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NACARAT, is a term derived from the Spanish word nacar, which signifies mother of pearl; and is applied to a pale red colour, with an orange cast. See Calico-printing. The nacarat of Portugal or Bezetta is a crape or fine linen fabric, dyed fugitively of the above tint, which ladies rub upon their countenances to give them a roseate hue. The Turks of Constantinople manufacture the brightest red crapes of this kind. See Rouge.

NAILS, MANUFACTURE OF. (Clou, Fr.; Nagel, Germ.)

The forging of nails was till of late years a handicraft operation, and therefore belonged to a book of trades, rather than to a dictionary of arts. But several combinations of machinery have been recently employed, under the protection of patents, for making these useful implements, with little or no aid of the human hand; and these deserve to be noticed, on account both of their ingenuity and importance.

As nails are objects of prodigious consumption in building their block-houses, the citizens of the United States very early turned their mechanical genius to good account in the construction of various machines for making them. So long since as the year 1810, it appears, from the report of the secretary of their treasury, that they possessed a machine which performed the cutting and heading at one operation, with such rapidity that it could turn out upwards of 100 nails per minute. “Twenty years ago,” says the secretary of the state of Massachusetts, in that report, “some men, then unknown, and then in obscurity, began by cutting slices out of old hoops, and, by a common vice griping these pieces, headed them with several strokes of the hammer. By progressive improvements, slitting-mills were built, and the shears and the heading tools were perfected; yet much labour and expense were requisite to make nails. In a little time Jacob Perkins, Jonathan Ellis, and a few others, put into execution the thought of cutting and of heading nails by water power; but, being more intent upon their machinery than upon their pecuniary affairs, they were unable to prosecute the business. At different times other men have spent fortunes in improvements, and it may be said with truth that more than one million of dollars has been expended; but at length these joint efforts are crowned with complete success, and we are now able to manufacture, at about one-third of the expense that wrought nails can be manufactured for, nails which are superior to them for at least three-fourths of the purposes to which nails are applied, and for most of those purposes they are full as good. The machines made use of by Odiorne, those invented by Jonathan Ellis, and a few others, present very fine specimens of American genius.

“To northern carpenters, it is well known that in almost all instances it is unnecessary to bore a hole before driving a cut nail; all that is requisite is, to place the cutting edge of the nail across the grain of the wood; it is also true, that cut nails will hold better in the wood. These qualities are, in some rough building works, worth twenty per cent. of the value of the article, which is equal to the whole expense of manufacturing. For sheathing and drawing, cut nails are full as good as wrought nails; only in one respect are the best wrought nails a little superior to cut nails, and that is where it is necessary they should be clenched. The manufacture of cut nails was born in our country, and has advanced, within its bosom, through all the various stages of infancy to manhood; and no doubt we shall soon be able, by receiving proper encouragement, to render them superior to wrought nails in every particular.

“The principal business of rolling and slitting-mills, is rolling nail plates; they also serve to make nail rods, hoops, tires, sheet iron, and sheet copper. In this State we have not less than twelve.

“These mills could roll and slit 7000 tons of iron a year; they now, it is presumed, roll and slit each year about 3500 tons, 2400 tons of which, probably, are cut up into nails and brads, of such a quality that they are good substitutes for hammered nails, and, in fact, have the preference with most people, for the following reasons; viz., on account of the sharp corner and true taper with which cut nails are formed; they may be driven into harder wood without bending or breaking, or hazard of splitting the wood, by which the labour of boring is saved, the nail one way being of the same breadth or thickness from head to point.”

Since the year 1820, the following patents have been obtained in England for making nails; many of them of American origin:—

Alexander Law, September, 1821, for nails and bolts for ships’ fastenings, made in a twisted form, by hand labour.

Glascott and Mitchell, December, 1823, for ship nails with rounded heads, by hand labour.

Wilks and Ecroyd, November, 1825, for an engine for cutting wedge-form pieces from plates.

Ledsom and Jones, December 11, 1827, for machinery for cutting brads and sprigs from plates; it does not form heads.

The first nail apparatus to which I shall particularly advert, is due to Dr. Church; it was patented in his absence by his correspondent, Mr. Thomas Tyndall, of Birmingham, in December, 1827. It consists of two parts; the first is a mode of forming nails, and the shafts of screws, by pinching or pressing ignited rods of iron between indented rollers; the second produces the threads on the shafts of the screws previously pressed. The metallic rods, by being passed between a pair of rollers, are rudely shaped, and then cut asunder between a pair of shears; after which they are pointed and headed, or otherwise brought to their finished forms, by the agency of dies placed in a revolving cylinder. The several parts of the mechanism are worked by toothed wheels, cams, and levers. The second part of Dr. Church’s invention consists of a mechanism for cutting the threads of screws to any degree of obliquity or form.[35]

[35] For further details, see Newton’s Journal, 2nd series, vol. iii. p. 184.

Mr. L. W. Wright’s (American) apparatus should have been mentioned before the preceding, as the patent for it was sealed in March of the same year; though an amended patent was obtained in September, 1828. Its object was to form metal screws for wood. I have seen the machinery, but consider it much too complex to be described in the present work.

Mr. Edward Hancorne, of Skinner street, London, nail manufacturer, obtained a patent in October, 1828 for a nail-making machine, of which a brief description may give my readers a conception of this kind of manufacture. Its principles are similar to those of Dr. Church’s more elaborate apparatus.

Nail making machine

The rods or bars having been prepared in the usual way, either by rolling or hammering, or by cutting from sheets or plates of iron, called slitting, are then to be made redhot, and in that state passed through the following machine, whereby they are at once cut into suitable lengths, pressed into wedge forms for pointing at the one end, and stamped at the other end to produce the head. A longitudinal view of the machine is shown in fig. 749. A strong iron frame-work, of which one side is shown at a a, supports the whole of the mechanism. b is a table capable of sliding to and fro horizontally. Upon this table are the clamps, which lay hold of the sides of the rod as it advances; as also the shears which cut the rod into nail lengths.

These clamps or holders consist of a fixed piece and a movable piece; the latter being brought into action by a lever. The rod or bar of iron shown at c, having been made redhot, is introduced into the machine by sliding it forward upon the table b, when the table is in its most advanced position; rotatory motion is then given to the crank shaft d, by means of a band passing round the rigger pulley e, which causes the table b to be drawn back by the crank rod f: and as the table recedes, the horizontal lever is acted upon, which closes the clamps. By these means the clamps take fast hold of the sides of the heated rod, and draw it forward, when the movable chap of the shears, also acted upon by a lever, slides laterally, and cuts off the end of the rod held by the clamps: the piece thus separated is destined to form one nail.

Suppose that the nail placed at g, having been thus brought into the machine and cut off, is held between clamps, which press it sideways (these clamps are not visible in this view); in this state it is ready to be headed and pointed.

The header is a steel die h, which is to be pressed up against the end of the nail by a cam i, upon the crank-shaft; which cam, at this period of the operation, acts against the end of a rod k, forming a continuation of the die h, and forces up the die, thus compressing the metal into the shape of a nail-head.

The pointing is performed by two rolling snail pieces or spirals l, l. These pieces are somewhat broader than the breadth of the nail; they turn upon axles in the side frames. As the table b advances, the racks m, on the edge of this table, take into the toothed segments n, n, upon the axles of the spirals, and cause them to turn round.

These spirals pinch the nail at first close under its head with very little force; but as they turn round, the longer radius of the spiral comes into operation upon the nail, so as to press its substance very strongly, and squeeze it into a wedge form. Thus the nail is completed, and is immediately discharged from the clamps or holders. The carriage is then again by the rotation of the crank-shaft, which brings another portion of the rod c forward, cuts it off, and then forms it into a nail.

Richard Prosser, July, 1831, for making tacks for ornamental furniture, by soldering or wedging the spike into the head. This also is the invention of Dr. Church.

Dr. William Church, February, 1832, for improvements in machinery for making nails. These consist, first, in apparatus for forming rods, bars, or plates of iron, or other metals; secondly, in apparatus for converting the rods, &c., into nails; thirdly, in improvements upon Prosser’s patent. The machinery consists in laminating rollers, and compressing dies.

The method of forming the rods from which the nails are to be made, is very advantageous. It consists in passing the bar or plate iron through pressing rollers, which have indentations upon the peripheries of one or both of them, so as to form the bar or plate into the required shape for the rods, which may be afterwards separated into rods of any desired breadth, by common slitting rollers.

The principal object of rolling the rods into these wedge forms, is to measure out a quantity of metal duly proportioned to the required thickness or strength of the nail in its several parts; which quantity corresponds to the indentations of the rollers.

Thomas John Fuller, February 27, 1834, for an improved apparatus for making square-pointed, and also flat-pointed nails. He claims as his invention, the application of vertical and horizontal hammers (mounted in his machine) combined for the purpose of tapering and forming the points of the nails; which, being made to act alternately, resemble hand work, and are therefore not so apt to injure the fibrous texture of the iron, he imagines, as the rolling machinery is. He finishes the points by rollers.

Miles Berry, February 19, 1834, for machinery for forming metal into bolts, rivets, nails and other articles; being a communication from a foreigner residing abroad. He employs in his machine holding chaps, heading dies, toggle joints, cams, &c., mechanisms apparently skilfully contrived, but too complex for admission under the article nail in this volume.

William Southwood Stocker, July, 1836. This is a machine apparently of American parentage, as it has the same set of features as the old American mechanisms of Perkins and Dyer, at the Britannia Nailworks, Birmingham, and all the other American machines since described, for pressing metal into the forms of nails, pins, screw-shafts, rivets, &c.; for example, it possesses pressers or hammers for squeezing the rods of metal, and forming the shanks, which are all worked by a rotatory action; cutters for separating the appropriate lengths, and dies for forming the heads by compression, also actuated by revolving cams or cranks.

Mr. Stocker intends, in fact, to effect the same sorts of operations by automatic mechanisms as are usually performed by the hands of a nail-maker with his hammer and anvil; viz., the shaping of a nail from a heated rod of iron, cutting it off at the proper length, and then compressing the end of the metal into the form of the head. His machine may be said to consist of two parts, connected in the same frame; the one for shaping the shank of the nail, the other for cutting it off and heading it. The frame consists of a strong table to bear the machinery. Two pairs of hammers, formed as levers, the one pair made to approach each other by horizontal movements, the other pair by vertical movements, are the implements by which a portion at the end of a redhot rod of iron is beaten or pressed into the wedge-like shape of the shaft of a nail. This having been done, and the rod being still hot, is withdrawn from the beaters, and placed in the other part of the machine, consisting of a pair of jaws like those of a vice, which pinch the shank of the nail and hold it fast. A cutter upon the side of a wheel now comes round, and, by acting as the moving chap of a pair of shears, cuts the nail off from the rod. The nail shank being still firmly held in the jaws of the vice, with a portion of its end projecting outwardly, the heading die is slidden laterally until it comes opposite to the end of the nail; the dye is then projected forward with great force, for the purpose of what is termed upsetting the metal at the projecting end of the nail, and thereby blocking out the head.

A main shaft, driven by a band and rigger as usual, brings, as it revolves, a cam into operation upon a lever which carries a double inclined plane or wedge in its front or acting part. This wedge being by the rotatory cam projected forwards between the tails of one of the pairs of hammers, causes the faces of these hammers to approach each other, and to beat or press the redhot iron introduced between them, so as to flatten it upon two opposite sides. The rotatory cam passing round, the wedge lever is relieved, when springs instantly throw back the hammers; another cam and wedge-lever now brings the second pair of hammers to act upon the other two sides of the nail in a similar way. This is repeated several times, until the end of the redhot iron rod, gradually advanced by the hands of the workman, has assumed the desired form, that is, has received the bevel and point of the intended nail.

The rod is then withdrawn from between the hammers, and in its heated state is introduced between the jaws of the holders, for cutting off and finishing the nail. A bevel pinion upon the end of the main shaft, takes into and drives a wheel upon a transverse shaft, which carries a cam that works the lever of the holding jaws. The end of the rod being so held in the jaws or vice, a cutter at the side of a wheel upon the transverse shaft separates, as it revolves, the nail from the end of the rod, leaving the nail firmly held by the jaws. By means of a cam, the heading die is now slidden laterally opposite to the end of the nail in the holding jaws, and by another cam, upon the main shaft, the die is forced forward, which compresses the end of the nail, and spreads out the nail into the form of a head. As the main shaft continues to revolve, the cams pass away, and allow the spring to throw the jaws of the vice open, when the nails fall out; but to guard against the chance of a nail sticking in the jaws, a picker is provided, which pushes the nail out as soon as it is finished.

In order to produce round shafts, as for screw blanks, bolts, or rivets, the faces of the hammers, and the dies for heading, must be made with suitable concavities.

In 1835, 5,180, and in 1836, 5,580 tons of iron nails were exported from the United Kingdom.

NANKIN, is a peculiarly coloured cotton cloth, originally manufactured in the above named antient capital of China, from a native cotton of a brown yellow hue. Nankin cloth has been long imitated in perfection by our own manufacturers; and is now exported in considerable quantities from England to Canton. The following is the process for dyeing calico a nankin colour.

1. Take 300 pounds of cotton yarn in hanks, being the quantity which four workmen can dye in a day. The yarn for the warp may be about No. 27’s, and that for the weft 23’s or 24’s.

2. For aluming that quantity, take 10 pounds of saturated alum, free from iron (see Mordant); divide this into two portions; dissolve the first by itself in hot water, so as to form a solution, of spec. grav. 1° BaumÉ. The second portion is to be reserved for the galling bath.

3. Galling, is given with about 80 pounds of oak bark finely ground. This bark may serve for two quantities, if it be applied a little longer the second time.

4. Take 30 pounds of fresh slaked quicklime, and form with it a large bath of lime-water.

5. Nitro-muriate of tin. For the last bath, 10 or 12 pounds of solution of tin are used, which is prepared as follows:

Take 10 pounds of strong nitric acid, and dilute with pure water till its specific gravity be 26° B. Dissolve in it 4633 grains (101/2 oz. avoird.) of sal ammoniac, and 3 oz. of nitre. Into this solvent, contained in a bottle set in cold water, introduce successively, in very small portions, 28 ounces of grain-tin granulated. This solution, when made, must be kept in a well stoppered bottle.

Three coppers are required, one round, about five feet in diameter, and 32 inches deep, for scouring the cotton; 2. two rectangular coppers tinned inside, each 5 feet long and 20 inches deep. Two boxes or cisterns of white wood are to be provided, the one for the lime-water bath, and the other for the solution of tin, each about 7 feet long, 32 inches wide, and 14 inches deep; they are set upon a platform 28 inches high. In the middle between these two chests, a plank is fixed, mounted with twenty-two pegs for wringing the hanks upon, as they are taken out of the bath.

6. Aluming. After the cotton yarn has been scoured with water, in the round copper, by being boiled in successive portions of 100 pounds, it must be winced in one of the square tinned coppers, containing two pounds of alum dissolved in 96 gallons of water, at a temperature of 165° F. It is to be then drained over the copper, exposed for some time upon the grass, rinsed in clear water, and wrung.

7. The galling. Having filled four-fifths of the second square copper with water, 40 pounds of ground oak bark are to be introduced, tied up in a bag of open canvas, and boiled for two hours. The bag being withdrawn, the cotton yarn is to be winced through the boiling tan bath for a quarter of an hour. While the yarn is set to drain above the bath, 28 ounces of alum are to be dissolved in it, and the yarn being once more winced through it for a quarter of an hour, is then taken out, drained, wrung, and exposed to the air. It has now acquired a deep but rather dull yellowish colour, and is ready without washing for the next process. Bablah may be substituted for oak bark with advantage.

8. The liming. Into the cistern filled with fresh made lime-water, the hanks of cotton yarn suspended upon a series of wooden rods, are to be dipped freely three times in rapid succession; then each hank is to be separately moved by hand through the lime bath, till the desired carmelite shade appear. A weak soda lye may be used instead of lime water.

9. The brightening, is given by passing the above hanks, after squeezing, rinsing, and airing them, through a dilute bath of solution of tin. The colour thus produced is said to resemble perfectly the nankin of China.

Another kind of nankeen colour is given by oxide of iron, precipitated upon the fibre of the cloth, from a solution of the sulphate, by a solution of soda. See Calico-printing.

NAPLES YELLOW (Jaune minÉral, Fr.; Neapelgelb, Germ.); is a fine yellow pigment, called giallolino, in Italy, where it has been long prepared by a secret process; for few of the recipes which have been published produce a good colour. It is employed not only in oil painting, but also for porcelain and enamel. It has a fresh, brilliant, rich hue, but is apt to be very unequal in different samples.

The following prescription has been confidently recommended. Twelve parts of metallic antimony are to be calcined in a reverberatory furnace, along with eight parts of red lead, and four parts of oxide of zinc. These mixed oxides being well rubbed together, are to be fused; and the fused mass is to be triturated and elutriated into a fine powder. Chromate of lead has in a great measure superseded Naples yellow.

NAPHTHA, or ROCK-OIL (Huile pÉtrole, Fr.; SteinÖl, Germ.); the Seneca oil of North America, is an ethereous or volatile oil, which is generated within the crust of the earth, and issues in many different localities. The colourless kind, called naphtha, occurs at Baku, near the Caspian Sea, where the vapours which it exhales are kindled, and the flame is applied to domestic and other economical purposes. Wells are also dug in that neighbourhood, in which the naphtha is collected. Similar petroleum wells exist in the territory of the Birmans, at Yananghoung, upon the river Erawaddy, 80 hours’ journey north-east of Pegu, where no less than 520 such springs issue from a pale blue clay, soaked with oil, which rests upon roofing slate. Under the slate is coal containing much pyrites. Each spring yields annually 173 casks of 950 pounds each. Petroleum is also found at Amiano in the duchy of Parma, at Saint Zibio in the grand duchy of Modena, at Neufchatel in Switzerland, at Clermont in France, upon some points of the banks of the Iser, at Gabian, a village near BeziÈres, at Tegernsee in Bavaria, at Val di Noto in Sicily, in Zante, Gallicia, Wallachia, Trinidad, Barbadoes, the United States, Rangoon, near Ava, &c. What is found in the market comes mostly from Trinidad. The city of Parma is lighted with naphtha.

The Persian rock-oil is colourless, limpid, very fluid, of a penetrating odour, a hot taste, and a specific gravity of 0·753; it is said to boil at 160° F. The common petroleum has a reddish-yellow colour, which appears blue by reflected light, is transparent, has a spec. grav. of 0·836, and contains, according to Unverdorben, several oils of different degrees of volatility, a little oleine and stearine, resin, with a brown indifferent substance held in solution. By repeated rectifications its density may be reduced to 0·758 at 60° F. Native naphtha, of specific gravity 0·749, is said by some to boil at 201° F. The condensed vapour consists of 85·05 carbon, and 14·30 hydrogen.

The naphtha procured by distilling the coal oil of the gas works, is of specific gravity 0·857, boils at 316° F., and consists of, carbon 83·04, hydrogen 12·31, and oxygen 4·65, by my experiments.

Rock-oil is very inflammable; its vapour forms with oxygen gas a mixture which violently detonates, and produces water and carbonic acid gas. It does not unite with water, but it imparts a peculiar smell and taste to it; it combines in all proportions with strong alcohol, with ether and oils, both essential and unctuous; it dissolves sulphur, phosphorus, iodine, camphor, most of the resins, wax, fats, and softens caoutchouc into a glairy varnish. When adulterated with oil of turpentine, it becomes thick and reddish brown, on being agitated in contact with strong sulphuric acid. A very fine black pigment may be prepared from the soot of petroleum lamps.

NAPHTHALINE, is a peculiar white crystallizable substance, which may be extracted by distillation from coal tar. It has a pungent aromatic smell and taste, and a specific gravity of 1·048. It is a solid bicarburet of hydrogen, consisting, by my experiments, of 92·9 of carbon, and 7·1 of hydrogen. It has not been applied to any use.

NATRON, is the name of the native sesquicarbonate of soda, which occurs in Egypt, in the west of the Delta; also in the neighbourhood of Fessan, in the province of Sukena in Northern Africa, where it exists under the name of Trona, crystallized along with sulphate of soda; near Smyrna, in Tartary, Siberia, Hungary, Hindostan, and Mexico. In the last country, there are several natron lakes, a little to the north of Zucatecas, as well as in many other provinces. In Columbia, 48 miles from Merida, native mineral natron is dug up from the bottom of lakes in large quantities, under the name of Urao.

According to Laugier, the Egyptian natron consists of carbonate of soda 22·44, sulphate of soda 18·35, muriate of soda 38·64, water 14·0, insoluble matter 6·0. Trona is composed of carbonate of soda 65·75, sulphate of soda 7·65, muriate of soda 2·63, water 24, insoluble matter 1. The sesquicarbonate may be artificially prepared by boiling for a short time a solution of the bicarbonate.

NEALING. See Annealing.

NEB-NEB, is the East Indian name of Bablah.

NEEDLE MANUFACTURE. When we consider the simplicity, smallness, and moderate price of a needle, we would be naturally led to suppose that this little instrument requires neither much labour nor complicated manipulations in its construction; but when we learn that every sewing needle, however inconsiderable its size, passes through the hands of 120 different operatives, before it is ready for sale, we cannot fail to be surprised.

The best steel, reduced by a wire-drawing machine to the suitable diameter, is the material of which needles are formed. It is brought in bundles to the needle factory, and carefully examined. For this purpose, the ends of a few wires in each bundle are cut off, ignited, and hardened by plunging them into cold water. They are now snapped between the fingers, in order to judge of their quality; the bundles belonging to the most brittle wires are set aside, to be employed in making a peculiar kind of needles.

After the quality of the steel wire has been properly ascertained, it is calibred by means of a gauge, to see if it be equally thick and round throughout, for which purpose merely some of the coils of the bundle of wires are tried. Those that are too thick are returned to the wire-drawer, or set apart for another size of needles.

Wire unwinding apparatus

The first operation, properly speaking, of the needle factory, is unwinding the bundles of wires. With this view the operative places the coil upon a somewhat conical reel, fig. 750., whereon he may fix it at a height proportioned to its diameter. The wire is wound off upon a wheel B, formed of eight equal arms, placed at equal distances round a nave, which is supported by a polished round axle of iron, made fast to a strong upright C, fixed to the floor of the workshop. Each of the arms is 54 inches long; and one of them D, consists of two parts; of an upper part, which bears the cross bar E, to which the wire is applied; and of an under part, connected with the nave. The part E slides in a slot in the fixed part F, and is made fast to it by a peg at a proper height for placing the ends of all the spokes in the circumference of a circle. This arrangement is necessary, to permit the wire to be readily taken off the reel, after being wound tight round its eight branches. The peg is then removed, the branch pushed down, and the coil of wire released. Fig. 751. shows the wheel in profile. It is driven by the winch-handle G.

Shears

The new made coil is cut in two points diametrically opposite, either by hand shears, of which one of the branches is fixed in a block by a bolt and a nut, as shown in fig. 752., or by means of the mechanical shears, represented in fig. 753. The crank A is moved by a hydraulic wheel, or steam power, and rises and falls alternately. The extremity of this crank enters into a mortise cut in the arm B of a bent lever B G C, and is made fast to it by a bolt. An iron rod D F, hinged at one of its extremities to the end of the arm C, and at the other to the tail of the shears or chisel E, forces it to open and shut alternately. The operative placed upon the floor under F presents the coil to the action of the shears, which cut it into two bundles, composed each of 90 or 100 wires, upwards of 8 feet long. The chisel strikes 21 blows in the minute.

These bundles are afterwards cut with the same shears into the desired needle lengths, these being regulated by the diameter. For this purpose the wires are put into a semi-cylinder of the proper length, with their ends at the bottom of it, and are all cut across by this gauge. The wires, thus cut, are deposited into a box placed alongside of the workman.

Straightening tools

Two successive incisions are required to cut 100 wires, the third is lost; hence the shears, striking 21 blows in a minute, cut in 10 hours fully 400,000 ends of steel wire, which produce more than 800,000 needles. The wires thus cut are more or less bent, and require to be straightened. This operation is executed with great promptitude, by means of an appropriate instrument. In two strong iron rings A B, fig. 754., of which one is shown in front view at C, 5000 or 6000 wires, closely packed together, are put; and the bundle is placed upon a flat smooth bench L M, fig. 757., covered with a cast-iron plate D E, in which there are two grooves of sufficient depth for receiving the two ring bundles of wire, or two openings like the rule F, fig. 757., upon which is placed the open iron rule F, shown in front in fig. 756. upon a greater scale. The two rings must be carefully set in the intervals of the rule. By making this rule come and go five or six times with such pressure upon the bundles of wires as causes it to turn upon its axis, all the wires are straightened almost instantaneously.

The construction of the machine, represented in fig. 757., may require explanation. It consists of a frame in the form of a table, of which L M is the top; the cast-iron plate D E is inserted solidly into it. Above the table, seen in fig. 755. in plan, there are two uprights C H, to support the cross bar A A, which is held in forks cut out in the top of each of the two uprights. This cross bar A A, enters tightly into a mortise cut in the swing piece N, at the point N, where it is fixed by a strong pin, so that the horizontal traverse communicated to the cross bar A A affects at the same time the swing piece N. At the bottom of this piece is fixed, as shown in the figure, the open rule F, seen upon a greater scale in fig. 756.

When the workman wishes to introduce the bundle B, he raises, by means of two chains I K, fig. 757., and the lever G O, the swing piece and the cross bar. For this purpose he draws down the chain I; and when he has placed the bundle properly, so that the two rings enter into the groove E D, fig. 755., he allows the swing piece to fall back, so that the same rings enter the open clefts of the rule F; he then seizes one of the projecting arms of the cross bar A, alternately pulling and pushing it in the horizontal direction, whereby he effects, as already stated, the straightening of the wires.

Thumb-piece

The wires are now taken to the pointing-tools, which usually consist of about 30 grindstones arranged in two rows, driven by a water-wheel. Each stone is about 18 inches in diameter, and 4 inches thick. As they revolve with great velocity, and are liable to fly in pieces, they are partially encased by iron plates, having a proper slit in them to admit of the application of the wires. The workman seated in front of the grindstone, seizes 50 or 60 wires between the thumb and forefinger of his right hand, and directs one end of the bundle to the stone. By means of a bit of stout leather called a thumb-piece, of which A, fig. 758., represents the profile, and B the plan, the workman presses the wires, and turns them about with his forefinger, giving them such a rotatory motion as to make their points conical. This operation, which is called roughing down, is dry grinding; because, if water were made use of, the points of the needles would be rapidly rusted. It has been observed long ago, that the siliceous and steel dust thrown off by the stones, was injurious to the eyes and lungs of the grinders; and many methods have been proposed for preventing its bad effects. The machine invented for this purpose by Mr. Prior, for which the Society of Arts voted a premium, deserves to be generally known.

Prior's machine

A A, fig. 759., is the fly-wheel of an ordinary lathe, round which the endless cord B B passes, and embraces the pulley C, mounted upon the axle of the grindstone D. The flywheel is supported by a strong frame E E, and may be turned by a winch-handle, as usual, or by mechanical power. In the needle factories, the pointing-shops are in general very large, and contain several grindstones running on the same long horizontal shaft, placed near the floor of the apartment, and driven by water or steam power. One of the extremities of the shaft of the wheel A has a kneed or bent winch F, which by means of an intermediate crank G G, sets in action a double bellows H I, with a continuous blast, consisting of the air feeder H below, and the air regulator I above. The first is composed of two flaps, one of them a a, being fast and attached to the floor, and the other e e, moving with a hinge-joint; both being joined by strong leather nailed to their edges. This flap has a tail g, of which the end is forked to receive the end of the crank G. Both flaps are perforated with openings furnished with valves for the admission of the air, which is thence driven into a horizontal pipe K, placed beneath the floor of the workshop, and may be afterwards directed in an uninterrupted blast upon the grindstone, by means of the tin tubes N O O, which embrace it, and have longitudinal slits in them. A brass socket is supposed to be fixed upon the ground; it communicates with the pipe K, by means of a small copper tube, into which one of the extremities of the pipe N is fitted; the other is supported by the point of a screw Q, and moves round it as a pivot, so as to allow the two upright branches O O, to be placed at the same distance from the grindstone. These branches are soldered to the horizontal pipe N, and connected at their top by the tube P.

The wind which escapes through the slits of these pipes, blows upon the grindstone, and carries off its dust into a conduit R, fig. 759., which may be extended to S, beyond the wall of the building, or bent at right angles, as at T, to receive the conduits of the other grindstones of the factory.

A safety valve J, placed in an orifice formed in the regulator flap I, is kept shut by a spiral spring of strong iron wire. It opens to allow the superfluous air to escape, when, by the rising of the bellows, the tail L presses upon a small piece of wood, and thereby prevents their being injured.

Wire holder

The wires thus pointed at both ends are transferred to the first workshop, and cut in two, to form two needles, so that all of one quality may be of equal length. For each sort a small instrument, fig. 760., is employed, being a copper plate nearly square, having a turned up edge only upon two of its sides; the one of which is intended to receive all the points, and the other to resist the pressure of the shears. In this small tool a certain number of wires are put with their points in contact with the border, and they are cut together flush with the plate by means of the shears, fig. 752., which are moved by the knee of the workman. The remainder of the wires are then laid upon the same copper or brass tool, and are cut also even; there being a trifling waste in this operation. The pieces of wire out of which two needles are formed, are always left a little too long, as the pointer can never hit exact uniformity in his work.

These pointed wires are laid parallel to each other in little wooden boxes, and transferred to the head-flattener. This workman, seated at a table with a block of steel before him, about 3 inches cube, seizes in his left hand 20 or 25 needles, between his finger and thumb, spreading them out like a fan, with the points under the thumb, and the heads projecting; he lays these heads upon the steel block, and with a small flat-faced hammer strikes successive blows upon all the heads, so as to flatten each in an instant. He then arranges them in a box with the points turned the same way.

The flatted heads have become hardened by the blow of the hammer; when annealed by heating and slow cooling, they are handed to the piercer. This is commonly a child, who laying the head upon a block of steel, and applying the point of a small punch to it, pierces the eye with a smart tap of a hammer, applied first upon the one side, and then exactly opposite upon the other.

Another child trims the eyes, which he does by laying the needle upon a lump of lead, and driving a proper punch through its eye; then laying it sidewise upon a flat piece of steel, with the punch sticking in it, he gives it a tap on each side with his hammer, and causes the eye to take the shape of the punch. The operation of piercing and trimming the eyes, is performed by clever children with astonishing rapidity; who become so dexterous as to pierce with their punch a human hair, and thread it with another, for the amusement of visitors.

Pincers

The next operative makes the groove at the eye, and rounds the head. He fixes the needle in pincers, fig. 761., so that the eye corresponds to their flat side; he then rests the head of the needle in an angular groove, cut in a piece of hard wood fixed in a vice, with the eye in an upright position. He now forms the groove with a single stroke of a small file, dexterously applied, first to the one side of the needle, and then to the other. He next rounds and smooths the head with a small flat file. Having finished, he opens the pincers, throws the needle upon the bench, and puts another in its place. A still more expeditious method of making the grooves and finishing the heads has been long used in most English factories. A small ram is so mounted as to be made to rise and fall by a pedal lever, so that the child works the tool with his foot; in the same way as the heads of pins are fixed. A small die of tempered steel bears the form of the one channel or groove, another similar die, that of the other, both being in relief; these being worked by the lever pedal, finish the grooving of the eye at a single blow, by striking against each other, with the head of the needle between them.

The whole of the needles thus prepared are thrown pell-mell into a sort of drawer or box, in which they are by a few dexterous jerks of the workman’s hand made to arrange themselves parallel to each other.

The needles are now ready for the tempering; for which purpose they are weighed out in quantities of about 30 pounds, which contain from 250,000 to 500,000 needles, and are carried in boxes to the temperer. He arranges these upon sheet-iron plates, about 10 inches long, and 5 inches broad, having borders only upon the two longer sides. These plates are heated in a proper furnace to bright redness for the larger needles, and to a less intense degree for the smaller; they are taken out, and inverted smartly over a cistern of water, so that all the needles may be immersed at the same moment, yet distinct from one another. The water being run off from the cistern, the needles are removed, and arranged by agitation in a box, as above described. Instead of heating the needles in a furnace, some manufacturers heat them by means of a bath of melted lead in a state of ignition.

After being suddenly plunged in the cold water, they are very hard and excessively brittle. The following mode of tempering them is practised at Neustadt. The needles are thrown into a sort of frying-pan along with a quantity of grease. The pan being placed on the fire, the fatty matter soon inflames, and is allowed to burn out; the needles are now found to be sufficiently well tempered. They must, however, be re-adjusted upon the steel anvil, because many of them get twisted in the hardening and tempering.

Polishing bag and table

Polishing is the longest, and not the least expensive process in the needle manufacture. This is done upon bundles containing 500,000 needles; and the same machine under the guidance of one man, polishes from 20 to 30 bundles at a time; either by water or steam power. The needles are rolled up in canvas along with some quartzose sand interstratified between their layers, and the mixture is besmeared with rape-seed oil. Fig. 762. represents one of the rolls or packets of needles 12 inches long, strongly bound with cords. These packets are exposed to the to-and-fro pressure of wooden tables, by which they are rolled about, with the effect of causing every needle in the bundle to rub against its fellow, and against the siliceous matter, or emery, enclosed in the bag. Fig. 763. represents an improved table for polishing the needles by attrition-bags. The lower table M M is movable, whereas in the old constructions it was fixed; the table C has merely a vertical motion, of pressure upon the bundles, whereas formerly it had both a vertical and horizontal motion. Several bundles may obviously be polished at once in the present machine. The table M M may be of any length that is required, and from 24 to 27 inches broad; resting upon the wooden rollers B, B, B, placed at suitable distances, it receives a horizontal motion, either by hand or other convenient power; the packets of needles A, A, A, are laid upon it, and over them the tables C, C, C, which are lifted by means of the chains K, K, K, and the levers L, L, L, in order to allow the needles to be introduced or removed. The see-saw motion forces the rouleaux to turn upon their own axes, and thereby creates such attrition among their contents as to polish them. The workman has merely to distribute these rolls upon the table M, in a direction perpendicular to that in which the table moves; and whenever one of them gets displaced, he sets it right, lifting by the help of the chain the loaded table. The table makes about 20 horizontal double vibrations in the minute; whereby each bundle, running over 24 inches each time, passes through 40 feet per minute, or 800 yards in the hour.

Scouring cask

Scouring by the cask. After being worked during 18 or 20 hours under the tables, the needles are taken out of the packets, and put into wooden bowls, where they are mixed with sawdust to absorb the black grease upon their surfaces. They are next introduced into a cask, fig. 764., and a workman seizing the winch P, turns it round a little; he now puts in some more sawdust at the door, A, B, which is then shut by the clasps G G, and continues the rotation till the needles be quite clean and clear in their eyes; which he ascertains by taking out a sample of them from time to time.

Winnowing is the next process, by means of a mechanical ventilator similar to that by which corn is winnowed. The sawdust is blown away, and the grinding powder is separated from the needles, which remain apart clean and bright.

The needles are in the next place arranged in order, by being shaken, as above described, in a small somewhat concave iron tray. After being thus laid parallel to each other, they are shaken up against the end of the tray, and accumulated in a nearly upright position, so that they can be seized in a heap and removed in a body upon a pallet knife, with the help of the forefinger.

Scouring cask

The preceding five operations, of making up the rouleaux, rolling them under the tables, scouring the needles in the cask, winnowing, and arranging them, are repeated ten times in succession, in manufacturing the best articles; the only variation being in the first process. Originally the bundles of needles are formed with alternate layers of siliceous schistus and needles; but after the seventh time, bran freed from flour by sifting is substituted for the schistus. The subsequent four processes are, however, repeated as described. It has been found in England, that emery powder mixed with quartz and mica or pounded granite, is preferable to every thing else for polishing needles at first by attrition in the bags; at the second and following operations, emery mixed with olive oil is used, up to the eighth and ninth, for which putty or oxide of tin with oil is substituted for the emery; at the tenth the putty is used with very little oil; and lastly bran is employed to give a finish. In this mode of operating, the needles are scoured in the copper cask shown in elevation fig. 765., and in section fig. 766. The inner surface of this cask is studded with points to increase the friction among the needles; and a quantity of hot soap suds is repeatedly introduced to wash them clean. The cask must be slowly turned upon its axis, for fear of injuring the mass of needles which it contains. They are finally dried in the wooden cask by attrition with sawdust; then wiped individually with a linen rag or soft leather; when the damaged ones are thrown aside.

Sorting ring and handle

Sorting of the needles. This operation is performed in a dry upper chamber, kept free from damp by proper stoves. Here all the points are first laid the same way; and the needles are then picked out from each other in the order of their polish. The sorting is effected with surprising facility. The workman places 2000 or 3000 needles in an iron ring, fig. 767., two inches in diameter, and sets all their heads in one plane; then on looking carefully at their points, he easily recognises the broken ones; and by means of a small hook fixed in a wooden handle, fig. 768., he lays hold of the broken needle, and turns it out. These defective needles pass into the hands of another workman, who points them anew upon a grindstone, and they form articles of inferior value. The needles which have got bent in the polishing must now be straightened. The whole are finally arranged exactly according to their lengths by the tact of the finger and thumb of the sorter.

The needles are divided into quantities for packing in blue papers, by putting into a small balance the equivalent weight of 100 needles, and so measuring them out without the trouble of counting them individually.

Hone-stone

The bluer receives these packets, and taking 25 of their needles at a time between the forefinger and thumb, he presses their points against a very small hone-stone of compact micaceous schist, mounted in a little lathe, as shown in fig. 769., he turns them briskly round, giving the points a bluish cast, while he polishes and improves them. This partial polish is in the direction of the axis; that of the rest of the needle is transverse, which distinguishes the boundaries of the two. The little hone-stone is not cylindrical, but quadrangular, so that it strikes successive blows with its corners upon the needles as it revolves, producing the effect of filing lengthwise. Whenever these angles seem to be blunted, they are set again by the bluer.

It is easy to distinguish good English needles from spurious imitations; because the former have their axis coincident with their points, which is readily observed by turning them round between the finger and thumb.

The construction of a needle requires, as already stated, about 120 operations; but they are rapidly and uninterruptedly successive. A child can trim the eyes of 4000 needles per hour.

When we survey a manufacture of this kind, we cannot fail to observe, that the diversity of operations which the needles undergo bears the impress of great mechanical refinement. In the arts, to divide labour, is to abridge it; to multiply operations, is to simplify them; and to attach an operative exclusively to one process, is to render him much more economical and productive.

NEROLI, is the name given by perfumers to the essential oil of orange flowers. It is procured by distillation with water, in the same way as the other volatile oils. Since in distilling water from neroli, an aroma is obtained different from that of the orange-flower, it has been concluded that the distilled water of orange-flowers owes its scent to some principle different from an essential oil.

NET (Filet, reseau, Fr.; Netz, Germ.); is a textile fabric of knotted meshes, for catching fish, and other purposes. Each mesh should be so secured as to be incapable of enlargement or diminution. The French government offered in 1802 a prize of 10,000 francs to the person who should invent a machine for making nets upon automatic principles, and adjudged it to M. Buron, who presented his mechanical invention to the Conservatoire des Arts et MÉtiers. It does not appear, however, that this machine has accomplished the object in view; for no establishment was ever mounted to carry it into execution. Nets are usually made by the fishermen and their families during periods of leisure. The formation of a mesh is too simple a matter to require description in this Dictionary.

NEUTRALIZATION, is the state produced when acid and alkaline matters are combined in such proportions that neither predominates, as evinced by the colour of tincture of litmus and cabbage remaining unaffected by the combination.

NICARAGUA WOOD, is the wood of the CÆsalpinia echinata, a tree which grows in Nicaraca. It is used with solution of tin as a mordant to dye a bright but fugitive red. It is an inferior sort of Brazil wood.

NICKEL, is a metal rather sparingly found, and in few localities; being usually associated with cobalt. Native nickel occurs at Westerwald in the Erzgebirge, in Bohemia, combined with arsenic, under the significant name of Kupfernickel; with cobalt, iron, and copper, as Arsenic-nickel, in the Harz; at Riechelsdorf in Hessia; as an oxide, in NickelschwÄrtze; as a sulphuret of nickel in Haarkies; as a sulphuret and arseniate of nickel in Nickelglanz; and with sulphur and antimony in Nickelspiess glanzerz at Siegen. Nickel is always present in meteoric stones. Kupfernickel occurs in numerous external shapes; as reniform, globular, botroidal, arborescent, massive, and disseminated; fracture, coarse or fine grained, with metallic lustre; colour, copper red, occasionally brown and gray; in silver and cobalt veins, in gneiss, sienite, mica-slate, kupfer-schiefer, accompanied by speisse cobalt, native silver, quartz, &c. It is found in Westphalia near Olpe, in Hessia at Riechelsdorf, and Biber, in Baden; in the Saxon Erzgebirge near Schneeberg, and Freiberg; in Bohemia, at Joachimsthal; in Thuringia, at Saalfeld; in Steyermark near Schladming; in Hungary, France, and England.

Since the manufacture of German silver, or Argentane, became an object of commercial importance, the extraction of nickel has been undertaken upon a considerable scale. The cobalt ores are its most fruitful sources, and they are now treated by the method of WÖhler, to effect the separation of the two metals. The arsenic is expelled by roasting the powdered speise first by itself, next with the addition of charcoal powder, till the garlic smell be no longer perceived. The residuum is to be mixed with three parts of sulphur and one of potash, melted in a crucible with a gentle heat, and the product being edulcorated with water, leaves a powder of metallic lustre, which is a sulphuret of nickel free from arsenic; while the arsenic associated with the sulphur, and combined with the resulting sulphuret of potassium, remains dissolved. Should any arsenic still be found in the sulphuret, as may happen if the first roasting heat was too great, the above process must be repeated. The sulphuret must be finally washed, dissolved in concentrated sulphuric acid, with the addition of a little nitric, the metal must be precipitated by a carbonated alkali, and the carbonate reduced with charcoal.

In operating upon kupfernickel, or speise, in which nickel predominates, after the arsenic, iron, and copper have been separated, ammonia is to be digested upon the mixed oxides of cobalt and nickel, which will dissolve them into a blue liquor. This being diluted with distilled water deprived of its air by boiling, is to be decomposed by caustic potash, till the blue colour disappears, when the whole is to be put into a bottle tightly stoppered, and set aside to settle. The green precipitate of oxide of nickel, which slowly forms, being freed by decantation from the supernatant red solution of oxide of cobalt, is to be edulcorated and reduced to the metallic state in a crucible containing crown glass. Pure nickel in the form of a metallic powder is readily obtained by exposing its oxalate to moderate ignition.

The reduction of the oxide of nickel with charcoal requires the heat of a powerful air furnace or smith’s forge.

Nickel possesses a fine silver white colour and lustre; it is hard, but malleable, both hot and cold; may be drawn into wire 1/50 of an inch, and rolled into plates 1/500 of an inch thick. A small quantity of arsenic destroys its ductility. When fused it has a specific gravity of 8·279, and when hammered, of 8·66 or 8·82; it is susceptible of magnetism, in a somewhat inferior degree to iron, but superior to cobalt. Mariner’s compasses may be made of it. Its melting point is nearly as high as that of manganese. It is not oxidized by contact of air, but may be burned in oxygen gas.

There is one oxide and two suroxides of nickel. The oxide is of an ash-gray colour, and is obtained by precipitation with an alkali from the solution of the muriate or nitrate. The niccolous suroxide of Berzelius is black, and may be procured by exposing the nitrate to a heat under redness. The niccolic suroxide has a dirty pale green colour; but its identity is doubtful.

NICOTIANINE, is the name of an oil recently extracted from the leaves of tobacco, which possesses the smell of tobacco smoke.

NICOTINE, is a peculiar principle, obtainable from the leaves and seeds of tobacco (nicotiana tabacum), by infusing them in acidulous water, evaporating the infusion to a certain point, adding lime to it, distilling and treating the product which comes over with ether. It is colourless, has an acrimonious taste, a pungent smell, remains liquid at 20° F., mixes in all proportions with water, but is in a great measure separable from it by ether, which dissolves it abundantly. It combines with acids, and forms salts acrid and pungent like itself; the phosphate, oxalate, and tartrate being crystallizable. Nicotine causes the pupils to contract. A single drop of it is sufficient to kill a dog.

NITRATE OF AMMONIA, is prepared by neutralizing nitric acid with carbonate of ammonia, and crystallizing the solution.

NITRATE OF LEAD (Nitrate de plomb, Fr.; Salpetersaures bleioxyd, Germ.); is made by saturating somewhat dilute nitric acid with oxide of lead (litharge), evaporating the neutral solution till a pellicle appears, and then exposing it in a hot chamber till it be converted into crystals, which are sometimes transparent, but generally opaque white octahedrons. Their spec. grav. is 4·068; they have a cooling, sweetish, pungent taste. They dissolve in 7 parts of cold, and in much less boiling water; they fuse at a moderate elevation of temperature, emit oxygen gas, and pass into oxide of lead. Their constituents are 67·3 oxide, and 32·7 acid. Nitrate of lead is much employed in the chrome yellow style of Calico-printing; which see.

There are three other compounds of nitric acid and lead oxide; viz. the bi-basic, the tri-basic, and the se-basic; which contain respectively 2, 3, and 6 atoms of base to 1 of acid.

NITRATE OF POTASH, Nitre, Saltpetre. (Nitrate de potasse, Fr.; Salpetersaures kali, Germ.) This salt occurs native as an efflorescence upon limestones, sandstones, marls, chalk, and calctuff; it forms a saline crust in caverns, as also upon the surface of the ground in certain places, especially where animal matters have been decomposed. Such caverns exist in Germany near Homburg (Burkardush); in Apulia upon the Adriatic sea (Pulo di Mofetta); in France; in the East Indies; in Ceylon, where 22 nitriferous caverns are mentioned; in North America, at Crooked river, Tennessee, Kentucky, and upon the Missouri; in Brazil, Teneriffe, and Africa. Nitre occurs as an efflorescence upon the ground in Arragon, Hungary, Podolia, Sicily, Egypt, Persia, Bengal, China, Arabia, North America, and South America. Several plants contain saltpetre; particularly borage, dill, tobacco, sunflowers, stalks of maize, beet-root, bugloss, parietaria, &c. It has not hitherto been found in animal substances.

The question has been frequently put; how is nitre annually reproduced upon the surface of limestones, and the ground, after it has been removed by washing? It has been said, in reply, that as secondary limestones contain remains of animal matters, the oxygen of the atmosphere, absorbed in virtue of the porous structure, will combine with their azote to form nitric acid; whence nitrate of lime will result. Where potash is present in the ground, a nitrate of that base will be next formed. The generation of nitre is in all cases limited to a very small distance from the surface of porous stones; no further, indeed, than where atmospherical air and moisture can penetrate; and none is ever produced upon the surface of compact stones, such as marble and quartz, or of argillaceous minerals. Dr. John Davy and M. Longchamp have advanced an opinion, that the presence of azotized matter is not necessary for the generation of nitric acid or nitrous salts, but that the oxygen and azote of the atmosphere, when condensed by capillarity, will combine in such proportions as to form nitric acid, through the agency of moisture and of neutralizing bases, such as lime, magnesia, potash, or soda. They conceive that as spongy platina serves to combine oxygen and hydrogen into water, or the vapour of alcohol and oxygen into acetic acid, and as the peroxide as well as the hydrate of iron, and argillaceous minerals, serve to generate ammonia from the oxygen of the air and the hydrogen of water; in like manner, porous limestones, through the agency of water, operate upon the constituents of the atmosphere to produce nitric acid, without the presence of animal matter. This opinion may certainly be maintained: for in India, Spain, and several other countries, at a distance from all habitations, immense quantities of saltpetre are reproduced in soils which have been washed the year before. But, on the other hand, it is known that the production of this salt may be greatly facilitated and increased by the admixture of animal offals with calcareous earths.

The spontaneous generation of nitre in Spain, Egypt, and especially in India, is sufficient to supply the wants of the whole world. There this salt is observed to form upon the surface of the ground in silky tufts, or even in slender prismatic crystals, particularly during the continuance of the hot weather that succeeds copious rains. These saline efflorescences, after being collected by rude besoms of broom, are lixiviated, allowed to settle, evaporated, and crystallized. In France, Germany, Sweden, Hungary, &c., vast quantities of nitrous salts are obtained by artificial arrangements called nitriaries, or nitre-beds. Very little nitrate of potash, indeed, is obtained in the first place; but the nitrates of lime and magnesia, which being deliquescent, remain in the nitrous earths in a semi-liquid state. The operation of converting these salts into good nitre is often sufficiently complex, in consequence of the presence of several muriates, which are difficult to eliminate.

The following instructions have been given by the consulting committee of poudres et salpÊtres in France, for the construction of their nitriÈres artificielles. The permeability of the materials to the atmospherical air, being found to be as indispensable as is the presence of a base to fix the nitric acid at the instant of its formation, the first measure is to select a light friable earth, containing as much carbonate of lime or old mortar-rubbish as possible; and to interstratify it with beds of dung, five or six inches thick, till a considerable heap be raised in the shape of a truncated pyramid, which should be placed under an open shed, and kept moist by watering it from time to time. When the whole appears to be decomposed into a kind of mould, it is to be spread under sheds in layers of from two to three feet thick; which are to be watered occasionally with urine and the drainings of dunghills, taking care not to soak them too much, lest they should be rendered impermeable to the air, though they should be always damp enough to favour the absorption and mutual action of the atmospherical gases. Moist garden mould affords an example of the physical condition most favourable to nitre-beds. The compost should be turned over, and well mixed with the spade once at least in every fortnight, and the sides of the shed should be partially closed, for although air be essential, wind is injurious, by carrying off the acid vapours, instead of allowing them to rest incumbent upon, and combine with, the bases. The chemical reaction is slow and successive, and can be made effective only by keeping the agents and materials in a state of quiescence. The whole process lasts two years; but since organic matters would yield in the lixiviation several soluble substances detrimental to the extraction of saltpetre, they must not be added during the operations of the latter six months; nor must any thing except clear water be used for watering during this period; at the end of which the whole organic ingredients of the beds will be totally decomposed. Where dung is not sufficiently abundant for the above stratifications, a nitre-bed should be formed in a stable with friable earth, covered with a layer of litter; after four months the litter is to be lifted off, the earth is to be turned over, then another layer of fresh earth, 8 or 9 inches thick, is to be placed over it, and a layer of the old and fresh litter over all. At the end of other four months, this operation is to be repeated; and in the course of a year the whole is ready to be transferred into the regular nitre-beds under a shed, as above described. Such are the laborious and disagreeable processes practised by the peasants of Sweden, each of whom is bound by law to have a nitre-bed, and to furnish a certain quantity of nitre to the state every year. His nitriary commonly consists of a small hut built of boards, with a bottom of rammed clay, covered by a wooden floor, upon which is spread a mixture of ordinary earth with calcareous sand or marl, and lixiviated wood-ashes. This mixture is watered with stable urine, and its surface is turned over once a week in summer, and once a fortnight in winter. In some countries, walls 2 or 3 feet thick, and 6 or 7 high, are raised with the nitrifying compost, interspersed with weeds and branches of trees, in order at once to bind them together, and to favour the circulation of air. These walls are thatched with straw; they are placed with one of their faces in the direction of the rains; and must be moistened with water not rich in animal matter. One side of the walls is upright and smooth; while the other is sloped or terraced, to favour the admission of humidity into their interior. The nitre eventually forms a copious efflorescence upon the smooth side, whence it may be easily scraped off.

M. Longchamp, convinced that organic matters are a useless expense, and not in the least essential to nitrification, proposes to establish nitre-beds where fuel and labour are cheapest, as amidst forests, choosing as dry and low a piece of ground as possible, laying them out upon a square space of about 1000 feet in each side, in the middle of which the graduation-house may be built, and alongside of it sheds for the evaporation furnaces and pans. Upon each of the four sides the nitrifying sheds are to be erected, 130 feet long by 30 feet wide, where the lixiviation would be carried on, and whence the water would be conducted in gutters to the graduation-house. The sheds are to be closed at the sides by walls of pisÉ, and covered with thatch. No substance is so favourable to nitrification as the natural stony concretion known under the name of lime-tuf. In Touraine, where it is used as a building stone, the saltpetre makers re-establish the foundations of old houses at their own expense, provided they are allowed to carry off the old tuf, which owes its nitrifying properties not only to its chemical nature, but to its texture, which being of a homogeneous porosity, permits elastic fluids and vapours to pass through it freely in all directions. With the rough blocks of such tuf, walls about 20 inches thick, and moderately high, are to be raised, upon the principles above prescribed; in the absence of tuf, porous walls may be raised with a mixture of arable soil, sand, and mortar-rubbish, chalk or rich marl. The walls ought to be kept moist.

In France, the greater part of the indigenous saltpetre is obtained by lixiviating the mortar-rubbish of old buildings, especially of those upon the ground-floor, and in sunk cellars; which are by law reserved for this purpose. The first object of the manufacturer is then to ascertain the richness of his materials in nitrous salts, to see if they be worth the trouble of working; and this point he commonly determines merely by their saline, bitter, and pungent taste, though he might readily have recourse to the far surer criteria of lixiviation and evaporation. He next pounds them coarsely, and puts them into large casks open at top, and covered with straw at bottom; which are placed in three successive levels. Water is poured into the casks till they are full, and after 12 hours’ digestion it is run off, loaded with the salts, by a spigot near the bottom. A fresh quantity of water is then added, and drawn off after an interval of four hours; even a third and fourth lixiviation are had recourse to; but these weak liquors are reserved for lixiviating fresh rubbish. The contents of the casks upon the second and third lower levels are lixiviated with the liquors of the upper cask, till the lyes indicate from 12 to 14 degrees of BaumÉ’s hydrometer. They are now fit for evaporating to a greater density, and of then receiving the dose of wood-ashes requisite to convert the materials of lime and magnesia into nitrate of potash, with the precipitation of the carbonates of magnesia and lime. The solution of nitre is evaporated in a copper pan, and as it boils, the scum which rises to the surface must be diligently skimmed off into a cistern alongside. Muriate of soda being hardly more soluble in boiling than in cold water, separates during the concentration of the nitre, and is progressively removed with cullender-shaped ladles. The fire is withdrawn whenever the liquor has acquired the density of 80° B.; it is allowed to settle for a little while, and is then drawn off, by a lead syphon adjusted some way above the bottom, into iron vessels, to cool and crystallize. The crystals thus obtained are set to drain, then re-dissolved and re-crystallized. The further purification of nitre, is fully described under the article Gunpowder.

The annual production of saltpetre in France, by the above-described processes, during the wars of the Revolution, amounted to 2000 tons (2 millions of kilogrammes) of an article fit for the manufacture of gunpowder; of which seven-twentieths were furnished by the saltpetre works of Paris alone. Considerably upwards of six times that quantity of common and cubic nitre were imported into the United Kingdom, for home consumption, during the year ending January 5, 1838.

Nitrate of potash crystallizes in six-sided prisms, with four narrow and two broad faces: the last being terminated by a dihedral summit, or two-sided acumination; they are striated lengthwise, and have fissures in their long axis, which are apt to contain mother water. The spec. gravity of nitre, varies from 1·93 to 2·00. It possesses a cooling, bitterish-pungent taste, is void of smell, permanent in the air when pure, fuses at a heat of about 662, into an oily-looking liquid, and concretes upon cooling into a solid mass, with a coarsely radiating fracture. This has got the unmeaning names of sal-prunelle and mineral crystal. At a red heat, nitre gives out at first a great deal of pretty pure oxygen gas; but afterwards nitrous acid fumes, while potash remains in the retort. It is soluble in 7 parts of water at 32°; in about 31/2 at 60° F., in less than half a part at 194°, and in four-tenths at 212°. It is very slightly soluble in spirit of wine, and not at all in absolute alcohol. It causes a powerful deflagration when thrown upon burning coals; and when a mixture of it with sulphur is thrown into a red-hot crucible, a very vivid light is emitted. Its constituents are, 46·55 potash, and 53·45 nitric acid.

Nitre is applied to many purposes:—1, to the manufacture of gunpowder; 2, to that of sulphuric acid; 3, to that of nitric acid, though nitrate of soda or cubic nitre has lately superseded this use of it to a considerable extent; 4, to that of flint-glass; 5, it is used in medicine; 6, for many chemical and pharmaceutical preparations; 7, for procuring by deflagration with charcoal or cream of tartar, pure carbonate of potash, as also black and white fluxes; 8, for mixing with salt in curing butcher meat; 9, in some countries for sprinkling in solution upon grain, to preserve it from insects; 10, for making fire-works. See Fire-works.

An Account of the quantities of Saltpetre and Cubic Nitre imported into, exported from, and retained for consumption in the United Kingdom. Duty 6d. per cwt:—

Imported in Exported in Retained for Consumption in
1835. 1836. 1837. 1835. 1836. 1837. 1835. 1836. 1837.
cwts. 264,338; 279,902; 349,993. 73,379; 38,414; 93,024. 204,580; 242,131; 256,969.

Duty received in 1837, £6,424.

NITRATE OF SILVER (Nitrate d’argent, Fr.; Silbersalpeter, Germ.); is prepared by saturating pure nitric acid of specific grav. 1·25 with pure silver, evaporating the solution, and crystallizing the nitrate. When the drained crystals are fused in a platina capsule, and cast into slender cylinders in silver moulds, they constitute the lunar caustic of the surgeon. This should be white, and unchangeable by light. It is deliquescent in moist air. The crystals are colourless transparent 4 and 6 sided tables; they possess a bitter, acrid, and most disagreeable metallic taste; they dissolve in their own weight of cold, and in much less of hot water; are soluble in four parts of boiling alcohol, but not in nitric acid; they deflagrate on redhot coals, like all the nitrates; and detonate with phosphorus when the two are struck together upon an anvil. They consist of 68·2 of oxide, and 31·8 of acid. Nitrate of silver, when swallowed, is a very energetic poison: but it may be readily counteracted, by the administration of a dose of sea-salt, which converts the corrosive nitrate into the inert chloride of silver. Animal matter, immersed in a weak solution of neutral nitrate of silver, will keep unchanged for any length of time; and so will polished iron or steel. Nitrate of silver is such a delicate reagent of hydrochloric or muriatic acid, as to show by a sensible cloud, the presence of one 113 millionth part of it, or one 7 millionth part of sea-salt in distilled water. It is much used under the name of indelible ink, for writing upon linen with a pen; for which purpose one drachm of the fused salt should be dissolved in three quarters of an ounce of water, adding to the solution as much water of ammonia as will re-dissolve the precipitated oxide, with sap-green to colour it, and gum-water to make the volume amount to one ounce. Traces written with this liquid should be first heated before a fire to expel the excess of ammonia, and then exposed to the sun-beam to blacken. Another mode of using nitrate of silver as an indelible ink, is to imbue the linen first with solution of carbonate of soda, to dry the spot, and write upon it with a solution of nitrate of silver, thickened with gum, and tinted with sap-green.

NITRATE OF SODA, Cubical Nitre (Nitrate de soude, Fr.; WÜrfelsalpeter, Germ.); occurs under the nitre upon the lands in Spain, India, Chile, and remarkably in Peru, in the districts of Atacama and Taracapa, where it forms a bed several feet thick. It appears in several places upon the surface, and extends over a space of more than 40 leagues, approaching near to the frontiers of Chile. It is sometimes efflorescent, sometimes crystallized, but oftener confusedly mixed with clay and sand. This immensely valuable deposit is only three days’ journey from the port of Conception in Chile, and from Iquiqui, another harbour situated in the southern part of Peru.

Nitrate of soda may be artificially prepared by neutralizing nitric acid with soda, and crystallizing the solution. It crystallizes in rhomboids, has a cooling, pungent, bitterish taste, less disagreeable than nitre; it becomes moist in the air; dissolves in 3 parts of water at 60° F., in less than 1 part of boiling water; deflagrates more slowly than nitre, and with an orange yellow flame. It consists, in its dry state, of 36·6 soda and 63·4 nitric acid; but its crystals contain one prime equivalent of water; hence they are composed of, acid 56·84, base 33·68, water 9·47.

It is susceptible of the same applications as nitre, with the exception of making gunpowder; for which it is not adapted, on account of its deliquescent property.

NITRATE OF STRONTIA. (Nitrate de strontiane, Fr.; Salpetersaurer strontian, Germ.) This salt is usually prepared from the sulphuret of strontium, obtained by decomposing sulphate of strontia with charcoal, by strong ignition of the mixed powders in a crucible. This sulphuret being treated with water, and the solution being filtered, is to be neutralized with nitric acid, as indicated by the test of turmeric paper; care being taken to avoid breathing the noxious sulphuretted hydrogen gas, which is copiously disengaged. The neutral nitrate being properly evaporated and set aside, affords colourless, transparent, slender octahedral crystals. It has a cooling, yet somewhat acrid taste; is soluble in 5 parts of cold, and in one half part of boiling water, as also in alcohol; is permanent in the air, deflagrates upon burning coals, gives off oxygen when calcined, and leaves caustic strontia. The salt consists of 48·9 strontia and 51·1 nitric acid. That salt is anhydrous; but there is another variety of it, which contains nearly 40 per cent. of water of crystallization, which occurs in large octahedrons. This is preferred for fire-works, because by efflorescence it is easily obtained in a fine powder, which mixes more intimately with the chlorate of potash and charcoal, for the composition of the brilliant red fires, now so much admired in theatrical conflagrations.

NITRIC ACID, Aquafortis (Acide nitrique, Fr.; SalpetersaÜre, Germ.); exists, in combination with the bases, potash, soda, lime, magnesia, in both the mineral and vegetable kingdoms. This acid is never found insulated. It was distilled from saltpetre so long ago as the 13th century, by igniting that salt, mixed with copperas or clay, in a retort. Nitric acid is generated when a mixture of oxygen and nitrogen gases, confined over water or an alkaline solution, has a series of electrical explosions passed through it. In this way the salubrious atmosphere may be converted into corrosive aquafortis. When a little hydrogen is introduced into the mixed gases, standing over water, the chemical agency of the electricity becomes more intense, and the acid is more rapidly formed from its elements, with the production of some nitrate of ammonia.

Nitric acid is usually made on the small scale by distilling, with the heat of a sand-bath, a mixture of 3 parts of pure nitre, and 2 parts of strong sulphuric acid, in a large glass retort, connected by a long glass tube with a globular receiver surrounded by cold water. By a well regulated distillation, a pure acid, of specific gravity 1·500, may be thus obtained, amounting in weight to about two-thirds of the nitre employed. To obtain easily the whole nitric acid, equal weights of nitre and concentrated sulphuric acid may be taken; in which case but a moderate heat need be applied to the retort. The residuum will be bisulphate of potash. When only the single equivalent proportion of sulphuric acid is used, namely 48 parts for 100 of nitre, a much higher heat is required to complete the distillation, whereby more or less of the nitric acid is decomposed, while a compact neutral sulphate of potash is left in the retort, very difficult to remove by solution in water, and therefore apt to destroy the vessel.

Aquafortis is manufactured upon the great scale in iron pots or cylinders of the same construction as I have described under muriatic acid. The more concentrated the sulphuric acid is, the less corrosively will it act upon the metal; and it is commonly used in the proportion of one part by weight to two of nitre. The salt being introduced into the cool retort, and the lid being luted tight, the acid is to be slowly poured in through the aperture f, fig. 748.; while the aperture g is connected by a long glass tube with a range of balloons inserted into each other, and laid upon a sloping bed of sand. The bottle i, with 3 tubulures partly filled with water, which is required for condensing muriatic acid gas, must, for the present purpose, be replaced by a series of empty receivers, either of glass or salt-glazed stoneware. The cylinders should be only half filled, and be worked off by a gradually raised heat.

Commercial aquafortis is very generally contaminated with sulphuric and muriatic acids, as also with alkaline sulphates and muriates. The quantity of these salts may be readily ascertained by evaporating in a glass capsule a given weight of the aquafortis; while that of the muriatic acid may be determined by nitrate of silver; and of sulphuric acid, by nitrate of baryta. Aquafortis may be purified in a great measure, by re-distillation at a gentle heat; rejecting the first liquid which comes over, as it contains the chlorine impregnation; receiving the middle portion as genuine nitric acid; and leaving a residuum in the retort, as being contaminated with sulphuric acid.

Since nitrate of soda has been so abundantly imported into Europe from Peru, it has been employed by many manufacturers in preference to nitre for the extraction of nitric acid, because it is cheaper, and because the residuum of the distillation, being sulphate of soda, is more readily removed by solution from glass retorts, when a range of these set in a gallery furnace is the apparatus employed. Nitric acid of specific gravity 1·47 may be obtained colourless; but by further concentration a portion of it is decomposed, whereby some nitrous acid is produced, which gives it a straw-yellow tinge. At this strength it exhales white or orange fumes, which have a peculiar, though not very disagreeable smell; and even when largely diluted with water, it tastes extremely sour. The greatest density at which it can be obtained is 1·51 or perhaps 1·52, at 60° F., in which state, or even when much weaker, it powerfully corrodes all animal, vegetable, and most metallic bodies. When slightly diluted it is applied, with many precautions, to silk and woollen stuffs, to stain them of a bright yellow hue. See Calico-printing; page 240.

In the dry state, as it exists in nitre, this acid consists of 26·15 parts by weight of azote, and 73·85 of oxygen; or of 2 volumes of the first gas, and 5 volumes of the second.

When of specific gravity 1·5, it boils at about 210° Fahr.; of 1·45, it boils at about 240°; of 1·42, it boils at 253°; and of 1·40, at 246° F. If an acid stronger than 1·420 be distilled in a retort, it gradually becomes weaker; and if weaker than 1·42, it gradually becomes stronger, till it assumes that standard density. Acid of specific gravity 1·485 has no more action upon tin than water has, though when either stronger or weaker it oxidizes it rapidly, and evolves fumes of nitrous gas with explosive violence. In my two papers upon nitric acid published in the fourth and sixth volumes of the Journal of Science (1818 and 1819), I investigated the chemical relations of these phenomena. Acid of 1·420 consists of 1 atom of dry acid, and 4 of water; acid of 1·485, of 1 atom of dry acid, and 2 of water; the latter compound possesses a stable equilibrium as to chemical agency; the former as to calorific. Acid of specific gravity 1·334, consisting of 7 atoms of water, and 1 of dry acid, resists the decomposing agency of light. Nitric acid acts with great energy upon most combustible substances, simple or compound, giving up oxygen to them, and resolving itself into nitrous gas, or even azote. Such is the result of its action upon hydrogen, phosphorus, sulphur, charcoal, sugar, gum, starch, silver, mercury, copper, iron, tin, and most other metals.

A Table of Nitric Acid, by Dr. Ure.

Specific
gravity.
Liq.
Acid
in 100.
Dry
acid
in 100.
1·5000 100 79·700
1·4980 99 78·903
1·4960 98 78·106
1·4940 97 77·309
1·4910 96 76·512
1·4880 95 75·715
1·4850 94 74·918
1·4820 93 74·121
1·4790 92 73·324
1·4760 91 72·527
1·4730 90 71·730
1·4700 89 70·933
1·4670 88 70·136
1·4640 87 69·339
1·4600 86 68·542
1·4570 85 67·745
1·4530 84 66·948
1·4500 83 66·155
1·4460 82 65·354
1·4424 81 64·557
1·4385 80 63·760
1·4346 79 62·963
1·4306 78 62·166
1·4269 77 61·369
1·4228 76 60·572
1·4189 75 59·775
1·4147 74 58·978
1·4107 73 58·181
1·4065 72 57·384
1·4023 71 56·587
1·3978 70 55·790
1·3945 69 54·993
1·3882 68 54·196
1·3833 67 53·399
1·3783 66 52·602
1·3732 65 51·805
1·3681 64 51·068
1·3630 63 50·211
1·3579 62 49·414
1·3529 61 48·617
1·3477 60 47·820
1·3427 59 47·023
1·3376 58 46·226
1·3323 57 45·429
1·3270 56 44·632
1·3216 55 43·835
1·3163 54 43·038
1·3110 53 42·241
1·3056 52 41·444
1·3001 51 40·647
1·2947 50 39·850
1·2887 49 39·053
1·2826 48 38·256
1·2765 47 37·459
1·2705 46 36·662
1·2644 45 35·865
1·2583 44 35·068
1·2523 43 34·271
1·2462 42 33·474
1·2402 41 32·677
1·2341 40 31·880
1·2277 39 31·083
1·2212 38 30·286
1·2148 37 29·489
1·2084 36 28·692
1·2019 35 27·895
1·1958 34 27·098
1·1895 33 26·301
1·1833 32 25·504
1·1770 31 24·707
1·1709 30 23·900
1·1648 29 23·113
1·1587 28 22·316
1·1526 27 21·519
1·1465 26 20·722
1·1403 25 19·925
1·1345 24 19·128
1·1286 23 18·331
1·1227 22 17·534
1·1168 21 16·737
1·1109 20 15·940
1·1051 19 15·143
1·0993 18 14·346
1·0935 17 13·549
1·0878 16 12·752
1·0821 15 11·955
1·0764 14 11·158
1·0708 13 10·361
1·0651 12 9·564
1·0595 11 8·767
1·0540 10 7·970
1·0485 9 7·173
1·0430 8 6·376
1·0375 7 5·579
1·0320 6 4·782
1·0267 5 3·985
1·0212 4 3·188
1·0159 3 2·391
1·0106 2 1·594
1·0053 1 0·797

NITROGEN, DEUTOXIDE OF; Nitrous gas, Nitric oxide (Deutoxide d’azote, Fr.; Stickstoffoxyd, Germ.); is a gaseous body which may be obtained by pouring upon copper or mercury, in a retort, nitric acid of moderate strength. The nitrous gas comes over in abundance without the aid of heat, and may be received over water freed from air, or over mercury, in the pneumatic trough. It is elastic and colourless; what taste and smell it possesses are unknown, because the moment it is exposed to the mouth or nostrils, it absorbs atmospherical oxygen, and becomes nitrous or nitric acid. Its specific gravity is 1·0393, or 1·04; whence 100 cubic inches weigh 36·66 gr. Water condenses not more than 1/20 of its volume of this gas. It extinguishes animal life, and the flame of many combustibles; but of phosphorus well kindled, it brightens the flame in a most remarkable degree. It consists of 47 parts of nitrogen gas, and 53 of oxygen gas, by weight; and of equal parts in bulk, without any condensation; so that the specific gravity of deutoxide of nitrogen is the arithmetical mean of the two constituents. The constitution of this gas, and the play of affinities which it exercises in the formation of sulphuric acid, are deeply interesting to the chemical manufacturer.

The Hyponitrous acid (SalpetrigesaÜre, Germ.), like the preceding compound, deserves notice here, on account of the part it plays in the conversion of sulphur into sulphuric acid, by the agency of nitre. It is formed by mingling four volumes of deutoxide of nitrogen with one volume of oxygen; and appears as a dark orange vapour which is condensable into a liquid at a temperature of 4° -zero, Fahr. When distilled, this liquid leaves a dark yellow fluid. The pure hyponitrous acid consists of 37·12 nitrogen, and 62·88 oxygen; or of two volumes of the first, and three of the second. Water converts it into nitric acid and deutoxide of nitrogen; the latter of which escapes with effervescence. This acid oxidizes most combustible bodies with peculiar energy and though its vapour does not operate upon dry sulphurous acid, yet, through the agency of steam it converts it into sulphuric acid, itself being simultaneously transformed into deutoxide of nitrogen; ready to become hyponitrous acid again, and to perform a circulating series of important metamorphoses. See Sulphuric Acid.

NITROGEN GAS, or AZOTE (Eng. and Fr.; Stickstoffgas, Germ.); constitutes about 79 hundredths of the bulk of the atmospheric air; it is copiously disengaged from several mineral springs, as from the natural basins of hot water which supply the baths of Leuk, near the Gemmi in Switzerland, and from other springs, in the Pyrenees, in Ceylon, South and North America, &c. It exists also in flesh and most animal substances, as well as in some vegetable products, being one of their essential constituents. When phosphorus is burnt within a jar filled with air, standing over water in the pneumatic trough, it consumes or absorbs the oxygen, and leaves nitrogen, which may be rendered pure by agitation with water. By exposing nitrite of ammonia to heat in a retort, nitrogen comes over alone in great abundance; for the hydrogen of the ammonia is sufficient to saturate the oxygen of the acid, and to convert it into water; while the nitrogen of both constituents is set at liberty. By transmitting chlorine through water of ammonia, or digesting lean flesh in warm nitric acid, nitrogen may also be obtained. This permanently elastic gas is destitute of colour, taste, and smell; it has a specific gravity of 0·976, air being 1·000. Hence 100 cubic inches of it weigh 29·7 gr. It extinguishes all burning bodies, and when respired without oxygen is fatal to animal life.

NITROGEN, PROTOXIDE OF; Nitrous oxide (Protoxide d’azote, Fr.; Stickstoffoxydul, Germ.); is a gas which displays remarkable powers when breathed, causing in many persons unrestrainable feelings of exhilaration, whence it has been called the laughing or intoxicating gas. It is prepared by exposing crystallized nitrate of ammonia to a heat of about 350° Fahr., in a glass retort. It is much denser than the air of the atmosphere, having a spec. grav. of 1·527; whence 100 cubic inches weigh 46·6 grains. It consists of 63·64 parts of nitrogen, and 36·36 of oxygen, by weight; or of two volumes of nitrogen and one volume of oxygen, condensed by reciprocal attraction into two volumes. It is colourless, and possesses all the mechanical properties of the atmosphere. Water previously freed from air absorbs its own volume of this gas; and thus affords a ready criterion for estimating its freedom from incondensable gases, as oxygen, nitrogen, and its deutoxide. Several combustibles burn in this gas with an enlarged blue and very vivid flame; and it relumes a taper, which has been blown out, provided its tip be redhot. By powerful pressure it may be liquefied. See Gas.

NITRO-MURIATIC ACID, Aqua regia (Acide nitro-muriatique, Fr.; Salpeter-salzsaÜre, KÖnigswasser, Germ.); is the compound menstruum invented by the alchemists for dissolving gold. If strong nitric acid, orange-coloured by saturation with nitrous gas (deutoxide of azote), be mixed with the strongest liquid muriatic acid, no other effect is produced than might be expected from the action of nitrous acid of the same strength upon an equal quantity of water; nor has the mixed acid so formed, any power of acting upon gold or platina. But if colourless aquafortis and ordinary muriatic acid be mixed together, the mixture immediately becomes yellow, and acquires the power of dissolving these two noble metals. When gently heated, pure chlorine gas rises from it, and its colour becomes deeper; when further heated, chlorine still rises, but now mixed with nitrous acid gas. If the process has been very long continued, till the colour becomes very dark, no more chlorine can be procured, and the liquor has lost the power of dissolving gold. It then consists of nitrous and muriatic acids. It appears, therefore, that aqua regia owes its peculiar properties to the mutual decomposition of the nitric and muriatic acids; and that water, chlorine, and nitrous acid gas are the results of that reaction. Aqua regia does not, strictly speaking, oxidize gold and platinum; it causes merely their combination with chlorine. It may be composed of very different proportions of the two acids; the nitric being commonly of specific gravity 1·34; the muriatic, of specific gravity 1·18 or 1·19. Sometimes 3 parts, and at others 6 parts of the muriatic acid are mixed with 1 of nitric; and occasionally muriate of ammonia, instead of muriatic acid, is added to nitric acid for particular purposes, as for making a solution of tin for the dyers. An aqua regia may also be prepared by dissolving nitre in muriatic acid.

NITROUS ACID (Acide nitreux, Fr.; Salpetrige salpetersaÜre, Germ.), may be procured by distilling, in a coated glass retort, perfectly dry nitrate of lead, into a glass receiver surrounded with a freezing mixture. The acid passes over in vapour, and condenses into a liquid; oxygen gas escapes through the safety tube; while oxide of lead remains in the bottom of the retort. Nitrous acid may also be obtained by distilling strong fuming nitric acid, at the lowest possible temperature, and rectifying what comes over. At 4° -zero, Fahr., this acid is colourless; at 32° it is wax yellow; at 60° it has an orange hue. It possesses a strong smell, has a very pungent, acrid, sour taste, and a specific gravity of 1·42. It powerfully decomposes organic bodies, staining them yellow. It boils at 82° Fahr. with the disengagement of red or orange fumes. Its constituents are, 41·34 of hyponitrous acid, and 58·66 of anhydrous nitric acid; or ultimately, 30·68 nitrogen = 1 volume, and 69·32 oxygen = 2 volumes. In its other habitudes, it is quite analogous to hyponitrous acid.

A mixture of this double or compound acid with nitric acid, constitutes the orange-brown fuming nitrous acid of the British apothecaries.

The hyponitrous and nitrous are two acids remarkable for containing no water in their composition; being therefore dry liquids.

NOPAL, is the Mexican name of the plant cactus opuntia, upon which the cochineal insect breeds.

NUTMEG (Muscade, Fr.; Muskatennuss, Germ.); is the fruit of the myristica moschata, a beautiful tree of the family of the laurineÆ of Jussieu, which grows in the Molucca islands. All the parts of this tree are very aromatic; but only those portions of the fruit called mace and nutmeg are sent into the market. The entire fruit is a species of drupa, of an ovoid form, of the size of a peach, and furrowed longitudinally. The nutmeg is the innermost kernel, or seed, contained in a thin shell, which is surrounded by the mace; and this again is enclosed in a tough fleshy skin, which opening at the tip, separates into two valves. The nutmeg tree yields three crops annually; one in April, which is the best; one in August; and one in December.

Good nutmegs should be dense, and feel heavy in the hand. When they have been perforated by worms, they feel light, and though the holes have been fraudulently stopped, the unsound ones may be easily detected by this criterion.

Nutmegs afford two oily products. 1. Butter of nutmeg, vulgarly called oil of mace, is obtained in the Moluccas, by expression, from the fresh nutmegs, to the amount of 50 per cent. of their weight. It is a reddish yellow butter-like substance, interspersed with light and dark streaks, and possesses the agreeable smell and taste of the nutmeg, from the presence of a volatile oil. It consists of two fats; one reddish and soft, soluble in cold alcohol; another white and solid, soluble in hot alcohol. 2. The volatile oil is solid, or a stereoptÈne, and has been styled Myristicine.

NUT OIL. See Oils, Unctuous.

NUX VOMICA, a poisonous nut, remarkable for containing the vegeto-alkali Strychnia.


                                                                                                                                                                                                                                                                                                           

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