of acid matter.

At the extremity l, of the chamber, which, having a downward slope of 1 inch in every 20 feet, should stand from 3 to 6 inches (according to its length) lower than i, one leg of an inverted syphon pipe is fixed by fusion, into which the liquid of the chamber passing, will show by its altitude the depth on the bottom within. From the cup-shaped orifice of that bent-up pipe, the acid of the chamber is drawn off by an ordinary leaden syphon into the concentration pans.

The sheet lead of which the sides and top are made, should weigh from 5 to 6 pounds per square foot; that of the bottom should be nearly of double thickness.

Having now detailed, with sufficient minuteness, the construction of the chamber, I shall next describe the mode of operating with it. There are at least two plans at present in use for burning the sulphur continuously in the oven. In the one, the sulphur is laid on the hearth e, (or rather on the flat hearth in the separate oven, above described,) and is kindled by a slight fire placed under it; which fire, however, is allowed to go out after the first day, because the oven becomes by that time sufficiently heated by the sulphur flames to carry on the subsequent combustion. Upon the hearth, an iron tripod is set, supporting, a few inches above it, a hemispherical cast-iron bowl (basin) charged with nitre and its decomposing proportion of strong sulphuric acid. In the other plan, 12 parts of bruised sulphur, and 1 of nitre, are mixed in a leaden trough on the floor with 1 of strong sulphuric acid, and the mixture is shovelled through the sliding iron door upon the hot hearth. The successive charges of sulphur are proportioned, of course, to the size of the chamber. In one of the largest, which is 120 feet long, 20 broad, and 16 high, 12 cwt. are burned in the course of 24 hours, divided into 6 charges, every fourth hour, of 2 cwt. each. In chambers of one-sixth greater capacity, containing 1400 metres cube, 1 ton of sulphur is burned in 24 hours. This immense production was first introduced at Chaunay and Dieuze, under the management of M. Clement-Desormes. The bottom of the chamber should be covered at first with a thin stratum of sulphuric acid, of spec. grav. 1·07, which decomposes nitrous acid into oxygen and nitrous gas; but not with mere water, which would absorb the nitrous acid vapours, and withdraw them from their aerial sphere of action. The vapour of nitric acid, disengaged from the nitre on the hearth of the oven, when brought into intimate contact with the sulphurous acid, either gives up oxygen to it, becomes itself nitrous gas, and converts it into sulphuric acid; or combines with the sulphurous acid into the crystalline compound above described, which, the moment it meets with moisture, is decomposed into sulphuric acid and nitrous gas. The atmospherical oxygen of the chamber immediately reconverts this gas into nitrous or nitric acid fumes, which are again ready, with the co-operation of sulphurous acid gas and aqueous vapour, to produce fresh quantities of hydrous sulphuric acid (oil of vitriol) and nitrous gas. At low temperatures, this curious play of chemical affinities has a great tendency to form the crystalline compound, and to deposit it in a crust of considerable thickness (from one-half to one inch) on the sides of the chamber, so as to render the process inoperative. A circumstance of this kind occurred, in a very striking manner, during winter, in a manufacture of oil of vitriol in Russia; and it has sometimes occurred, to a moderate extent, in Scotland. It is called, at Marseilles, the maladie des chambres. It may be certainly prevented, by maintaining the interior of the chamber, by a jet of steam, at a temperature of 100° F. When these crystals fall into the dilute acid at the bottom, they are decomposed with a violent effervescence, and a hissing gurgling noise, somewhat like that of a tun of beer in brisk fermentation.

M. Clement-Desormes demonstrated the proposition relative to the influence of temperature by a decisive experiment. He took a glass globe, furnished with three tubulures, and put a bit of ice into it. Through the first opening he then introduced sulphurous acid gas; through the second, oxygen; and through the third, nitrous gas (deutoxide of azote). While the globe was kept cool, by being plunged in iced water, no sulphuric acid was formed, though all the ingredients essential to its production were present. But on exposing the globe to a temperature of 100° Fahr., the four bodies began immediately to react on each other, and oil of vitriol was condensed in visible striÆ.

The introduction of steam is a modern invention, which has vastly facilitated and increased the production of oil of vitriol. It serves, by powerful agitation, not only to mix the different gaseous molecules intimately together, but to impel them against each other, and thus bring them within the sphere of their mutual chemical attraction. This is its mechanical effect. Its chemical agency is still more important. By supplying moisture at every point of the immense included space, it determines the formation of hydrous sulphuric acid, from the compound of nitric, nitrous, sulphurous, and dry sulphuric acids. No sooner is this reaction accomplished, than the nitrous gas resumes its oxygen, from the continuous atmospherical current, and becomes again fit to operate a like round of transmutations with sulphurous acid, steam, and oxygen. The nitrogen (azote), which ought to be the only residuum in a perfectly regulated vitriol chamber, escapes, by its relative lightness, at the opening c, in the roof, or, more properly speaking, is displaced by the influx of the heavier gases at the entrance-pipe.

On the intermittent plan, after the consumption of each charge, and condensation of the product, the chamber was opened, and freely ventilated, so as to expel the residuary azote, and replenish it with fresh atmospheric air. In this system there were four distinct stages or periods:—1. Combustion for two hours; 2. Admission of steam, and settling, for an hour and a half; 3. Conversion, for three hours, during which interval the drops of strong acid were heard falling like heavy hailstones on the bottom; 4. Purging of the chamber, for three quarters of an hour.

By the continuous method, sulphuric acid may be currently obtained in the chambers, of the specific gravity 1·350, or 1·450 at most; for, when stronger, it absorbs and retains permanently much nitrous acid gas; but by the intermittent, so dense as 1·550, or even 1·620; whence in a district where fuel is high priced, as near Paris, this method recommended itself by economy in the concentration of the acid. In Great Britain, and even in most parts of France, however, where time, workmen’s wages, and interest of capital, are the paramount considerations, manufacturers do not find it for their interest in general to raise the density of the acid in the chambers above 1·400, or at most 1·500; as the further increase goes on at a retarded rate, and its concentration from 1·400 to 1·600, in leaden pans, costs very little.

At about the specific gravity of 1·35, in Great Britain, the liquid of the chambers is run off, by the syphon above described, into a leaden gutter or spout, which discharges it into a series of rectangular vessels made of large sheets of lead, of 12 or 14 lbs. to the square foot, simply folded up at the angles into pans 8 or 10 inches deep, resting upon a grate made of a pretty close row of wrought-iron bars of considerable strength, under which the flame of a furnace plays. Where coals are very cheap, each pan may have a separate fire; but where they are somewhat dear, the flame, after passing under the lowest pan of the range, which contains the strongest acid (at about 1·600), proceeds upwards with a slight slope to heat the pans of weaker acid, which, as it concentrates, is gradually run down by syphons to replenish the lower pans, in proportion as their aqueous matter is dissipated. The 3 or 4 pans constituting the range are thus placed in a straight line, but each at a different level, terrace-like; en gradins, as the French say.

When the acid has thereby acquired the density of 1·650, or 1·700 at most, it must be removed from the leaden evaporators, because, when of greater strength, it would begin to corrode them; and it is transferred into leaden coolers, or run through a long refrigeratory worm-pipe surrounded by cold water. In this state it is introduced into glass or platinum retorts, to undergo a final concentration, up to the specific gravity of 1·842, or even occasionally 1·845, in consequence of slight saline impurities. When glass retorts are used, they are set in a long sand-bath over a gallery furnace, resting on fire tiles, under which a powerful flame plays; and as the flue gradually ascends from the fireplace, near to which it is most distant from the tiles; to the remoter end, the heat acts with tolerable equality on the first and last retort in the range. When platinum stills are employed, they are fitted into the inside of cast-iron pots, which protect the thin bottom and sides of the precious metal. The fire being applied directly to the iron, causes a safe, rapid, and economical concentration of the acid. The iron pots, with their platinum interior, filled with concentrated boiling-hot oil of vitriol, are lifted out of the fire-seat by tackle, and let down into a cistern of cold water, to effect the speedy refrigeration of the acid, and facilitate its transvasion into carboys packed in osier baskets lined with straw. Sometimes, however, the acid is cooled by running it slowly off through a long platinum syphon, surrounded by another pipe filled with cold water. Fig. 1102. shows my contrivance for this purpose.

The under stopcock a, being shut, and the leg b, being plunged to nearly the bottom of the still, the worm is to be filled with concentrated cold acid through the funnel c. If that stopcock is now shut, and a opened, the acid will flow out in such quantity as to rarefy the small portion of air in the upper part of the pipe b, sufficiently to make the hot acid rise up over the bend, and set the syphon in action. The flow of the fluid is to be so regulated by the stopcock a, that it may be greatly cooled in its passage by the surrounding cold water in the vessel f, which may be replenished by means of the tube and funnel d, and overflow at e.

A manufacturer of acid in Scotland, who burns in each chamber 210 pounds of sulphur in 24 hours, being at the rate of 420 pounds for 20,000 cubic feet (= nearly 2000 metres cube) has a product of nearly 3 pounds of concentrated oil of vitriol for every pound of sulphur and twelfth of a pound of nitre. The advantage of his process results, I conceive, from the lower concentration of the acid in the chambers, which favours its more rapid production.

The platinum retort admits of from 4 to 6 operations in a day, when it is well mounted and managed. It has a capital of platinum, furnished with a short neck, which conducts the disengaged vapours into a lead worm of condensation; and the liquid thus obtained is returned into the lead pans. Great care must be taken to prevent any particles of lead from getting into the platinum vessel, since at the temperature of boiling sulphuric acid, the lead unites with the precious metal, and thus causes holes in the retort. These must be repaired by soldering-on a plate of platinum with gold.

Before the separate oven or hearth for burning the sulphur in contact with the nitre was adopted, this combustible mixture was introduced into the chamber itself, spread on iron trays or earthen pans, supported above the water on iron stands. But this plan was very laborious and unproductive. It is no longer followed.

One of the characters of the good quality of sulphuric acid, is its dissolving indigo without altering its fine blue colour.

Sulphuric acid, when well prepared, is a colourless and inodorous liquid, of an oily aspect, possessing a specific gravity, in its most concentrated state, of 1·842, when redistilled, but as found in commerce, of 1·845. It is eminently acid and corrosive, so that a single drop will communicate the power of reddening litmus to a gallon of water, and will produce an ulcer of the skin when allowed to remain upon it. If swallowed in its strongest state, in even a small quantity, it acts so furiously on the throat and stomach as to cause intolerable agony and speedy death. Watery diluents, mixed with chalk or magnesia, are the readiest antidotes. At a temperature of about 600° F., or a few degrees below the melting point of lead, it boils and distils over like water. This is the best method of procuring sulphuric acid free from the saline and metallic matters with which it is sometimes contaminated.

The affinity of sulphuric acid for water is so strong that, when exposed in an open saucer, it imbibes one-third of its weight from the atmosphere in 24 hours, and fully six times its weight in a few months. Hence it should be kept excluded from the air. If four parts, by weight, of the strongest acid be suddenly mixed with one part of water, both being at 50° F., the temperature of the mixture will rise to 300°; while, on the other hand, if four parts of ice be mixed with one of sulphuric acid, they immediately liquefy and sink the thermometer to 4° below zero. From the great attraction existing between this acid and water, a saucer of it is employed to effect the rapid condensation of aqueous vapour as it exhales from a cup of water placed over it; both standing under the exhausted receiver of an air-pump. By the cold produced by this unchecked evaporation in vacuo, the water is speedily frozen.

To determine the purity of sulphuric acid, let it be slowly heated to the boiling point of water, and if any volatile acid matter be present, it will evaporate, with its characteristic smell. The presence of saline impurity, which is the common one, is discovered by evaporating a given weight of it in a small capsule of platinum placed on red-hot cinders. If more than two grains remain out of 500, the acid may be reckoned to be impure. The best test for sulphuric acid, and the soluble salts into which it enters, is the nitrate of baryta, of which 182 parts are equivalent to 49 of the strongest liquid acid, or to 40 of the dry, as it exists in crystallized sulphate of potassa. One twenty thousandth part of a grain of the acid may be detected by the grayish-white cloud which baryta forms with it. 100 parts of the concentrated acid are neutralized by 143 parts of dry carbonate of potassa, and by 110 of dry carbonate of soda, both perfectly pure.

Of all the acids, the sulphuric is most extensively used in the arts, and is, in fact, the primary agent for obtaining almost all the others, by disengaging them from their saline combinations. In this way, nitric, muriatic, tartaric, acetic, and many other acids, are procured. It is employed in the direct formation of alum, of the sulphates of copper, zinc, potassa, soda; in that of sulphuric ether, of sugar by the saccharification of starch, and in the preparation of phosphorus, &c. It serves also for opening the pores of skins in tanning, for clearing the surfaces of metals, for determining the nature of several salts by the acid characters that are disengaged, &c.

According to the analysis of Dr. Thomson, the crystalline compound deposited occasionally in the leaden chambers above described consists of—

He admits that the proportion of water is a little uncertain; and that the presence of sulphurous acid was not proved by direct analysis. When heated with water, the crystalline matter disengages nitrous gas in abundance; lets fall some sulphate of lead; and the liquid is found to be sulphuric acid. When heated without water, it is decomposed with emission of nitrous gas and fuming nitric acid; leaving a liquid which, mixed with water, produces a brisk effervescence, consisting chiefly of nitrous gas.

The following Table shows the quantity of concentrated and dry sulphuric acid in 100 parts of dilute, at different densities, by my experiments, published in the Quarterly Journal of Science, for October, 1817:—

SUMACH (Eng. and Fr.; Schmack, Germ.); is the powder of the leaves, peduncles, and young branches of the Rhus coriaria, and Rhus cotinus, shrubs which grow in Hungary, the Bannat, and the Illyrian provinces. Both kinds contain tannin, with a little yellow colouring-matter, and are a good deal employed for tanning light-coloured leathers; but the first is the best. With mordants, it dyes nearly the same colours as galls. In calico-printing, sumach affords, with a mordant of tin, a yellow colour; with acetate of iron, weak or strong, a gray or black; and with sulphate of zinc, a brownish-yellow. A decoction of sumach reddens litmus paper strongly; gives white flocks with the protomuriate of tin; pale-yellow flocks with alum; blue flocks with red sulphate of iron, with an abundant precipitate. In the south of France, the twigs and leaves of the Coriaria myrthifolia are used for dyeing, under the name of rÉdoul, or rodou.

SWEEP-WASHER, is the person who extracts from the sweepings, potsherds, &c., of refineries of silver and gold, the small residuum of precious metal.

SYNTHESIS, is a Greek word, which signifies combination, and is applied to the chemical action which unites dissimilar bodies into a uniform compound; as sulphuric acid and lime, into gypsum; or chlorine and sodium, into culinary salt.

SYRUP, is a solution of sugar in water. Cane-juice, concentrated to a density of 1·300, forms a syrup which does not ferment in the transport home from the West Indies, and may be boiled and refined at one step into superior sugar-loaves, with eminent advantage to the planter, the refiner, and the revenue.