CALORIC. The chemical name of the power or matter of heat.

CALORIFÈRE OF WATER. (CalorifÈre d’eau, Fr.; Wasser-Heitzung, Germ.) In the Dictionnaire Technologique, vol. iv., published in 1823, we find the following description of this apparatus, of late years so much employed in Great Britain for heating conservatories, &c. by hot water circulating in pipes:—

“This mode of heating is analogous to that by stove pipes: it is effected by the circulation of water, which, like air, is a bad conductor, but may serve as a carrier of caloric by its mobility. We may readily form an idea of the apparatus which has been employed for this purpose. We adapt to the upper part of either a close kettle, or of an ordinary cylindric boiler A, fig. 252, a tube B, which rises to a certain height, then descends, making several sinuosities with a gentle slope till it reaches the level of the bottom of the boiler, to whose lowest part, as that which is least heated, it is fitted at C. At the highest point of the tube F we adapt a vertical pipe, destined to serve as an outlet to the steam which may be formed if the temperature be too much raised: it serves also for the escape of the air expelled from the water by the heat; and it permits the boiler to be replenished from time to time as the water is dissipated by evaporation; lastly, it is a tube of safety.

“The apparatus being thus arranged, and all the tubes as well as the boiler filled with water, if we kindle fire in the grate D, the first portions of water heated, having become specifically lighter, will tend to rise: they will actually mount into the upper part of the boiler, and, of course, enter the tube B F: at the same time an equivalent quantity of water will re-enter the boiler by the other extremity C of the tube. We perceive that these simultaneous movements will determine a circulation in the whole mass of the liquid, which will continue as long as heat is generated in the fire-place; and if we suppose that the tubes, throughout their different windings, are applied against the walls of a chamber, or a stove-room, the air will get warmed by contact with the hot surfaces; and we may accelerate the warming by multiplying these contacts in the mode indicated.

“This calorifÈre cannot be employed so usefully as those with heated air, when it is wished to heat large apartments. In fact, the passage of heat through metallic plates is in the ratio of the difference of temperature and quantity of the heating surfaces. In the present case, the temperature of the water, without pressure, in the tubes, must be always under 100° C. (212° F.), even in those points where it is most heated, and less still in all the other points, while the temperature of the flues in air stoves, heated directly by the products of combustion, may be greatly higher. In these stoves, also, the pipes may without inconvenience have a large diameter, and present, consequently, a large heating surface; whereas, with the water calorifÈre, the pressure exercised by the liquid upon the sides of the tubes being in the ratio of the surfaces, we are obliged, in order to avoid too great pressure, to employ a multitude of small tubes, which is expensive. Lastly, if the hot-water circulation is to be carried high, as may be often necessary in lofty buildings, the pressure resulting from the great elevation would call for proportional thickness in the tubes and the boiler: for these reasons, and others which we shall state in treating of heating by steam, it appears that water cannot be advantageously substituted for air or steam in the applications above stated; yet this mode of heating presents very decided advantages where it is useful to raise the temperature a small number of degrees in a uniform manner.” See Incubation, artificial.

“M. Bonnemain applied, with much success, these ingenious processes of heating by the circulation of water, to maintain a very equal temperature in hot-houses (serres-chaudes), in stoves adapted to artificial incubation, and in preserving or quickening vegetation within hot-houses, or outside of their walls, during seasons unpropitious to horticulture.

“Since the capacity of water for heat is very great, if the mass of it in a circulation-apparatus be very considerable, and the circulation be accelerated by proper arrangements, as by cooling the descending tube exterior to the stove-room, we may easily obtain by such means a moderately high and uniform temperature, provided the heat generated in the fire-place be tolerably regular. We may easily secure this essential point by the aid of the fire-regulator, an instrument invented by M. Bonnemain, and which is described under the article Incubation, because there its use seems to be indispensable.”

From the above quotation, and, more especially, from the evidence adduced in the article Incubation, we see how little claim the Marquis de Chabannes, or any of his followers, can have to invention in their arrangements for heating apartments by the calorific motions of the particles of water, enclosed in pipes of any kind.

CAMBRIC. (Batiste, Fr.; Kammertuch, Germ.) A sort of very fine and rather thin linen fabric, first made at Cambray. An excellent imitation of this fabric is made in Lancashire, woven from fine cotton yarn hard twisted. Linen cambric of a good quality is also now manufactured in the United Kingdom from power-spun flax.

CAMLET OR CAMBLET. A light stuff, much used for female apparel. It is made of long wool hard spun, sometimes mixed in the loom with cotton or linen yarn.

CAMPHOR, or CAMPHIRE. This immediate product of vegetation was known to the Arabs under the names of kamphur and kaphur, whence the Greek and Latin name camphora. It is found in a great many plants, and is secreted, in purity, by several laurels: it occurs combined with the essential oils of many of the labiatÆ; but it is extracted, for manufacturing purposes only, from the Laurus camphora, which abounds in China and Japan, as well as from a tree which grows in Sumatra and Borneo, called, in the country, Kapour barros, from the name of the place where it is most common. The camphor exists, ready formed, in these vegetables, between the wood and the bark; but it does not exude spontaneously. On cleaving the tree Laurus sumatrensis, masses of pure camphor are found in the pith.

The wood of the laurus is cut into small pieces, and put, with plenty of water, into large iron boilers, which are covered with an earthen capital or dome, lined within with rice straw. As the water boils, the camphor rises with the steam, and attaches itself as a sublimate to the stalks, under the form of granulations of a grey colour. In this state it is picked off the straw, and packed up for exportation to Europe.

Formerly Venice held the monopoly of refining camphor, but now France, England, Holland, and Germany refine it for their own markets. All the purifying processes proceed on the principle that camphor is volatile at the temperature of 400° F. The substance is mixed, as intimately as possible, with 2 per cent. of quicklime, and the mixture is introduced into a large bottle made of thin uniform glass, sunk in a sand bath. The fire is slowly raised till the whole vessel becomes heated, and then its upper part is gradually laid bare in proportion as the sublimation goes on. Much attention and experience are required to make this operation succeed. If the temperature be raised too slowly, the neck of the bottle might be filled with camphor before the heat had acquired the proper subliming pitch; and, if too quickly, the whole contents might be exploded. If the operation be carried on languidly, and the heat of the upper part of the bottle be somewhat under the melting point of camphor, that is to say, a little under 350° F., the condensed camphor would be snowy, and not sufficiently compact and transparent to be saleable. Occasionally, sudden alternations of temperature cause little jets to be thrown up out of the liquid camphor at the bottom upon the cake formed above, which soil it, and render its re-sublimation necessary.

If, to the mixture of 100 parts of crude camphor and 2 of quicklime, 2 parts of bone-black, in fine powder, be added, the small quantity of colouring matter in the camphor will be retained at the bottom, and whiter cakes will be produced. A spiral slip of platina foil immersed in the liquid may tend to equalise its ebullition.

By exposing some volatile oils to spontaneous evaporation, at the heat of about 70° F., Proust obtained a residuum of camphor; from oil of lavender, 25 per cent. of its weight; from oil of sage, 12¹/₂; from oil of marjoram, 10.

Refined camphor is a white translucid solid, possessing a peculiar taste and smell. It may be obtained, from the slow cooling of its alcoholic solution, in octahedral crystals. It may be scratched by the nail, is very flexible, and can be reduced into powder merely by mixing it with a few drops of alcohol. Its specific gravity varies from 0·985 to 0·996. Mixed and distilled with six times its weight of clay, it is decomposed, and yields a golden yellow aromatic oil, which has a flavour analogous to that of a mixture of thyme and rosemary; along with a small quantity of acidulous water tinged with that oil, charcoal remains in the retort. In the air, camphor takes fire on contact of an ignited body, and burns all away with a bright fuliginous flame.

Camphor is little soluble in water; one part being capable of communicating smell and taste to 1000 of the fluid. 100 parts of alcohol, spec. grav. 0·806, dissolve 120 parts of camphor, at ordinary temperatures. It is separated, in a pulverulent state, by water. Ether and oils, both expressed and volatile, also dissolve it.

When distilled with eight parts of aquafortis, camphor is converted into camphoric acid. Camphor absorbs 144 times its volume of muriatic acid gas, and is transformed into a colourless transparent liquid, which becomes solid in the air, because the acid attracts humidity, which precipitates the camphor. One part of strong acetic acid dissolves two parts of camphor. By my analysis, camphor consists of 77·38 carbon, 11·14 hydrogen, and 11·48 oxygen. Berzelius’s numbers are certainly erroneous.

CAMWOOD. An article imported from Sierra Leone, which seems to possess similar dyeing powers with Brazil or Nicaragua wood.

CANDLE. (Chandelle, Fr.; Kerze, Licht, Germ.) I shall first briefly describe the ordinary manufacture of candles. They are either dipped or moulded. But the first part of the process is the sorting of the tallow. Mutton suet with a proportion of ox-tallow is selected for mould candles, because it gives them gloss and consistence. Coarser tallow is reserved for the dipped candles. After being sorted, it is cut into small pieces, preparatory to being melted or rendered; and the sooner this is done after the fat is taken from the carcase the better, because the fibrous and fleshy matters mixed with it promote its putrefaction. Tallow is too commonly melted by a naked fire applied to the bottom of the vessel, whereas it should be done either in a cold set pan, where the flame plays only round the sides a little way above the bottom, or in a steam-cased pan. After being fused a considerable time, the membranous matters collect at the surface, constituting the cracklings used sometimes for feeding dogs, after the fat has been squeezed out of it by a press. The liquid tallow is strained through a sieve into another copper, where it is treated with water at a boiling temperature in order to wash it. After a while, when the foul water has settled to the bottom, the purified tallow is lifted out, by means of tinned iron buckets, into tubs of a moderate size, where it concretes, and is ready for use.

It is a remarkable circumstance, that the wicks for the best candles are still cotton rovings imported from Turkey, notwithstanding the vast extension and perfection of cotton-spinning in this country. Four or more of these Turkey skeins, according to the intended thickness of the wick, are wound off at once into bottoms or clues, and afterwards cut by a simple machine into lengths corresponding to those of the candles to be made. Mr. Colebank obtained a patent, in June, 1822, for a machine for cutting, twisting, and spreading wicks, which, though convenient, does not seem to have come into general use. The operations are performed upon a series of threads at once. The apparatus is placed in a box, in front of which the operator sits. A reel extends across the box, at the hinder part, upon which the cotton threads have been previously wound: from this reel they are drawn off in proper lengths, doubled, and cut by an ingenious mechanism. By dipping the wicks into the melted tallow, rubbing them between the palms of the hands, and allowing the tallow which adheres to harden, they may be arranged with facility upon the broaches for the purpose of dipping. The dipping room is furnished with a boiler for melting the tallow, the dipping mould, or cistern, and a large wheel for supporting the broaches. From the ceiling of the workshop a long balance-shaped beam is suspended, to one end of which a wooden frame is attached for holding the broaches with the wicks arranged at proper distances. The opposite arm is loaded with a weight to counterbalance the wooden frame, and to enable the workman to ascertain the proper size of the candles. The end of the lever which supports the frame is placed immediately above the dipping cistern; and the whole machine is so balanced that, by a gentle pressure of the hand, the wicks are let down into the melted tallow as often as may be required.

The following convenient apparatus for dipping candles has been long in use at Edinburgh. In the centre of the dipping-room a strong upright post A A, fig. 253., is erected, with turning iron pivots at its two ends. Near its middle, six mortises are cut at small distances from one another, into each of which is inserted a long bar of wood B B, which moves vertically upon an iron pin, also passing through the middle of the shaft. The whole presents the appearance of a large horizontal wheel with twelve arms. A complete view of two of them only is given in the figure. From the extremity of each arm is suspended a frame, or port, as the workmen call it, containing 6 rods, on each of which are hung 18 wicks, making the whole number of wicks upon the wheel 1296. The machine, though apparently heavy, turns round by the smallest effort of the workman; and each port, as it comes in succession over the dipping-mould, is gently pressed downwards, by which means the wicks are regularly immersed in melted tallow. As the arms of the lever are all of the same length, and as each is loaded with nearly the same weight, it is obvious that they will all naturally assume a horizontal position. In order, however, to prevent any oscillation of the machine in turning round, the levers are kept in a horizontal position by means of small chains a a, one end of which is fixed to the top of the upright shaft, and the other terminates in a small square piece of wood b, which exactly fills the notch c in the lever. As one end of the levers must be depressed at each dip, the square piece of wood is thrown out of the notch by the workman pressing down the handle D, which communicates with the small lever e, inserted into a groove in the bar B. In order that the square piece of wood, fixed in one extremity of the chain, may recover its position upon the workman’s raising the port, a small cord is attached to it, which passes over a pulley inserted in a groove near c, and communicates with another pulley and weight, which draws it forward to the notch. In this way the operation of dipping may be conducted by a single workman with perfect ease and regularity, and even dispatch. No time is lost, and no unnecessary labour expended, in removing the ports after each dip; and, besides, the process of cooling is much accelerated by the candles being kept in constant motion through the air. The number of revolutions which the wheel must make, in order to complete one operation, must obviously depend upon the state of the weather and the size of the candles; but it is said that, in moderately cold weather, not more than two hours are necessary for a single person to finish one wheel of candles of a common size. Upon the supposition, therefore, that six wheels are completed in one day, no less a number than 7776 candles will be manufactured in that space of time by one workman.

I shall next describe the process of moulding, which, if possible, is even less complicated in its details than that of dipping. The moulds are made of some metallic substance, usually pewter, and consist of two parts. The shaft or great body of the mould is a hollow cylinder, finely polished in the inside, and open at both extremities. The top of the mould is a small metallic cup, having a moulding within-side, and a hole to admit the wick. The two parts are soldered together, and when united, as will readily be imagined, have the shape of a moulded candle. A third piece, called the foot, is sometimes added; it is a kind of small funnel, through which the liquid tallow runs into the mould, and, being screwed to the opposite extremity of the shaft, is removable at pleasure. This additional piece may certainly be useful in very mild weather; since, by removing it, the candles may be drawn more easily from the moulds; but, in general, it may be dispensed with.

Eight or twelve of these moulds, according to their size, are fixed in a frame, which bears a great resemblance to a wooden stool, the upper surface of which forms a kind of trough. The top of the moulds points downwards, and the other extremity, which is open, is inserted into the bottom trough or top of the stool, and made quite level with its upper surface. In order to introduce the wicks into the mould, the workman lays the frame upon its side on an adjoining table, and holding in his left hand a quantity of wicks, previously cut to the proper length, he introduces into the mould a long wire with a hooked point. As soon as the hook of the wire appears through the hole in the top of the mould, he attaches to it the looped end of the wick, and, immediately drawing back the wire, carries the wick along with it. In this manner each mould in succession is furnished with a wick. Another workman now follows, and passes a small wire through the loop of each wick. This wire is obviously intended to keep the wick stretched, and to prevent it from falling back into the mould upon the frame being placed in the proper position for filling. The frame is then handed to the person that fills the moulds, who previously arranges the small wires in such a manner that each wick may be exactly in the middle of the mould.

The moulds are filled by running tallow into each of them, or into the trough, from a cistern furnished with a cock, and which is regularly supplied with tallow of the proper temperature from an adjoining boiler. When the workman observes that the moulds are nearly half filled he turns the cock, and, laying hold of that portion of the wick which hangs out of the mould, pulls it tight, and thus prevents any curling of the wick, which might injure the candles: he then opens the cock, and completes the process of filling. The frame is now set aside to cool; and when the tallow has acquired a proper consistence, which the workman easily discovers by a snapping noise emitted by the candles upon pressing his thumb against the bottom of the moulds, he first withdraws the small wires which kept the wicks tense, and then, scraping off the loose tallow from the top of the frame with a small wooden spade, he introduces a bodkin into the loop of the wick, and thus draws each candle in succession from its mould. The candles are now laid upon a table for the inspection of the exciseman, and afterwards removed to the storehouse. Previous to storing them up, some candle-makers bleach their candles, by exposing them to the air and dews for several days. This additional labour can be necessary only when the dealer is obliged to have early sales; for if the candles are kept for some months, as they ought to be, before they are brought to market, they become sufficiently whitened by age.

Wax candles.—Next to tallow, the substance most employed in the manufacture of candles is wax. Wax candles are made either by the hand or with a ladle. In the former case, the wax, being kept soft in hot water, is applied bit by bit to the wick, which is hung from a hook in the wall; in the latter, the wicks are hung round an iron circle, placed immediately over a large copper-tinned basin full of melted wax, which is poured upon their tops, one after another, by means of a large ladle. When the candles have by either process acquired the proper size, they are taken from the hooks, and rolled upon a table, usually of walnut-tree, with a long square instrument of box, smooth at the bottom.

A few years ago I made a set of experiments upon the relative intensities of light, and duration of different candles, the results of which are contained in the following table.

A Scotch mutchkin, or ¹/₈ of a gallon of good seal oil, weighs 6010 gr., or 13¹/₁₀ oz., avoirdupois, and lasts in a bright Argand lamp 11 hours 44 minutes. The weight of oil it consumes per hour is equal to 4 times the weight of tallow in candles 8 to the pound, and ¹/₇ the weight of tallow in candles 6 to the pound. But, its light being equal to that of 5 of the latter candles, it appears from the above table that 2 pounds weight of oil, value 9d. in an Argand, are equivalent in illuminating power to 3 pounds of tallow candles, which cost about two shillings. The larger the flame in the above candles the greater the economy of light.

In June, 1825, M. Gay Lussac obtained a patent in England for making candles from margaric and stearic acids, improperly called stearine, by converting tallow into the above fat acids by the following process:—Tallow consists, by Chevreul’s researches, of stearine, a solid fat, and elaine, a liquid fat; the former being in much the larger proportion. When tallow is treated with an alkaline body, such as potash, soda, or lime, it is saponified; that is, its stearine and elaine become respectively stearic and elaic acids, and, as such, form compounds with these bases. When by the action of an acid, such as the sulphuric or muriatic, these combinations are decomposed, the fats reappear in the altered form of stearic and elaic acids; the former body being harder than tallow, and of a texture, somewhat like spermaceti, the latter body being fluid, like oil. “The decomposition of the soap should be made,” says the patentee, “in a large quantity of water, kept well stirred during the operation, and warmed by steam introduced in any convenient way. When the mixture has been allowed to stand, the acid of the tallow or fat will rise to the surface, and the water being drawn off will carry the alkaline or saline matters with it; but, if the acids of the tallow should retain any portion of the salts, fresh water may be thrown upon it, and the whole well agitated, until the acids have become perfectly free from the alkaline matters; and, when allowed to cool, the acids will be formed into a solid mass. This mass is now to be submitted to considerable pressure in such an apparatus as is employed in expressing oil from seeds; when the liquid acid will run off in the form of a substance resembling oil, leaving a solid matter, similar, in every respect, to spermaceti, which is fit for making candles.”

The wick to be used in the manufacture of these improved candles, and which forms one of the features of this invention, is to be made of cotton yarn, twisted rather hard, and laid in the same manner as wire is sometimes coiled round the bass strings of musical instruments. For this purpose, straight rods or wires are to be procured, of suitable lengths and diameters, according to the intended size of the candles about to be made; and these wires, having been covered with cotton coiled round them, as described, are to be inserted in the candle moulds as the common wicks are; and when the candle is made, and perfectly hard, the wire is to be withdrawn, leaving a hollow cylindrical aperture entirely through the middle of the candle. See Stearine.

CANE-MILL. See Mill and Sugar.

CANNON. For the composition of these implements of destruction, see Bronze.

CANVASS (Canevas, Fr.; Segeltuch, Germ.) It has been found that sails of ships made with the selvages and seams of the canvass running down parallel to their edges, are very apt to bag, and become torn in the middle, from the strain to which they are subjected by the pressure of the wind. To obviate this inconvenience, a mode of making sails, with the seams and selvages running diagonally, was proposed by Admiral Brooking, and a patent granted to him for the same on 4th of September, 1828. The invention of Messrs. Ramsay and Orr, which we are about to describe, has a similar object, viz., that of giving additional strength to sails by a peculiar manner of weaving the canvass of which they are made.

The improvement proposed under their patent of March, 1830, consists in weaving the canvass with diagonal threads; that is, placing the weft yarn, or shoot, in weaving, at an oblique angle to the warp yarns, instead of making the decussation of the warp, or weft threads, or yarns, at right angles to each other, as in the ordinary mode of weaving.

To accomplish this object the loom must be peculiarly constructed; that is, its warp and work beams must stand at an oblique angle with the sides of the loom, and the batten and slay must be hung in a peculiar manner, in order to beat up the weft, or shoot, in lines ranging diagonally with the warp. No drawing is shown of the method by which this arrangement of the loom is to be made, but it is presumed that any weaver would know how to accomplish it: the invention consisting solely in producing sail cloth with the threads, or yarns, of the weft ranging diagonally at any desired angle with the direction of the warp thread.

CAOUTCHOUC, GUM-ELASTIC, OR INDIAN-RUBBER, (Federharz, Germ.) occurs as a milky juice in several plants, such as the siphonia cahuca, called also hevea guianensis, cautschuc, jatropha elastica, castilleja elastica, cecropia pellata, ficus religiosa and indica, urceolaria elastica, &c. It is, however, extracted chiefly from the first plant, which grows in South America and Java. The tree has incisions made into it through the bark in many places, and it discharges the milky juice, which is spread upon clay moulds, and dried in the sun, or with the smoke of a fire, which blackens it.

The juice itself has been of late years imported. It is of a pale yellow colour, and has the consistence of cream. It becomes covered in the bottles containing it with a pellicle of concrete caoutchouc. Its spec. grav. is 1·012. When it is dried it loses 55 per cent. of its weight: the residuary 45 is elastic gum. When the juice is heated it immediately coagulates, in virtue of its albumen, and the elastic gum rises to the surface. It mixes with water in any proportion; and, when thus diluted, it coagulates with heat and alcohol as before.The specific gravity of caoutchouc is 0·925, and it is not permanently increased by any degree of pressure. By cold or long quiescence it becomes hard and stiff. When the milky juice has become once coherent, no means hitherto known can restore it to the emulsive state. By long boiling in water it softens, swells, and becomes more readily soluble in its peculiar menstrua; but when exposed to the air it speedily resumes its pristine consistence and volume. It is quite insoluble in alcohol; but in ether, deprived of alcohol by washing with water, it readily dissolves, and affords a colourless solution. When the ether is evaporated, the caoutchouc becomes again solid, but is somewhat clammy for a while. When treated with hot naphtha, distilled from native petroleum, or from coal tar, it swells to 30 times its former bulk; and if then triturated with a pestle, and pressed through a sieve, it affords a homogeneous varnish, which being applied by a flat edge of metal or wood to cloth, prepares it for forming the patent water-proof cloth of Mackintosh. Two surfaces of cloth, to which several coats of the above varnish have been applied, are, when partially dried, brought evenly in contact, and then passed between rollers, in order to condense and smooth them together. This double cloth is afterwards suspended in a stove-room to dry, and to discharge the disagreeable odour of the naphtha.

Caoutchouc dissolves in the fixed oils, such as linseed oil, but the varnish has not the property of becoming concrete upon exposure to air.

It has been lately asserted that caoutchouc is soluble in the oils of lavender and sassafras.

It melts at 248° F., and stands afterwards a much higher heat without undergoing any further change. When the melted caoutchouc is exposed to the air, it becomes hard on the surface in the course of a year. When kindled it burns with a bright flame and a great deal of smoke.

Neither chlorine, sulphurous acid gas, muriatic acid gas, ammonia, nor fluosilicic acid gas, affect it, whence it forms very valuable flexible tubes for pneumatic chemistry. Cold sulphuric acid does not readily decompose it, nor does nitric acid, unless it be somewhat strong. The strongest caustic potash lye does not dissolve it even at a boiling heat.

Caoutchouc, according to my experiments, which have been confirmed by those of Mr. Faraday, contains no oxygen, as almost all other solid vegetable products do, but is a mere compound of carbon and hydrogen, in the proportion, by my results, of 90 carbon to 10 hydrogen, being three atoms of the former to two of the latter. Mr. Faraday obtained only 87·2 carbon, from which I would infer that some of the carbon, which in this substance is difficult to acidify by peroxide of copper, had escaped its action. It is obvious that too little carbonic acid gas may be obtained, but certainly not more than corresponds to the carbon in the body. No carbon can be created in the process of ultimate analysis by pure peroxide of copper such as I employed; and I repeated the ignition after attrition of the mixture used in the experiment. Melted caoutchouc forms a very excellent chemical lute, as it adheres very readily to glass vessels, and withstands the corrosive action of acid vapours. This substance is much used for effacing the traces of plumbago pencils, whence it derived the name of Indian-rubber. It has been lately employed very extensively for making elastic bands or braces. The caoutchouc bottles are skilfully cut into long spiral slips, which are stretched, and kept extended till nearly deprived of their elasticity, and till they form a thread of moderate fineness. This thread is put into a braid machine, and covered with a sheath of cotton, silk, linen, or worsted. The clothed caoutchouc is then laid as warp in a loom, and woven into an elegant riband. When woven, it is exposed, upon a table to the action of a hot smoothing iron, which restoring to the caoutchouc all its primitive elasticity, the riband retracts considerably in length, and the braiding corrugates equally upon the caoutchouc cores. Such bands possess a remarkable elasticity, combined with any desired degree of softness. Sometimes cloth is made of these braided strands of caoutchouc used both as warp and as weft, which is therefore elastic in all directions. When a light fabric is required, the strands of caoutchouc, either naked or braided, are alternated with common warp yarns. For this mixed fabric a patent has been obtained. The original manufacturer of these elastic webs is a major in the Austrian service, who has erected a great factory for them at St. Denys, near Paris. See Elastic Bands.

Mr. William Henry Barnard, in the course of some experiments upon the impregnation of ropes with caoutchouc, at the factory of Messrs. Enderby at Greenwich, discovered that when this substance was exposed to a heat of about 600° F. it resolved itself into a vapour, which, by proper refrigeratory methods, was condensable into a liquid possessing very remarkable properties, to which the name caoutchoucine has been given. For this invention “of a solvent not hitherto used in the arts” Mr. Barnard obtained a patent, in August, 1833. His process for preparing it is described in his specification as follows:—I take a mass of the said caoutchouc, or Indian rubber, as imported, and having cut it into small lumps, containing about two cubic inches each (which I prefer), I throw these lumps into a cast-iron still (which I find adapted for the purpose, and a diagram of which is annexed to, and forms part of, this my specification), with a worm attached; fig. 254., A is the still, B the cover ground to a metallic fit, to admit of a thermometer to take the temperature; C the fire-place, D the ash-pit, E the worm-tub and worm, F the brick-work of the still, G a roller and carriage, in conjunction with a crane, or other means, to raise the cover to take out the residue, and to charge the same; H the chain.

I then apply heat to the still in the usual manner, which heat is increased until the thermometer ranges at 600 degrees of Fahrenheit, or thereabouts. And, as the thermometer ranges progressively upwards to 600 degrees of Fahrenheit, a dark-coloured oil or liquid is distilled over, which I claim as my said invention, such liquid being a solvent of caoutchouc, and other resinous and oleaginous substances. When the thermometer reaches 600 degrees, or thereabouts, nothing is left in the still but dirt and charcoal.

I have found the operation of distillation to be facilitated by the addition of a portion of this oil, either previous or subsequent to rectification, as hereinafter mentioned, in the proportion of one third of oil to two thirds of caoutchouc.

I afterwards subject the dark-coloured liquid thus distilled to the ordinary process of rectification, and thereby obtain fluids varying in specific gravity, of which the lightest hitherto has not been under 670, taking distilled water at 1000, which fluids I also claim as my said invention.

At each rectification the colour of the liquid becomes more bright and transparent, until at the specific gravity of 680, or thereabouts, it is colourless and highly volatile.

In the process of rectification (for the purpose of obtaining a larger product of the oil colourless) I put about one third of water into the still. In each and every state the liquid is a solvent of caoutchouc, and several resinous and oleaginous substances, and also of other substances (such as copal), in combination with very strong alcohol.

Having experienced much difficulty in removing the dirt which adheres to the bottom of the still, I throw into the still, lead and tin in a state of alloy (commonly called solder), to the depth of about half an inch, and, as this becomes fused, the dirt which lies on the surface of it is more easily removed.

Objections have been made to the smell of this liquid:—I have found such smell removed by mixing and shaking up the liquid with nitro-muriatic acid, or chlorine, in the proportion of a quarter of a pint of the acid (of the usual commercial strength) to a gallon of the liquid.

The discovery of the chemical solvent, which forms the subject of the patent above described, has excited considerable interest in the philosophic world, not only from its probable usefulness as a new article of commerce, but also from two very extraordinary characteristics which it is found to possess, viz., that, in a liquid state, it has less specific gravity than any other liquid known to chemists, being considerably lighter than sulphuric ether, and, in a state of vapour, is heavier than the most ponderous of the gases.

Its elementary constituents are,

This new material (when mixed with alcohol) is a solvent of all the resins and particularly of copal, which it dissolves, without artificial heat, at the ordinary temperature of the atmosphere; a property possessed by no other solvent known; and hence it is peculiarly useful for making varnishes in general. It also mixes readily with oils, and will be found to be a valuable and cheap menstruum for liquefying oil-paints; and without in the slightest degree affecting the most delicate colours, will, from its ready evaporation, cause the paint to dry almost instantly.

Cocoa-nut oil, at the common temperature of the atmosphere, always assumes a concrete form; but a portion of this caoutchoucine mixed with it will cause the oil to become fluid, and to retain sufficient fluidity to burn in a common lamp with extraordinary brilliancy.

Caoutchoucine is extremely volatile; and yet its vapour is so exceedingly heavy, that it may be poured, without the liquor, from one vessel into another like water.

CAPERS. The caper is a small prickly shrub, cultivated in Spain, Italy, and the southern provinces of France. The flowers are large roses of a pretty appearance, but the flower buds alone are the objects of this cultivation.

They are plucked before they open, and thrown into strong vinegar slightly salted, where they are pickled. The crop of each day is added to the same vinegar tub, so that in the course of the six months during which the caper shrub flowers, the vessel gets filled, and is sold to persons who sort the capers, (the smallest being most valued) by means of copper sieves. This metal is attacked by the acid, wherefrom the fruit acquires a green colour, much admired by ignorant connoisseurs.

The capers, as found in the French market, are distinguished into five sorts; the non-pareille, the capucine, the capote, the second, and the third; this being the decreasing order of their quality, which depends upon the strength of the vinegar used in pickling them, as also the size and colour of the buds.

The caper shrub grows in the driest situations, even upon walls, and does not disdain any soil; but it loves a hot and sheltered exposure. It is multiplied by grafts made in autumn, as also by slips of the roots taken off in spring.

CARAT or CARACT is a weight used by goldsmiths and jewellers. See Assay and Diamond.

CARBON, (Carbone, Fr.; Kohlenstoff, Germ.) in a perfectly pure state, constitutes diamond. Carbonaceous substances are usually more or less compound, containing hydrogen, or sometimes oxygen, and azote, along with earthy and metallic matters. Carbon, tolerably pure, abounds in the mineral kingdom; and, in a combined state, it forms a main constituent of vegetable and animal bodies. Anthracite is a mineral charcoal, differing from common pit-coal in containing no bitumen, and, therefore, burning without flame or smoke. Coke is the carbonaceous mass which remains after pit-coal has been exposed to ignition for some time out of contact of air; its volatile parts having been dissipated by the heat. It is a spongy substance, of an iron-black colour, a somewhat metallic lustre, and does not easily burn unless several pieces are kindled together. With a good draught, however, it produces a most intense heat. Wood charcoal is obtained by the calcination of wood in close vessels, as described under the article Acetic Acid, or in piles of various shapes, covered with loam, to screen it from the free action of the atmosphere, which would otherwise consume it entirely. See Charcoal. Such carbon is a solid, without smell or taste, and bears the strongest heats of our furnaces without suffering any change, provided air be excluded: it is a bad conductor of heat, but conducts electricity very well. When burned, it unites with oxygen, and forms carbonic acid, the fixed air of Dr. Black, the choke-damp of the miner. When this carbonic acid is made to traverse red hot charcoal it dissolves a portion of it, and becomes carbonic oxide, which contains only one half of its volume of oxygen; whereas carbonic acid consists of one volume of oxygen combined with one volume of the vapour of carbon, the two being condensed into one volume. If the specific gravity of oxygen, = 1·1025, be deducted from that of carbonic acid, = 1·5245, the difference, = 0·422, will be the specific gravity of the vapour of carbon; as well as the proportion present in that weight of the acid.

Charcoal obtained by the action of a rapid fire in close vessels is not so solid and so good a fuel as that which is made in the ancient way by the slow calcination of pyramidal piles covered with earth. One of the most economical ovens for making wood charcoal is that invented by M. Foucauld, which he calls a shroud, or abri. To construct one of these, 30 feet in diameter at the base, 10 feet at its summit, and from 8 to 9 feet high, he forms, with wood 2 inches square, a frame 12 feet long, 3 feet broad at one end, and one foot at the other. The figure will explain the construction. The uprights, A B and C D, of this frame are furnished with three wooden handles a a a, and a' a' a', by means of which they can be joined together, by passing through two contiguous handles a wooden fork, the frame being previously provided with props, as shewn in fig. 259, and covered with loam mixed with grass. A flat cover of 10 feet diameter, made of planks well joined, and secured by four cross bars, is mounted with two trap doors, M N, fig. 261., for giving egress to the smoke at the commencement of the operation; a triangular hole P, cut out in the cover, receives the end of a conduit Q R S, (figs. 262. and 261.) of wood formed of three deals, destined to convey the gases and condensed liquids into the casks F G H. Lastly, a door T, which may be opened and shut at pleasure, permits the operator to inspect the state of the fire. The charcoal calcined by this abri, has been found to be of superior quality.

When it is wished to change the place where the abri is erected, and to transport it to a store of new-felled timber, the frame is taken down, after beating off the clay which covers it, the joints are then cut by a saw, as well as the ends of the forks which fixed the frames to one another. This process is economical in use, simple and cheap in construction; since all the pieces of the apparatus are easily moved about, and may be readily mounted in the forests. For obtaining a compact charcoal, for the use of artisans, this mixed process of Foucauld is said to be preferable to either the close iron cylinder or the pile.

For making gunpowder-charcoal the lighter woods, such as the willow, dogwood, and alder answer best; and in their carbonization care should be taken to let the vapours freely escape, especially towards the end of the operation, for when they are re-absorbed, they greatly impair the combustibility of the charcoal.

By the common process of the forests, about 18 per cent. of the weight of the wood is obtained; by the process of Foucauld about 24 per cent. are obtained, with 20 of crude pyrolignous acid of 10 degrees BaumÉ. By the process described under Acetic Acid, 27 of charcoal, and 18 of acid at 6 degrees, are procured from 100 parts of wood, besides the tar. These quantities were the results of careful experimenting, and are greater than can be reckoned upon in ordinary hands.

Charcoal for chemical purposes may be extemporaneously prepared by calcining pieces of wood covered with sand in a crucible, till no more volatile matter exhales.

The charcoal of some woods contains silica, and is therefore useful for polishing metals. Being a bad conductor of heat, charcoal is employed sometimes in powder to encase small furnaces and steam-pipes. It is not affected by water; and hence, the extremities of stakes driven into moist ground are not liable to decomposition. In like manner casks when charred inside preserve water much better than common casks, because they furnish no soluble matter for fermentation or for food to animalcules.

Lowitz discovered that wood charcoal removes offensive smells from animal and vegetable substances, and counteracts their putrefaction. He found the odour of succinic and benzoic acids, of bugs, of empyreumatic oils, of infusions of valerian, essence of wormwood, spirits distilled from bad grain, and sulphureous substances were all absorbable by freshly calcined charcoal properly applied. A very ingenious filter has been constructed for purifying water, by passing it through strata of charcoal of different fineness.

When charcoal is burned, one third of the heat is discharged by radiation, and two thirds by conduction.

The following table of the quantity of charcoal yielded by different woods was published by Mr. Mushet, as the result of experiments carefully made upon the small scale. He says, the woods before being charred were thoroughly dried, and pieces of each kind were selected as nearly alike in every respect as possible. One hundred parts of each sort were taken, and they produced as under:—

Messrs. Allen and Pepys, from 100 parts of the following woods, obtained the quantities of charcoal as under:—

It is observable that the quantities obtained by Messrs. Allen and Pepys are in general less than those given by Mr. Mushet, which may be owing to Mr. Mushet not having applied sufficient heat, or operated long enough, to dissipate the aqueous matter of the gaseous products.

To those persons who buy charcoal by weight, it is important to purchase it as soon after it is made as possible, as it quickly absorbs a considerable portion of water from the atmosphere. Different woods, however, differ in this respect. Messrs. Allen and Pepys found that by a week’s exposure to the air, the charcoal of

The following is a tabular view of the volumes of the different gases which were absorbed in the course of 24 hours, by one volume of charcoal, in the experiments of M. Theodore de Saussure, which were conducted in a way likely to produce correct results. Each portion of charcoal was heated afresh to a red heat, and allowed to cool under mercury. When taken from the mercury, it was instantly plunged into the vessel of gas.

Neumann, who made many experiments on charcoal, informs us that for the reduction of the metallic oxides, the charcoal of the heavier woods, as that of the oak and the beech, is preferable, and that, for common fuel, such charcoal gives the greatest heat, and requires the most plentiful supply of air to keep it burning; while those of the lighter woods preserve a glowing heat with a much less draught of air; and that for purposes where it is desirable to have a steady and a still fire, charcoal should be employed which has been made from wood previously divested of its bark, since it is the cortical part which crackles and flies off in sparks during combustion, while the coal of the wood itself seldom does.

For making crayons of charcoal, the willow is the best wood that can be employed, as the softness is uniform in all its parts. Its durability may be seen in several of our old churchyards, where the letters made with lamp-black are still perfect, though the white lead with which the body of the stones was painted is entirely destroyed.

This property of carbon is shewn, however, in a more striking manner by the writings that were found in the ruins of Herculaneum, which have retained their original blackness for two thousand years. The ancients wrote with ink made from ground charcoal.

If it be required to purify any carbonaceous matter, to render it fitter for delicate pigments, this may be done by first calcining it in a close vessel, and then lixiviating it in water slightly acidulated by nitric acid.

The incorruptibility of charcoal was well known to the ancients, and they availed themselves of this property upon all important occasions.

About sixty years ago a quantity of oak stakes were found in the bed of the Thames, in the very spot where Tacitus says that the Britons fixed a vast number of such stakes, to prevent the passage of Julius CÆsar and his army. These stakes were charred to a considerable depth, had retained their form completely, and were firm at the heart.

Most of the houses in Venice stand upon piles of wood, which have all been previously charred for their preservation. In this country, estates were formerly marked out by charred stakes driven to a considerable depth into the ground. See Bone-black, Charcoal, and Graphite.

CARBONATED WATER, is water either pure, or holding various saline matters in solution, impregnated with carbonic acid gas. For general sale in this country, the water usually contains a little soda, which being charged with the gas, is called Soda water; see this article for a description of an excellent machine for the manufacture of this fashionable beverage.

CARBONATES. Saline compounds in definite proportions, of carbonic acid, with alkalis, earths, and the ordinary metallic oxides.

The carbonates principally used in the arts and manufactures are those of ammonia, copper, iron, lead, lime, magnesia, potash, soda. Native carbonate of copper is the beautiful green mineral called Malachite.

Carbonates are easily analyzed by estimating either by weight or measure the quantity of carbonic acid which they evolve under the decomposing action of somewhat dilute sulphuric, nitric, or muriatic acid; for as they are all compounds of acid, and base in equivalent proportions, the quantity of acid will indicate the quantity of base. Thus, as pure limestone consists of 56 of lime and 44 of acid, in 100 parts, if upon examining a sample of limestone we find it to give out only 22 per cent. of carbonic acid gas, during its slow solution in muriatic acid, we are sure that there are only 28 parts of lime present. I have described, in the Annals of Philosophy, for October, 1817, a simple form of apparatus for analyzing the carbonates with equal readiness and precision. The simple rule by measure to which I was led, may be thus stated: From the bulk of evolved gas, expressed in cubic inches and tenths, deduct ¹/₂₀, the remainder will express the proportion of real limestone present in the grains employed. Pure magnesian limestone yields very nearly a cubic inch of the gas for every grain in weight.

CARBONATE OF AMMONIA. A salt called in modern chemistry sesquicarbonate, to denote its being composed of one and a half equivalent primes of carbonic acid, and one of ammonia. It consists by my analysis of 55·89 carbonic acid, 28·86 ammonia, and 15·25 water, in 100 parts. It is generally prepared by mixing from 1¹/₄ to 1¹/₂ parts of well-washed dry chalk, with 1 of sal-ammoniac, introducing the mixture into an earthen or cast-iron retort, or subliming pot, and exposing it to a heat gradually raised to redness. By double decomposition, the ammonia is volatilized in combination with the carbonic acid of the chalk, and the vapours are received in a condensing receiver made either of glass, stone ware, or lead. The chlorine of the sal-ammoniac remains in the retort, associated with the basis of the chalk in the state of chloride of calcium. Some ammonia gas escapes during the process.

The saline mass thus sublimed is purified by a second sublimation in glass, or salt-glazed earthen vessels. The salt may be obtained, by the above method carefully conducted, in rhomboidal octahedrons, but it is generally made for the market in a compact semi-crystalline white cake. It has a pungent ammoniacal smell, a hot, pungent, alkaline taste, a strong alkaline reaction, and dissolves in two parts of cold water. It must be kept in well-closed vessels, as by exposure to the air a portion of its ammonia exhales, and it passes into the state of the scentless bi-carbonate. It is employed much in medicine, chemical analysis, and by the pastry-cooks to give sponginess to their cakes in consequence of its volatilization from their dough in the oven. See Sal-Ammoniac.

For the other carbonates used in the arts, see their respective bases; copper, lead, lime, &c.

CARBONIC ACID (Acide carbonique, Fr.; KohlensÄure, Germ.), consists of 1 prime equivalent of carbon = 6·125 + 2 of oxygen = 16·026, whose joint sum = 22·151, represents the atomic weight or combining ratio of this acid, in the neutral or protocarbonate salts. Its composition by volume is stated under Carbon. Its natural form is a gas, whose specific gravity is 1·5245, compared to atmospheric air 1·000; and being so dense, it may be poured out of one vessel into another. Hence it was called at first aËrial acid. From its existing copiously, in a solid state, in limestones and the mild alkalies, it was styled fixed air by its proper discoverer, Dr. Black. About one volume of it exists in 1000 volumes of common atmospheric air, which may be made manifest by the crust of carbonate it occasions upon the surface of lime water. Carbonic acid gas is found accumulated in many caverns of volcanic districts, and particularly in the grotto dei cani at Pausilippo, near Puzzuoli; being disengaged in such circumstances by the action of subterranean fire, and, possibly, of certain acids, upon the limestone strata. It often issues from fountains in copious currents, as at Franzensbrunn, near Eger, in Polterbrunnen; near Trier; and Byrreshorn. This acid gas occurs also frequently in mines and wells, being called choke damp, from its suffocating quality. Its presence may, at all times, be detected, by letting down a lighted candle, suspended from a string, into the places suspected of containing this mephitic air. It exists, in considerable quantities, in the water of every pump well, and gives it a fresh and pleasant taste. Water, exposed some time to the air, loses these aerial particles, and becomes vapid. Many springs are highly impregnated with carbonic acid gas, and form a sparkling beverage; such as the Selterswasser, from Selters upon the Lahn, in the grand duchy of Nassau; of which no less than two millions and a half of bottles are sold every year. A prodigious quantity of a similar water is also artificially prepared in Great Britain, and many other countries, under the name of aËrated or soda water.

Carbonic acid occurs in nature, combined with many salifiable bases; as in the carbonates of soda, baryta, strontia, magnesia; the oxides of iron, manganese, zinc, copper, lead, &c. From these substances it may be separated, generally speaking, by strong ignition, or, more readily, by the superior affinity of muriatic, sulphuric, or nitric acid, for the earth or metallic oxide. It is formed whenever vegetable or animal substances are burned with free access of air, from the union of their carbonaceous principle with atmospheric oxygen. It is also formed in all cases of the spontaneous decomposition of organic substances, particularly in the process of fermentation; and constitutes the pungent, noxious, heavy gas thrown off, in vast volumes, from beer vats. See Distillation and Fermentation. Carbonic acid is also generated in the breathing of animals; from 4 to 5 per cent., in volume, of the inhaled oxygen being converted, at each expiration, into this gas, which contaminates the air of crowded apartments, and renders ventilation essential to health, and even to life: witness the horrible catastrophe of the Black-hole at Calcutta.

Carbonic acid gas is destitute of colour, has a sourish, suffocating smell, an acidulous pungent taste, imparts to moist, but not dry, litmus paper, a transient reddish tint, and weighs per 100 cubic inches, 46¹/₂ grains; and per cubic foot, 803¹/₂ grains; a little more than 3³/₄ oz. avoirdupoid. A cubic foot of air weighs about two thirds of that quantity, or 527 grains. It may be condensed into the liquid state by a pressure of 40 atmospheres, and this liquid may be then solidified by its own sudden spontaneous evaporation. If air contain more than 15 per cent. in bulk of this gas, it becomes unfit for respiration and combustion, animal life and candles being speedily extinguished by it.

Before a person ventures into a deep well, or vault containing fermenting materials, he should introduce a lighted candle into the space, and observe how it burns. Carbonic acid, being so much denser than common air, may be drawn out of cellars or fermenting tubs, by a pump furnished with a leather hose, which reaches to the bottom. Quicklime, mixed with water, may be used also to purify the air of a sunk apartment by its affinity for, or power of, absorbing this aËrial acid. See Mineral Waters and Soda Water.

CARBONIC OXIDE. See the article Carbon.

CARBUNCLE. A gem highly prized by the ancients; most probably a variety of the noble garnet of modern mineralogists.

CARBURET OF SULPHUR, called also sulphuret of carbon, and alcohol of sulphur, is a limpid volatile liquid, possessing a penetrating fetid smell, and an acrid burning taste. Its specific gravity is 1·265; and its boiling point is about 112° Fahr. It evaporates so readily, and absorbs so much heat in the vaporous state, that if a tube containing quicksilver, surrounded with lint dipped in this liquid, be suspended in the receiver of an air-pump, on making the vacuum, the quicksilver will be congealed. It consists of 15·8 carbon and 84·2 sulphur, in 100 parts; being two equivalent primes of the latter to one of the former.

CARBURETTED HYDROGEN. A compound of carbon and hydrogen, of which there are several species—such as oil-gas, coal-gas, olefiant gas, oil of lemons, otto of roses, oil of turpentine, petroleum, naphta, naphthaline, oil of wine, caoutchoucine and caoutchouc.

CARDS, PLAYING. (Cartes À jouer, Fr.; Karten, Germ.) Mr. de la Rue obtained, in February, 1832, a patent for certain improvements in the manufacture of playing cards, which he distributed under three heads: first, printing the pips, and also the picture or court-cards, in oil colours by means of types or blocks; secondly, effecting the same in oil colours by means of lithography; and thirdly, gilding or silvering borders, and other parts of the characters, by the printing process, either by types, blocks, or lithography.

In the ordinary mode of manufacturing playing cards, their devices are partly produced by copperplate printing, and they are filled up with water colours by the means called stencilling.

The patentee does not propose any material alteration in the devices or forms upon the cards, but only to produce them with oil colours; and, to effect this, he follows precisely the same mode as that practised by calico printers.

A set of blocks or types properly devised, are produced for printing the different pips of hearts, diamonds, spades, and clubs, or they are drawn, as other subjects, in the usual way upon stone. The ink or colour, whether black or red, is to be prepared from the best French lamp-black, or the best Chinese vermillion ground in oil, and laid on the types and blocks, or on the stone, in the same way as printers’ ink, and the impressions taken-on to thick drawing paper by means of a suitable press in the ordinary manner of printing.

The picture or court-cards are to be produced by a series of impressions in different colours, fitting into each other exactly in the same way as in printing paper hangings, or silks and calicoes, observing that all the colours are to be prepared with oil.

For this purpose a series of blocks or types are to be provided for each subject, and which, when put together, will form the whole device. These blocks are to be used separately, that is, all the yellow parts of the picture, for instance, are to be printed at one impression, then all the red parts, next all the flesh colour, then the blue portions, and so on, finishing with the black outlines, which complete the picture.

If the same is to be done by lithography, there must be as many stones as there are to be colours, each to print its portion only; and the impression, or part of the picture given by one stone, must be exactly fitted into by the impression given from the next stone, and so on until the whole subject is complete.

A superior kind of card is proposed to be made, with gold or silver devices in parts of the pictures, or gold or silver borders round the pips. This is to be effected by printing the lines which are to appear as gold or silver, with gilders’ size, in place of ink or colour; and immediately after the impression has been given, the face of the card is to be powdered over with gold dust, silver, or bronze, by means of a soft cotton or wool dabber, by which the gold, silver, or bronze will be made to adhere to the picture, and the superfluous portions of the metal will wipe off by a very slight rubbing. When the prints are perfectly dry, the face of the card may be polished by means of a soft brush.

If it should be desirable to make these improved cards to resemble ivory, that may be done by preparing the face of the paper in the first instance with a composition of size and fine French white, and a drying oil, mixed together to about the consistence of cream; this is to be washed over the paper, and dried before printing, and when the cards are finished, they will exactly resemble ivory.

The only thing remaining to be described, is the means by which the successive impressions of the types, blocks, or stones forming the parts of the pictures, are to be brought exactly to join each other, so as to form a perfect whole design when complete; this is by printers called registering, and is to be effected much in the usual way, by points in the tympan of the press, or by marks upon the stones.

The parts of the subject having been all accurately cut or drawn to fit, small holes are to be made with a fine awl through a quire or more of the paper at once, by placing upon the paper a gauge-plate, having marks or guide-holes, and by observing these, the same sheet laid on several times, and always made to correspond with the points or marks, the several parts of the picture must inevitably register, and produce a perfect subject.

CARD CUTTING. Mr. Dickinson’s patent machine for cutting cards, consists of a pair of rollers with circular revolving cutters, the edges of which are intended to act against each other as circular shears, and the pasteboards in passing between these rollers are cut by the circular shears into cards of the desired dimensions. These rollers are mounted in suitable standards, with proper adjustments, and are made to revolve by a band and pulley connected to the axle of a crank, or by any other convenient means.

Fig. 263. is a front view of this machine; a a and b b are the two rollers, the upper one turning upon an extended axle, bearing in the standards, the lower one upon pivots. These rollers are formed by a series of circular blocks, between a series of circular steel cutters, which are slidden on to iron shafts, and held together upon their axle by nuts screwed up at their ends. The accurate adjustment of the cutters is of the first importance to their correct performance; it is therefore found necessary to introduce spiral springs within the blocks, in order to press the cutters up to their proper bearings. A section of one of the blocks is shewn at fig. 265, and an end view of the same at fig. 266, with the spiral springs inserted.

At the outer extremity of the axle of the roller a, a rigger c, is attached, whence a band passes to a pulley d, on the crank shaft e, to which a flywheel f, is affixed, for the purpose of rendering the action uniform. Rotatory motion being given to the crank shaft, the upper roller is turned, the lower roller moving at the same time by the friction against the edges of the cutters.

Fig. 264 is an end view of the rollers, showing the manner in which the pasteboards are guided and conducted between the cutters. In the front of the machine a movable frame g, is to be placed, for the purpose of receiving the pasteboards, preparatory to cutting them into cards, and a stop is screwed to this frame for the edge of the pasteboard to bear against, which stop is adjustable to suit different sizes. From the back part of this frame an arm h, extends, the extremity of which acts against the periphery of a ratchet wheel i, fixed at the end of the roller b, and hence, as the roller goes round, the frame is made to rise and fall upon its pivots, for the purpose of guiding the pasteboard up to the cutters; at the same time a rod k, hanging in arms from the sides of the standards (shewn by dots in fig. 263), falling upon the pasteboard, confines it, while the cutters take hold, and racks, corresponding with the indentations of the rollers, are placed as at l l, by means of which the cards, when cut, are pushed out of the grooves.

As various widths of cards will require to be cut by this machine, the patentee proposes to have several pairs of rollers ready adjusted to act together, when mounted in the standards, in preference to shifting the circular cutters, and introducing blocks of greater or less width.

The second part of the invention is a machine for pasting the papers, and pressing the sheets together to make pasteboard. This machine consists of several reels (we suppose rollers are intended) on which the paper is to be wound, along with a paste trough, and rotatory brushes. The several parts of this machine, and their operations in making pasteboard, are described in the specification, but the patentee having omitted the letters of reference in the drawing which he has enrolled, it becomes difficult to explain it.

As far as we are enabled to understand the machine, it appears, that damped paper is to be wound upon two rollers, and conducted from thence over two other rollers; that two fluted rollers revolving in the paste trough are to supply paste to two circular brushes, and that by those brushes the papers are to be pasted upon one side, and then pressed together, to make the pasteboard; after this, the pasteboard is to be drawn on to a table, and to remain there until sufficiently dry to be wound upon other rollers. By comparing this description with the figure, perhaps the intended operations of the machine may be discovered, it is the best explanation we are enabled to give.

CARDS, (Cardes, Fr.; Karden, Ger.) are instruments which serve to disentangle the fibres of wool, cotton, or other analogous bodies, to arrange them in an orderly lap or fleece, and thereby prepare them for being spun into uniform threads. The fineness and the levelness of the yarn, as well as the beauty of the cloth into which it enters, depend as much upon the regularity and perfection of the carding, as upon any subsequent operations of the factory. The quality of the carding depends more upon that of the cards than upon any attention or skill in the operative; since it is now nearly an automatic process, conducted by young women called card-tenters.

Cards are formed of a sheet or fillet of leather pierced with a multitude of small holes, in which are implanted small staples of wire with bent projecting ends called teeth. Thus every piece of wire is double toothed. The leather is afterwards applied to a flat or cylindrical surface of wood or metal, and the co-operation of two or more such surfaces constitutes a card. The teeth of cards are made thicker or slenderer, according as the filaments to be carded are coarser or finer, stiffer or more pliant, more valuable or cheaper. It is obviously of great importance that the teeth should be all alike, equably distributed, and equally inclined over the surface of the leather, a degree of precision which is scarcely possible with handwork. To judge of the difficulty of this manipulation we need only inspect the annexed figures. The wire must first be bent at right angles in c and d, fig. 268, then each branch must receive a second bend in a and b at a determinate obtuse angle, invariable for each system of cards. It is indispensable that the two angles c a e and d b f be mathematically equal, not only as to the twin teeth of one staple, but through the whole series; for it is easy to see that if one of the teeth be more or less sloped than its fellow, it will lay hold of more or less wool than it, and render the carding irregular. But though the perfect regularity of the teeth be important, it is not the sole condition towards making a good card. It must be always kept in view that these teeth are to be implanted by pairs in a piece of leather, and kept in it by the cross part c d. The leather must therefore be pierced with twin holes at the distance c d; and pierced in such a manner, that the slope of the holes, in reference to the plane of the leather, be invariably the same; for otherwise the length of the teeth would vary with this angle of inclination, and the card would be irregular.

A third condition essential towards producing perfect regularity, is that the leather ought to be of the same thickness throughout its whole surface, otherwise the teeth, though of the same length and fixed at the same angle, would be rendered unequal by the different thicknesses of the leather, and the operation of carding would be in consequence extremely defective. Fig. 267. shows the card-teeth acting against each other, as indicated by the arrows in two opposite directions; in fig. 269. they work one way.

Of late years very complex but complete and well-acting machines have been constructed for splitting the leather or equalizing it by shaving, for bending and cutting the wires, and implanting them in the leather, into holes pierced with perfect regularity. Card machines which fashion the teeth with great precision and rapidity, and pierce the leather, have been for a considerable time in use at Halifax, in Yorkshire, a town famous for the excellence of its card-cloth, as also at Leeds, Glasgow, and several other places. The wires and the leather thus prepared are given out by the manufacturer to women and children, who put them together.

1. The simplest machine for equalizing the leather which can be employed, is that which I saw operating in MM. Scrive’s automatic card factory at Lille, the most magnificent I believe in the world, where the leather was drawn forwards by a roller over a solid horizontal table, or bed, and passed under a nicely adjusted vertical blade, which shaved it by a scraping motion to a perfectly uniform thickness. About one half the weight of the leather is lost in this process, and in the subsequent squaring and trimming.

The machine for making cards, invented I believe by a Mr. Ellis of the United States, for which a first patent was obtained in this country by Joseph Cheeseborough Dyer, Esq. of Manchester, in 1811, and a second and third with further improvements in 1814, and 1824, is one of the most elegant automatons ever applied to productive industry. It is however necessarily so complicated with different mechanisms as to render its representation impracticable in such engravings as are compatible with the scope of this dictionary. I must therefore content myself with the following general description of its constituent parts.

The first thing to be done after having, as above, prepared the long sheets or fillets of leather, of suitable length, breadth, and thickness, for making the cards, is to stretch the leather, and hold it firmly; which is accomplished by winding the fillet of leather upon the roller or drum, like the warp roller of a loom, and then conducting it upwards between guide rollers, to a receiving or work roller at top of the machine, where the fillet is held fast by a cramp, by which means the leather is kept stretched.

Secondly, the holes are pierced in the leather to receive the wire staples or teeth of the card, by means of a sliding fork, the points of which are presented to the face of the leather; while the fork is made to advance and recede continually, by the agency of levers worked by rotatory cams upon a revolving main shaft.

The points of the fork being thus made to penetrate into the leather, the holes for receiving the staples are pierced, at regular distances, and in correct order, by shifting the leather fillet so as to bring different parts of its surface opposite to the points of the sliding fork. This is done by cams, or indented wheels and gear, which shift the guide rollers and confining drums laterally, as they revolve, and consequently move the fillet of leather at intervals a short distance, so as to present to the points of the fork or piercer at every movement, a different part of the surface of the leather.

Thirdly, the wire of which the teeth or points of the card are to be made, is supplied from a coil on the side of the machine, and is brought forward at intervals, by a pair of sliding pincers, which are slidden to and fro through the agency of levers actuated by rotatory cams upon the main shaft. The pincers having advanced a distance equal to the length of wire intended to form one staple, or two points, this length of wire is pressed upon exactly in the middle by a square piece of steel, and being there confined, a cutter is brought forward, which cuts it off from that part of the wire held in the pincers.

The length of wire thus separated and confined, is now, by a movement of the machine, bent up along the sides of the square steel holder, and shaped to three edges of the square, that is, formed as a staple; and in the same way, by the continued movements of the machine, a succession of pieces of wire are cut off, and bent into staples for making the teeth of the card as long as the mechanism is kept in action.

Fourthly, the wire staple thus formed is held with its points or ends outwards, closely contiguous to the forked piercer described above, and by another movement of the mechanism, the staple is protruded forward, its end entering into the two holes made previously in the leather by the sliding of the fork.

While the wire staple is being thus introduced into the leather, its legs or points are to be bent, that is, formed with a knee or angle, which is the fifth object to be effected. This is done by means of a small apparatus consisting of a bar or bed, which bears up against the under side of the wire staple when it has been passed half-way into the holes in the leather, and another bar above it, which being brought down behind the staple, bends it over the resisting bar to the angle required; that is, forms the knee in each leg. A pusher now acts behind the staple, and drives it home into the leather, which completes the operation.

The leather being thus conducted, and its position shifted before the piercer progressively, a succession of the above described operations of cutting the wire, forming the staple, passing it into the leather, and bending its legs to the angular form, produces a sheet of card of the kind usually employed for carding or combing wool, cotton, and other fibrous materials. It may be necessary to add, that as these wire staples are required to be set in the leathers sometimes in lines crossing the sheet, which is called ribbed, and at other times in oblique lines, called twilled, these variations are produced by the positions of the notches or steps upon the edge or periphery of the cam or indented wheel, which shifts the guide rollers that hold the fillet or sheet of leather as already described.

CARPET. (Tapis, Fr.; Teppich, Germ.) A thick woollen fabric of variegated colours, for covering the floors of the better sort of apartments. This luxurious manufacture took its origin in Persia and Turkey, whence the most beautiful patterns were wont to come into Europe; but they have been for some time surpassed by the workmanship of France, Great Britain, and Belgium. To form a just conception of the elegant and ingenious processes by which carpets are made, we should visit the royal establishment of the Gobelins at Paris, where we would see the celebrated carpet manufactory of the Savonnerie, which has been transported thither. A detailed set of engravings of this art is given by Roland de la PlatiÈre in the first and second volumes of the EncyclopÉdie MÉthodique, to which I must refer my readers, as a due exposition of its machines and operations would far exceed the scope of the present volume.

The warp, says M. Roland, being the foundation of the fabric, ought to be of fine wool, equally but firmly spun, and consist of three yarns twisted into one thread. The yarns that are to form the velvety surface of the carpet, ought also to be of the best quality, but soft and downy in their texture, so that the dye may penetrate every filament. Hemp, or linen yarns, are likewise employed in this manufacture, as a woof, to bind the warp firmly together after each shoot of the velvety threads. Thus we see that good carpeting consists essentially of two distinct webs woven at the same time, and firmly decussated together by the woof threads. Hence the form of the pattern is the same upon the two sides of the cloth, only the colours are reversed, so that what was green upon one side becomes red or black upon the other, and vice versÂ. The smaller the figures the more frequent the decussations of the two planes, and the firmer and more durable the fabric.

The carpet manufacture, as now generally practised, may be distributed into two systems—that of double fabrics, and that cut in imitation of velvet. Of late years the Jacquard loom has been much used in weaving carpets, the nature of which will be found fully explained under that title.

For the sake of illustration, if we suppose the double carpets to be composed of only two colours, the principle of weaving will be easily understood; for it is only necessary to raise the warp of each web alternately for the passage of the shuttle, the upper web being entirely above when the under web is being woven, or decussated, and vice versÂ. In a Brussels carpet the worsted yarn raised to form the pile, and make the figure, is not cut; in the Wilton the pile is cut to give it a velvety aspect and softness. In the imperial Brussels carpet the figure is raised above the ground, and its pile is cut, but the ground is uncut; and in the royal Wilton, the pile is both raised higher than in the common Wilton, and it is cut, whereby it has a rich cushion-like appearance. The cloth of all these superior carpets consists of woollen and linen, or hemp; the latter being put upon a beam, and brought, of course, through heddles and a reed; but as its only purpose is to bind together the worsted fabric, it should not be visible upon the upper face of the carpet. The worsted yarn is wound upon small bobbins or pirns, with a weight affixed to each, for giving proper tension to the threads. Their number varies, for one web, from 1300 to 1800, according as the carpet is to be 27 or 36 inches wide; and, they are placed, in frames, behind the loom, filled with differently coloured yarn, to correspond with the figure. This worsted warp is then drawn through the harness, heddles, and reed, to be associated with the linen yarn in the compound fabric.

In Kidderminster carpeting, both warp and weft appear upon the face of the cloth, whereas, in the Brussels style, only the warp is seen, its binding weft being fine hempen or linen threads. The three-ply imperial carpet, called the Scotch, is coming very much into vogue, and is reckoned by many to be little inferior in texture, look, and wear to the Brussels. Kilmarnock has acquired merited distinction by this ingenious industry. In this fabric, as well as in the two-ply Kidderminster, the weft predominates, and displays the design; but, in the French carpets, the worsted warp of the web shows the figure. Plain Venetian carpets, as used for stairs and passages, are woven in simple looms, provided merely with the common heddles and reed. The warp should be a substance of worsted yarn, so heavy as to cover in the weft completely from the view. Figured Venetian carpets are woven in the two-ply Kidderminster looms, and are provided with a mechanism to raise the pattern upon the worsted warp. The weft is an alternate shoot of worsted and linen yarn, and must be concealed.

The following figure and description will explain the construction of the three-ply imperial Scotch and two-ply Kidderminster carpet loom, which is merely a modification of the Jacquard mÉtier. The Brussels carpet-loom, on the contrary, is a draw-boy loom on the damask plan, and requires the weaver to have an assistant. Fig. 270. A A A, is the frame of the loom, consisting of four upright posts, with caps and cross rails to bind them together. The posts are about six feet high. C C, the cloth-beam, is a wooden cylinder, six inches or thereby in diameter, of sufficient length to traverse the loom, with iron gudgeons in the two ends, which work in bushes in the side frame. On one end of this beam is a ratchet wheel, with a tooth to keep it from turning round backwards by the tension of the web. D, the lay, with its reed, its under and upper shell, its two lateral rulers or swords, and rocking-tree above. There are grooves in the upper and under shell, into which the reed is fitted. E, the heddles, or harness, with a double neck attached to each of the tower or card mechanisms F F, of the Jacquard loom. The heddles are connected and work with the treddles B B, by means of cords, as shown in the figure. G G are wooden boxes for the cards. H, the yarn, or warp beam.

In draw-looms of every kind, there is no sinking of any portion of the warp, as in plain cloth-weaving; but the plane of the warp is placed low, and the threads under which the shuttle is to pass are raised, while all the rest remains stationary. The harness part of this carpet loom is moved by an assistant boy or girl, who thus allows the weft to be properly decussated, while the weaver attends to working the front mounting or heddles. Fig. 271., A represents the frame of a carpet draw-loom; B is a box or frame of pulleys, over which the cords of the harness pass, and are then made fast to a piece of wood, seen at E, which the weavers call a table. From the tail of the harness the simples descend, and to the end of each is attached a small handle G, called a bob. These handles being disposed in pairs, and their regularity preserved by means of a perforated board C, it is merely necessary to pull every handle in succession; the weaver, at the same time, working his treddles with his feet, as in any other loom. The treddles are four in number, the fabric being that of plain or alternate cloth, and two treddles allotted for each web. The harness part of the carpet draw-loom is furnished with mails, or metallic eyes, to save friction; two threads being drawn through each eye. The design or pattern of a carpet is drawn upon cross-rule paper, exactly in the same way as every other kind of fancy-loom work, and is transferred from the paper to the mounting by the rules for damask weaving. Suppose that a double web is so mounted that every alternate thread of the one may be raised, so as to form a sufficient shed-way for the shuttle, without depressing the other in the least. Then suppose another web placed above the former, at such a distance that it will exactly touch the convexity of those threads of the former, which are raised. Then, if the threads of the latter web are sunk while the others are raised, the two would be entirely incorporated. But if this be only partially done, that is, at particular places, only those parts immediately operated upon will be affected by the action of the apparatus. If the carpet is a two-coloured pattern, as black and red, and if upon the upper surface, as extended in the loom, red flowers are to be represented upon a black ground, then all those species of design paper which are coloured may be supposed to represent the red, and those which are vacant the black. Then counting the spaces upon the paper, omit those which are vacant, and cord those which are coloured, and the effect will be produced. But as the two webs are to be raised alternately, whatever is corded for the first handle must be passed by for the second, and vice versÂ; so that the one will form the flower, and the other the ground.

The board by which the simples are regulated appears at F. D shows the weights.

CARTHAMUS, or safflower (carthamus tinctorius), (Carthame, Fr.; FÄrber distel, Germ.), the flower of which alone is used in dyeing, is an annual plant cultivated in Spain, Egypt, and the Levant. There are two varieties of it—one which has large leaves, and the other smaller ones. It is the last which is cultivated in Egypt, where it forms a considerable article of commerce.

Carthamus contains two colouring matters, one yellow and the other red. The first alone is soluble in water; its solution is always turbid: with re-agents it exhibits the characters usually remarked in yellow colouring matters. The acids render it lighter, the alkalies deepen it, giving it more of an orange hue: both produce a small dun precipitate, in consequence of which it becomes clearer. Alum forms a precipitate of a deep yellow, in small quantity. The solution of tin and the other metallic solutions cause precipitates which have nothing remarkable in them.

The yellow matter of carthamus is not employed; but in order to extract this portion, the carthamus is put into a bag, which is trodden under water, till no more colour can be pressed out. The flowers, which were yellow, become reddish, and lose in this operation nearly one half of their weight. In this state they are used.

For extracting the red part of carthamus, and thereafter applying it to stuff, the property which alkalies possess of dissolving it is had recourse to, and it is afterwards precipitated by an acid.

The process of dyeing consists, therefore, in extracting the colouring matter by means of an alkali, and precipitating it on the stuff by means of an acid. It is this fecula which serves for making the rouge employed by ladies.

As to this rouge, the solution of carthamus is prepared with crystallised carbonate of soda, and it is precipitated by lemon juice. It has been remarked that lemons, beginning to spoil, were fitter for this operation than those which were less ripe, whose juice retained much mucilage. After squeezing out the lemon juice, it is left to settle for some days. The precipitate of carthamus is dried at a gentle heat upon plates of stone-ware; from which it is detached and very carefully ground with talc, which has been reduced to a very subtile powder, by means of the leaves of shave-grass (presle), and successively passed through sieves of increasing fineness. It is the fineness of the talc, and the greater or less proportion which it bears to the carthamus precipitate, which constitute the difference between the high and low priced rouges.

Carthamus is used for dyeing silk, poppy, nacarat (a bright orange-red), cherry, rose colour, and flesh colour. The process differs according to the intensity of the colour, and the greater or less tendency to flame colour that is wanted. But the carthamus bath, whose application may be varied, is prepared as follows:

The carthamus, from which the yellow matter has been extracted, and whose lumps have been broken down, is put into a trough. It is repeatedly sprinkled with cendres gravelÉes (crude pearl ashes), or soda (barilla) well powdered and sifted at the rate of 6 pounds for 120 lbs. of carthamus; but soda is preferred, mixing carefully as the alkali is introduced. This operation is called amestrer. The amestred carthamus is put into a small trough with a grated bottom, first lining this trough with a closely woven cloth. When it is about half filled, it is placed over the large trough, and cold water is poured into the upper one, till the lower becomes full. The carthamus is then set over another trough, till the water comes from it almost colourless. A little more alkali is now mixed with it, and fresh water is passed through it. These operations are repeated till the carthamus be exhausted, when it turns yellow.

After distributing the silk in hanks upon the rods, lemon juice, brought in casks from Provence, is poured into the bath till it becomes of a fine cherry colour; this is called turning the bath (virer le bain). It is well stirred, and the silk is immersed and turned round the skein-sticks in the bath, as long as it is perceived to take up the colour. For ponceau (poppy colour), it is withdrawn, the liquor is run out of it upon the peg, and it is turned through a new bath, where it is treated as in the first. After this it is dried and passed through fresh baths, continuing to wash and dry it between each operation, till it has acquired the depth of colour that is desired. When it has reached the proper point, a brightening is given it by turning it round the sticks seven or eight times in a bath of hot water, to which about half a pint of lemon juice for each pailful of water has been added.

When silk is to be dyed ponceau or flame colour, it must be previously boiled as for white; it must then receive a slight foundation of annotto, as explained in treating of this substance. The silk should not be alumed.

The nacarats, and the deep cherry colours, are given precisely like the ponceaux, only they receive no annotto ground; and baths may be employed which have served for the ponceau, so as to complete their exhaustion. Fresh baths are not made for the latter colours, unless there be no occasion for the poppy.

With regard to the lighter cherry-reds, rose colour of all shades and flesh colours, they are made with the second and last runnings of the carthamus, which are weaker. The deepest shades are passed through first.

The lightest of all these shades, which is an extremely delicate flesh colour, requires a little soap to be put into the bath. This soap lightens the colour, and prevents it from taking too speedily, and becoming unevenly. The silk is then washed, and a little brightening is given it, in a bath which has served for the deeper colours.

All these baths are employed the moment they are made, or as speedily as possible, because they lose much of their colour upon keeping, by which they are even entirely destroyed at the end of a certain time. They are, moreover, used cold, to prevent the colour from being injured. It must have been remarked in the experiments just described, that the caustic alkalies attack the extremely delicate colour of carthamus, making it pass to yellow. This is the reason why crystals of soda are preferred to the other alkaline matters.

In order to diminish the expense of the carthamus, it is the practice in preparing the deeper shades to mingle with the first and the second bath about one fifth of the bath of archil.

Dobereiner regards the red colouring matter of carthamus as an acid, and the yellow as a base. His carthamic acid forms, with the alkalies, colourless salts, decomposed by the tartaric and acetic acids, which precipitate the acid of a bright rose-red. Heat has a remarkable influence upon carthamus, rendering its red colour yellow and dull. Hence, the colder the water is by which it is extracted, the finer is the colour. Light destroys the colour very rapidly, and hitherto no means have been found of counteracting this effect. For this reason this brilliant colour must be dried in the shade, its dye must be given in a shady place, and the silk stuffs dyed with it must be preserved as much as possible from the light. Age is nearly as injurious as light, especially upon the dye in a damp state. The colour is very dear, because a thousand parts of carthamus contain only five of it.

In preparing the finest rouge, the yellow colouring matter being separated by washing with water, the red is then dissolved by the aid of alkali, and is thrown down on linen or cotton rags by saturating the solution with vegetable acid. The colour is rinsed out of these rags, dissolved anew in alkalis, and once more precipitated by lemon juice. The best and freshest carthamus must be selected. It is put into linen bags, which are placed in a stream of water, and kneaded till the water runs off colourless. The bags are then put into water soured with a little vinegar, kneaded till the colour is all expelled, and finally rinsed in running water. By this treatment the carthamus loses nearly half its weight. 6633 cwts. of safflower were imported into the United Kingdom in 1835, of which 2930 cwts. were retained for internal consumption.

CASE-HARDENING, is the name of the process by which iron tools, keys, &c., have their surfaces converted into steel.

Steel when very hard is brittle, and iron alone is for many purposes, as for fine keys, far too soft. It is therefore an important desideratum to combine the hardness of a steely surface with the toughness of an iron body. These requisites are united by the process of case-hardening, which does not differ from the making of steel, except in the shorter duration of the process. Tools, utensils, or ornaments, intended to be polished, are first manufactured in iron and nearly finished, after which they are put into an iron box, together with vegetable or animal charcoal in powder, and cemented for a certain time. This treatment converts the external part into a coating of steel, which is usually very thin, because the time allowed for the cementation is much shorter than when the whole substance is intended to be converted. Immersion of the heated pieces into water hardens the surface, which is afterwards polished by the usual methods. Moxon in his Mechanic Exercises, p. 56., gives the following receipt for case-hardening:—“Cow’s horn or hoof is to be baked or thoroughly dried and pulverised. To this add an equal quantity of bay salt; mix them with stale chamber-lye or white wine vinegar: cover the iron with this mixture, and bed it with the same in loam, or enclose it in an iron box: lay it on the hearth of the forge to dry and harden: then put it into the fire, and blow till the lump have a blood-red heat, and no higher, lest the mixture be burnt too much. Take the iron out, and immerse it in water to harden.” I consider the vinegar to be quite superfluous.

I shall now describe the recent application of prussiate (ferrocyanate) of potash to this purpose. The piece of iron, after being polished, is to be made brightly red-hot, and then rubbed or sprinkled over with the above salt in fine powder, upon the part intended to be hardened. The prussiate being decomposed, and apparently dissipated, the iron is to be quenched in cold water. If the process has been well managed, the surface of the metal will have become so hard as to resist the file. Others propose to smear over the surface of the iron with loam made into a thin paste with a strong solution of the prussiate, to dry it slowly, then expose the whole to a nearly white heat, and finally plunge the iron into cold water, when the heat has fallen to dull redness. See Steel.

CASHMERE or CACHEMERE, a peculiar textile fabric first imported from the kingdom of Cashmere, and now well imitated in France and Great Britain. The material of the Cashmere shawls is the downy wool found about the roots of the hair of the Thibet goat. The year 1819 is remarkable in the history of French husbandry for the acquisition of this breed of goats, imported from the East under the auspices of their government, by the indefatigable courage and zeal of M. Jaubert, who encountered every fatigue and danger to enrich his country with these valuable animals, aided by the patriotism of M. Ternaux, who first planned this importation, and furnished funds for executing it at his own expence and responsibility. He placed a portion of the flock brought by M. Jaubert, at his villa of Saint Ouen, near Paris, where the climate seemed to be very favourable to them, since for several successive years after their introduction M. Ternaux was enabled to sell a great number of both male and female goats. The quantity of fine fleece or down afforded by each animal annually, is from a pound and a half to two pounds.

The wool imported into Europe comes by the way of Casan, the capital of a government of the Russian empire upon the eastern bank of the Wolga; it has naturally a grayish colour, but is easily bleached. Its price a few years back at Paris was 17 francs per kilogramme; that is, about 6 shillings the pound avoirdupois. The waste in picking, carding, and spinning, amounts to about one third of its weight.

The mills for spinning Cachemere wool have multiplied very much of late years in France, as appears from the premiums distributed at the exposition of 1834, and the prices of the yarn have fallen from 25 to 30 per cent. notwithstanding their improved fineness and quality. There is a fabric made with a mixture of Cachemere down and spun silk, which is becoming very general. One of the manufacturers, M. Hindenlang, exhibited samples of Cachemere cloth woven with yarn so fine as No. 130 for warp, and No. 228 for weft.

Messrs. Pollino, brothers, of Paris, produced an assortment of Cachemere pieces from 22 to 100 francs the yard, dyed of every fancy shade. Their establishment at FertÉ-Bernard occupies 700 operatives, with an hydraulic wheel of 60 horse power.

The oriental Cashmere shawls are woven by processes extremely slow and consequently costly; whence their prices are very high. They are still sold in Paris at from 4,000 to 10,000 francs a piece; and from 100 to 400 pounds sterling in London. It became necessary therefore either to rest satisfied with work which should have merely a surface appearance, or contrive economical methods of weaving, to produce the real Cachemere style with much less labour. By the aid of the draw-loom and still better of the Jacquard loom, M. Ternaux first succeeded in weaving Cachemere shawls perfectly similar to the oriental in external aspect, which became fashionable under the name of French Cachemere. But to construct shawls altogether identical on both sides with the eastern, was a more difficult task, which was accomplished only at a later period by M. Bauson of Paris.

In both modes of manufacture, the piece is mounted by reading-in the warp for the different leaves of the heddles, as is commonly practised for warps in the Jacquard looms. The weaving of imitation shawls is executed, as usual, by as many shuttles as there are colours in the design, and which are thrown across the warp in the order established by the reader. The greater number of these weft yarns being introduced only at intervals into the web, when the composition of the pattern requires it, they remain floating loose at the back of the piece, and are cut afterwards, without affecting in the least the quality of the texture; but there is a considerable waste of stuff in the weaving, which is worked up into carpets.

The weaving of the imitation of real Cachemere shawls is different from the above. The yarns intended to form the weft are not only equal in number to that of the colours of the pattern to be imitated, but besides this, as many little shuttles or pirns (like those used by embroiderers) are filled with these yarns, as there are to be colours repeated in the breadth of the piece; which renders their number considerable when the pattern is somewhat complicated and loaded with colours. Each of these small bobbins or shuttles passes through only that portion of the flower in which the colour of its yarn is to appear, and stops at the one side and the other of the cloth exactly at its limit; it then returns upon itself after having crossed the thread of the adjoining shuttle. From this reciprocal intertexture of all the yarns of the shuttles, it results, that although the weft is composed of a great many different threads, they no less constitute a continuous line in the whole breadth of the web, upon which the lay or batten acts in the ordinary way We see therefore that the whole art of manufacturing this Cachemere cloth consists in avoiding the confusion of the shuttles, and in not striking up the lay till all have fulfilled their function. The labour does not exceed the strength of a woman, even though she has to direct the loom and work the treddles. Seated on her bench at the end opposite to the middle of the beam, she has for aids in weaving shawls from 45 to 52 inches wide, two girl apprentices, whom she directs and instructs in their tasks. About four hundred days of work are required for a Cachemere shawl of that breadth. For the construction of the loom, see Jacquard.

In the oriental process all the figures in relief are made simply with a slender pirn without the shuttle used in European weaving. By the Indians the flower and its ground are made with the pirn, by means of an intertwisting, which renders them in some measure independent of the warp. In the Lyons imitation of this style, the leaves of the heddles lift the yarns of the warp, the needles embroider as in lappett weaving, and the flower is united to the warp by the weft thrown across the piece. Thus a great deal of labour is saved, the eye is pleased with an illusion of the loom, and the shawls cost little more than those made by the common fly shuttle.

Considered in reference to their materials, the French shawls present three distinct classes, which characterise the three fabrics of Paris, Lyons, and Nimes.

Paris manufactures the French Cachemere, properly so called, of which both the warp and the weft are the yarn of pure Cachemere down. This web represents with fidelity the figures and the shades of colour of the Indian shawl, which it copies; the deception would be complete if the reverse of the piece did not show the cut ends. The Hindoo shawl, also woven at Paris, has its warp in spun silk, which reduces its price without impairing its beauty much.

Lyons however has made the greatest progress in the manufacture of shawls. It excels particularly in the texture of its Thibet shawls, the weft of which is yarn spun with a mixture of wool and spun silk.

Nimes is remarkable for the low price of its shawls, in which spun silk, Thibet down, and cotton, are all worked up together.

The value of shawls exported from France in the following years was:—

It appears that M. J. Girard at SÈvres, near Paris, has succeeded best in producing Cachemere shawls equal in stuff and style of work to the oriental, and at a lower price. They have this advantage over the Indian shawls, that they are woven without seams, in a single piece, and exhibit all the variety and the raised effect of the eastern colours. Women and children alone are employed in his factory.

CASK, (Tonneau, Fr.; Fass, Germ.) manufacture of by mechanical power. Mr. Samuel Brown obtained a patent in Nov., 1825, for certain improvements in machinery for making casks, which seems to be ingenious and worthy of record. His mechanism consists in the first place of a circular saw attached to a bench, with a sliding rest, upon which rest each piece of wood intended to form a stave of a cask is fixed; and the rest being then slidden forward in a curved direction, by the assistance of an adjustable guide, brings the piece of wood against the edge of the rotatory saw, and causes it to be cut into the curved shape required for the edge of the stave. The second feature is an apparatus with cutters attached to a standard, and traversing round with their carrier upon a centre, by means of which the upper and lower edges of the cask are cut round and grooved, called chining, for the purpose of receiving the heads. Thirdly, an apparatus not very dissimilar to the last, by which the straight pieces of wood designed for the heads of the cask are held together, and cut to the circular figure required, and also the bevelled edges produced. And fourthly, a machine in which the cask is made to revolve upon an axis, and a cutting tool to traverse for the purpose of shaving the external part of the cask, and bringing it to a smooth surface.

The pieces of wood intended to form the staves of the cask, having been cut to their required length and breadth, are placed upon the slide-rest of the first mentioned machine, and confined by cramps; and the guide, which is a flexible bar, having been previously bent to the intended curve of the stave and fixed in that form, the rest is then slidden forward upon the bench by the hand of the workman, which as it advances (moving in a curved direction) brings the piece of wood against the edge of the revolving circular saw, by which it is cut to the curved shape desired.

The guide is a long bar held by a series of movable blocks fitted to the bench by screws, and is bent to any desired curve by shifting the screws: the edge of the slide-rests which holds the piece of wood about to be cut, runs against the long guide bar, and of consequence is conducted in a corresponding curved course. The circular saw receives a rapid rotatory motion by means of a band or rigger from any first mover; and the piece of wood may be shifted laterally by means of racks and pinions on the side-rest, by the workman turning a handle, which is occasionally necessary in order to bring the piece of wood up to, or away from, the saw.

The necessary number of staves being provided, they are then set round within a confining hoop at bottom, and brought into the form of a cask in the usual way, and braced by temporary hoops. The barrel part of the cask being thus prepared, in order to effect the chining, it is placed in a frame upon a platform, which is raised up by a treddle lever, that the end of the barrel may meet the cutters in a sort of lathe above: the cutters are then made to traverse round within the head of the barrel, and, as they proceed, occasionally to expand, by which means the bevels and grooves are cut on the upper edge of the barrel, which is called chining. The barrel being now reversed, the same apparatus is brought to act against the other end, which becomes chined in like manner.

The pieces of wood intended to form the heads of the cask are now to be cut straight by a circular saw in a machine, similar to the first described; but in the present instance the slide-rest is to move forward in a straight course. After their straight edges are thus produced, they are to be placed side by side, and confined, when a scribing cutter is made to traverse round, and cut the pieces collectively into the circular form desired for heading the cask.

The cask having now been made up, and headed by hand as usual, it is placed between centres, or upon an axle in a machine, and turned round by a rigger or band with a shaving cutter, sliding along a bar above it, which cutter being made to advance, and recede as it slides along, shaves the outer part of the cask to a smooth surface.

CASSAVA. Cassava bread, conaque, &c., are different names given to the starch of the root of the Manioc (Jatropha Manihot, Linn.), prepared in the following manner in the West Indies, the tropical regions of America, and upon the African coast. The tree belongs to the natural family of the euphorbiaceÆ.

The roots are washed, and reduced to a pulp by means of a rasp or grater. The pulp is put into coarse strong canvas bags, and thus submitted to the action of a powerful press, by which it parts with most of its noxious juice (used by the Indians for poisoning the barbs of their arrows). As the active principle of this juice is volatile, it is easily dissipated by baking the squeezed cakes of pulp upon a plate of hot iron. Fifty pounds of the fresh juice, when distilled, afford, at first, three ounces of a poisonous water, possessing an intolerably offensive smell; of which, 35 drops being administered to a slave convicted of the crime of poisoning, caused his death in the course of six minutes, amid horrible convulsions.[16]

The pulp dried in the manner above described concretes into lumps, which become hard and friable as they cool. They are then broken into pieces, and laid out in the sun to dry. In this state they afford a wholesome nutriment, and are habitually used as such by the negroes, as also by many white people. These cakes constitute the only provisions laid in by the natives, in their voyages upon the Amazons. Boiled in water with a little beef or mutton they form a kind of soup similar to that of rice.

The Cassava cakes sent to Europe (which I have eaten with pleasure) are composed almost entirely of starch, along with a few fibres of the ligneous matter. It may be purified by diffusion through warm water, passing the milky mixture through a linen cloth, evaporating the strained liquid over the fire, with constant agitation. The starch dissolved by the heat, thickens as the water evaporates, but on being stirred, it becomes granulated, and must be finally dried in a proper stove. Its specific gravity is 1·530—that of the other species of starch.

The product obtained by this treatment is known in commerce under the name of tapioca; and being starch very nearly pure, is often prescribed by physicians as an aliment of easy digestion. A tolerably good imitation of it is made by heating, stirring, and drying potato starch in a similar way.

The expressed juice of the root of manioc contains in suspension a very fine fecula, which it deposits slowly upon the bottom of the vessels. When freed by decantation from the supernatant liquor, washed several times and dried, it forms a beautiful starch, which creaks on pressure with the fingers. It is called cipipa, in French Guyana; it is employed for many delicate articles of cookery, especially pastry, as also for hair powder, starching linen, &c.

Cassava flour, as imported, may be distinguished from arrow-root and other kinds of starch, by the appearance of its particles viewed in a microscope. They are spherical, all about 1-1000th of an inch in diameter, and associated in groups; those of potato starch are irregular ellipsoids, varying in size from 1-300th to 1-3000th of an inch; those of arrow-root have the same shape nearly, but vary in size from 1-500th to 1-800th of an inch; those of wheat are separate spheres 1-1000th of an inch.

CASSIS, the black currant (ribes nigra, Linn.), which was formerly celebrated for its medicinal properties with very little reason.

The only technical use to which it is now applied is in preparing the agreeable liqueur called ratafia, by the following French recipe:—Stone, and crush three pounds of black currants, adding to the magma one drachm of cloves, two of cinnamon, four quarts of spirit of wine, at 18° BaumÉ (see ArÉomÈtre of BaumÉ), and 2¹/₂ pounds of sugar. Put the mixture into a bottle which is to be well corked; let it digest for a fortnight, shaking the bottle once daily during the first eight days; then strain through a linen cloth, and finally pass through filtering paper.

CASTING OF METALS. (See Founding.) Casts from elastic moulds.—Being much engaged in taking casts from anatomical preparations, Mr. Douglas Fox, Surgeon, Derby, found great difficulty, principally with hard bodies, which, when undercut, or having considerable overlaps, did not admit of the removal of moulds of the ordinary kind, except with injury. These difficulties suggested to him the use of elastic moulds, which, giving way as they were withdrawn from complicated parts, would return to their proper shape; and he ultimately succeeded in making such moulds of glue, which not only relieved him from all his difficulties, but were attended with great advantages, in consequence of the small number of pieces into which it was necessary to divide the mould.

The body to be moulded, previously oiled, must be secured one inch above the surface of a board, and then surrounded by a wall of clay, about an inch distant from its sides. The clay must also extend rather higher than the contained body: into this, warm melted glue, as thick as possible so that it will run, is to be poured, so as to completely cover the body to be moulded; the glue is to remain till cold, when it will have set into an elastic mass, just such as is required.

Having removed the clay, the glue is to be cut into as many pieces as may be necessary for its removal, either by a sharp-pointed knife, or by having placed threads in the requisite situations of the body to be moulded, which may be drawn away when the glue is set, so as to cut it out in any direction.

The portions of the glue mould having been removed from the original, are to be placed together and bound round by tape.

In some instances it is well to run small wooden pegs through the portions of glue, so as to keep them exactly in their proper positions. If the mould be of considerable size, it is better to let it be bound with moderate tightness upon a board to prevent it bending whilst in use; having done as above described, the plaster of Paris, as in common casting, is to be poured into the mould, and left to set.

In many instances wax may also be cast in glue, if it is not poured in whilst too hot; as the wax cools so rapidly when applied to the cold glue, that the sharpness of the impression is not injured.

Glue has been described as succeeding well where an elastic mould is alone applicable; but many modifications are admissible. When the moulds are not used soon after being made, treacle should be previously mixed with the glue (as employed by printers) to prevent it becoming hard.

The description thus given is with reference to moulding those bodies which cannot be so done by any other than an elastic mould; but glue moulds will be found greatly to facilitate casting in many departments, as a mould may be frequently taken by this method in two or three pieces, which would, on any other principle, require many.

CASTOR or CASTOREUM. This name is given to a secretion of the castors, contained in pear-shaped cellular organic sacs, placed near the genital organs of both the male and female animals. It is a substance analogous to civet and musk, of a consistence similar to thick honey. It has a bitter acrid taste; a powerful, penetrating, fetid, and very volatile smell; but, when dried, it becomes inodorous. Several chemists, and in particular Bouillon Lagrange, Laugier, and Hildebrandt have examined castor; and found it to be composed of a resin, a fatty substance, a volatile oil, an extractive matter, benzoic acid, and some salts.

The mode of preparing it is very simple. The sacs are cut off from the castors when they are killed, and are dried to prevent the skin being affected by the weather. In this state, the interior substance is solid, of a dark colour, and a faint smell; it softens with heat, and becomes brittle by cold. Its fracture betrays fragments of membranes, indicating its organic structure. When chewed, it adheres to the teeth somewhat like wax; it has a bitter, slightly acrid, and nauseous taste.

The castor bags, as imported, are often joined in pairs by a kind of ligature. Sometimes the substance which constitutes their value is sophisticated; a portion of the castoreum being extracted, and replaced by lead, clay, gums, or some other foreign matters. This fraud may be easily detected, even when it exists in a small degree, by the absence of the membranous partitions in the interior of the bags, as well as by the altered smell and taste.

The use of castoreum in medicine is considerable, especially in nervous and spasmodic diseases, and it is often advantageously combined with opium.

CASTORINE. A chemical principle lately discovered to the amount of a few parts per cent. in Castoreum.

CASTOR OIL. The expressed oil of the seeds of the Palma Christi, or Ricinus communis, a native tree of the West Indies and South America; but which has been cultivated in France, Italy, and Spain. Bussy and Lecanu discovered in it 3 species of fatty matters, obtained partly by saponification, and partly by dry distillation—the margaritic, ricinic, and elaiodic acids. None of these has been separately applied to any use in the arts.

The quantity of castor oil imported in 1835 into the United Kingdom, was 1,109,307 libs.; retained for home consumption, 670,205 libs. See Oils.

CATECHU, absurdly called Terra Japonica, is an extract made from the wood of the tree mimosa catechu, which grows in Bombay, Bengal, and other parts of India. It is prepared by boiling the chips of the interior of the trunk in water, evaporating the solution to the consistence of syrup over the fire, and then exposing it in the sun to harden. It occurs in flat rough cakes, and under two forms. The first, or the Bombay, is of uniform texture, of a dark red colour, and of specific gravity 1·39. The second is more friable and less solid. It has a chocolate colour, and is marked inside with red streaks. Its specific gravity is 1·28.

According to Sir H. Davy, these two species are composed as follows:—

Areka nuts are also found to yield catechu; for which purpose they are cut into pieces watered in an earthen pot with solution of nitre, and have a little of the bark of a species of mimosa added to them. The liquor is then boiled with the nuts, and affords an inspissated decoction.

Good catechu is a brittle, compact solid, of a dull fracture. It has no smell, but a very astringent taste. Water dissolves the whole of it, except the earthy matter, which is probably added during its preparation. Alcohol dissolves its tannin and extractive. The latter may be oxidized, and thus rendered insoluble in alcohol, by dissolving the catechu in water, exposing it for some time to a boiling heat, and evaporating to dryness.

The tannin of catechu differs from that of galls, in being soluble in alcohol, and more soluble in water. It precipitates iron of an olive colour, and gelatine in a mass which gradually becomes brown.

It has been long employed in India for tanning skins, where it is said to effect this object in five days. I have seen a piece of sole leather completely tanned by it in this country in ten days, the ox-hide having been made into a bag, with the hair outside, and kept filled with the solution of catechu. In India it has also been used to give a brown dye to cotton goods, and of late years it has been extensively introduced into the calico print-works of Europe. The salts of copper with sal ammoniac cause it to give a bronze colour, which is very fast; the proto-muriate of tin, a brownish yellow; the per-chloride of tin, with the addition of nitrate of copper, a deep bronze hue; acetate of alumina alone, a reddish brown, and, with nitrate of copper, a reddish olive gray; nitrate of iron, a dark brown gray. For dyeing a golden coffee brown, it has entirely superseded madder; one pound of it being equivalent to six pounds of this root.

A solution of one part of catechu in ten parts of water, which is reddish brown, exhibits the following results with—

Pure tannin may be obtained from catechu, by treating it with sulphuric acid and carbonate of lead; but this process has no manufacturing application.

CATGUT, (Corde À boyau, Fr.; Darmsaite, Germ.) the name absurdly enough given to cords made of the twisted intestines of the sheep. The guts being taken while warm out of the body of the animal, are to be cleared of feculent matter, freed from any adhering fat, and washed in a tub of water. The small ends of all the intestines are next to be tied together, and laid on the edge of the tub, while the body of them is left to steep in some water, frequently changed, during two days, in order to loosen the peritoneal and mucous membranes. The bundle of intestines is then laid upon a sloping table which overhangs the tub, and their surface is scraped with the back of a knife, to try if the external membrane will come away freely in breadths of about half the circumference. This substance is called by the French manufacturers filandre, and the process filer. If we attempt to remove it by beginning at the large end of the intestine, we shall not succeed. This filandre is employed as thread to sew intestines, and to make the cords of rackets and battledores. The flayed guts are put again into fresh water, and after steeping a night, are taken out and scraped clean next day, on the wooden bench with the rounded back of a knife. This is called curing the gut. The large ends are now cut off, and sold to the pork-butchers. The intestines are again steeped for a night in fresh water, and the following day in an alkaline lixivium made by adding 4 ounces of potash, and as much pearlash, to a pail of water containing about 3 or 4 imperial gallons. This lye is poured in successive quantities upon the intestines, and poured off again, after 2 or 3 hours, till they be purified. They are now drawn several times through an open brass thimble, and pressed against it with the nail, in order to smooth and equalize their surface. They are lastly sorted, according to their sizes, to suit different purposes.

Whip-cord is made from the above intestines, which are sewed together endwise by the filandre, each junction being cut aslant, so as to make it strong and smooth. The cord is put into the frame, and each end is twisted separately; for whip-cord is seldom made out of two guts twisted together. When twisted it is to be sulphured (see Sulphuring) once or twice. It may also be dyed black with common ink, pink with red ink, which the sulphurous acid changes to pink, and green with a green dye which the colour dealers sell for the purpose. The guts take the dyes readily. After being well smoothed, the cord is to be dried, and coiled up for sale.

Hatter’s cords for bowstrings.—The longest and largest intestines of sheep, after being properly treated with the potash, are to be twisted 4, 6, 8, 10, or 12 together, according to the intended size of the cord, which is usually made from 15 to 25 feet long. This cord must be free from seams and knots. When half dry, it must be exposed twice to the fumes of burning sulphur; and, after each operation, it is to be well stretched and smoothed; it should be finally dried in a state of tension.

Clockmaker’s cord.—This cord should be extremely thin, and be therefore made from very small intestines, or from intestines slit up in their length by a knife fitted for the purpose; being a kind of lancet surmounted with a ball of lead or wood. The wet gut is strained over the ball which guides the knife, and the two sections fall down into a vessel placed beneath. Each hand pulls a section. Clockmakers also make use of stronger cords made of 2 or more guts twisted together.

Fiddle and harp strings.—These require the greatest care and dexterity on the part of the workmen. The treble strings are peculiarly difficult to make, and are best made at Naples, probably because their sheep, from their small size and leanness, afford the best raw material.

The first scraping of the guts intended for fiddle-strings must be very carefully performed; and the alkaline lyes being clarified with a little alum, are added, in a progressively stronger state from day to day, during 4 or 5 days, till the guts be well bleached and swollen. They must then be passed through the thimble, and again cleansed with the lixivium; after which they are washed, spun, or twisted and sulphured during two hours. They are finally polished by friction, and dried. Sometimes they are sulphured twice or thrice before being dried, and are polished between horse-hair cords.

It has been long a subject of complaint, as well as a serious inconvenience to musicians, that catgut strings cannot be made in England of the same goodness and strength as those imported from Italy. These are made of the peritoneal covering of the intestines of the sheep; and, in this country, they are manufactured at Whitechapel, and probably elsewhere in considerable quantity; the consumption of them for harps, as well as for the instruments of the violin family, being very great. Their chief fault is weakness; whence it is difficult to bring the smaller ones, required for the higher notes, to concert pitch; maintaining at the same time, in their form and construction, that tenuity or smallness of diameter, which is required to produce a brilliant and clear tone.

The inconvenience arising from their breaking when in use, and the expense in the case of harps, where so many are required, are such as to render it highly desirable to improve a manufacture which, to many individuals may, however, appear sufficiently contemptible.

It is well known to physiologists, that the membranes of lean animals are far more tough than of those animals which are fat or in high condition; and there is no reason to doubt that the superiority of the Italian strings arises from the state of the sheep in that country. In London, where no lean animals are slaughtered, and where, indeed, an extravagant and useless degree of fattening, at least for the purpose of food, is given to sheep in particular, it is easy to comprehend why their membranes can never afford a material of the requisite tenacity. It is less easy to suggest an adequate remedy; but a knowledge of the general principle, should this notice meet the eyes of those interested in the subject, may at least serve the purpose of diminishing the evil and improving the manufacture, by inducing them to choose in the market the offal of such carcases as appear least overburthened with fat. It is probable that such a manufacture might be advantageously established in those parts of the country where the fashion has not, as in London, led to the use of meat so much overfed; and it is equally likely, that in the choice of sheep for this purpose, advantage would arise from using the Welch, the Highland, or the Southdown breeds, in preference to those which, like the Lincoln, are prone to excessive accumulations of fat. It is equally probable, that sheep dying of some of the diseases accompanied by emaciation, would be peculiarly adapted to this purpose.

That these suggestions are not merely speculative is proved by comparing the strength of the membranes in question, or that of the other membranous parts, in the unfattened Highland sheep, with that of those found in the London markets.

CATHARTINE. The name proposed by MM. Feneulle and Lassaigne for a chemical principle, which they suppose to be the active constituent of senna.

CAUSTIC. Any chemical substance corrosive of the skin and flesh; as potash, called common caustic, and nitrate of silver, called lunar caustic, by surgeons.

CAVIAR. The salted roe of certain species of fish, especially the sturgeon. This product forms a considerable article of trade, being exported annually from the town of Astrachan alone, upon the shores of the Caspian sea, to the amount of several hundred tons. The Italians first introduced it into Eastern Europe from Constantinople, under the name of caviale. Russia has now monopolized this branch of commerce. It is prepared in the following manner:—

The female sturgeon is gutted; the roe is separated from the other parts, and cleaned by passing it through a very fine searce, by rubbing it into a pulp between the hands: this is afterwards thrown into tubs, with the addition of a considerable quantity of salt; the whole is then well stirred, and set aside in a warm apartment. There is another sort of caviar, the compressed, in which the roe, after having been cured in strong brine, is dried in the sun, then put into a cask, and subjected to strong pressure.

CAWK. The English miner’s name for sulphate of baryta, or heavy spar.

CEDRA, (Cedrat, Fr.) is the fruit of a species of orange, citron, or lemon, a tree which bears the same name. Its peel is very thick, and covered with an epidermis which encloses a very fragrant and highly prized essential oil. The preserves flavoured with it are very agreeable. The citrons are cut into quarters for the dry comfits, but are put whole into the liquid ones. The liquorist-perfumer makes with the peel of the cedra an excellent liqueur; for which purpose, he plucks them before they are quite ripe; grates down the peel into a little brandy, or cuts them into slices, and infuses these in the spirits. This infusion is distilled for making perfume; but the flavour is better when the infusion itself is used. See Essences, Liquorist, Perfumery.

CELESTINE. Native sulphate of strontia, found abundantly near Bristol, in the red marl formation. It is decomposed, by ignition with charcoal, into sulphuret of strontia, which is converted into nitrate by saturation with nitric acid, evaporation, and crystallization. This nitrate is employed for the production of the red light in theatrical fire-works.

CEMENTATION. A chemical process, which consists in imbedding a solid body, in a pulverulent matter, and exposing both to ignition in an earthen or metallic case. In this way, iron is cemented with charcoal to form steel, and bottle glass with gypsum powder, or sand, to form Reaumur’s porcelain.

CEMENTS. (Ciments, Fr.; CÄmente, Kitte, Germ.) Substances capable of taking the liquid form, and of being in that state applied between the surfaces of two bodies, so as to unite them by solidifying. They may be divided into two classes, those which are applied through the agency of a liquid menstruum, such as water, alcohol, or oil, and those which are applied by fusion with heat.

The diamond cement for uniting broken pieces of china, glass, &c. which is sold as a secret at an absurdly dear price, is composed of isinglass soaked in water till it becomes soft, and then dissolved in proof spirit, to which a little gum resin, ammoniac, or galbanum, and resin mastic are added, each previously dissolved in a minimum of alcohol. When to be applied, it must be gently heated to liquefy it; and it should be kept for use in a well-corked phial. A glass stopper would be apt to fix so as not to be removable. This is the cement employed by the Armenian jewellers in Turkey for glueing the ornamental stones to trinkets of various kinds. When well made it resists moisture.

Shell-lac dissolved in alcohol, or in a solution of borax, forms a pretty good cement. White of egg alone, or mixed with finely sifted quick lime, will answer for uniting objects which are not exposed to moisture. The latter combination is very strong, and is much employed for joining pieces of spar and marble ornaments. A similar composition is used by copper-smiths to secure the edges and rivets of boilers; only bullock’s blood is the albuminous matter used instead of white of egg. Another cement in which an analogous substance, the curd or caseum of milk is employed, is made by boiling slices of skim-milk cheeses into a gluey consistence in a great quantity of water, and then incorporating it with quicklime on a slab with a muller, or in a marble mortar. When this compound is applied warm to broken edges of stoneware, it unites them very firmly after it is cold.

A cement which gradually indurates to a stony consistence may be made by mixing 20 parts of clean river sand, two of litharge, and one of quicklime, into a thin putty with linseed oil. The quicklime may be replaced with litharge. When this cement is applied to mend broken pieces of stone, as steps of stairs, it acquires after some time a stony hardness. A similar composition has been applied to coat over brick walls, under the name of mastic.

The iron-rust cement is made of from 50 to 100 parts of iron borings, pounded and sifted, mixed with one part of sal-ammoniac, and when it is to be applied moistened with as much water as will give it a pasty consistency. Formerly flowers of sulphur were used, and much more sal-ammoniac in making this cement, but with decided disadvantage, as the union is effected by the oxidizement, consequent expansion and solidification of the iron powder, and any heterogeneous matter obstructs the effect. The best proportion of sal-ammoniac is, I believe, one per cent. of the iron borings. Another composition of the same kind is made by mixing 4 parts of fine borings or filings of iron, 2 parts of potter’s clay, and 1 part of pounded potsherds, and making them into a paste with salt and water. When this cement is allowed to concrete slowly on iron joints, it becomes very hard.

For making architectural ornaments in relief, a moulding composition is formed of chalk, glue, and paper paste. Even statues have been made with it, the paper aiding the cohesion of the mass.

Mastics of a resinous or bituminous nature which must be softened or fused by heat are the following:—

Mr. S. Varley’s consists of sixteen parts of whiting sifted and thoroughly dried by a red heat, adding when cold a melted mixture of 16 parts of black rosin and 1 of bees’-wax, and stirring well during the cooling.

Mr. Singer’s electrical and chemical apparatus cement consists of 5 lbs. of rosin, 1 of bees’-wax, 1 of red ochre, and two table-spoonsful of Paris-plaster, all melted together. A cheaper one for cementing voltaic plates into wooden troughs is made with 6 pounds of rosin, 1 pound of red ochre, ¹/₂ of a pound of plaster of Paris, and ¹/₄ of a pound of linseed oil. The ochre and the plaster of Paris should be calcined beforehand, and added to the other ingredients in their melted state. The thinner the stratum of cement that is interposed, the stronger generally speaking is the junction.

Boiled linseed oil and red lead mixed together into a putty are often used by coppersmiths and engineers, to secure joints. The washers of leather or cloth are smeared with this mixture in a pasty state.

The resin mastic alone is sometimes used by jewellers to cement by heat cameos of white enamel or coloured glass to a real stone, as a ground to produce the appearance of an onyx. Mastic is likewise used to cement false backs or doublets to stones to alter their hue.

Melted brimstone either alone, or mixed with rosin and brick dust, forms a tolerably good and very cheap cement.

Plumber’s cement consists of black rosin one part, brick dust two parts, well incorporated by a melting heat.

The cement of dihl for coating the fronts of buildings consists of linseed oil, rendered dry by boiling with litharge, and mixed with porcelain clay in fine powder, to give it the consistence of stiff mortar. Pipe-clay would answer equally well if well dried, and any colour might be given with ground bricks, or pottery. A little oil of turpentine to thin this cement aids its cohesion upon stone, brick, or wood. It has been applied to sheets of wire cloth, and in this state laid upon terraces, in order to make them water tight; but it is little less expensive than lead.

The bituminous or black cement for bottle corks consists of pitch hardened by the addition of rosin and brick-dust.

In certain localities where a limestone impregnated with bitumen occurs, it is dried, ground, sifted, and then mixed with about its own weight of melted pitch, either mineral, vegetable, or that of coal tar. When this mixture is getting semifluid, it may be moulded into large slabs or tiles in wooden frames lined with sheet iron, previously smeared over with common lime mortar, in order to prevent adhesion to the moulds, which, being in movable pieces, are easily dismounted so as to turn out the cake of artificial bituminous stone. This cement is manufactured upon a great scale in many places, and used for making Italian terraces, covering the floors of balconies, flat roofs, water reservoirs, water conduits, &c. When laid down, the joints must be well run together with hot irons. The floor of the terrace should be previously covered with a layer of Paris plaster or common mortar, nearly an inch thick, with a regular slope of one inch to the yard. Such bituminous cement weighs 144 pounds the cubic foot; or a foot of square surface, one inch thick, weighs 12 pounds. Sometimes a second layer of these slabs or tiles is applied over the first, with the precaution of making the seams or joints of the upper correspond with the middle of the under ones. Occasionally a bottom bed, of coarse cloth or gray paper, is applied. The larger the slabs are made, as far as they can be conveniently transported and laid down, so much the better. For hydraulic cements, see Mortar.

CERASIN. The name given by Dr. John to those gums which swell, but do not dissolve in water; such as gum tragacanth. It is synonymous with Bassorine, which see.

CERATE from cera, wax. An unguent, of rather a stiff consistence, made of oil, or lard and wax, thickened occasionally with pulverulent matters.

CERINE. A substance which forms from 70 to 80 per cent. of bees’-wax. It may be obtained by digesting wax, for some time, in spirit of wine, at a boiling temperature. The myricine separates, while the cerine remains dissolved, and may be obtained from the decanted liquor by evaporation. Cerine is white, analogous to wax, fusible at 134° F., hardly acted upon by hot nitric acid, but is readily carbonized by hot sulphuric acid. When treated with caustic alkaline lye, it is converted into margaric acid and ceraÏne.

CERIUM. A peculiar metal discovered in the rare mineral, called cerite, found only in the copper mine of Bastnaes, near Riddarhytta, in Sweden. Cerium, extracted from its chloride by potassium, appears as a dark red or chocolate powder, which assumes a metallic lustre by friction. It does not conduct electricity well, like other metals; it is infusible; its specific gravity is unknown. It has been applied to no use in the arts.

CERUSE. A name of white lead. See Lead.

CETINE. The name given by Chevreul to spermaceti.

CHAINWORK is a peculiar style of textile fabric, to which hosiery and tambouring belong. See Hosiery.

CHALK. (Craie, Fr.; Kreide, Germ.) A friable carbonate of lime, white, opaque, soft, dull, or without any appearance of polish in its fracture. Its specific gravity varies from 2·4 to 2·6. It usually contains a little silica, alumina, and oxide of iron. It may be purified by trituration, and elutriation. The siliceous and ferruginous matters subside first, and the finer chalky particles floating in the supernatant liquid, may be decanted with it, and obtained by subsidence. When thus purified, it is called whitening and Spanish white, in England; schlemmkreide, in Germany; blanc de Troyes, and blanc de Meudon, in France. Pure chalk should dissolve readily in dilute muriatic acid, and the solution should afford no precipitate with water of ammonia.

CHALK—Black. A mineral, called also drawing-slate.

CHALK—French. Steatite, or soap stone; a soft magnesian mineral.

CHALK—Red. A clay coloured with the peroxide of iron, of which it contains about 17 per cent.

CHARCOAL. The fixed residuum of vegetables exposed to ignition out of contact of air. In the article Carbon, I have described the general properties of charcoal and the simplest mode of making it. I shall here detail the best systems of manufacturing this product upon the continent of Europe.

To carbonize wood under a movable covering, the plan of meiler, or heaps, is employed very much in Germany. The wood is arranged either in horizontal layers, or in nearly vertical ones, with a slight slope, so as to form conical rounded heaps of different sizes. The former are called lying meiler, fig. 272.; the latter standing meiler, figs. 273. and 274. Both are distributed in much the same way.

In districts where the wood can be transported into one place by means of rivers, or mountain slides, a dry flat space must be pitched upon, screened from storms and floods, which may be walled round, having a slight declivity made in the ground, towards the centre. See fig. 275. Into this space the tarry acid will partially fall, and may be conducted outwards, through a covered gutter beneath, into a covered tank. The mouth of the tank must be shut, during the coaking, with an iron or stone slab, luted with clay. A square iron plate is placed over the inner orifice of the gutter, to prevent it being choked with coal ashes. Fig. 275. represents a walled meiler station; a, the station; b, the gutter; c, the tank, which is covered with the slab d; e, a slab which serves to keep the gutter clear of coals. The cover of the heaps is formed of earth, sand, ashes, or such other matter as may be most readily found in the woods. They should be kindled in the centre. From 6 days to 4 weeks may be required for charring a heap, according to its size; hard wood requiring most time; and the slower the process, the better and greater is the product, generally speaking.

Charring of wood in mounds (Haufe or liegende werke) figs. 276. and 277. differs from that in the meiler, because the wood in the haufe is successively charred, and the charcoal is raked out by little and little. The product is said to be greater in this way, and also better. Uncleft billets, 6 or 8 feet long, being laid over each other, are covered with ashes, and then carbonized. The station is sometimes horizontal, and sometimes made to slope. The length may be 24 feet, the breadth 8 feet; and the wood is laid crosswise. Piles are set perpendicularly to support the roof, made of boughs and leaves, covered with ashes. Pipes are occasionally laid within the upper part of the mounds, which serve to catch and carry off some of the liquid products into proper tanks.

Fig. 278. is a vertical section, and fig. 279. a half bird’s-eye view, and half cross section, at the height of the pit-bottom, of ChabeaussiÈre’s kiln for making wood charcoal. a is the oven; b, vertical air-pipes; c c, horizontal flues for admitting air to the kiln; d d, small pits which communicate by short horizontal pipes e e, with the vertical ones; f, the sole of the kiln, a circle of brickwork, upon which the cover or hood h reposes; i, a pipe which leads to the cistern k; l, the pipe destined for carrying off the gaseous matter; m m, holes in the iron cover or lid.

The distribution of the wood is like that in the horizontal meilers, or heaps; it is kindled in the central vertical canal with burning fuel, and the lid is covered with a few inches of earth. At the beginning of the operation all the draught flues are left open, but they are progressively closed, as occasion requires. In eight kilns of this kind, 500 decasters of oak wood are carbonized, from which 16,000 hectolitres of charcoal are obtained, equal to 64,000 pounds French, being about 25 per cent.; besides tar and 3000 velts of wood vinegar, of from 2° to 3°. BaumÉ.

At Crouy upon the Ourcq, near Meaux, there is a well constructed kiln for making turf-charcoal. It resembles most nearly a tar-kiln. In fig. 280. a is the cylindrical coaking place, whose surrounding walls are heated by the flame which passes through the intermediate space b. The place itself is divided by partitions of fire tiles into three stages, through the apertures in which the flames of the fire c c, rise, and heat the exterior of the coaking apartment. In order to confine the heat, there is in the enclosing walls of the outer kiln a cylindrical hollow space d, where the air is kept stagnant. Through the apertures left in the upper end at e, the turf is introduced; they are then shut with an iron plate f, which is covered with ashes or sand. The fire-place opens above this aperture, and its outlet is provided with a moveable iron cover g, in which there is a small hole for the issue of the gases. The sole of the kiln consists of a cast iron slab h, which may be raised by means of a hook i upon it. This is drawn back after the carbonization is completed, whereby the charcoal falls from the coaking space into a subjacent vault. The volatile products are carried off by the pipe k, and led into the condensing cistern; the gases escaping to the fire-place where they are burned. The iron slab is protected from the corrosion of the acid vapours by a layer of coal ashes.

CHICA is a red colouring principle made use of in America by some Indian tribes to stain their skins. It is extracted from the bignonia chica by boiling its leaves in water, decanting the decoction, and allowing it to settle and cool, when a red matter falls down, which is formed into cakes and dried. This substance is not fusible, and, when burned, diffuses the same odour as animal bodies do. It is insoluble in cold water, very soluble in alcohol and ether, but, after the evaporation of these liquids, it is recovered unchanged. Fats and unctuous oils both dissolve it. It is soluble in carbonated and caustic alkaline lyes, from which it is precipitated by the acids without alteration. An excess of alkali, however, speedily decomposes it. Nitric acid transforms it into oxalic acid, and a bitter matter. Chlorine makes it white.

The savages mix this pigment with the fat of the cayman or alligator, and rub their skins with the mixture. It may probably be turned to account in the arts of civilized nations.

CHIMNEY. (CheminÉe, Fr.; Schornstein, Germ.) Chimney is a modern invention for promoting the draught of fires and carrying off the smoke, introduced into England so late as the age of Elizabeth, though it seems to have been employed in Italy 100 years before. The Romans, with all their luxurious refinements, must have had their epicurean cookery placed in perpetual jeopardy from their kitchen fires, which, having no vent by a vertical tunnel in the walls, discharged their smoke and frequently their flames at the windows, to the no small alarm of their neighbours, and annoyance of even the street passengers.

Chimneys in dwelling houses serve also the valuable purpose of promoting salubrious circulation of air in the apartments, when not foolishly sealed with anti-ventilating stove-chests.

The first person who sought to investigate the general principles of chimney draughts, in subserviency to manufacturing establishments, was the celebrated Montgolfier. As the ascent of heated air in a conduit depends upon the diminution of its specific gravity, or, in other words, upon the increase of its volume by the heat, the ascensional force may be deduced from the difference between the density of the elastic fluid in the interior of the chimney, and of the external air; that is, between the different heights of the internal and external columns of elastic fluid supposed to be reduced to the same density. In the latter case, the velocity of the gaseous products of combustion in the interior of the chimney is equal to that of a heavy body let fall from a height equal to the difference in height of the two aerial columns.

To illustrate this position by an example, let us consider the simple case of a chimney of ventilation for carrying off foul air from a factory of any kind; and suppose that the tunnel of iron be incased throughout with steam at 212 degrees Fahr. Suppose this tunnel to be 100 yards high, then the weight of the column of air in it will be to that of a column of external air 100 yards high, assumed at 32° F. inversely as its expansion by 180°; that is, as 1000 is to 1·375; or as 72·727 is to 100. The column of external air at 32° being 100 yards, the internal column will be represented by 72·727; and the difference = 27·27, will be the amount of unbalanced weight or pressure, which is the effective cause of the ventilation. Calculating the velocity of current due to this difference of weight by the well-known formula for the fall of heavy bodies, that is to say, multiplying the above difference, which is 27·27, by the constant factor 19·62, and extracting the square root of the product; thus, v19·62× 27·27 = 23·13 will be the velocity in yards per second, which, multiplied by 3, gives 69·39 feet. The quantity of air which passes in a second is obtained of course by multiplying the area or cross section of the tunnel by this velocity. If that section is half a yard, that is = a quadrangle 2¹/₄ feet by 2, we shall have 23·13× 0·5 = 11·565 cubic yards, = 312¹/₄ cubic feet.

The problem becomes a little more complicated in calculating the velocity of air which has served for combustion, because it has changed its nature, a variable proportion of its oxygen gas of specific gravity 1·111, being converted into carbonic acid gas of specific gravity 1·524. The quantity of air passed through well-constructed furnaces may, in general, be regarded as double of what is rigorously necessary for combustion, and the proportion of carbonic acid generated, therefore, not one half of what it would be were all the oxygen so combined. The increase of weight in such burned air of the temperature of 212°, over that of pure air equally heated, being taken into account in the preceding calculation, will give us about 19 yards or 57 feet per second for the velocity in a chimney 100 yards high incased in steam.

Such are the deductions of theory; but they differ considerably from practical results, in consequence of the friction of the air upon the sides of the chimneys, which varies likewise with its form, length, and quality. The direction and force of the winds also exercise a variable influence upon chimney furnaces differently situated. In chimnies made of wrought iron, like those of steam boats, the refrigeration is considerable, and causes a diminution of velocity far greater than what occurs in a factory stalk of well-built brick work. In comparing the numbers resulting from the trials made on chimneys of different materials and of different forms, it has been concluded that the obstruction to the draught of the air, or the deduction to be made from the theoretical velocity of efflux, is directly proportional to the length of the chimneys and to the square of the velocity, and inversely to their diameter. With an ordinary wrought-iron pipe, of from 4 inches to 5 inches diameter, attached to an ordinary stove, burning good charcoal, the difference is prodigious between the velocity calculated by the above theoretical rule, and that observed by means of a stop-watch, and the ascent of a puff of smoke from a little tow, dipped in oil of turpentine thrust quickly into the fire. The chimney being 45 feet high, the temperature of the atmosphere 68° Fahr., the velocity per second was,—

To obtain congruity between calculation and experiment, several circumstances must be introduced into our formulÆ. In the first place, the theoretical velocity must be multiplied by a factor, which is different according as the chimney is made of bricks, pottery, sheet iron, or cast iron. This factor must be multiplied by the square root of the diameter of the chimney (supposed to be round), divided by its length, increased by four times its diameter. Thus, for pottery, its expression is 2·06 vDL + D; D being the diameter, and L the length of the chimney.

A pottery chimney, 33 feet high, and 7 inches in diameter, when the excess of its mean temperature above that of the atmosphere was 205° Fahr., had a pressure of hot air equal to 11·7 feet, and a velocity of 7·2 feet per second. By calculating from the last formula, the same number very nearly is obtained. In none of the experiments did the velocity exceed 12 feet per second, when the difference of temperature was more than 410° Fahr.

Every different form of chimney would require a special set of experiments to be made for determining the proper factor to be used.

This troublesome operation may be saved by the judicious application of a delicate differential barometer, such as that invented by Dr. Wollaston; though this instrument does not seem to have been applied by its very ingenious author in measuring the draughts or ventilating powers of furnaces.

If into one leg of this differential syphon, water be put, and fine spermaceti oil into the other, we shall have two liquids, which are to each other in density as the numbers 8 and 7. If proof spirit be employed instead of water, we shall then have the relation of very nearly 20 to 19. I have made experiments on furnace draughts with the instrument in each of these states, and find the water and oil syphon to be sufficiently sensible: for the weaker draughts of common fire-places the spirits and oil will be preferable barometric fluids.

To the lateral projecting tube of the instrument, as described by Dr. Wollaston, I found it necessary to attach a stop-cock, in order to cut off the action of the chimney, while placing the syphon, to allow of its being fixed in a proper state of adjustment, with its junction line of the oil and water at the zero of the scale. Since a slight deviation of the legs of the syphon from the perpendicular, changes very considerably the line of the level, this adjustment should be made secure by fixing the horizontal pipe tightly into a round hole, bored into the chimney stalk, or drilled through the furnace door. On gently turning the stop-cock, the difference of atmospherical pressure corresponding to the chimney draught, will be immediately indicated by the ascent of the junction-line of the liquids in the syphon. This modification of apparatus permits the experiment to be readily rectified by again shutting off the draught, when the air will slowly re-enter the syphon; because the projecting tube of the barometer is thrust into the stop-cock, but not hermetically joined; whereby its junction line is allowed to return to the zero of the scale in the course of a few seconds.

Out of many experiments made with this instrument, I shall content myself with describing a few, very carefully performed at the breweries of Messrs. Trueman, Hanbury, and Buxton, and of Sir H. Meux, Bart., and at the machine factory of Messrs. Braithwaite; in the latter of which I was assisted by Captain Ericsson. In the first trials at the breweries, the end of the stop-cock attached to the differential barometer was lapped round with hemp, and made fast into the circular peep-hole of the furnace door of a wort copper, communicating with two upright parallel chimneys, each 18 inches square, and 50 feet high. The fire was burning with fully its average intensity at the time. The adjustment of the level being perfect, the stop-cock orifice was opened, and the junction level of the oil and water rose steadily, and stood at 1¹/₄ inches, corresponding to 1·258 = 0·156 of 1 inch of water, or a column of air 10·7 feet high. This difference of pressure indicates a velocity of 26 feet per second. In a second set of experiments, the extremity of the stop-cock was inserted into a hole, bored through the chimney stalk of the boiler of a Boulton and Watt steam-engine of twenty-horse power. The area of this chimney was exactly 18 inches square at the level of the bored hole, and its summit rose 50 feet above it. The fire-grate was about 10 feet below that level. On opening the stop-cock, the junction line rose 2¹/₄ inches. This experiment was verified by repetition upon different days, with fires burning at their average intensity, and consuming fully 12 lbs. of the best coals hourly for each horse’s power, or nearly one ton and a third in twelve hours. If we divide the number 2¹/₄ by 8, the quotient 0·28 will represent the fractional part of 1 inch of water, supported in the syphon by the unbalanced pressure of the atmosphere in the said chimney; which corresponds to 19¹/₄ feet of air, and indicates a velocity in the chimney current of 35 feet per second. The consumption of fuel was much more considerable in the immense grate under the wort copper, than it was under the steam-engine boiler.

In my experiments at Messrs. Braithwaite’s factory, the maximum displacement of the junction line was 1 inch, when the differential oil and water barometer was placed in direct communication with a chimney 15 inches square, belonging to a steam boiler, and when the fire was made to burn so fiercely, that, on opening the safety-valve of the boiler, the excess of steam beyond the consumption of the engine, rushed out with such violence as to fill the whole premises. The pressure of one-eighth of an inch of water denotes a velocity of draught of 23·4 feet per second.

In building chimneys, we should be careful to make their area rather too large than too small; because we can readily reduce it to any desired size, by means of a sliding register plate near its bottom, or a damper plate applied to its top, adjustable by wires or chains, passing over pulleys. Wide chimneys are not so liable as narrow ones to have their draught affected by strong winds. In a factory, many furnace flues are often conducted into one vertical chimney stalk, with great economy in the first erection, and increased power of draught in the several fires.

Vast improvements have been made in this country, of late years, in building stalks for steam boilers and chemical furnaces. Instead of constructing an expensive, lofty scaffolding of timber round the chimney, for the bricklayers to stand upon, and to place their materials, pigeon-holes, or recesses, are left at regular intervals, a few feet apart, within the chimney, for receiving the ends of stout wooden bars, which are laid across, so as to form a species of temporary ladder in the interior of the tunnel. By means of these bars, with the aid of ropes and pulleys, every thing may be progressively hoisted, for the building of the highest engine or other stalks. An expert bricklayer, with a handy labourer, can in this way raise, in a few weeks, a considerable chimney, 40 feet high, 5 feet 8 inches square outside, 2 feet 8 inches inside at the base, 28 inches outside, and 20 inches inside at the top. To facilitate the erection, and at the same time increase the solidity of an insulated stalk of this kind, it is built with three or more successive plinths, or recedures, as shown in fig. 281. It is necessary to make such chimneys thick and substantial near the base, in order that they may sustain the first violence of the fire, and prevent the sudden dissipation of the heat. When many flues are conducted into one chimney stalk, the area of the latter should be nearly equal to the sum of the areas of the former, or at least of as many of them as shall be going simultaneously. When the products of combustion from any furnace must be conducted downwards, in order to enter near the bottom of the main stalk, they will not flow off until the lowest part of the channel be heated by burning some wood shavings or straw in it, whereby the air syphon is set agoing. Immediately after kindling this transient fire at that spot, the orifice must be shut by which it was introduced; otherwise the draught of the furnace would be seriously impeded. But this precaution is seldom necessary in great factories, where a certain degree of heat is always maintained in the flues, or, at least, should be preserved, by shutting the damper plate of each separate flue, whenever its own furnace ceases to act. Such chimneys are finished at top with a coping of stone-slabs, to secure their brickwork against the infiltration of rains, and they should be furnished with metallic conducting rods, to protect them from explosions of lightning.

When small domestic stoves are used, with very slow combustion, as has been recently proposed, upon the score of a misjudged economy, there is great danger of the inmates being suffocated or asphyxied, by the regurgitation of the noxious burned air. The smoke doctors who recommend such a vicious plan, from their ignorance of chemical science, are not aware that the carbonic acid gas, of coke or coal, must be heated 250° F. above the atmospheric air, to acquire the same low specific gravity with it. In other words, unless so rarefied by heat, that gaseous poison will descend through the orifice of the ash-pit, and be replaced by the lighter air of the apartment. Drs. Priestley and Dalton have long ago shown the co-existence of these two-fold crossing currents of air, even through the substance of stone-ware tubes. True economy of heat, and salubrity, alike require vivid combustion of the fuel, with a somewhat brisk draught inside of the chimney, and a corresponding abstraction of air from the apartment. Wholesome continuous ventilation, under the ordinary circumstances of dwelling houses, cannot be secured in any other way. Were these mephitic stoves, which have been of late so ridiculously puffed in the public prints, generally introduced, the faculty would need to be immediately quadrupled to supply the demand for medical advice; for headaches, sickness, nervous ailments, and apoplexy, would become the constant inmates of every inhabited mansion. The phenomena of the grotto of Pausilippo might then be daily realised at home, among those who ventured to recline upon sofas in such carbonated apartments; only instead of a puppy being suffocated pro tempore, human beings would be sacrificed, to save two-penny worth of fuel per diem.

The figures upon the preceding page represent one of the two chimneys, recently erected at the Camden Town station, for the steam boilers of the two engines of 60 horse-power each, belonging to the London and Birmingham Railway Company. These engines draw their train of carriages up the inclined plane of Hampstead Hill. The chimneys were designed by Robert Stephenson, Esq., engineer to the Company, executed by William Cubitt, Esq., of Gray’s Inn Road,—and do equal honour to both gentlemen, being probably the most elegant and substantial specimens of this style of architecture in the world. In the section, fig. 281.,

A represents a bed of concrete, 6 feet thick, and 24 feet square.

B, brick footings set in cement; the lower course 19 feet square.

C, Bramley-fall stone base, with a chain of wrought iron let into it.

D, a portion, 15 feet high, curved to a radius of 113 feet, built entirely of Malm paviours, (a peculiarly good kind of bricks.)

E, shaft built of Malm paviours in mortar.

F, ditto, built from the inside, without exterior scaffolding.

G, the cap ornamented, (as shown in the plan alongside,) with Portland stone, the dressings being tied together with copper cramps and an iron bond.

Fig. 282. represents the mouldings of the top, upon an enlarged scale.

Fig. 283., a plan of the foundation, ditto.

Fig. 284., ditto, at the level of the entrance of the flue, as seen in

Fig. 285., the elevation of the chimney.

Fig. 286., plan at the ground level I, in fig. 281. and 285.

K, fig. 281., the lightning conducting rod.

CHLORATE OF POTASH, commonly called oxymuriate of potash. This interesting saline compound has become the object of a pretty extensive manufacture, in consequence of its application to make matches for procuring instantaneous light, and a detonating powder for fire-arms. It may be prepared both in the humid and dry way.

Having made a strong solution of purified potash, or carbonate of potash, with from two to three parts of water, we pass through it in a Woulfe’s apparatus a current of chlorine gas, till it ceases to absorb any more. Chloride of potash and chloride of potassium alone are formed as long as there is an excess of alkali in the solution; but afterwards in the further reaction of the materials, the chloride passes into the state of a chlorate, and, as such, precipitates from the solution. During the first half of the operation, that is, till the potash be about one half saturated with chlorine, as indicated by litmus paper ceasing to be darkened and beginning to be blanched, only the chloride of potassium or muriate of potash falls. The process should be interrupted at this point in order to remove the salt, to wash it, to add the washings to the liquor, and then to transmit the gas freely through the solution. As the operation advances, less muriate of potash is formed, and at length nothing but the pure chlorate is separated in crystals. When finally the bubbles of gas pass through without being sensibly absorbed, the process is known to be completed; the liquid may then be allowed to settle, and be poured off from the crystals of chlorate of potash, which are purified from the muriate by dissolving them in three times their weight of boiling water, and filtering the solution while hot. On its cooling, the chlorate will separate in pearly-looking crystalline plates. It may be rendered quite pure by a second crystallization, in which state it does not affect solution of nitrate of silver.

The above potash lye usually gets a reddish tint in the course of the process in consequence of a little manganesic acid coming over with the chlorine, but it gradually loses this colour as the saturation becomes complete, when the solution turns yellow. The tubes for conveying the gas should be of large diameter, if they be plunged into the saline solution, because the crystallization which takes place in it is apt to choke them up. This inconvenience may however be obviated by attaching to the end of the glass tube, a tube of caoutchouc terminated in a small glass funnel, or simply the neck of a caoutchouc bottle with a part of its body, whose width will not be readily closed with a saline crust. The residuary lixivium may be used against another operation, or it may be evaporated down to half its bulk and set aside to crystallize, whereby some more chlorate will be obtained, mixed indeed with muriate and carbonate, from which however it may be separated by a second crystallization. In general the pure chlorate obtained does not exceed one tenth the weight of the potash employed; because in thus treating potash with chlorine, five-sixths of it are converted into muriate of potash and only one sixth into chlorate, and a part of the latter adheres to the muriate, or is lost in the mother waters of the crystallizations.

The chlorate of potash may be more conveniently manufactured, like that of lime, in the dry way. St. Romer patented at Vienna the following method for that purpose in 1821:—Ten pounds of crystallised peroxide of manganese are to be finely pulverised, mixed with ten pounds of plumbago, and thirty pounds of common salt, and put into the leaden retort represented in fig. 287. p. 287. From the middle of the helmet-shaped lid of this vessel, a lead tube, two feet long and two inches wide, conducts to the receiver, which is a square earthen pan, hard glazed both within and without, of the same capacity with the retort. The end of the tube must be made fast to a frame at the height of six inches above the bottom of the receiver. Upon its inner sides four inches apart, brackets are to be fixed for supporting a series of laths or shelves of white wood, on which a number of little paper or paste-board boxes are to be laid. In these boxes ten pounds of the purest carbonate of potash, prepared from tartar, are to be spread. The receiver must now be covered with a lid made tight by a water lute. Twenty pounds of concentrated sulphuric acid previously diluted with sixteen pounds of water, and then cooled, are to be poured upon the mixed materials in the retort, the lid immediately secured, with the tube adjusted in the receiver. The whole must be allowed to operate spontaneously without heat for twelve hours. At the end of this time the retort is to be surrounded with a water bath and steadily heated during twelve hours, and then left to cool for six hours. The apparatus must now be opened, the cakes of chlorate of potash removed, and freed from muriate by solution and crystallization.

M. Liebig proposes the following process for obtaining chlorate of potash:—

Heat chloride of lime in water till it ceases to destroy vegetable colours. In this case a mixture of chloride of calcium and chlorate of potash is obtained. This is to be dissolved in hot water, and to the solution concentrated by evaporation, chloride of potassium is to be added, and then suffered to cool. After cooling, a quantity of crystals of chlorate of potash is obtained, which are to be redissolved and crystallized again to purify them. M. Liebig considers that this will be a cheap process for obtaining chlorate of potash. From 12 ounces of chloride of lime, of so bad a quality that it left 65 per cent. of insoluble matter, he obtained an ounce of chlorate of potash.

The only difficulty to overcome in this process is, from the chloride of lime not being so easily decomposed by heat as is generally supposed; a solution of it may be kept boiling for an hour without losing its bleaching power. The best method is to form a thin paste with chloride of lime and water, and then to evaporate it to dryness. If it be required to prepare it by passing chlorine into cream of lime, it is advantageous to keep it very hot.

The chlorate of potash which separates from the solution by crystallization, has not the form of scales which it usually possesses, but is prismatic: whether this is occasioned by some admixture has not been ascertained; but on re-crystallizing, it is obtained in the usual form.

The solution ought not merely to be left to cool, in order to procure crystals, for the crystallization is far from being terminated even after complete cooling; crystals continue to be deposited for 3 or 4 days.

The following modification of the process for making chlorate of potash is that of M. VÉe. A solution of chloride of lime marking 18° or 20° BaumÉ, is to be set upon the fire in a lead or cast iron pot, and when it begins to get hot, there is to be dissolved in it, a quantity of chloride of potassium sufficient to raise the hydrometer 3 or 4 degrees. It must be then concentrated as quickly as possible till it marks 30° or 31°, taking care that it does not boil over by the sudden extrication of oxygen. The concentrated liquor is set aside to crystallize in a cool place; where a deposit of chlorate of potash forms, mixed with chloride of potassium. The mother waters being evaporated to the density of 36°, afford another crop of crystals, after which they may be thrown away.

The salts obtained at the first crystallization are to be re-dissolved, and the solution being brought to 15° or 16° is to be filtered, when it will afford upon cooling pure chlorate of potash.

Chlorate or oxymuriate of potash has a cooling, somewhat unpleasant and nitrous taste. It does not bleach. At 60° F. 100 parts of water dissolve six parts of it, and at its boiling point or 220°, sixty parts. When heated to dull ignition in a glass retort it gives out 39·15 per cent. of its weight of oxygen, and becomes thereby chloride of potassium. When strongly triturated in a mortar it crackles, throws out sparks, and becomes luminous. It deflagrates upon red-hot cinders like nitre: when triturated along with sulphur, or phosphorus, it detonates with great violence, not without danger to the hands of the operator, if they be not protected by a thick glove. Similar detonations may be produced with cinnabar or vermillion, sulphuret of potassium, sugar, volatile oils, &c.; but they can be effected only by the smart blow of a heated hammer and anvil. A mixture of sugar or starch with chlorate of potash is readily inflamed by a drop of sulphuric acid, and this experiment is the basis of the preparation of the oxygenated matches, as they have been commonly called. The following formula forms a good paste for tipping the said matches, made of narrow slips of either wood or card. Thirty parts of the chlorate in fine powder are to be mixed gently with a spatula upon paper with ten parts of flowers of sulphur well levigated, eight of sugar, five of gum arabic, and enough of vermillion to give the whole a rose tint. We begin by mixing tenderly together the sugar, the gum, and the salt previously pulverised; we then add as much water as shall reduce the mixture to a thin paste, and lastly introduce the sulphur; after which all must be well incorporated. The points of the matches, either previously tipped with sulphur or not, are to be dipped in that paste, so as to get coated with a little of it, and are lastly laid in a warm place till they become thoroughly dry. To kindle one of them, it must be touched with strong sulphuric acid, which for this purpose is usually kept in a small well-stoppered phial, and thickened with amianthus. Aspen is reckoned the best wood for matches.

Of late years a detonating priming for fire-arms has been much used with the percussion locks. The simplest formula for making it is to take ten parts of gunpowder, to lixiviate it with water, and to mix the residuum, while moist, with five parts and a quarter of chlorate of potash, reduced to an extremely fine powder. The paste may be made pretty thin, for the salt is sparingly soluble in the cold water, and it mixes best when tolerably fluid. This powder when dry is dangerous to handle, being very apt to explode. But this danger is guarded against by letting fall a drop of the paste into each copper percussion cap, and leaving it to dry there. In the detonation of this powder, besides muriate of potash, there are generated a little sulphate of potash and chlorine gas, which rust the metal very fast. For which reason fulminate of mercury is now preferred by many sportsmen as a detonating powder. See Fulminate.

CHLORATES, compounds of chloric acid with the salifiable bases. The only acid belonging to this class of any manufacturing importance is the following:

CHLORIC ACID; the acid constituent of the preceding salt; it consists of one equivalent prime of chlorine = 35·476, + 5 of oxygen, = 40·065; of which the sum 75·535 is the prime equivalent of the acid.

CHLORINE; the most energetic of the undecompounded bodies, or chemical elements as they are usually called, exists, under ordinary circumstances, as a greenish yellow gas, but, when exposed to a pressure of 4 atmospheres, it becomes a yellow transparent liquid. In the first state, its density compared to air, reckoned 1·000, is 2·47; in the second, its density compared to water, 1·000, is 1·33. No degree of cold, hitherto tried, has liquefied the gas when dry. It is obtained by putting into a glass retort a mixture of 3 parts of common salt, with 2 parts of peroxide of manganese, and pouring upon it 2 parts of sulphuric acid diluted with its own weight of water; or, more conveniently, by pouring moderately strong muriatic acid upon peroxide of manganese in a retort; and in either case applying the gentle heat of a spirit lamp or a water bath, while the beak of the retort is plunged under brine upon the shelf of the pneumatic trough. The gas issues, and may be received in the usual way into inverted glass jars, or phials; but the first which comes over being mixed with the air of the retort, must be rejected. It has a peculiar smell, and irritates the nostrils most violently when inhaled, as also the windpipe and lungs. It is eminently noxious to animal life, and, if breathed in its undiluted state, would prove instantly fatal. It supports the combustion of many bodies, and indeed spontaneously burns several without their being previously kindled. The resulting combinations are called chlorides, and act most important parts in many manufacturing processes.

Water absorbs, at the ordinary temperature of the atmosphere, about double its volume of chlorine, and acquires the colour, smell, and taste of the gas, as well as its power of destroying or bleaching vegetable colours. When this aqueous chlorine is cooled to 36° F. dark yellow crystalline plates appear in it of the hydrate of chlorine, which are composed in 100 parts of 27·7 chlorine, and 72·3 water. If these crystals be heated to about 45° they liquefy, and the gas flies off.

Chlorine has a powerful affinity for hydrogen, not only combining with it rapidly in the gaseous, but seizing it in many of its liquid and solid combinations, as in volatile oils, which it inflames, and in yellow wax, cotton, and flax, which it whitens. The compound of chlorine and hydrogen gases is muriatic acid gas. Manganese, when mixed with liquid muriatic acid, as in the above process, abstracts the hydrogen, and lets the chlorine gas go free. When chlorine is passed into water, it decomposes some of it, seizes its hydrogen to form a little muriatic acid, and enables its oxygen to unite either with the chlorine, into chlorous acid, or with the remaining water, and to constitute oxygenated water. Hence, aqueous chlorine, exposed to the sunbeam, continually evolves oxygen, and, ere long, becomes muriatic acid.

This watery compound acts in a powerful way upon coloured vegetable fibres, extracting their hydrogen or colouring element by the twofold affinities of the chlorine and oxygen for it.

Hence chlorine, as a bleaching agent, requires to be tempered by the quiescent affinity of some alkaline base, potash or lime. Malaria, or morbific and putrescent miasmata, consist chiefly of hydrogenous matter as their basis, and are best counteracted by chlorine, where it can be conveniently applied.

Chlorides of Potash, Soda, and Lime.—These are the most important preparations through which chlorine exercises its peculiar powers upon the objects of manufactures. When a weak solution of caustic potash or soda is saturated with chlorine, it affords a bleaching liquor which is still used by some bleachers and calico-printers for their most delicate processes; but the price of the alkalis has led to the disuse of these chlorides as a general means, and has occasioned an extensive employment of chloride of lime. Upon the manufacture of this interesting compound I made an elaborate series of experiments several years ago, and published the results in the 13th volume of Brande’s Journal, for April 1822. I have no reason to suppose, from any thing that has been published since, that the processes there described have been essentially improved, or that any errors, either theoretical or practical, of any moment, exist in that memoir. I shall therefore first present my readers with a brief abstract of it, and then make such observations as subsequent inquiries suggest.

In the researches which I made, at many different times, upon the nature of the chloride of lime, I generally sought to combine the information flowing from both synthesis and analysis; that is, I first converted a known portion of hydrate of lime into bleaching-powder, and then subjected this chloride to analysis.

Two hundred grains of the atomic proto-hydrate of pure lime were put into a glass globe, which was kept cold by immersion in a body of water at 50°. A stream of chlorine, after being washed in water of the same temperature in another glass globe, connected to the former by a long narrow glass tube, was passed over the calcareous hydrate. The globe with the lime was detached from the rest of the apparatus from time to time, that the process might be suspended as soon as the augmentation of weight ceased. This happened when the 200 grains of hydrate, containing 151·9 of lime, had absorbed 130 grains of chlorine. By one analytical experiment it was found, that dilute muriatic acid expelled from 50 grains of the chloride, 20 grains of chlorine, or 40 per cent.; and by another, from 40 grains, 16·25 of gas, which is 40·6 per cent. From the residuum of the first 39·7 grains of carbonate of lime were obtained by carbonate of ammonia; from that of the second, 36·6 of ignited muriate of lime. The whole results are therefore as follows:—

Though the heat generated by the action of the dilute acid had carried off in the analytical experiments a small portion of moisture with the chlorine, yet their accordance with the synthetic experiment is sufficiently good to confirm the general results. The above powder appears to have been a pure chloride, without any mixture of muriate. But it exhibits no atomic constitution in its proportions.

To 200 grains of that hydrate of lime 30 grains of water being added, the powder was subjected to a stream of chlorine in the above way, till saturation took place. Its increase of weight was 150 grains.

It ought to be remarked, that in this and the preceding experiment, there was no appreciable pneumatic pressure employed to aid the condensation of the chlorine. In the last case, we see that the addition of 30 grains of water has enabled the lime to absorb 20 grains more of chlorine, being altogether a quantity of gas nearly equal to that of the dry lime. Thus, an atom of lime seems associated with ⁷/₉ of an atom of chlorine. Analysis by muriatic acid confirmed this composition. It gave

A great variety of apparatus has been at different times contrived for favouring the combination of chlorine with the slacked lime for the purposes of commerce. One of the most ingenious forms, is that of a cylinder, or barrel, furnished with narrow wooden shelves within, and suspended on a hollow axis by which the chlorine was admitted, and round which the barrel was made to revolve. By this mode of agitation, the lime-dust being exposed on the most extensive surface, was speedily impregnated with the gas to the requisite degree. Such a mechanism I saw at MM. Oberkampf and Widmer’s celebrated fabrique de toiles peintes, at Jouy, in 1816. But this is a costly refinement, inadmissible on the largest scale of British manufacture. The simplest, and, in my opinion, the best construction for subjecting lime-powder to chlorine, is a large chamber 8 or 9 feet high, built of siliceous sandstone, having the joints of the masonry secured with a cement composed of pitch, resin, and dry gypsum in equal parts. A door is fitted into it at one end, which can be made air-tight by strips of cloth and clay lute. A window on each side enables the operator to judge how the impregnation goes on by the colour of the air, and also gives light for making the arrangements within at the commencement of the process. As water lutes are incomparably superior to all others where the pneumatic pressure is small, I would recommend a large valve or door on this principle to be made in the roof, and two tunnels of considerable width at the bottom of each side wall. The three covers could be simultaneously lifted off by cords passing over a pulley, without the necessity of the workman approaching the deleterious gas, when the apartment is to be opened. A great number of wooden shelves, or rather trays, 8 or 10 feet long, 2 feet broad, and 1 inch deep, are provided to receive the riddled slacked lime, containing generally about 2 atoms of lime to 3 of water. These shelves are piled one over another in the chamber, to the height of 5 or 6 feet, cross bars below each keeping them about an inch asunder, that the gas may have free room to circulate over the surface of the calcareous hydrate.

The alembics for generating the chlorine, which are usually nearly spherical, are in some cases made entirely of lead, in others of two hemispheres, joined together in the middle, the upper hemisphere being lead, the under one cast-iron. The first kind of alembic is enclosed for two-thirds from its bottom, in a leaden or iron case, the interval of two inches between the two being destined to receive steam from an adjoining boiler. Those which consist below of cast-iron, have their bottom directly exposed to a very gentle fire; round the outer edge of the iron hemisphere a groove is cast, into which the under edge of the leaden hemisphere fits, the joint being rendered air-tight by Roman or patent cement. In this leaden dome there are four apertures, each secured by a water-lute. The first opening is about 10 or 12 inches square, and is shut with a leaden valve, with incurvated edges, that fit into the water channel at the margin of the hole. It is destined for the admission of a workman to rectify any derangement in the apparatus of rotation, or to detach hard concretions of salt from the bottom.

The second aperture is in the centre of the top. Here a tube of lead is fixed, which descends nearly to the bottom, and down through which the vertical axis passes. To its lower end the cross bars of iron, or of wood, sheathed with lead, are attached, by whose revolution the materials receive the proper agitation for mixing the dense manganese with the sulphuric acid and salt. The motion is communicated either by the hand of a workman applied from time to time to a winch at top, or it is given by connecting the axis with wheel work, impelled by a stream of water or a steam-engine. The third opening admits the syphon-formed funnel, through which the sulphuric acid is introduced; and the fourth is the orifice of the eduction-pipe.

Manufacturers differ much from each other in the proportion of their materials for generating chlorine. In general, 10 cwt. of salt are mixed with from 10 to 14 cwt. of manganese, to which mixture, after its introduction into the alembic, from 12 to 14 cwt. of sulphuric acid are added in successive portions. That quantity of oil of vitriol must, however, be previously diluted with water, till its specific gravity becomes about 1·6. But, indeed, this dilution is seldom actually made, for the manufacturer of bleaching-powder almost always prepares his own sulphuric acid for the purpose, and therefore carries its concentration no higher in the leaden boilers than the density of 1·65, which from my table of sulphuric acid, indicates ¹/₄th of its weight of water, and therefore ¹/₃d more of such acid must be used.

The fourth aperture, I have said, admits the eduction pipe. This pipe is afterwards conveyed into a leaden chest or cylinder, in which all the other eduction pipes also terminate. They are connected with it simply by water-lutes, having a hydrostatic pressure of 2 or 3 inches. In this general diversorium the chlorine is washed from adhering muriatic acid, by passing through a little water, in which each tube is immersed, and from this the gas is let off by a pretty large leaden tube, into the combination room. It usually enters in the top of the ceiling, whence it diffuses its heavy gas equally round.

Four days are required, at the ordinary rate of working, for making good marketable bleaching-powder. A more rapid formation would merely endanger an elevation of temperature, productive of muriate of lime, at the expense of the bleaching quality. But skilful manufacturers use here an alternating process. They pile up, first of all, the wooden trays only in alternate shelves in each column. At the end of two days the distillation is intermitted, and the chamber is laid open. After two hours the workman enters, to introduce the alternate trays covered with fresh hydrate of lime, and at the same time rakes up thoroughly the half-formed chloride in the others. The door is then secured, and the chamber, after being filled for two days more with chlorine, is again opened, to allow the first set of trays to be removed, and to be replaced by others, containing fresh hydrate, as before. Thus the process is conducted in regular alternation; thus, to my knowledge, very superior bleaching-powder is manufactured, and thus the chlorine may be suffered to enter in a pretty uniform stream. But for this judicious plan, as the hydrate advances in impregnation, its faculty of absorption becoming diminished, it would be requisite to diminish proportionately the evolution of chlorine, or to allow the excess to escape to the great loss of the proprietor, and, what is of more consequence, to the great detriment of the health of the workmen.

The manufacturer generally reckons on obtaining from one ton of rock-salt, employed as above, a ton and a half of good bleaching-powder. But the following analysis of the operation will show that he ought to obtain two tons.

When a mixture of sulphuric acid, common salt, and black oxide of manganese are the ingredients used, as by the manufacturer of bleaching-powder, the absolute proportions are, upon the oxygen scale of equivalents:—

And the products ought to be:—

These proportions are, however, very different from those employed, by many, nay I believe by all manufacturers; and they ought to be so, on account of the impurity of their oxide of manganese. Yet making allowance for this, I am afraid that many of them commit great errors in the relative quantities of their materials.

From the preceding computation, it is evident that 1 ton of salt with 1 ton of the above native oxide of manganese properly treated, would yield 0·59 of a ton of chlorine, which would impregnate 1·41 tons of slaked lime, producing 2 tons of bleaching-powder, stronger than the average of the commercial specimens; or allowing for a little loss, which is unavoidable, would afford 2 tons of ordinary powder, with a little more slaked lime.

Fig. 287. represents a retort of lead, well adapted to the evolution of chlorine from the mixture of salt, manganese, and sulphuric acid, or from manganese and muriatic acid. The interior vessel is cast in lead, and it has round its bottom part a cast-iron steam case. The salt and manganese are introduced by the aperture C, and the sulphuric acid by the syphon funnel F. The contact of these three substances is continually renewed by the agitator or stirrer B, which consists of wrought or cast iron sheathed with lead. e is the gas discharge pipe. The residuums are drawn off by the bottom discharge pipe G. The heating case receives its steam by the pipe h.

The chlorine gas fig. 288. is conveyed from the retort B into the chamber I, by the tube E E E. This chamber is divided into four compartments, to receive the gas disengaged from four retorts, like the above. The bottom of it is covered with a stratum three or four inches thick of quicklime, newly slaked and sifted, which is stirred about from time to time, by the rakes L L L L. When the saturation is sufficient, the chloride of lime is taken out by the doors K K K K. The size of this apparatus allows 2 cwt. of manganese, and its equivalent quantity of salt and sulphuric acid, or of muriatic acid, to be introduced at once into the retort. D is the handle of the agitator.

The same form of retort will suit perfectly well to prepare chlorine for making liquid chloride of lime, which is preferred by many bleachers and calico-printers who have conveniences for preparing it themselves. The most concentrated solutions of the dry chloride of lime do not mark more than 6° B. (sp. grav. 1·04), and discolour only 50 volumes of Gay Lussac’s solution of indigo, whilst the chloride made in the humid way marks from 8° to 9° B. (about 1·060), and discolours 80 volumes of the same solution.

In the chloride of lime apparatus, most generally used by the skilful calico-printers of Mulhausen, the mixture of muriatic acid and manganese is put into glass globes, with long necks, heated upon a sand-bath. The chlorine is conveyed by glass tubes into a cylindrical stone cistern, containing milk of lime. The furnace of the sand baths is made of cast iron, and has brick partitions, to give each retort its own fire. The smoke of all these fires goes off by a flue into sheet iron pipes. The cistern is made of siliceous sandstone. Its cover is of wood, coated with a resinous cement; and it fits at its edges into grooves cut in the stone. A wheel serves to agitate the liquid continually; its paddles being kept at two inches distance from the sides of the cistern. The milk of lime is introduced by a funnel, and the chloride is drawn off by a discharge pipe. I think the lead retort and agitator used in this country greatly preferable to the experimental laboratory plan described above. In all such apparatus we should avoid giving any pressure to the tubes or vessels, and should not therefore dip the extremities of the gas pipes beneath the surface of the liquid, but rather facilitate the combination of the chlorine and the lime, by enlarging the surfaces of contact and by agitating. Intermediate vessels containing water, or the chemical cascade of M. Clement, are very useful for absorbing any muriatic acid which may be disengaged along with the chlorine, and thereby preventing the needless formation of muriate of lime in the chambers or cisterns of impregnation.

When the solution of the chloride of lime is mixed with hydrate of lime, it bears, without decomposing, a pretty high temperature, provided it be not too long continued; it may even, in certain cases, be raised to near the boiling point without suffering a marked loss of its discolouring power; but when the chloride is deprived of that excess of lime, it is decomposed in a short time, even at a heat of 110° F.

When chlorine is admitted to milk of lime, it infallibly produces some muriate of lime; but the quantity is kept at a minimum by constantly presenting an excess of lime to the gas with the agitator, and by keeping the temperature as low as possible. Hence the influx of gas should not be so rapid as to generate much heat. An automatic agitator, moved by steam or water power, is therefore much better than one driven by the hand of the operator, who is apt to intermit his labours. If the liquor becomes hot at the end of the process, it should be immediately drawn off into large stone bottles, and cooled. The rose-colour, which sometimes supervenes, is due to a minute quantity of manganese. The strongest liquid chloride of lime that can be prepared will not discolour more than 80 times its volume of Gay Lussac’s indigo test.

On acting upon cotton cloth with a concentrated solution of chloride of lime, at from 110° to 120° F., pure carbonic acid gas is disengaged, and the texture of the cloth is injured. Here the hydrogen of the water and the cotton being seized by the chlorine, the liberated oxygen combines with the carbon to form carbonic acid. In the discharge troughs where printed calicoes are passed through strong solutions of chloride of lime, stalactitic crusts of carbonate of lime come to be formed in this way.

The chlorometre of Gay Lussac consists of a test solution of indigo and a graduated tube. One part of the best indigo, passed through a silk sieve, is to be dissolved in nine parts of concentrated sulphuric acid, by the aid of a water-bath heat applied for six hours. The sulphate of indigo is now to be diffused through such a body of water that one volume of chlorine gas shall discolour exactly ten times its volume of this dilute solution. The test liquor should be protected from the agency of light.

Mr. Crum, of Thorniebank, near Glasgow, has lately modified Dr. Dalton’s copperas test for chloride of lime, and made it convenient to the practical man. The Doctor justly considered that the more chlorine any bleaching powder contains, the more of the green sulphate of iron will it convert into the red sulphate, so that we have only to add successive portions of the chloride to a given weight of the dissolved copperas, and note the point at which all the iron gets peroxidized. See Bleaching.

Besides the method of analysis already quoted from my memoir on the manufacture of the chloride of lime, another occurred to me long ago, which I often practised as an easy and expeditious test. Chlorine decomposes ammonia. If therefore water of ammonia, faintly tinged with litmus, be added slowly to a solution of a given weight of chloride of lime, the colour will continue to disappear till the chlorine be all neutralized by the reaction of the hydrogen of the ammonia. The quantity of liquid ammonia of a certain strength requisite to neutralize in this way, a certain volume, say, one cubic inch, or a thousand grain measures of chlorine gas, may be assumed as the standard of such a chlorometer. As chlorine or chloride of lime, when mixed with water of ammonia, causes the disengagement of azote, the quantity of this gas evolved may also be made the foundation of an accurate and convenient chlorometer. The two substances should be mixed over mercury, in a graduated syphon tube. The shut end A and the open end B are both graduated to one scale; for example, to hundredths of a cubic inch, or to grain or 10 grain measures. The tube is to be filled with mercury, and then 10 measures of it are to be displaced at the open end, by inserting a wooden plug. This space, being filled with the solution of chloride of lime, is to be turned up into the shut end by covering the open end with the finger, and inverting the tube; a few drops of water may be sent through to wash the mercury. The ammonia being now let up, will cause a reaction, and evolve a quantity of azote, equivalent to the chlorine present. The action may be quickened by holding the sealed end of the tube obliquely over a lamp heat. The mercury is protected from the chlorine by the ammonia; and should any notion be entertained of such an action, the ammonia may be let up first. I have made innumerable researches over mercury with a detached apparatus of that kind, which combines precision with rapidity of result. It was by a similar mercurial syphon that I analyzed the carbonates, as described in the first edition of my Dictionary of Chemistry, twenty-one years ago.

M. Gay Lussac takes, as the basis of his indigo chlorometer, the fact, that one pound of pure crystallized peroxide of manganese is capable of affording, with muriatic acid, 0·7964 parts of a pound of chlorine; or one kilogramme yields 251¹/₄ litres; that is, one pound yields 251¹/₄ pound measures. Hence 3·98 grammes of that manganese are capable of affording 1000 gramme measures, or 1 litre of chlorine; or, in round numbers, 4 grains will yield 1000 grain measures. This quantity of gas, being received into that volume of milk of lime, constitutes therefore Gay Lussac’s primary standard. The small retort in which the manganese and muriatic acid are put, ought to be heated to ebullition, to discharge every particle of chlorine. To prevent the manganese, in this experiment, from sticking to the bottom in a cake, it has been proposed to mix it previously with a little plumbago. See Chlorometry.

For preparing the chlorides of potash and soda, the same apparatus may be employed as for the liquid chloride of lime. The alkaline solutions should be weak, containing not more than a pound to the gallon of water. Potash liquor saturated with chlorine, is much employed at Paris for whitening linen, under the name of the water of Javelle, the place where it was first made as a manufacture. One hundred parts of chlorine are said to saturate 133 parts of pure potash, and 195 of the carbonate; but the latter should not be used for preparing the bleaching fluid, as the carbonic acid resists the combination of the chlorine. A chloride of carbonate of soda has been lately recommended as a disinfecting substance against contagious miasmata or fomites. One hundred parts of chlorine will saturate 150 of the dry carbonate, and 405 of the crystallized. M. Payen prepares this medicinal chloride by adding 138 parts of carbonate of soda to a liquid, consisting of water 1800, chloride of lime 100, at 98° of strength, by Gay Lussac’s standard. The chloride of lime is to be dissolved, and the sediment well washed; the carbonate of soda, dissolved by heat, is to be poured into the solution, the precipitate allowed to subside, the clear fluid decanted, and the solid matter washed upon a filter. The collected solutions are neutral chloride of soda. Sixty-two parts of the carbonate of soda are then to be dissolved in the remainder of the water, and added to the preparation; the whole being thus filtered, a limpid liquor is obtained, indicating 5° by the hydrometer of BaumÉ.

The chloride of magnesia was long ago proposed by Sir H. Davy for bleaching linen, as being preferable to chloride of lime, because the resulting muriate of magnesia was not injurious to the fibre of cloth, as muriate of lime may be, under certain circumstances. I prepared a quantity of chloride of magnesia, by exposing a hydrate of that earth in the chlorine chamber of a large manufactory of chloride of lime at Glasgow, and obtained a compound possessed of considerable discolouring powers; but I found that the chlorine was so feebly saturated by the base, that it destroyed the colours of fast-dyed calicoes as readily as chlorine gas or chlorine water did, and was therefore dangerous for common bleaching, and destructive in clearing the grounds of printed goods, which is one of the most valuable applications of the calcareous and alkaline chlorides. The occasion of my making these experiments was the importation of a considerable quantity of magnesite, or native atomic carbonate of magnesia, from the district of Madras, by an enterprising friend of mine. Encouraged by the encomiums bestowed on the chloride of magnesia by many chemical writers, he expected to have benefited both the country and himself, by bringing home the earthy base of that compound, at a moderate price; but was disappointed to his cost.

Dr. Thomson is of opinion that the bleaching compound of lime and chlorine is not a chloride of lime, but a combination of chlorous acid with lime and of chlorine with calcium; consisting in its most concentrated state of

So that about one third of the weight is chlorite of lime, to which alone the bleaching powers of the substance are owing. He admits a fact, rather inconsistent with this opinion, that bleaching powder does not attract moisture from the atmosphere with nearly so much rapidity as might be expected from a mixture containing two thirds of its weight of so deliquescent a salt as muriate of lime; unless this indeed be prevented by the chloride and chlorite being united into a double salt, which is a mere conjecture without either proof or analogy. And further, when dilute sulphuric or muriatic acid is poured upon bleaching powder, a profusion of chlorine is given out immediately, which he also admits to be inconsistent with the notion of its being a mixture of chloride of calcium and chlorite of lime, for no such evolution takes place when the above acids are mixed with solutions of chloride of calcium and chlorate of potash. Though I am of opinion that bleaching powder is simply a chloride of lime, in which the lime corresponds to the water in the aqueous chlorine, yet I cannot see the truth or appositeness of his last reason, because chlorine is certainly given out when chlorate of potash is acted upon by dilute muriatic acid, as any man may prove by adding to a mixture of these two substances a vegetable colour; for it will be speedily blanched. Dr. Thomson considers the chloride which is at present made in Mr. Tennant’s great factory, as containing one atom of chlorine associated with one atom of lime, or, taking his numbers, as consisting of

Or nearly equal weights of the chlorine and the base; indicating a surprising degree of excellence in the preparation. The average commercial samples of bleaching powder from different factories which I examined some years ago, did not possess nearly that strength; but varied in their quantity of chlorine from 20 to 28 per cent. In my synthetic experiments related above, the greatest quantity of chlorine that would combine with the atomic hydrate of lime, was in the proportion of 130 to 200; but there is no doubt that if the lime contains additional water, it will condense more gas. I have never seen a chloride of lime of the strength mentioned by Dr. Thomson, and I should think there must be some fallacy in his statements. I have recorded in the paper above quoted an experiment which proves that with additional moisture, a chloride of lime may be obtained of the following composition:—

In the article Bleaching, of the EncyclopÆdia Britannica, Dr. Thomson deduces from a test trial of Mr. Crum, that the best bleaching powder is a compound of 1 atom chlorite of lime = 11, 3 atoms chloride of calcium = 21, and 8 atoms of water = 9. “But,” adds he, “in general the whole lime is not accurately saturated with chlorine. Accordingly, when the bleaching powder is dissolved in water a small residue almost always remains undissolved. Unless the powder be fresh made, a portion of chlorite is always converted into chloride of calcium. It is probable therefore that the best bleaching powder, as it comes into the hands of the bleachers, consists of

“If we consider the bleaching powder as a compound of chlorine and lime, our mode of calculating will not be altered. Instead of 1 atom chlorite of lime, and 3 atoms chloride of calcium, we shall have 4 atoms chloride of lime, 6 atoms water, and 2·25 of impurity as before.” In such ambiguity does this able chemist place this interesting compound, for theoretical reasons, of which I cannot see the value. Surely there is no difficulty in conceiving chlorine to exercise a direct attractive force towards the hydrate of lime, as it is known to do towards each of its elementary constituents, the oxygen and the calcium. Such refinements as the preceding tend merely to mystify a plain matter. Even the chlorous acid here brought into play to form the ideal chlorite, is by his own admission a hypothetical being. “When chlorate of potash” says Dr. Thomson, “is mixed with sulphuric acid, and made into small balls the size of a pea, if we expose these balls to a heat somewhat lower than that of boiling water, a bright yellowish green gas separates, which may be received over mercury. Its smell is peculiar and aromatic. Water absorbs at least seven times its volume of it. It destroys vegetable blues. Its constituents are,

Thus this compound consists in weight of chlorine 4·5, oxygen 4 = 8·5. It has been called quarteroxide of chlorine, but it is more probably a teroxide. It has been supposed by some to possess acid properties, and has therefore been called chlorous acid. But this is only as yet a hypothesis.”

Surely this by the Doctor’s own showing is very slender authority for renouncing our long-received doctrines concerning the constitution of bleaching powder. I shall conclude by remarking that the ultra-atomists are now in a dilemma about this substance; M. Welter, and many French chemists calling it a sub-chloride, of 1 atom of chlorine to 2 atoms of lime, and Dr. Thomson showing that Mr. Tennant, the greatest and best manufacturer of it, has produced it in the state of a chloride, or 1 atom of each. The fact is, in chloride of lime, as in water of ammonia, alcohol, and muriatic acid, there is no sufficient reason for definite proportion in any term short of saturation, and therefore we shall find that chloride in every gradation of strength from 1 per cent. of chlorine up to 40 per cent.—the strongest which I succeeded in preparing, though I passed a constant stream of chlorine in great excess over a pure hydrate of lime for upwards of 24 hours, with frequent renewal of the surface; indeed, till it refused to absorb any more gas, as indicated by its remaining stationary in weight.

CHOCOLATE. Is an alimentary preparation of very ancient use in Mexico, from which country it was introduced into Europe by the Spaniards in the year 1520, and by them long kept a secret from the rest of the world. LinnÆus was so fond of it, that he gave the specific name, theobroma, food of the gods, to the cacao tree which produced it. The cacao-beans lie in a fruit somewhat like a cucumber, about 5 inches long and 3¹/₂ thick, which contains from 20 to 30 beans, arranged in 5 regular rows with partitions between, and which are surrounded with a rose-coloured spongy substance, like that of water-melons. There are fruits, however, so large as to contain from 40 to 50 beans. Those grown in the West India islands, Berbice and Demerara, are much smaller, and have only from 6 to 15; their development being less perfect than in South America. After the maturation of the fruit, when their green colour has changed to a dark yellow, they are plucked, opened, their beans cleared of the marrowy substance, and spread out to dry in the air. Like almonds, they are covered with a thin skin or husk. In the West Indies they are immediately packed up for the market when they are dried; but in the Caraccas they are subjected to a species of slight fermentation, by putting them into tubs or chests, covering them with boards or stones, and turning them over every morning, to equalize the operation. They emit a good deal of moisture, lose the natural bitterness and acrimony of their taste by this process, as well as some of their weight. Instead of wooden tubs, pits or trenches dug in the ground are sometimes had recourse to for curing the beans; an operation called earthing (terrer). They are lastly exposed to the sun, and dried. The latter kind are reckoned the best; being larger, rougher, of a darker brown colour, and, when roasted, throw off their husk readily, and split into several irregular fragments; they have an agreeable mild bitterish taste, without acrimony. The Guiana and West India sorts are smaller, flatter, smoother-skinned, lighter coloured, more sharp and bitter to the taste. They answer best for the extraction of the butter of cacao, but afford a less aromatic and agreeable chocolate. According to Lampadius, the kernels of the West India cacao beans contain, in 100 parts, besides water, 53·1 of fat or oil, 16·7 of an albuminous brown matter, which contains all the aroma of the bean, 10·91 of starch, 7³/₄ of gum or mucilage, 0·9 of lignine, and 2·01 of a reddish dye stuff somewhat akin to the pigment of cochineal. The husks form 12 per cent. of the weight of the beans; they contain no fat, but, besides lignine, or woody fibre, which constitutes half their weight, they yield a light brown mucilaginous extract by boiling in water. The fatty matter is of the consistence of tallow, white, of a mild agreeable taste, called butter of cacao, and not apt to turn rancid by keeping. It melts only at 122° Fahr., and should, therefore, make tolerable candles. It is soluble in boiling alcohol, but precipitates in the cold. It is obtained by exposing the beans to strong pressure in canvass bags, after they have been steamed or soaked in boiling water for some time. From 5 to 6 ounces of butter may be thus obtained from a pound of cacao. It has a reddish tinge when first expressed, but it becomes white by boiling with water.

The beans, being freed from all spoiled and mouldy portions, are to be gently roasted over a fire in an iron cylinder, with holes in its ends for allowing the vapours to escape; the apparatus being similar to a coffee-roaster. When the aroma begins to be well developed, the roasting is known to be finished; and the beans must be turned out, cooled, and freed by fanning and sifting from their husks. The kernels are then to be converted into a paste, either by trituration in a mortar heated to 130° F., or by the following ingenious and powerful machine. The chocolate paste has usually in France a little vanilla incorporated with it, and a considerable quantity of sugar, which varies from one third of its weight to equal parts. For a pound and a half of cacao, one pod of vanilla is sufficient. Chocolate paste improves in its flavour by keeping, and should therefore be made in large quantities at a time. But the roasted beans soon lose their aroma, if exposed to the air.

Fig. 290. represents the chocolate mill. Upon the sole A, made of marble, six conical rollers B B, are made to run by the revolution of the upright axis or shaft q, driven by the agency of the fly wheel E and bevel wheels I K. The sole A rests upon a strong iron plate, which is heated by a small stove, introduced at the door H. The wooden frame work F, forms a ledge, a few inches high, round the marble slab, to confine the cocoa in the act of trituration. C is the hopper of the mill through which the roasted beans are introduced to the action of the rollers, passing first into the flat vessel D to be thence evenly distributed. After the cacao has received the first trituration, the paste is returned upon the slab, in order to be mixed with the proper quantity of sugar, and vanilla, previously sliced and ground up with a little hard sugar. When the chocolate is sufficiently worked, and while it is thin with the heat and trituration, it must be put carefully into the proper moulds. If introduced too warm, it will be apt to become damp and dull on the surface; and, if too cold, it will not take the proper form. It must be previously well kneaded with the hands to ensure the expulsion of every air bubble.

In Barcelona, chocolate mills on this construction are very common, but they are turned by a horse-gin set to work in the under story, corresponding to H in the above figure. The shaft G is, in this case, extended down through the marble slab, and is surrounded at its centre with a hoop to prevent the paste coming into contact with it. Each of these horse-mills turns out about ten pounds of fine chocolate in the hour, from a slab two feet seven inches in diameter.

Chocolate is flavoured with cinnamon and cloves, in several countries, instead of the more expensive vanilla. In roasting the beans the heat should be at first very slow, to give time to the humidity to escape; a quick fire hardens the surface, and injures the process. In putting the paste into the tin plate, or other moulds, it must be well shaken down to insure its filling up all the cavities, and giving the sharp and polished impression so much admired by connoisseurs. Chocolate is sometimes adulterated with starch; in which case it will form a pasty consistenced mass when treated with boiling water. The harder the slab upon which the beans are triturated, the better; and hence porphyry is far preferable to marble. The grinding rollers of the mill should be made of iron, and kept very clean.

CHROMATES, saline compounds of chromic acid with the bases. See Chromium.

CHROMIC ACID; see Chromium.

CHROMIUM. The only ore of this metal, which occurs in sufficient abundance for the purposes of art, is the octohedral chrome-ore, commonly called chromate of iron, though it is rather a compound of the oxides of chromium and iron. The fracture of this mineral is uneven; its lustre imperfect metallic; its colour between iron-black and brownish-black, and its streak brown. Its specific gravity, in the purest state, rises to 4·5; but the usual chrome-ore found in the market varies from 3 to 4. According to Klaproth, this ore consists of oxide of chromium, 43; protoxide of iron, 34·7; alumina, 20·3; and silica, 2; but Vauquelin’s analysis of another specimen gave as above, respectively, 55·5, 33, 6, and 2. It is infusible before the blowpipe; but it acts upon the magnetic needle, after having been exposed to the reducing smoky flame. It is entirely soluble in borax, at a high blowpipe heat, and imparts to it a beautiful green colour.

Chrome-ore is found at the Bare Hills, near Baltimore, in Maryland; in the Shetland isles, Unst and Fetlar; the department of Var, in France, in small quantity; and near Portsoy, in Banffshire; as also in Silesia and Bohemia.

The chief application of this ore is to the production of chromate of potash, from which salt the various other preparations of this metal used in the arts are obtained. The ore, freed, as well as possible, from its gangue, is reduced to a fine powder, by being ground in a mill under ponderous edge-wheels, and sifted. It is then mixed with one third or one half its weight of coarsely bruised nitre, and exposed to a powerful heat, for several hours, on a reverberatory hearth, where it is stirred about occasionally. In the large manufactories of this country, the ignition of the above mixture in pots is laid aside, as too operose and expensive. The calcined matter is raked out, and lixiviated with water. The bright yellow solution is then evaporated briskly, and the chromate of potash falls down in the form of a granular salt, which is lifted out from time to time from the bottom with a large ladle, perforated with small holes, and thrown into a draining-box. This saline powder may be formed into regular crystals of neutral chromate of potash, by solution in water and slow evaporation; or it may be converted into a more beautiful crystalline body, the bichromate of potash, by treating its concentrated solution with nitric, muriatic, sulphuric, or acetic acid, or, indeed, any acid exercising a stronger affinity for the second atom of the potash than the chromic acid does.

Bichromate of potash, by evaporation of the above solution, and slow cooling, may be obtained in the form of square tables, with bevelled edges, or flat four-sided prisms. They are permanent in the air, have a metallic and bitter taste, and dissolve in about one tenth of their weight of water, at 60° F.; but in one half of their weight of boiling water. They consist of chromic acid 13, potash 6; or, in 100 parts, 68·4 + 31·6. This salt is much employed in calico-printing and in dyeing; which see.Chromate of lead, the chrome-yellow of the painter, is a rich pigment of various shades, from deep orange to the palest canary yellow. It is made by adding a limpid solution of the neutral chromate (the above granular salt), to a solution, equally limpid, of acetate or nitrate of lead. A precipitate falls, which must be well washed, and carefully dried out of the reach of any sulphuretted vapours. A lighter shade of yellow is obtained by mixing some solution of alum, or sulphuric acid, with the chromate, before pouring it into the solution of lead; and an orange tint is to be procured by the addition of subacetate of lead, in any desired proportion.

For the production of chromate of potash from chrome ore, various other processes have been recommended. The following formulÆ, which have been verified in practice, will prove useful to the manufacturers of this important article:—

Some manufacturers have contrived to effect the conversion of the oxide into an acid, and of course to form the chromate of potash, by the agency of potash alone, in a calcining furnace, or in earthen pots fired in a pottery kiln.

After lixiviating the calcined mixtures with water, if the solution be a tolerably pure chromate of potash, its value may be inferred, from its specific gravity, by the following table:—

In making the red bichromate of potash from these solutions of the yellow salt, nitric acid was at first chiefly used; but, in consequence of its relatively high price, sulphuric, muriatic or acetic acid has been frequently substituted upon the great scale.

There is another application of chrome which merits some notice here; that of its green oxide to dyeing and painting on porcelain. This oxide may be prepared by decomposing, with heat, the chromate of mercury, a salt made by adding to nitrate of protoxide of mercury, chromate of potash, in equivalent proportions. This chromate has a fine cinnabar red, when pure; and, at a dull red heat, parts with a portion of its oxygen and its mercurial oxide. From M. Dulong’s experiments it would appear, that the purest chromate of mercury is not the best adapted for preparing the oxide of chrome to be used in porcelain painting. He thinks it ought to contain a little oxide of manganese and chromate of potash, to afford a green colour of a fine tint, especially for pieces that are to receive a powerful heat. Pure oxide of chrome preserves its colour well enough in a muffle furnace; but, under a stronger fire, it takes a dead-leaf colour.The green oxide of chrome has come so extensively into use as an enamel colour for porcelain, that a fuller account of the best modes of manufacturing it must prove acceptable to many of my readers.

That oxide, in combination with water, called the hydrate, may be economically prepared by boiling chromate of potash, dissolved in water, with half its weight of flowers of sulphur, till the resulting green precipitate ceases to increase, which may be easily ascertained by filtering a little of the mixture. The addition of some potash accelerates the operation. This consists in combining the sulphur with the oxygen of the chromic acid, so as to form sulphuric acid, which unites with the potash of the chromate into sulphate of potash, while the chrome oxide becomes a hydrate. An extra quantity of potash facilitates the deoxidizement of the chromic acid by the formation of hyposulphite and sulphuret of potash, both of which have a strong attraction for oxygen. For this purpose the clear lixivium of the chromate of potash is sufficiently pure, though it should hold some alumina and silica in solution, as it generally does. The hydrate may be freed from particles of sulphur by heating dilute sulphuric acid upon it, which dissolves it; after which it may be precipitated, in the state of a carbonate, by carbonate of potash, not added in excess.

By calcining a mixture of bichromate of potash and sulphur in a crucible, chromic acid is also decomposed, and a hydrated oxide may be obtained; the sulphur being partly converted into sulphuret of potassium, and partly into sulphuric acid (at the expense of the chromic acid), which combines with the rest of the potash into a sulphate. By careful lixiviation, these two new compounds may be washed away, and the chrome green may be freed from the remaining sulphur, by a slight heat.

Liebig and WÖhler have lately contrived a process for producing a subchromate of lead of a beautiful vermillion hue. Into saltpetre, brought to fusion in a crucible at a gentle heat, pure chrome yellow is to be thrown by small portions at a time. A strong ebullition takes place at each addition, and the mass becomes black, and continues so while it is hot. The chrome yellow is to be added till little of the saltpetre remains undecomposed, care being taken not to overheat the crucible, lest the colour of the mixture should become brown. Having allowed it to settle for a few minutes, during which the dense basic salt falls to the bottom, the fluid part, consisting of chromate of potash and saltpetre, is to be poured off, and it can be employed again in preparing chrome yellow. The mass remaining in the crucible is to be washed with water, and the chrome red being separated from the other matters, is to be dried after proper edulcoration. It is essential for the beauty of the colour, that the saline solution should not stand long over the red powder, because the colour is thus apt to become of a dull orange hue. The fine crystalline powder subsides so quickly to the bottom after every ablution, that the above precaution may be easily observed.

As Chromic Acid will probably ere long become an object of interest to the calico printer, I shall describe here the best method of preparing it. To 100 parts of yellow chromate of potash, add 136 of nitrate of barytes, each in solution. A precipitate of the yellow chromate of barytes falls, which being washed and dried would amount to 130 parts. But while still moist it is to be dissolved in water by the intervention of a little nitric acid, and then decomposed by the addition of the requisite quantity of sulphuric acid, whereby the barytes is separated, and the chromic acid remains associated with the nitric acid, from which it can be freed by evaporation to dryness. On re-dissolving the chromic acid residuum in water, filtering and evaporating to a proper degree, 50 parts of chromic acid may be obtained in crystals.

This acid may also be obtained from chromate of lime, formed by mixing chromate of potash and muriate of lime; washing the insoluble chromate of lime which precipitates, and decomposing it by the equivalent quantity of oxalic acid, or for ordinary purposes even sulphuric acid may be employed.

Chromic acid is obtained in quadrangular crystals, of a deep red colour; it has a very acrid and styptic taste. It reddens powerfully litmus paper. It is deliquescent in the air. When heated to redness, it emits oxygen and passes into the deutoxide. When a little of it is fused along with vitreous borax, the compound assumes an emerald green colour.

As chromic acid parts with its last dose of oxygen very easily, it is capable in certain styles of calico printing of becoming a valuable substitute for chlorine where this more powerful substance would not from peculiar circumstances be admissible. For this ingenious application, the arts are indebted to that truly scientific manufacturer, M. Daniel Koechlin, of Mulhouse. He discovered that whenever chromate of potash has its acid set free by its being mixed with tartaric or oxalic acid, or a neutral vegetable substance, (starch or sugar for example), and a mineral acid, a very lively action is produced, with disengagement of heat, and of several gases. The result of this decomposition is the active reagent, chromic acid, possessing valuable properties to the printer. Watery solutions of chromate of potash and tartaric acid being mixed, an effervescence is produced which has the power of destroying vegetable colours. But this power lasts no longer than the effervescence. The mineral acids react upon the chromate of potash only when vegetable colouring matter, gum, starch, or a vegetable acid are present, to determine the disengagement of gas. During this curious change carbonic acid is evolved; and when it takes place in a retort, there is condensed in the receiver a colourless liquid, slightly acid, exhaling somewhat of the smell of vinegar, and containing a little empyreumatic oil. This liquid heated with the nitrates of mercury or silver reduces these metals. On these principles M. Koechlin discharged indigo blue by passing the cloth through a solution of chromate of potash, and printing nitric acid thickened with gum upon certain spots. It is probable that the employment of chromic acid would supersede the necessity of having recourse in many cases to the more corrosive chlorine.

The following directions have been given for the preparation of a blue oxide of chrome. The concentrated alkaline solution of chromate of potash is to be saturated with weak sulphuric acid, and then to every 8 lbs. is to be added 1 lb. of common salt, and half-a-pound of concentrated sulphuric acid; the liquid will now acquire a green colour. To be certain that the yellow colour is totally destroyed, a small quantity of the liquor is to have potash added to it, and filtered; if the fluid is still yellow, a fresh portion of salt and of sulphuric acid is to be added: the fluid is then to be evaporated to dryness, redissolved, and filtered; the oxide of chrome is finally to be precipitated by caustic potash. It will be of a greenish-blue colour, and being washed, must be collected upon a filter.

Chromate of Potash, adulteration of, to detect. The chromate of potash has the power of combining with other salts up to a certain extent without any very sensible change in its form and appearance; and hence it has been sent into the market falsified by very considerable quantities of sulphate and muriate of potash, the presence of which has often escaped observation, to the great loss of the dyers who use it so extensively. The following test process has been devised by M. Zuber, of Mulhouse. Add a large excess of tartaric acid to the chromate in question, which will decompose it, and produce in a few minutes a deep amethyst colour. The supernatant liquor will, if the chromate be pure, afford now no precipitate with the nitrates of barytes or silver; whence the absence of the sulphates and muriates may be inferred. We must, however, use dilute solutions of the chromate and acid, lest bitartrate of potash be precipitated, which will take place if less than 60 parts of water be employed. Nor must we test the liquid till the decomposition be complete, and till the colour verge rather towards the green than the yellow. Eight parts of tartaric acid should be added to one of chromate to obtain a sure and rapid result. If nitrate of potash (saltpetre) is the adulterating ingredient, it may be detected by throwing it on burning coals, when deflagration will ensue. The green colour is a certain mark of the transformation of the chromic acid partially into the chrome oxide; which is effected equally by the sulphurous acid and sulphuretted hydrogen. Here this metallic acid is disoxygenated by the tartaric, as has been long known. The tests which I should prefer, are the nitrates of silver and baryta, having previously added so much nitric acid to the solution of the suspected chromate, as to prevent the precipitation of the chromate of silver or baryta. The smallest adulteration by sulphates or muriates will thus be detected.

CINNABAR; the native red sulphuret of mercury. It occurs sometimes crystallized in rhomboids; has a specific gravity varying from 6·7 to 8·2; a flat conchoidal fracture; is fine grained; opaque; has an adamantine lustre, and a colour passing from cochineal to ruby red. The fibrous and earthy cinnabar has a scarlet hue. It is met with disseminated in smaller or larger lumps in veins, which are surrounded by a black clay, and is associated with native quicksilver, amalgam with iron-ore, lead-glance, blende, copper-ore, gold, &c. Its principal localities are Almaden in Spain, Idria in the Schiefergebirge, Kremnitz and Schemnitz in Hungary; in Saxony, Bavaria, Bohemia, Nassau, China, Japan, Mexico, Columbia, Peru. It consists of two primes of sulphur, = 32·240, combined with one of mercury, = 202,863; or in 100 parts of 12·7 sulphur + 87·3 mercury. It is the most prolific ore of this metal; and is easily smelted by exposing a mixture of it with iron or lime to a red heat in retorts. Factitious cinnabar is called in commerce Vermillion, which see, as also Mercury.

CINNAMON. (Cannelle, Fr.; Zimmt, Germ.) Is the inner bark of the laurus cinnamomum, a handsome-looking tree, which grows naturally to the height of 18 or 20 feet, in Java, Sumatra, Ceylon, and other islands in the East Indian seas. It has been transplanted to the Antilles, particularly Guadaloupe and Martinique, as well as Cayenne, but there it produces a bark of very inferior value to the Oriental.

Cinnamon is gathered twice a year, but not till after the tree has attained to a certain age and maturity. The young twigs yield a bark of better quality than the larger branches. The first and chief harvest takes place from April to August; the second, from November to January. After having selected the proper trees, all the branches more than three years old are cut off; the epidermis is first removed with a two-edged pruning knife, then a longitudinal incision is made through the whole extent of the bark, and lastly, with the bluntest part of the knife, the true bark is carefully stripped off in one piece. All these pieces of bark are collected, the smaller ones are laid within the larger, and in this state they are exposed to the sun, whereby in the progress of drying, they become rolled into the shape of a quill. These convoluted pieces are formed into oblong bundles of 20 or 30 lbs. weight, which are placed in warehouses, sorted and covered with mats. Good cinnamon should be as thin as paper, have its peculiar aromatic taste, without burning the tongue, and leave a sweetish flavour in the mouth. The broken bits of cinnamon are used in Ceylon for procuring the essential oil by distillation. 445,367 lbs. of cinnamon were imported into this kingdom in 1835, of which 16,604 only were retained for internal consumption.

CITRIC ACID. (Acide citrique, Fr.; CitronensÄure, Germ.) Scheele first procured this acid in its pure state from lemon juice, by the following process. The juice put into a large tub, is to be saturated with dry chalk in fine powder, noting carefully the quantity employed. The citrate of lime which precipitates being freed from the supernatant foul liquor, is to be well washed with repeated affusion and decantation of water. For every 10 pounds of chalk employed, nine and a half pounds of sulphuric acid, diluted with six times its weight of water, are to be poured while warm upon the citrate of lime, and well mixed with it. At the end of twelve hours, or even sooner, the citrate will be all decomposed, dilute citric acid will float above, and sulphate of lime will be found at the bottom. The acid being drawn off, the calcareous sulphate must be thrown on a canvass filter, drained, and then washed with water to abstract the whole acid.

The citric acid thus obtained may be evaporated in leaden pans, over a naked fire till it acquires the specific gravity 1·13; after which it must be transferred into another vessel, evaporated by a steam or water bath till it assumes a syrupy aspect, when a pellicle appears first in patches, and then over the whole surface. This point must be watched with great circumspection, for if it be passed, the whole acid runs a risk of being spoiled by carbonization. The steam or hot water must be instantly withdrawn, and the concentrated acid put into a crystallizing vessel in a dry, but not very cold apartment. At the end of four days, the crystallization will be complete. The crystals must be drained, re-dissolved in a small portion of water, the solution set aside to settle its impurities, then decanted, re-evaporated, and re-crystallized. A third or fourth crystallization may be necessary to obtain a colourless acid.

If any citrate of lime be left undecomposed by the sulphuric acid, it will dissolve in the citric acid, and obstruct its crystallization, and hence it will be safer to use the slightest excess of sulphuric acid, than to leave any citrate undecomposed. There should not however be any great excess of sulphuric acid. If there be, it is easily detected by nitrate of barytes, but not by the acetate of lead as prescribed by some chemical authors; because the citrate of lead is not very soluble in the nitric acid, and might thus be confounded with the sulphate, whereas citrate of barytes is perfectly soluble in that test acid. Sometimes a little nitric acid is added with advantage to the solution of the coloured crystals, with the effect of whitening them.

Twenty gallons of good lemon juice will afford fully ten pounds of white crystals of citric acid.

Attempts were made both in the West Indies and Sicily, to convert the lime and lemon juice into citrate of lime, but they seem to have failed through the difficulty of drying the citrate for shipment.

The crystals of citric acid are oblique prisms with four faces, terminated by dihedral summits, inclined at acute angles. Their specific gravity is 1·617. They are unalterable in the air. When heated, they melt in their water of crystallization; and at a higher heat, they are decomposed. They contain 18 per cent. of water, of which one half may be separated in a dry atmosphere, at about 100° F., when the crystals fall into a white powder.

Citric acid in crystals is composed by my analysis of carbon, 35·8, oxygen 59·7, and hydrogen 45; results which differ very little from those of Dr. Prout, subsequently obtained. I found its atomic weight to be 8·375, compared to oxygen 1,000. I cannot account for Berzelius’s statements relative to the composition of this acid.

Citric acid in somewhat crude crystals is employed with much advantage in calico-printing. If adulterated with tartaric acid, the fraud may be detected by adding potash to the solution of the acid, which will occasion a precipitate of cream of tartar.

CIVET. (Civette, Fr.; Zibeth, Germ.) This substance approaches in smell to musk and ambergris; it has a pale yellow colour, a somewhat acrid taste, a consistence like that of honey, and a very strong aromatic odour. It is the product of two small quadrupeds of the genus viverra (v. zibetha and v. civetta), of which the one inhabits Africa, the other Asia. They are reared with tenderness, especially in Abyssinia. The civet is contained in a sac, situated between the anus and the parts of generation, in either sex. The animal frees itself from an excess of this secretion by a contractile movement which it exercises upon the sac, when the civet issues in a vermicular form, and is carefully collected. The negroes are accustomed to increase the secretion by irritating the animal; and likewise introduce a little butter, or other grease, by the natural slit in the bag, which mixes with the odoriferous substance, and increases its weight. It is employed only in perfumery.

According to M. Boutron-Chalard, it contains a volatile oil, to which it owes its smell, some free ammonia, resin, fat, an extractiform matter, and mucus. It affords, by calcination, an ash, in which there are some carbonate and sulphate of potash, phosphate of lime, and oxide of iron.

CLAY (Argile, Fr.; Thon, Germ.) is a mixture of the two simple earths, alumina and silica, generally tinged with iron. Lime, magnesia, with some other colouring metallic oxides, are occasionally present in small quantities in certain natural clays.

The different varieties of clay possess the following common characters:—

1. They are readily diffusible through water, and are capable of forming with it a plastic ductile mass, which may be kneaded by hand into any shape. This plasticity exists, however, in very different degrees in the different clays.

2. They concrete into a hard mass upon being dried, and assume, upon exposure to the heat of ignition, a degree of hardness sometimes so great as to give sparks by collision with hardened steel. In this state they are no longer plastic with water, even when pulverised. Tolerably pure clays, though infusible in the furnace, become readily so by the admixture of lime, iron, manganese, &c.

3. All clays, even when previously freed from moisture, shrink in the fire in virtue of the reciprocal affinity of their particles; they are very absorbent of water in their dry state, and adhere strongly to the tongue.

4. Ochrey, impure clays emit a disagreeable earthy smell when breathed upon.

Brongniart distributes the clays into:—

1. Fire-clays, (argiles apyres, Fr.; feuerfeste, Germ.)

2. Fusible, (schmelzbare, Germ.)

3. Effervescing (brausende, Germ.), from the presence of chalk.

4. Ochrey (ocreuses, Fr.; ockrige, Germ.)

Fire-clay is found in the greatest abundance and perfection for manufacturing purposes in,

1. Slate-clay. (Thon-schiefer, Germ.) Its colour is gray or grayish-yellow. Massive, dull, or glimmering from admixture of particles of mica. Fracture slaty, approaching sometimes to earthy. Fragments tabular. Soft, sectile, and easily broken. Sp. gr. = 2·6. Adheres to the tongue, and breaks down in water. It occurs along with pit coal; which see. Slate-clay is ground, and reduced into a paste with water, for making fire-bricks; for which purpose it should be as free as possible from lime and iron.

2. Common clay or loam.—This is an impure coarse pottery clay, mixed with iron ochre, and occasionally with mica. It has many of the external characters of plastic clay. It is soft to the touch, and forms, with water, a somewhat tenacious paste; but is in general less compact, more friable, than the plastic clays, which are more readily diffusible in water. It does not possess the property of acquiring in water that commencement of translucency which the purer clays exhibit. Although soft to the touch, the common clay wants unctuosity, properly so called. The best example of this argillaceous substance is afforded in the London clay formation, which consists chiefly of bluish or blackish clay, mostly very tough. Those of its strata which effervesce with acids partake of the nature of marl. This clay is fusible at a strong heat, in consequence of the iron and lime which it contains. It is employed in the manufacture of bricks, tiles, and coarse pottery ware.

3. Potter’s clay, or Plastic clay.—This species is compact, soft, or even unctuous to the touch, and polishes with the pressure of the finger; it forms, with water, a tenacious, very ductile, and somewhat translucent paste. It is infusible in a porcelain kiln, but assumes in it a great degree of hardness. Werner calls it pipe-clay. Good plastic clay remains white, or if gray before, becomes white in the porcelain kiln.

The geological position of the plastic clay is beneath the London clay, and above the sand which covers the chalk formation. The plastic clay of the Paris basin is described as consisting of two beds separated by a bed of sand. The lower bed is the proper plastic clay. The plastic clay of Abondant, near the forest of Dreux, analysed by Vauquelin, gave—

Silica, 43·5; alumina, 33·2; lime, 0·35; iron, 1; water, 18.

This clay is employed as a fire clay for making the bungs or seggars, or coarse earthenware cases, in which china ware is fired.

The plastic clay of Dorsetshire and Devonshire supplies the great Staffordshire potteries. It is gray coloured, less unctuous than that of Dreux, and consequently more friable. It becomes white in the pottery kiln, and is infusible at that heat. It causes no effervescence with nitric acid, but falls down quickly in it, and becomes higher coloured. Its refractoriness allows of a harder glaze being applied to the ware formed from it without risk of the heat requisite for making the glaze flow, affecting the biscuit either in shape or colour. “Most of the plastic clays of France,” says M. Brongniart, “employed for the same ware, have the disadvantage of reddening a little in a somewhat strong heat; and hence it becomes necessary to coat them with a soft glaze, fusible by means of excess of lead at a low heat, in order to preserve the white appearance of the biscuit. Such a glaze has a dull aspect, and cracks readily into innumerable fissures by alternations of hot and cold water.” Hence one reason of the vast inferiority of the French stone-ware to the English.

4. Porcelain clay or Kaolin earth.—The Kaolins possess very characteristic properties. They are friable in the hand, meagre to the touch, and difficultly form a paste with water. When freed from the coarse and evidently foreign particles interspersed through them, they are absolutely infusible in the porcelain kiln, and retain their white colour unaltered. They harden with heat like other clays, and perhaps in a greater degree; but they do not acquire an equal condensation or solidity, at least when they are perfectly pure. The Kaolins in general appear to consist of alumina and silica in nearly equal proportions. Most of the Kaolin clays contain some spangles of mica which betray their origin from disintegrated granite.

This origin may be regarded as one of their most distinctive features. Almost all the porcelain clays are evidently derived from the decomposition of the felspars, granites, and principally those rocks of felspar and quartz, called graphic granite. Hence, they are to be found only in primitive mountain districts, among banks or blocks of granite, forming thin seams or partings between them. In the same partings, quartz and mica occur, being relics of the granite; while some seams of Kaolin retain the external form of felspar.

The most valuable Kaolins have been found:—

In China and Japan. The specimens imported from these countries appear pretty white; but are more unctuous to the touch, and more micaceous than the porcelain clays of France.

In Saxony. The Kaolin employed in the porcelain manufactories of that country has a slight yellow or flesh colour, which disappears in the kiln, proving as Wallerius observed, that this tint is not owing to any metallic matter.

In France, at Saint-Yriex-la-Perche, about 10 leagues from Limoges. The Kaolin occurs there in a bed, or perhaps a vein of beds of granite, or rather of that felspar rock called Pe-tun-tse, which exists here in every stage of decomposition. This Kaolin is generally white, but sometimes a little yellowish with hardly any mica. It is meagre to the touch, and some beds include large grains of quartz, called pebbly by the China manufacturers. This variety, when ground, affords, without the addition of any fusible ingredient, a very transparent porcelain.

Near Bayonne. A Kaolin possessing the lamellated structure of felspar, in many places. The rock containing it is a graphic granite in every stage of decomposition.

In England, in the county of Cornwall. This Kaolin or China clay is very white, and more unctuous to the touch than those upon the continent of Europe mentioned above. Like them it results from the decomposition of the felspars and granites, occurring in the middle of these rocks. Mr. Wedgewood found it to contain 60 of alumina or pure clay, and 40 of silica, in 100 parts.

Pure clay, the alumina of the chemist, is absolutely infusible; but when subjected to the fire of a porcelain kiln, it contracts into about one half of its total bulk. It must, however, be heated very cautiously, otherwise it will decrepitate and fly in pieces, owing to the sudden expansion into steam of the water combined with its particles, which is retained with a considerable attractive force. It possesses little plasticity, and consequently affords a very short paste, which is apt to crack when kneaded into a cake.

It is not only infusible by itself, but it will not dissolve in the fusible glasses; making them merely opaque. If either lime or silica be added separately to pure clay, in any proportion, the mixture will not melt in the most violent furnace; but if alumina, lime, and silica be mixed together, the whole melts, and the more readily, the nearer the mixture approaches to the following proportions:—1 of alumina, 1 of lime, and 3 of sand. If the sand be increased to five parts, the compound becomes infusible. These interesting facts show the reciprocal action of those earths which are mixed most commonly in nature with alumina.

Iron in small quantity, but in a state not precisely determined, though probably of protoxide, does not colour the clays till they are subjected to a powerful heat. There are very white clays, such as those of Montereau, which do not become red till calcined in the porcelain kiln; the oxide of iron contained in them, which colours them in that case, was previously imperceptible. It appears from this circumstance, that the clays fit for making fine white stone ware, as also the Kaolins adapted to the manufacture of porcelain, are very rare.

Iron, in larger proportion, usually colours the clays green or slate-blue, before they have been heated. Such clays, exposed to the action of fire, become yellow or red according to the quantity of iron which they contain. When the iron is very abundant, it renders the clays fusible; but a little lime and silica must also be present for this effect. The earthenware made with these ferruginous clays, can bear but a moderate baking heat; it is thick, porous, and possesses the advantage merely of cheapness, and of bearing considerable alternations of temperature without breaking.

Alumina and the very aluminous natural clays which possess most plasticity, are apt to crack in drying, or to lose their shape. This very serious defect for the purposes of pottery is rectified, in some measure, by adding to that earth a certain quantity of sand or silica. Thus, a compound is formed which possesses less attraction for water, and dries more equably from the openness of its body. The principal causes of the distortion of earthenware vessels, are the unequal thickness of their parts, and quicker desiccation upon one side than another. Hard burnt stone-ware ground to powder, and incorporated with clay, answers still better than sand for counteracting the great and irregular contraction which natural pottery paste is apt to experience. Such ground biscuit is called cement; and its grains interspersed through the ware, may be regarded as so many solutions of continuity, which arrest the fissures.

The preceding observations point out the principles of those arts which employ clay for moulding by the wheel, and baking in a kiln. See Porcelain and Pottery.

CLOTH-BINDING. Nothing places in so striking a point of view the superior taste, judgment, and resources of London tradesmen over those of the rest of the world, than the extensive substitution which they have recently made of embossed silks and calicoes for leather in the binding of books. In old libraries, cloth-covered boards indeed may occasionally be seen, but they have the meanest aspect, and are no more to be compared with our modern cloth-binding, than the jupon of a trull, with the ballet dress of Taglioni. The silk or calico may be dyed of any shade which use or fancy may require, impressed with gold or silver foil in every form, and variegated by ornaments in relief, copied from the most beautiful productions in nature. This new style of binding is distinguished not more for its durability, elegance, and variety, than for the economy and dispatch with which it ushers the offspring of intellect into the world. For example, should a house eminent in this line, such as that of Westleys, Friar-street, Doctors’-commons, receive 5000 volumes from Messrs. Longman & Co. upon Monday morning, they can have them all ready for publication, within the incredibly short period of two days; being far sooner than they could have rudely boarded them upon the former plan. The reduction of price is not the least advantage incident to the new method, amounting to fully 50 per cent. upon that with leather.

The dyed cloth being cut by a pattern to the size suited to the volume, is passed rapidly through a roller press, between engraved cylinders of hard steel, whereby it receives at once the impress characteristic of the back, and the sides, along with embossed designs over the surface in sharp relief. The cover thus rapidly fashioned, is as rapidly applied by paste to the stitched and pressed volume; no time being lost in mutual adjustments; since the steel rollers turn off the former, of a shape precisely adapted to the latter. Hard glazed and varnished calico is moreover much less an object of depredation to moths, and other insects, than ordinary leather has been found to be.

COBALT. This metal being difficult to reduce from its ores, is therefore very little known, and has not hitherto been employed in its simple state in any of the arts; but its oxide has been extensively used on account of the rich blue colour which it imparts to glass, and the glaze of porcelain and stone-ware. The principal ores of cobalt are those designated by mineralogists under the names of arsenical cobalt and gray cobalt. The first contains, in addition to cobalt, some arsenic, iron, nickel, and occasionally silver, &c. The other is a compound of cobalt with iron, arsenic, sulphur, and nickel. Among the gray cobalts, the ore most esteemed for its purity is that of Tunaberg in Sweden. It is often in regular crystals which possess the lustre and colour of polished steel. The specific gravity of cobalt pyrites is 6·36 to 4·66. The Tunaberg variety afforded to Klaproth, cobalt, 44; arsenic, 55·5; sulphur, 0·5: so that it is an arseniuret. Others, however, contain much sulphur as well as iron. It imparts at the blowpipe a blue colour to borax and other fluxes, and gives out arsenical fumes.

The ore being picked to separate its concomitant stony matters, is pounded fine and passed through a sieve; and is also occasionally washed. The powder is then spread on the sole of a reverberatory furnace, the flue of which leads into a long horizontal chimney. Here it is exposed to calcination for several hours, to expel the sulphur and arsenic that may be present; the former burning away in sulphurous acid gas, the latter being condensed into the white oxide or arsenious acid, whence chiefly the market is supplied with this article. This calcining process can never disengage the whole of these volatile ingredients, and there is therefore a point beyond which it is useless to push it; but the small quantities that remain are not injurious to the subsequent operations. The roasted ore is sifted anew; reduced to a very fine powder, and then mixed with 2 or 3 parts of very pure siliceous sand, to be converted into what is called zaffre. With this product glasses are generally coloured blue, as well as enamels and pottery glaze. In the works where cobalt ores are treated, a blue glass is prepared with the zaffre, which is well known under the name of smalt or azure blue. This azure is made by adding to the zaffre 2 or 3 parts of potash, according to its richness in cobalt, and melting the mixture in earthen crucibles. The fused mass is thrown out while hot into water; and is afterwards triturated and levigated in mills mounted for the purpose. There remains at the bottom of the earthen pot a metallic lump, which contains a little cobalt, much nickel, arsenic, iron, &c. This is called speiss.

As it is the oxide of cobalt which has the colouring quality, the calcination serves the purpose of oxidizement, as well as of expelling the foreign matters.

A finer cobalt-oxide is procured for painting upon hard porcelain, by boiling the cobalt ore in nitric acid, which converts the arsenic into an acid, and combines it with the different metals present in the mineral. These arseniates being unequally soluble in nitric acid, may be separated in succession by a cautious addition of carbonate of soda or potash; and the arseniate of cobalt as the most soluble remains unaffected. It has a rose colour; and is easily distinguishable, whence the precipitation may be stopped at the proper point. The above solution should be much diluted, and the alkali should be cautiously added with frequent agitation.

The cobalt ores, rich in nickel, are exposed to slow oxidizement in the air, whereby the iron, cobalt, arsenic, and sulphur get oxygenated by the atmospheric moisture, but the nickel continues in the metallic state. This action of the weather must not be extended beyond a year, otherwise the nickel becomes affected, and injures the cobalt blue. The ore hereby increases in weight, from 8 to 10 per cent. Fig. 291. is a longitudinal section of the furnace: fig. 292., a horizontal section upon a level with the sole of the hearth. It is constructed for wood fuel, and the hearth is composed of fire-bricks or tiles. The vapours and gases disengaged in the roasting, pass off through the flues a a, into the channels b b, and thence by c into the common vent, or poison chamber. See the representation of the poison tower of Altenberg, under the article Arsenic. The flues are cleared out by means of openings left at suitable situations in the brick-work of the chimneys.

The azure manufacture is carried on chiefly in winter, in order that the external cold may favour the more complete condensation of the acids of arsenic. From 3 to 5 cwt. of Schlich (pasty ore), are roasted at one operation, and its bed is laid from 5 to 6 inches thick. After two hours, it must be turned over; and the stirring must be repeated every half hour, till no more arsenic is observed to exhale. The process being then finished, the ore must be raked out of the furnace, and another charge introduced.

The duration of the roasting is regulated partly by the proportion of sulphur and arsenic present, and partly by the amount of nickel; which must not be suffered to become oxidized, lest it should spoil the colour of the smalt. The latter ores should be but slightly roasted, so as to convert the nickel into speiss. The roasted ore must be sifted in a safety apparatus. The loss of weight in the roasting amounts, upon the average, to 36 per cent. The roasted ore has a brownish gray hue, and is called safflor in German, and is distributed into different sorts. F F S is the finest safre; F S, fine; O S, ordinary; and M S, middling. These varieties proceed from various mixtures of the calcined ores. The roasted ore is ground up along with sand, elatriated, and, when dry, is called zaffre. It is then mixed with a sufficient quantity of potash for converting the mixture into a glass.

Figs. 293. and 294. represent a round smalt furnace, in two vertical sections, at right angles to each other. The fire-place is vaulted or arched; the flame orifice a, is in the middle of the furnace; b is the feed hole; c, a tunnel which serves as an ash-pit, and to supply air; d, openings through which the air arrives at the fuel, the wood being placed upon the vault; e, knee holes for taking out the scoriÆ from the pot bottoms; f, working orifices, with cast-iron plates g, in front of them. Under these are the additional outlets h. The smoke and flame pass off through the orifices i, which terminate in expanded flues, where the sand may be calcined or the wood may be baked. Eight hours are sufficient for one vitrifying operation, during which the glass is stirred about several times in the earthen melting pots.

The preparation of the different shades of blue glass are considered as secrets in the smelting works; and marked with the following letters:—F F F C, the finest; F C, fine; M C, middling; O C, ordinary. A melting furnace, containing 8 pots of glass; produces in 24 hours, from 24 cwts. of the mixture, 19 cwts. of blue glass; and from ¹/₂ to ³/₄ cwt. of scoriÆ or speiss (speise). The composition speise, according to Berthier, is,—nickel, 49·0; arsenic, 37·8; sulphur, 7·8; copper, 1·6; cobalt, 3·2 in 100. Nickel, arsenic, and sulphur, are its essential constituents; the rest are accidental, and often absent. The freer the cobalt ore is from foreign metals, the finer is the colour, and the deeper is the shade; paler tints are easily obtained by dilution with more glass. The presence of nickel gives a violet tone.

The production of smalt in the Prussian states amounted, in 1830, to 7452¹/₂ cwts.; and, in Saxony, to 9697 cwts.; in 1825, to 12,310 cwts.

One process for making fine smalt has been given under the title Azure; I shall introduce another somewhat different here.

The ore of cobalt is to be reduced to very fine powder, and then roasted with much care. One part, by weight, is next to be introduced, in successive small portions, into an iron vessel, in which three parts of acid sulphate of potassa has been previously fused, at a moderate temperature. The mixture, at first fluid, soon becomes thick and firm, when the fire is to be increased, until the mass is in perfect fusion, and all white vapours have ceased. It is then to be taken out of the crucible with an iron ladle, the crucible is to be recharged with acid sulphate of potash, and the operation continued as before, until the vessel is useless. The fused mass contains sulphate of cobalt, neutral sulphate of potassa, and arseniate of iron, with a little cobalt. It is to be pulverized, and boiled in an iron vessel, with water, as long as the powder continues rough to the touch. The white, or yellowish white residue, may be allowed to separate from the solution, either by deposition or filtration. Carbonate of potassa, free from silica, is then to be added to the solution, and the carbonate of cobalt thrown down is to be separated and well washed, if possible, with warm water; the same water may be used to wash other portions of the fused mass. The filtered liquid which first passes, is a saturated solution of sulphate of potassa: being evaporated to dryness in an iron vessel, it may be reconverted into acid sulphate by fusing it with one half its weight of sulphuric acid: this salt is then as useful as at first.

The oxide of cobalt thus obtained, contains no nickel; so little oxide of iron is present, that infusion of galls does not show its presence; it may contain a little copper, if that metal exists in the ore, but it is easily separated by the known methods. Sometimes sulphuretted hydrogen will produce a yellow brown precipitate in the solution of the fused mass; this, however, contains no arsenic, but is either sulphuret of antimony or bismuth, or a mixture of both.

It has been found advantageous to add to the fused mass, sulphate of iron, calcined to redness, and one tenth of nitre when the residue is arseniate of iron, and contains no arseniate of cobalt. There is then no occasion to act upon the residue a second time for the cobalt in it.

This process is founded on the circumstances that the sulphate of cobalt is not decomposed by a red heat, and that the arseniates of iron and cobalt are insoluble in all neutral liquids. It is quite evident that to obtain a perfect result, the excess of acid in the bisulphate of potassa must be completely driven off by the red heat applied.

110,646 lbs. of smalts were imported into the United Kingdom in 1835, and 96,949 were retained for home consumption. In 1834, only 16,223 lbs. were retained.

In 1835, 322,562 lbs. of zaffres were imported, and 336,824 are stated to have been retained, which is obviously an error. 284,000 lbs. were retained in 1834.

COCCULUS INDICUS, or Indian berry, is the fruit of the Menispermum Cocculus, a large tree, which grows upon the coasts of Malabar, Ceylon, &c. The fruit is blackish, and of the size of a large pea. It owes its narcotic and poisonous qualities to the vegeto-alkaline chemical principle called picrotoxia, of which it contains about one-fiftieth part of its weight. It is sometimes thrown into waters to intoxicate or kill fishes; and it is said to have been employed to increase the inebriating qualities of ale or beer. Its use for this purpose is prohibited by act of parliament, under a penalty of 200l. upon the brewer, and 500l. upon the seller of the drug.

COCHINEAL was taken in Europe at first for a seed, but was proved by the observations of Lewenhoeck to be an insect, being the female of that species of shield-louse, or coccus, discovered in Mexico, so long ago as 1518. It is brought to us from Mexico, where the animal lives upon the cactus opuntia or nopal. Two sorts of cochineal are gathered—the wild, from the woods, called by the Spanish name grana silvestra; and the cultivated, or the grana fina, termed also mesteque, from the name of a Mexican province. The first is smaller, and covered with a cottony down, which increases its bulk with a matter useless in dyeing; it yields, therefore, in equal weight, much less colour, and is of inferior price to that of the fine cochineal. But these disadvantages are compensated in some measure to the growers by its being reared more easily, and less expensively; partly by the effect of its down, which enables it better to resist rains and storms.

The wild cochineal, when it is bred upon the field nopal, loses in part the tenacity and quantity of its cotton, and acquires a size double of what it has on the wild opuntias. It may therefore be hoped, that it will be improved by persevering care in the rearing of it, when it will approach more and more to fine cochineal.

The fine cochineal, when well dried and well preserved, should have a gray colour, bordering on purple. The gray is owing to the powder, which naturally covers it, and of which a little adheres; as also to a waxy fat. The purple shade arises from the colour extracted by the water in which they were killed. It is wrinkled with parallel furrows across its back, which are intersected in the middle by a longitudinal one; hence, when viewed by a magnifier, or even a sharp naked eye, especially after being swollen by soaking for a little in water, it is easily distinguished from the factitious, smooth, glistening, black grains, of no value, called East India cochineal, with which it is often shamefully adulterated by certain London merchants. The genuine cochineal has the shape of an egg, bisected through its long axis, or of a tortoise, being rounded like a shield upon the back, flat upon the belly, and without wings.

These female insects are gathered off the leaves of the nopal plant, after it has ripened its fruit, a few only being left for brood, and are killed, either by a momentary immersion in boiling water, by drying upon heated plates, or in ovens: the last become of an ash-gray colour, constituting the silver cochineal, or jaspeada; the second are blackish, called negra, and are most esteemed, being probably driest; the first are reddish brown, and reckoned inferior to the other two. The dry cochineal being sifted, the dust, with the imperfect insects and fragments which pass through, are sold under the name of granillo.

Cochineal keeps for a long time in a dry place. Hellot says that he has tried some 130 years old, which produced the same effect as new cochineal.

We are indebted to MM. Pelletier and Caventou for a chemical investigation of cochineal, in which its colouring matter was skilfully eliminated.

Purified sulphuric ether acquired by digestion with it a golden yellow colour, amounting by Dr. John to one tenth of the weight of the insect. This infusion left, on evaporation, a fatty wax of the same colour.

Cochineal, exhausted by ether, was treated with alcohol at 40° B. After 30 infusions in the digester of M. Chevreul, the cochineal continued to retain colour, although the alcohol had ceased to have any effect on it. The first alcoholic liquors were of a red verging on yellow. On cooling, they let fall a granular matter. By spontaneous evaporation, this matter, of a fine red colour, separated, assuming more of the crystalline appearance. These species of crystals dissolved entirely in water, which they tinged of a yellowish-red.

This matter has a very brilliant purple-red colour; it adheres strongly to the sides of the vessels; it has a granular and somewhat crystalline aspect, very different, however, from those compound crystals alluded to above; it is not altered by the air, nor does it sensibly attract moisture. Exposed to the action of heat, it melts at about the fiftieth degree centigrade (122° Fahr.). At a higher temperature it swells up, and is decomposed with the production of carburetted hydrogen, much oil, and a small quantity of water, very slightly acidulous. No trace of ammonia was found in these products.

The colouring principle of cochineal is very soluble in water. By evaporation, the liquid assumes the appearance of syrup, but never yields crystals. It requires of this matter a portion almost imponderable to give a perceptible tinge of bright purplish red to a large body of water. Alcohol dissolves this colouring substance, but, as we have already stated, the more highly it is rectified the less of it does it dissolve. Sulphuric ether does not dissolve the colouring principle of cochineal; but weak acids do, possibly owing to their water of dilution. No acid precipitates it in its pure state. This colouring principle, however, appears to be precipitable by all the acids, when it is accompanied by the animal matter of the cochineal.

The affinity of alumina for the colouring matter is very remarkable. When that earth, newly precipitated, is put into a watery solution of the colouring principle, this is immediately seized by the alumina. The water becomes colourless, and a fine red lake is obtained, if we operate at the temperature of the atmosphere; but if the liquor has been hot, the colour passes to crimson, and the shade becomes more and more violet, according to the elevation of the temperature, and the continuance of the ebullition.

The salts of tin exercise upon the colouring matter of cochineal a remarkable action. The muriatic protoxide of tin forms a very abundant violet precipitate in the liquid. This precipitate verges on crimson, if the salt contains an excess of acid. The muriatic deutoxide of tin produces no precipitate, but changes the colour to scarlet-red. If gelatinous alumina be now added, we obtain a fine red precipitate, which does not pass to crimson by boiling.

To this colouring principle the name carminium has been given, because it forms the basis of the pigment called carmine.

The process followed in Germany for making carmine, which consists in pouring a certain quantity of solution of alum into a decoction of cochineal, is the most simple of all, and affords an explanation of the formation of carmine, which is merely the carminium and the animal matter precipitated by the excess of acid in the salt, which has taken down with it a small quantity of alumina; though it appears that alumina ought not to be regarded as essential to the formation of carmine. In fact, by another process, called by the name of Madame Cenette of Amsterdam, the carmine is thrown down, by pouring into the decoction of cochineal a certain quantity of the binoxalate of potash. When carbonate of soda is added, then carminated lake also falls down. That carmine is a triple compound of animal matter, carminium, and an acid appears from the circumstance, that liquors which have afforded their carmine, when a somewhat strong acid is poured into them, yield a new formation of carmine by the precipitation of the last portions of the animal matter. But whenever the whole animal matter is thrown down, the decoctions, although still much charged with the colouring principle, can afford no more carmine. Such decoctions may be usefully employed to make carminated lakes, saturating the acid with a slight excess of alkali, and adding gelatinous alumina. The precipitates obtained, on adding acids to the alkaline decoctions of cochineal, are therefore true carmines, since they do not contain alumina; but the small quantity of alumina which is thrown down by alum in the manufacture of carmine, augments its bulk and weight. It gives, besides, a greater lustre to the colour, even though diluting and weakening it a little.

The carmines found in the shops of Paris were analysed, and yielded the same products. They are decomposed by the action of heat, with the diffusion at first of a very strong smell of burning animal matter, and then of sulphur. A white powder remained, amounting to about one-tenth of the matter employed, and which was found to be alumina. Other quantities of carmine were treated with a solution of caustic potash, which completely dissolved them, with the exception of a beautiful red powder, not acted on by potash and concentrated acids, and which was recognized to be red sulphuret of mercury or vermillion. This matter, evidently foreign to the carmine, appears to have been added, in order to increase its weight.

The preceding observations and experiments seem calculated to throw some light on the art of dyeing scarlet and crimson. The former is effected by employing a cochineal bath, to which there have been added, in determinate proportions, acidulous tartrate of potash, and nitro-muriatic deutoxide of tin. The effect of these two salts is now well known. The former, in consequence of its excess of acid, tends to redden the colour, and to precipitate it along with the animal matter: the latter acts in the same manner, at first by its excess of acid, then by the oxide of tin which falls down also with the carmine and animal matter, and is fixed on the wool, with which it has of itself a strong tendency to combine. MM. Pelletier and Caventou remark, that “to obtain a beautiful shade, the muriate of tin ought to be entirely at the maximum of oxidizement; and it is in reality in this state that it must exist in the solution of tin prepared according to the proportions prescribed in M. Berthollet’s treatise on dyeing.”

We hence see why, in dyeing scarlet, the employment of alum is carefully avoided, as this salt tends to convert the shade to a crimson. The presence of an alkali would seem less to be feared. The alkali would occasion, no doubt, a crimson-coloured bath; but it would be easy in this case to restore the colour, by using a large quantity of tartar. We should, therefore, procure the advantage of having a bath better charged with colouring matter and animal substance. It is for experience on the large scale to determine this point. As to the earthy salts, they must be carefully avoided; and if the waters be selenitish, it would be a reason for adding a little alkali.

To obtain crimson, it is sufficient, as we know, to add alum to the cochineal bath, or to boil the scarlet cloth in alum water. It is also proper to diminish the dose of the salt of tin, since it is found to counteract the action of the alum.

The alkalies ought to be rejected as a means of changing scarlet to crimson. In fact, crimsons by this process cannot be permanent colours, as they pass into reds by the action of acids.

According to M. Von Grotthuss, carmine may be deprived of its golden shade by ammonia, and subsequent treatment with acetic acid and alcohol. Since this fact was made known, M. Herschel, colour maker at Halle, has prepared a most beautiful carmine.

The officers of Her Majesty’s Customs have lately detected a system of adulterating cochineal, which has been practised for many years upon a prodigious scale by a mercantile house in London. I have analyzed about 100 samples of such cochineal, from which it appears that the genuine article is moistened with gum-water, agitated in a box or leather bag, first, with sulphate of baryta in fine powder, afterwards with bone or ivory black, to give it the appearance of negra cochineal, and then dried. By this means about 12 per cent. of the worthless heavy spar is sold at the price of cochineal, to the enrichment of the sophisticators, and the disgrace and injury of British trade and manufactures.

The specific gravity of genuine cochineal is 1·25; that of the cochineal loaded with the barytic sulphate 1·35. It was taken in oil of turpentine and reduced to water as unity, because the waxy fat of the insects prevents the intimate contact of the latter liquid with them, and the ready expulsion of air from their wrinkled surface. They are not at all acted upon by the oil, but are rapidly altered by water, especially when they have been gummed and barytified.

The quantities of cochineal imported into the United Kingdom in the following years, were:—

The quantities re-exported were:—

Humboldt states that so long ago as the year 1736, there was imported into Europe from South America cochineal to the value of 15 millions of francs. Its high price had for a long time induced dyers to look out for cheaper substitutes in dyeing red, and since science has introduced so many improvements in tinctorial processes, both madder and lac have been made to supersede cochineal to a very great extent. Its price has, in consequence of this substitution, as well as from more successful modes of cultivation, fallen very greatly of late years. At present it is only 7s. per lib. in London. See Scarlet Dyeing.

COCOA, STEARINE, AND ELAINE. Mr. Soames obtained a patent in September 1829, for making these useful articles, by the following process:

He takes the substance called cocoa-nut oil, in the state of lard, in which it is imported into this country, and submits it to a strong hydraulic pressure, having made it up in small packages, 3 or 4 inches wide, 2 feet long, and 1 or 1¹/₂ inches thick. These packages are formed by first wrapping up the said substance in a strong linen cloth, of close texture, and then in an outward wrapper of strong sail cloth. The packages are to be placed side by side, in single rows, between the plates of the press, allowing a small space between the packages for the escape of the elaine.

The temperature at which the pressure is begun, should be from about 50 to 55 degrees, or in summer as nearly at this pitch as can be obtained, and the packages of the said substance intended for pressure, should be exposed for several hours previously to about the same temperature. When the packages will no longer yield their oil or elaine freely at this temperature, it is to be gradually raised; but it must at no time exceed 65 degrees, and the lower the temperature at which the separation can be effected, the better will be the quality of the oil expressed.

When the packages are sufficiently pressed, that is, when they will give out no more oil, or yield it only in drops at long intervals, the residuum in them is to be taken out and cleansed and purified, which is done by melting it in a well-tinned copper vessel, which is fixed in an outer vessel, having a vacant space between, closed at the top, into which steam is admitted, and the heat is kept up moderately for a sufficient time to allow the impurities to subside; but if a still higher degree of purity is required, it is necessary to pass it through filters of thick flannel lined with blotting paper.

Having been thus cleansed or purified, it is fit for the manufacture of candles, which are made by the ordinary process used in making mould tallow candles. Having thus disposed of the stearine, or what is called the first product, he proceeds with the elaine or oil expressed from it, and which he calls the second product, as follows: that is to say, he purifies it by an admixture, according to the degree of its apparent foulness, of from 1 to 2 per cent. by weight of the sulphuric acid of commerce, of about 1·80 specific gravity, diluted with six times its weight of water. The whole is then to be violently agitated by mechanical means, and he prefers for this purpose the use of a vessel constructed on the principle of a common barrel churn. When sufficiently agitated, it will have a dirty whitish appearance, and is then to be drawn off into another vessel, in which it is to be allowed to settle, and any scum that rises is to be carefully taken off. In a day or two the impurities will be deposited at the bottom of the oil, which will then become clear, or nearly so, and it is to be filtered through a thick woollen cloth, after which it will be fit for burning in ordinary lamps and for other uses.

The process of separating the elaine from the stearine, by pressure, in manner aforesaid, had never before been applied to the substance called cocoa-nut oil, and consequently no product had heretofore been obtained thereby from that substance, fit for being manufactured into candles in the ordinary way, or for being refined by any of the usual modes, so as to burn in ordinary lamps, both which objects are obtained by this method of preparing or manufacturing the said substance.

Candles well made from the above material are a very superior article. The light produced is more brilliant than from the same sized candle made of tallow; the flame is perfectly colourless, and the wick remains free from cinder, or any degree of foulness during combustion.

COFFEE. The coffee is the seed of a tree of the family rubiaceÆ, and belongs to the Pentandria monogynia of LinnÆus. There are several species of the genus, but the only one cultivated is the CoffÆa Arabica, a native of Upper Ethiopia and Arabia Felix. It rises to the height of 15 or 20 feet; its trunk sends forth opposite branches in pairs above and at right angles to each other; the leaves resemble those of the common laurel, although not so dry and thick. From the angle of the leaf-stalks small groups of white flowers issue, which are like those of the Spanish jasmine. These flowers fade very soon, and are replaced by a kind of fruit not unlike a cherry, which contains a yellow glairy fluid, enveloping two small seeds or berries convex upon one side, flat and furrowed upon the other in the direction of the long axis. These seeds are of a horny or cartilaginous nature; they are glued together, each being surrounded with a peculiar coriaceous membrane. They constitute the coffee of commerce.

It was not till towards the end of the 15th century that the coffee tree began to be cultivated in Arabia. Historians usually ascribe the discovery of the use of coffee as a beverage to the superior of a monastery there, who, desirous of preventing the monks from sleeping at their nocturnal services, made them drink the infusion of coffee upon the report of shepherds, who pretended that their flocks were more lively after browsing on the fruit of that plant. The use of coffee was soon rapidly spread, but it encountered much opposition on the part of the Turkish government, and became the occasion of public assemblies. Under the reign of Amurath III. the mufti procured a law to shut all the coffee-houses, and this act of suppression was renewed under the minority of Mahomet IV. It was not till 1554 under Solyman the Great that the drinking of coffee was accredited in Constantinople; and a century elapsed before it was known in London and Paris. Solyman Aga introduced its use into the latter city in 1669, and in 1672 an Armenian established the first cafÉ at the fair of Saint Germain.

When coffee became somewhat of a necessary of life from the influence of habit among the people, all the European powers who had colonies between the tropics, projected to form plantations of coffee trees in them. The Dutch were the first who transported the coffee plant from Moka to Batavia, and from Batavia to Amsterdam. In 1714 the magistrates of that city sent a root to Louis XIV. which he caused to be planted in the Jardin du Roi. This became the parent stock of all the French coffee plantations in Martinique.

The most extensive culture of coffee is still in Arabia Felix, and principally in the kingdom of Yemen, towards the cantons of Aden and Moka. Although these countries are very hot in the plains, they possess mountains where the air is mild. The coffee is generally grown halfway up on their slopes. When cultivated on the lower grounds it is always surrounded by large trees which shelter it from the torrid sun, and prevent its fruit from withering before their maturity. The harvest is gathered at three periods, the most considerable occurs in May, when the reapers begin by spreading cloths under the trees, then shaking the branches strongly, so as to make the fruit drop, which they collect, and expose upon mats to dry. They then pass over the dried berries a very heavy roller, to break the envelopes, which are afterwards winnowed away with a fan. The interior bean is again dried before being laid up in store.

In Demerara, Berbice, and some of our West India islands, where much good coffee is now raised, a different mode of treating the pulpy fruit and curing the beans is adopted. When the cherry-looking berry has assumed a deep-red colour it is gathered, and immediately subjected to the operations of a mill composed of two wooden rollers, furnished with iron plates, which revolve near a third fixed roller called the chops. The berries are fed into a hopper above the rollers, and falling down between them and the chops, they are stripped of their outer skins and pulp, while the twin beans are separated from each other. These beans then fall upon a sieve, which allows the skin and the pulp to pass through, while the hard beans accumulate and are progressively slid over the edge into baskets. They are next steeped for a night in water, thoroughly washed in the morning, and afterwards dried in the sun. They are now ready for the peeling mill, a wooden edge wheel turned vertically by a horse yoked to the extremity of its horizontal axis. In travelling over the coffee, it bursts and detaches the coriaceous or parchment-like skin which surrounds each hemispherical bean. It is then freed from the membranes by a winnowing machine, in which four pieces of tin made fast to an axle are caused to revolve with great velocity. Corn fanners would answer better than this rude instrument of negro invention. The coffee is finally spread upon mats or tables, picked clean, and packed up for shipment.

The most highly esteemed coffee is that of Moka. It has a smaller and a rounder bean; a more agreeable taste and smell than any other. Its colour is yellow. Next to it in European reputation is the Martinique and Bourbon coffees; the former is larger than the Arabian and more oblong; it is rounded at the ends; its colour is greenish, and it preserves almost always a silver gray pellicle, which comes off in the roasting. The Bourbon coffee approaches nearest to the Moka from which it originally sprung. The Saint Domingo coffee has its two extremities pointed, and is much less esteemed than the preceding.

The coffee tree flourishes in hilly districts where its root can be kept dry, while its leaves are refreshed with frequent showers. Rocky ground, with rich decomposed mould in the fissures, agrees best with it. Though it would grow, as we have said, to the height of 15 or 20 feet, yet it is usually kept down by pruning to that of five feet for increasing the production of the fruit, as well as for the convenience of cropping. It begins to yield fruit the third year, but is not in full bearing till the fifth, does not thrive beyond the twenty-fifth, and is useless in general at the thirtieth. In the coffee husbandry, the plants should be placed eight feet apart, as the trees throw out extensive horizontal branches, and in holes ten or twelve feet deep to secure a constant supply of moisture.

Coffee has been analysed by a great many chemists, with considerable diversity of results. The best analysis perhaps is that of Schrader. He found that the raw beans distilled with water in a retort communicated to it their flavour and rendered it turbid, whence they seem to contain some volatile oil. On reboiling the beans, filtering, and evaporating the liquor to a syrup, adding a little alcohol till no more matter was precipitated, and then evaporating to dryness, he obtained 17·58 per cent. of a yellowish-brown transparent extract, which constitutes the characteristic part of coffee, though it is not in that state the pure proximate principle, called cafeine. Its most remarkable reaction is its producing, with both the protoxide and the peroxide salts of iron, a fine grass green colour, while a dark green precipitate falls, which re-dissolves when an acid is poured into the liquor. It produces on the solution of the salts of copper scarcely any effect, till an alkali be added, when a very beautiful green colour is produced which may be employed in painting. Coffee beans contain also a resin, and a fatty substance somewhat like suet. According to Robiquet, ether extracts from coffee beans nearly 10 per cent. of resin and fat, but he probably exaggerates the amount. The peculiar substance cafeine contained in the above extract is crystallizable. It is remarkable in regard to composition, that after urea and the uric acid, it is among organic products the richest in azote. It was discovered and described in 1820 by Runge. It does not possess alkaline properties. Pfaff obtained only 90 grains of cafeine from six pounds of coffee beans. There is also an acid in raw coffee to which the name of cafeic acid has been given. When distilled to dryness and decomposed, it has the smell of roasted coffee.

Coffee undergoes important changes in the process of roasting. When it is roasted to a yellowish brown it loses, according to Cadet, 12¹/₂ per cent. of its weight, and is in this state difficult to grind. When roasted to a chestnut brown it loses 18 per cent., and when it becomes entirely black, though not at all carbonised, it has lost 23 per cent. Schrader has analyzed roasted coffee comparatively with raw coffee, and he found in the first 12¹/₂ per cent. of an extract of coffee, soluble in water and alcohol, which possesses nearly the properties of the extract of the raw coffee, although it has a deeper brown colour, and softens more readily in the air. He found also 10·4 of a blackish brown gum; 5·7 of an oxygenated extract or rather apothÈme soluble in alcohol, insoluble in water; 2 of a fatty substance and resin; 69 of burnt vegetable fibre, insoluble. On distilling roasted coffee with water, Schrader obtained a product which contained the aromatic principle of coffee; it reddened litmus paper, and exhaled a strong and agreeable odour of roasted coffee. If we roast coffee in a retort, the first portions of the aromatic principle of coffee condense into a yellow liquid in the receiver; and these may be added to the coffee roasted in the common way, from which this matter has been expelled and dissipated in the air.

Chenevix affirmed that by the roasting of coffee a certain quantity of tannin possessing the property of precipitating gelatine is generated. Cadet made the same observation, and found, moreover, that the tannin was most abundant in the lightly roasted coffee, and that there was nearly none of it in coffee highly roasted. PayssÉ and Schrader, on the contrary, state that solution of gelatine does not precipitate either the decoction of roasted coffee or the alcoholic extract of this coffee. Runge likewise asserts that he could obtain no precipitate with gelatine; but he says that albumen precipitates from the decoction of roasted coffee the same kind of tannin as is precipitated from raw coffee by the acetate of lead, and set free from the lead by sulphuretted hydrogen. With these results my own experiments agree. Gelatine certainly does not disturb clear infusion of roasted coffee, but the salts of iron blacken it.

Schrader endeavoured to roast separately the different principles of coffee, but none of them exhaled the aromatic odour of roasted coffee except the horny fibrous matter. He therefore concludes that this substance contributes mainly to the characteristic taste of roasted coffee, which cannot be imitated by any other vegetable matter, and which, as we have seen, should be ascribed chiefly to the altered cafeic acid. According to Garot we may extract the cafeine without alteration from roasted coffee by precipitating its decoction by subacetate of lead, treating the washed precipitate with sulphuretted hydrogen, and evaporating the liquid product to dryness.

Of late years, much ingenuity has been expended in contriving various forms of apparatus for making infusions of coffee for the table. I have tried most of them, and find, after all, none so good as a cafetiÈre À la Belloy, the coffee biggin, with the perforated tin plate strainer, especially when the filtered liquor is kept simmering in a close vessel, set over a lamp or steam pan. The useful and agreeable matter in coffee is very soluble: it comes off with the first waters of infusion, and needs no boiling.

To roast coffee rightly we should keep in view the proper objects of this process, which are to develop its aroma, and destroy its toughness, so that it may be readily ground to powder. Too much heat destroys those principles which we should wish to preserve, and substitutes new ones which have nothing in common with the first, but add a disagreeable empyreumatic taste and smell. If, on the other hand, the rawness or greenness is not removed by an adequate heat, it masks the flavour of the bean, and injures the beverage made with it. When well roasted in the sheet iron cylinders set to revolve over a fire, it should have a uniform chocolate colour, a point readily hit by experienced roasters, who now manage the business very well for the principal coffee dealers both of London and Paris, so far as my judgment can determine. The development of the proper aroma is a criterion by which coffee roasters frequently regulate their operations. When it loses more than 20 per cent. of its weight, coffee is sure to be injured. It should never be ground till immediately before infusion.

COKE, is carbonized pitcoal. See Charcoal; and Pitcoal at the end.

COLCOTHAR OF VITRIOL, (Rouge d’Angleterre, Fr.; Rothes Eisenoxyd, Germ.) is the brown-red peroxide of iron, produced by calcining sulphate of iron with a strong heat, levigating the resulting mass, and elutriating it into an impalpable powder. A better way of making it so as to complete the separation of the acid, is to mix 100 parts of the green sulphate of iron with 42 of common salt, to calcine the mixture, wash away the resulting sulphate of soda, and levigate the residuum. The sulphuric acid in this case expels the chlorine of the salt in the form of muriatic acid gas, and saturates its alkaline base produced by the chemical reaction; whence an oxide will be obtained free from acid, much superior to what is commonly found in the shops. The best sort of polishing powder called jewellers’ red rouge or plate powder is the precipitated oxide of iron prepared by adding solution of soda to solution of copperas, washing, drying, and calcining the powder in shallow vessels with a gentle heat, till it assumes a deep brown red colour. See Iron.

COLOURING MATTER. (MatiÈre colorante, Fr.; Farbstoff, Germ.) See Dyeing, the several dye-stuffs and pigments.

COLUMBIUM, a peculiar metal extracted from a rare mineral brought from Haddam in Connecticut. It is also called Tantalium from the mineral tantalite and yttrotantalite, found in Sweden. It has hitherto no application to the arts. It combines with two successive doses of oxygen; by the second it becomes an acid.

COLZA, is a variety of cabbage, the brassica oleracea, whose seeds afford, by pressure, an oil much employed in France and Belgium for burning in lamps, and for many other purposes. This plant requires a rich but light soil; it does not succeed upon either sandy or clayey lands. The ground for it must be deeply ploughed and well dunged. It should be sown in July, and be afterwards replanted in a richly manured field. In October it is to be planted out in beds, 15 or 18 inches apart. Colza may also be sowed in furrows 8 or 10 inches asunder.

Land which has been just cropped for wheat is that usually destined to colza; it may be fresh dunged with advantage. The harvest takes place in July, with the sickle, a little before the seeds are completely ripe, lest they should drop off. As the seed is productive of oil, however, only in proportion to its ripeness, the cut plants are allowed to complete their maturation, by laying them in heaps under airy sheds, or placing them in a stack, and thatching it with straw.

The cabbage stalks are thrashed with flails, the seeds are winnowed, sifted, spread out in the air to dry; then packed away in sacks, in order to be subjected to the oil mill at the beginning of winter. The oil-cake is a very agreeable food to cattle, and serves to fatten them. It is reckoned to defray the cost of the mill.

Colza impoverishes the soil very much, as do, indeed, all the plants cultivated for the sake of their oleaginous seeds. It must not, therefore, be come back upon again for six years, if fine crops be desired. The double ploughing which it requires, effectually cleans the ground. See Oils, Unctuous.

COMB, the name of an instrument made of a thin plate either plane or curved of wood, horn, tortoise-shell, ivory, bone, or metal, cut out upon one or both of its sides or edges, into a series of somewhat long teeth, not far apart; which is employed for disentangling, laying parallel and smooth the hairs of man, horses, or other animals.

A thin steel saw bow, mounted in an iron or wooden handle, is the implement used by the comb-maker to cut the bone, ivory, and wood into slices of from a twelfth to a quarter of an inch thick, and of a size suitable to that of the comb. The pieces of tortoise-shell as found in commerce are never flat, or, indeed, of any regular curvature, such as the comb must have. They are therefore steeped in boiling water sufficiently long to soften them, and set to cool in a press between iron or brass moulds, which impart to them the desired form which they preserve after cooling. After receiving their outline shape, and curvature, by proper flat files or fine rasps, the place of the teeth is marked with a triangular file, and then the teeth themselves are cut out with a double saw, composed of two thin slips of tempered steel, such as the main-spring of a watch, notched with very fine sharp teeth. These slips are mounted in a wooden or iron stock or handle, in which they may be placed at different distances to suit the width of the comb teeth. A comb-maker, however, well provided in tools, has an assortment of double saws set at every ordinary width. The two slips of this saw have their teeth in different planes, so that when it begins to cut, the most prominent slip alone acts, and when the teeth of this one have fairly entered into the comb, the other parallel blade begins to saw. The workman, meanwhile, has fixed the plate of tortoise-shell or ivory between the flat jaws of two pieces of wood, like a vice made fast to a bench, so that the comb intended to be cut is placed at an angle of 45° with the horizon. He now saws perpendicularly, forming two teeth at a time, proceeding truly in the direction of the first tracing.

A much better mode of making combs is to fix upon a shaft or arbour in a lathe a series of circular saws, with intervening brass washers or discs to keep them at suitable distances; to set in a frame like a vice, in front of these saws, the piece of ivory or horn to be cut; and to press it forward upon the saws at an angle of 45 degrees, by means of a regulated screw motion. When the teeth are thus cut, they are smoothed and polished with files, and by rubbing with pumice stone and tripoli.

Mr. Bundy, of Camden Town, obtained a patent so long ago as 1796, for an apparatus of that kind, which had an additional arbour fitted with a series of circular saws, or rather files, for sharpening the points of the comb teeth.

More recently, Mr. Lyne has invented a machine in which, by means of pressure, two combs are cut out at once with chisels from any tough material, such as horn or tortoise-shell, somewhat softened at the moment by the application of a heated iron to it. The piece of horn is made fast to a carriage, which is moved forwards by means of a screw until it comes under the action of a ratchet-wheel, toothed upon a part of its circumference. The teeth of this wheel bring a lever into action, furnished with a chisel or knife, which cuts out a double comb from the flat piece, the teeth of which combs are opposite to each other. By this means no part of the substance is lost, as in sawing out combs. The same carriage may be used, also, to bear a piece of ivory in the hard state towards a circular saw, on the principles above explained, with such precision, that from 80 to 100 teeth can be formed in the space of one inch by a proper disposition of the tool.

Bullocks’ horns, after the tips are sawed off, are roasted in the flame of a wood fire, till they are sufficiently softened; when they are slit up, pressed in a machine between two iron plates, and then plunged into a trough of cold water, whereby they are hardened. A paste of quicklime, litharge, and water is used to stain the horn to resemble tortoise-shell. See Horn.

COMBINATION (Combinaison, Fr.; Verbindung, Germ.); a chemical term which denotes the intimate union of dissimilar particles of matter, into a homogeneous looking compound, possessed of properties generally different from those of the separate constituents.

COMBUSTIBLE (Eng. and Fr.; Brennstoff, Germ.); any substance which exposed in the air to a certain temperature, consumes spontaneously with the emission of heat and light. All such combustibles as are cheap enough for common use go under the name of Fuel; which see. Every combustible requires a peculiar pitch of temperature to be kindled, called its accendible point. Thus phosphorus, sulphur, hydrogen, carburetted hydrogen, carbon, each takes fire at successively higher heats.

COMBUSTION (Eng. and Fr.; Verbrennung, Germ.) results in common cases from the mutual chemical reaction of the combustible, and the oxygen of the atmosphere, whereby a new compound is formed; the heat and light evolved being most probably produced by the rapid motions of the particles during the progress of this combination.

COMPOUND COLOURS. If the effects of the colouring particles did not vary according to the combinations which they form, and the actions exercised upon them by the different substances present in a dyeing bath, we might determine with precision the shade which ought to result from the mixture of any two colours, or of the ingredients affording these colours separately. Though the chemical action of the mordants, and of the liquor in the dye-bath often changes the results, yet theory may always predict them within a certain degree. It is not the colour appropriate to the dye-stuffs which is to be considered as the constituent part of compound colours, but that which they must assume with a certain mordant and dye-bath. Our attention ought therefore to be directed principally to the operation of the chemical agents employed.

1. The mixture of blue and yellow dyes produces green. D’Ambourney, indeed, says that he has extracted a fast green from the fermented juice of the berries of the buckthorn (rhamnus frangula), but no dyer would trust to such a colour.

2. The mixture of red and blue produces violet, purple, columbine (dove-colour), pansy, amaranth, lilac, mallow, and a great many other shades, determined by the nature and tone of the red and blue dye-stuffs, as well as their relative proportions in the bath.

3. The mixture of red and yellow produces orange, mordorÉ, cinnamon, coquelicot, brick, capuchin; with the addition of blue, olives of various shades; and with duns instead of yellows, chestnut, snuff, musk, and other tints.

4. Blacks of the lighter kinds constitute grays; and, mixed with other colours, produce marrone (marroons), coffees, damascenes. For further details upon this subject, see Calico Printing, Dyeing, as also the individual colours in their alphabetical places.

CONCRETE. The name given by architects to a compact mass of pebbles, sand and lime cemented together, in order to form the foundations of buildings. Semple says that the best proportions are 80 parts of pebbles, each about 7 or 8 ounces in weight, 40 parts sharp river sand, and 10 of good lime; the last is to be mixed with water to a thinnish consistence, and grouted in. It has been found that Thames ballast, as taken from the bed of the river, consists nearly of 2 parts of pebbles to 1 of sand, and therefore answers exceedingly well for making concrete; with from one-seventh to one-eighth part of lime. The best mode of making concrete, according to Mr. Godwin, is to mix the lime, previously ground, with the ballast in a dry state; sufficient water is now thrown over it to effect a perfect mixture, after which it should be turned over at least twice with shovels, or oftener; then put into barrows, and wheeled away for use instantly. It is generally found advisable to employ two sets of men to perform this operation, with three in each set; one man to fetch the water, &c., while the other two turn over the mixture to the second set, and they, repeating the process, turn over the concrete to the barrow-men. After being put into the barrows, it should at once be wheeled up planks, so raised as to give it a fall of some yards, and thrown into the foundation, by which means the particles are driven closer together, and greater solidity is given to the whole mass. Soon after being thrown in, the mixture is observed usually to be in commotion, and much heat is evolved with a copious emission of vapour. The barrow-load of concrete in the fall spreading over the ground, will form generally a stratum of from 7 to 9 inches thick, which should be allowed to set before throwing in a second.

Another method of making concrete, is first to cover the foundation with a certain quantity of water, and then to throw in the dry mixture of ballast and lime. It is next turned and levelled with shovels; after which more water is pumped in, and the operation is repeated. The former method is undoubtedly preferable.

In some cases it has been found necessary to mix the ingredients in a pug-mill, as in mixing clay, &c. for bricks. For the preparation of a concrete foundation, as the hardening should be rapid, no more water should be used than is absolutely necessary to effect a perfect mixture of the ingredients. Hot water accelerates the induration. There is about one-fifth of contraction in volume in the concrete, in reference to the bulk of its ingredients. To form a cubical yard of concrete, about 30 feet cube of ballast and 3¹/₂ feet cube of ground lime must be employed, with a sufficient quantity of water.

CONGELATION (Eng. and Fr.; Gefrierung, Germ.); the act of freezing liquids. Many means are supplied by chemistry of effecting or promoting this process, but they do not constitute any peculiar art or manufacture. See Ice-House.

COOLING OF FLUIDS. In Mr. Derosnes’s method, the cooling agents employed are a current of atmospheric air, and warm water of the same or nearly the same temperature as that of the vapours which are to be operated upon.

Fig. 295. represents merely a diagram of the general features of an apparatus constructed upon the principles proposed to be employed, which will serve to explain the nature of this improvement.

Let A be the source of the vapours, or the vessel, boiler, alembic, or closed pan that contains the liquid or syrup to be evaporated or concentrated. The pipe B, through which the vapour passes as it rises in the boiler, is surrounded by another tube C, of larger diameter, closed at both ends. A pump D, draws from the reservoir E, warm water, which water has been heated by its previous and continual passage through the apparatus in contact with the surface of the vapour pipes. This pump forces the water by the pipe F, into the annular space or chamber between the pipes B and C, in which chamber, by its immediate contact with the pipe B, it acquires the temperature of the vapours intended to be refrigerated. The pipe G conveys the water from the pipe C, into the annular colander or sieve H, which has a multitude of small holes pierced through its under part, and from whence the warm water descends in the form of a continued shower of rain. To the end of the pipe B, a distiller’s worm I I, is connected, which is placed beneath the colander H. The entire length of the worm-pipe should be bound round with linen or cotton cloth, as a conductor of the heat, which cloth will be continually moistened by the rain in its descent from the colander. As this water has been heated in passing along the tube C, the shower of rain descending from the colander will be at a higher temperature than that of the atmosphere, and, consequently, by heating the surrounding air as it descends, a considerable upward draft will be produced through the coils of the worm-pipe.

If the colander and the worm-pipe are enclosed within a chimney or upright tube, as K K, open at top and bottom, a current of ascending air will be produced within it by the descending shower of hot water, similar in effect to that which would be produced in a chimney communicating with a furnace, or to that of the burner of an argand lamp. Consequently, it will be perceived that in opposition to the descending rain, a strong upward current of air will blow through that part of the cylinder K K, which is beneath the colander. When the air first enters the lower aperture of the chimney or tube K, it is of the same temperature and moisture as the external atmosphere; but in its passage up the tube it meets with a warmer and damper atmosphere, caused by the heat given out from the hot fluid continually passing through the pipes, and by the hot shower of rain, and also by the steam evolved from the surfaces of the coils of the worm, which are continually wetted by the descending rain, the evaporation being considerably augmented by the cloth bound round the worm-pipe, retaining the water as it descends in drops from coil to coil.

The atmosphere within the tube being of a higher temperature than without, a current of air constantly ascends and escapes at the upper aperture K, and its place is supplied by fresh air from the surrounding atmosphere, entering the tube below. The fresh air thus admitted at the bottom of the tube being cold and dry, will be suited to take up the heat and moisture within, because the water within the tube being in a state of dispersion as rain, presents to the air many points, or a very extended surface, and also because it is of a higher temperature than the air; and, besides, cold dry air is continually renewed, and a source of warmth is furnished by the latent caloric to the steam, as fast as it is evolved. Thus a portion of the descending rain, or water, is evaporated, and the effect of this evaporation is to subtract caloric not only from the water held in contact with the coils of the worm-pipe by the cloth enveloping it, but also from the hot vapours which pass through the worm. This process of evaporation has, therefore, a cooling power, which is but slight in the lower part of the chimney or tube K; because the temperature of the water, or rain, and of the worm, at this part, are of a lower temperature; but its refrigerating power increases as it rises towards the colander, and there it acquires its maximum of intensity, so that at any point between the lower aperture of the cylinder and the colander, the current of air is always a little cooler than the atmosphere of the region through which it passes (that is, at its maximum); and in passing this region of higher temperature, it is not only put in equilibrium of temperature, but also made to take up an additional quantity of aqueous vapours, which equalises the new temperature it acquires with its capacity of saturation. The cooling caused by the evaporation acts in an incessant and progressive manner from the lower aperture of the cylinder to the under side of the colander; and this cooling not only acts as an agent of the evaporation which the current of air cools, but it refrigerates also, because it becomes warmed in abstracting caloric from the vapours or liquids passing through the worm; and this refrigeration acts also incessantly and progressively from the lower part of the tube or chimney to the colander.

The patentee states, in conclusion, that “the velocity or force of the current of air that passes through the chimney or tube K, can be accelerated by artificial means, either by conducting the air and vapour passing from the upper aperture of the cylinder into the chimney or flues of a furnace, or by means of a revolving, forcing, or exhausting fan, or ventilator, or any other contrivance which will produce an increased current of air, but which it is not necessary to be particularly described, as I only wish to explain the principles of a simple apparatus, constructed in any convenient form; and I would remark, that the area of the lower aperture through which the air is introduced into the chimney or tube K, and also the area of the upper aperture, or that through which it passes to the atmosphere, should be in accordance with the effect intended to be obtained.

“It is further to be remarked, that in order to obtain from this apparatus the best effect, the velocity of the current of air must be itself a maximum; and as the speed or velocity of the current of air is owing to and determined by the excess of the temperature of the descending water, or rain, and of the coils of the worm to that of the exterior atmosphere, it ensues that the temperature of the water, or rain, must be a maximum. But this excess of temperature is a maximum only when the source of the rain is at the same temperature as the vapours to be condensed: if less warm, it would attract less air; or, if warmer, it would augment the temperature of the vapours intended to be condensed. Consequently, the shower of water employed in the tube K, as the agent for cooling, bestows its maximum of effect when it is as warm as the vapours to be condensed; therefore, I may express this proposition, viz., ‘That in refrigerating with water, less of it may be expended when it is warm than when it is cold, and that the least quantity of water will be evaporated when it is as warm as the aqueous or spirituous vapours upon which it is to operate.’

“This proposition may appear strange, nevertheless it is conformable to the laws of nature; and appears only strange, because until now warm water has not been employed with currents of air for refrigerating.

“Hence it is necessary to raise the temperature of the water in the colander to the temperature of the vapours to be condensed: therefore, I cause the lukewarm water, pumped from the reservoir E, to circulate in the chamber C. In this circulation it also begins to act as a refrigerating medium, taking up a portion of heat from the vapours that pass through the pipe B, and afterwards it acts as a further condenser in the cylinder, in the way described. Finally, the portion of this water that is still in the fluid state, after having fallen down from coil to coil, arrives lukewarm to the inclined surface L, which conducts it into the reservoir E, from whence it is pumped up into the chamber C, as before described.

“The tube or chimney K, may have more or less altitude; the higher it is the greater is the current produced. The force or velocity of the current of air can be governed by the areas of the introduction and exit apertures. If the cylinder rises only to the height of the sieve, the effect is much less than when it is prolonged beyond this height. I would further remark, that if the cylinder was removed, a slight effect might be produced, provided that a current of air be preserved in the cylindrical space limited by the coils of the worm, and also if the current was produced between the coils; or a central passage might be formed in an apparatus of another shape than that above described.

“I have only shown the application of the worm, because intending only to explain the principles of this method of condensing and refrigerating.

“The small quantity of water wasted in this manner of condensation, (that is, that portion passed off to the atmosphere in the form of vapours, at the upper aperture of the cylinder K,) may be replaced by a small stream of cold water, which may be brought to the apparatus, and perhaps most conveniently introduced into the reservoir E, or into the chamber between the pipes B and C. When operating upon aqueous vapours, the waste of water is always less in weight than that of the vapours liquefied. When this apparatus is applied to the purposes of distillation, the end of the worm should terminate in a vessel M, which is to receive the produce of the condensation. It will be seen that this improved process is applicable to various purposes, where condensation or refrigeration is required; for instance, in the boiling or concentration of sugar; to condensing and refrigerating distilled vapours, or steam, or saline liquids, either in vacuum or not; to cooling brewers’ worts; and to the refrigeration of other liquors, or any other processes, when it may be required.”

I have inserted the specification of this patent verbatim. M. Derosne has busied himself during a long life with a prodigious number of ingenious little contrivances for clarifying and boiling syrups, distillation, &c., but he has in this invention taken a bolder flight, having secured the exclusive privilege of condensing vapours, and cooling liquors, with hot water, in preference to cold. No man at all versant in the scientific doctrines, or the practical applications of caloric, will ever seek to meddle with his monopoly of such a scheme. He may find, perhaps, some needy coppersmith ready to espouse that or any other equally foolish project, provided a productive job can be made of it, against credulous customers.

For some rational methods of cooling liquors, and condensing vapours, see Refrigeration, Still, and Sugar.

COPAL, a resin which exudes spontaneously from two trees, the Rhus copallinum, and the ElÆocarpus copalifer, the first of which grows in America, and the second in the East Indies. A third species of copal tree grows on the coasts of Guinea, especially on the banks of some rivers, among whose sands the resin is found. It occurs in lumps of various sizes and of various shades of colour, from the palest greenish yellow to darkish brown. I found its specific gravity to vary in different specimens from 1·059 to 1·071, being intermediate in density between its two kindred resins, animÉ and amber. Some rate its specific gravity so high as 1·139, which I should think one of the errors with which chemical compilations teem. Copal is too hard to be scratched by the nail, whence the excellence of its varnish. It has a conchoidal fracture, and is without smell or taste. When exposed to heat in a glass retort over a spirit lamp it readily melts into a liquid, which being further heated boils with explosive jets. A viscid oily-looking matter then distils over. After continuing the process for some time, no succinic acid is found in the receiver, but the copal blackens in the retort. Anhydrous alcohol boiled upon it, causes it to swell, and transforms it by degrees into an elastic viscid substance. It is not soluble in alcohol of 0·825 at the boiling point, as I have ascertained. Copal dissolves in ether, and this ethereous solution may be mixed with alcohol without decomposition. Caoutchoucine acts very slightly upon it by my experiments, even at the boiling temperature of this very volatile fluid; but a mixture of it with alcohol of 0·825 in equal parts dissolves it very rapidly in the cold into a perfectly liquid varnish. Alcohol holding camphor in solution also dissolves it, but not nearly so well as the last solvent. According to Unverdorben, copal may be completely dissolved by digesting one part of it for 24 hours with one part and a half of alcohol (probably anhydrous), because that portion of copal which is insoluble in alcohol, dissolves in a very concentrated solution of the soluble portion. Oil of petroleum and turpentine dissolve only 1 or 2 per cent. of raw copal. By particular management, indeed, oil of turpentine may be combined with copal, as we shall describe under the article Varnish.

Fused copal possesses different properties from the substance in its solid state; for it then may be made to combine both with alcohol and oil of turpentine.

Unverdorben has extracted from the copal of Africa, five different kinds of resin, none of which has however been applied to any use in the arts.

The ultimate constituents of copal by my analysis are, carbon 79·87, hydrogen 9·00, oxygen 11·1; being of hydrogen 7·6 in excess above the quantity necessary to form water with the oxygen. Of copal and animÉ, 551,166 libs. were imported in 1835.

COPPERAS. (Couperose verte, Fr.; Eisenvitriol, Germ.) Sulphate of iron.

CORAL, (Corail, Fr.; Koralle, Germ.) is a calcareous substance, formed by a species of sea polypus, which constructs in concert immense ramified habitations, consisting of an assemblage of small cells, each the abode of an animal. The coral is therefore a real polypary, which resembles a tree stripped of its leaves. It has no roots, but a foot not unlike a hemispherical skull-cap, which applies closely to every point of the surface upon which it stands, and is therefore difficult to detach. It merely serves as a basis or support to the coral, but contributes in no manner to its growth, like the root of an ordinary tree; for detached pieces have been often found at the bottom of the sea in a state of increase and reproduction. From the above base a stem usually single proceeds, which seldom surpasses an inch in diameter, and from it a small number of branches ramify in very irregular directions, which are studded over with cells, each containing an insect. The polypi, when they extend their arms, feelers, or tentacula, resemble flowers, whence, as well as from the form of the coral, they were classed among vegetable productions. They are now styled zoophytes by the writers upon Natural History.

The finest coral is found in the Mediterranean. It is fished for upon the coasts of Provence, and constitutes a considerable branch of trade at Marseilles. The coral is attached to the submarine rocks, as a tree is by its roots, but the branches, instead of growing upwards, shoot downwards towards the bottom of the sea; a conformation favourable to breaking them off and bringing them up. For this kind of fishing, eight men, who are excellent divers, equip a felucca or small boat, called commonly a coralline. They carry with them a large wooden cross, with strong, equal, and long arms, each bearing a stout bag-net. They attach a strong rope to the middle of the cross, and let it down horizontally into the sea, having loaded its centre with a weight sufficient to sink it. The diver follows the cross, pushes one arm of it after another into the hollows of the rocks, so as to entangle the coral in the nets. Then his comrades in the boat pull up the cross and its accompaniments.

Coral fishing is nearly as dangerous as pearl fishing, on account of the number of sharks which frequent the seas where it is carried on. One would think the diving-bell in its now very practicable state might be employed with great advantage for both purposes.

Coral is mostly of a fine red colour, but occasionally it is flesh-coloured, yellow, or white. The red is preferred for making necklaces, crosses, and other female ornaments. It is worked up like precious stones. See Lapidary.

CORK, (LiÉge, Fr.; Kork, Germ.) is the bark of the quercus liber, Linn., a species of oak-tree, which grows abundantly in the southern provinces of France, Italy, and Spain. The bark is taken off by making coronal incisions above and below the portions to be removed; vertical incisions are then made from one of these circles to another, whereby the bark may be easily detached. It is steeped in water to soften it, in order to be flattened by pressure under heavy stones, and next dried at a fire which blackens its surface. The cakes are bound up in bales and sent into the market.

There are two sorts of cork, the white and the black; the former grows in France and the latter in Spain. The cakes of the white are usually more beautiful, more smooth, lighter, freer from knots and cracks, of a finer grain, of a yellowish gray colour on both sides, and cut more smoothly than the black. When this cork is burned in close vessels it forms the pigment called Spanish black.

This substance is employed to fabricate not only bottle corks, but small architectural and geognostic models, which are very convenient from their lightness and solidity.

The cork-cutters divide the boards of cork first into narrow fillets, which they afterwards subdivide into short parallelopipeds, and then round these into the proper conical or cylindrical shape. The bench before which they work is a square table, where 4 workmen are seated, one at every side, the table being furnished with a ledge to prevent the corks from falling over. The cork-cutter’s knife is a broad blade, very thin, and fine edged. It is whetted from time to time upon a fine-grained dry whetstone. The workman ought not to draw his knife edge over the cork, for he would thus make misses, and might cut himself, but rather the cork over the knife edge. He should seize the knife with his left hand, rest the back of it upon the edge of the table; into one of the notches made to prevent it from slipping, and merely turns its edge sometimes upright and sometimes to one side. Then holding the squared piece of cork by its two ends, between his finger and his thumb, he presents it in the direction of its length to the edge; the cork is now smoothly cut into a rounded form by being dexterously turned in the hand. He next cuts off the two ends, when the cork is finished and thrown into the proper basket alongside, to be afterwards sorted by women or boys.

Of late years a much thicker kind of cork boards have been imported from Catalonia, from which longer and better corks may be made. In the art of cork-cutting the French surpass the English, as any one may convince himself by comparing the corks of their champagne bottles with those made in this country.

Cork, on account of its buoyancy in water, is extensively employed for making floats to fishermen’s nets, and in the construction of life-boats. Its impermeability to water has led to its employment for inner soles to shoes.

When cork is rasped into powder, and subjected to chemical solvents, such as alcohol, &c., it leaves 70 per cent. of an insoluble substance, called suberine. When it is treated with nitric acid, it yields the following remarkable products:—White fibrous matter 0·18, resin 14·72, oxalic acid 16·00, suberic acid (peculiar acid of cork) 14·4 in 100 parts.

Machine cork-cutting.—A patent was obtained some years ago by Sarah Thomson for this purpose. The cutting of the cork into slips is effected by fixing it upon the sliding bed of an engine, and bringing it, by a progressive motion, under the action of a circular knife, by which it is cut into slips of equal widths. The nature or construction of a machine to be used for this purpose may be easily conceived, as it possesses no new mechanical feature, except in its application to cutting cork. The motion communicated to the knife by hand, steam, horse, or other power, moves at the same time the bed also, which carries the cork to be cut.

The second part of the invention, viz. that for separating the cork into square pieces, after it has been cut in slips as above, is effected by a moving bed as before, upon which the slips are to be placed and submitted to the action of a cutting lever, which may be regulated to chop the cork into pieces of any given length.

The third part of the invention, viz., that for rounding or finishing the corks, consists of an engine to which is attached a circular knife that turns vertically, and a carriage or frame upon its side that revolves upon an axle horizontally.

This carriage or frame contains several pairs of clamps, intended respectively to hold a piece of the square cut cork by pressing it at the ends, and carrying it lengthways perpendicularly; which clamps are contrived to have a spindle motion, by means of a pinion at the lower end of their axles, working into a spur-wheel.

The machinery, thus arranged, is put in motion by means of bands and drum-wheels, or any other contrivance which may be found most eligible; and at the same time that the circular knife revolves vertically, the frame containing the clamps with the pieces of cork, turns horizontally, bringing the corks, one by one, up to the edge of the knife, when, to render each piece of cork cylindrical, the clamps, as above described, revolve upon their axes, independently of their carriage, by which means the whole circumference of the cork is brought under the action of the knife, the superfluous parts are uniformly pared off, and the cork finished smooth and cylindrical.

CORUNDUM; or Telesie; a very hard genus of aluminous minerals, to which the gems, sapphire, ruby, salamstein, and adamantine spar belong.

COTTON DYEING. (Teinture de Coton, Fr.; BaumwollenfÄrberei, Germ.) Cotton and linen yarns and cloths have nearly the same affinity for dyes, and may therefore with propriety be treated, in this respect, together. After they have acquired the proper degree of whiteness (see Bleaching) they are still unfit to receive and retain the dyes in a permanent manner. It is necessary, before dipping them into the dye-bath, to give them a tendency to condense the colouring particles within their cavities or pores, and to communicate such chemical properties as will fix these particles so that they will not separate, to whatever ordinary trial they may be subjected. All the colours which it would be desirable to transfer to these stuffs unfortunately do not possess this permanence. Men of science engaged in this important art have constantly aimed at the discovery of some new processes which may transfer into the class of fast colours those dyes which are at present more or less fugitive. Almost all the goods manufactured of cotton, flax, or hemp, are intended to be washed, and ought, therefore, to be so dyed as to resist the alkaline and soapy solutions commonly used in the laundry. Vitalis distinguished dyed cottons into three classes; 1. the fugitive, or fancy-coloured (petit teint), which change their hue or are destroyed by one or two boils with soap; 2. those which resist five or six careful washings with soap, are good dyes, (bon teint); and those which were still more durable, such as Turkey reds, may be called fast colours (grand teint). The colours of Brazil wood, logwood, annotto, safflower, &c., are fugitive; those made with madder without an oily base, are good; and those of madder with an oily mordant, are fast. It is, however, possible to point out certain processes for giving these different orders of dyes a greater degree of fixity.

I shall describe, in the five following paragraphs, the operations conducive to the fixation of colours upon cotton and linen.

1. Galling. Either gall nuts alone, or sumach alone, or these two substances united, are employed to give to cotton the fast dye preparation. 2 or 3 ounces of galls for every pound of cotton, being coarsely pounded, are to be put into a copper containing about 30 gallons of water for every 100 pounds of cotton, and the bath is to be boiled till the bits of galls feel pasty between the fingers. The fire being withdrawn, when the bath becomes moderately cool, it is passed through a hair-cloth sieve. If during this operation the liquor should become cold, it must be made once more as hot as the hand can bear. A portion of it is now transferred into another vessel, called a back, in which the cotton is worked till it be well penetrated with the decoction. It is then taken out, wrung at the peg or squeezed in a press, and straightway hung up in the drying house. Some more of the fresh decoction being added to the partially exhausted liquor in the back, the process is resumed upon fresh goods.

The manipulation is the same with sumach, but the bath is somewhat differently made; because the quantity of sumach must be double that of galls, and must be merely infused in very hot water, without boiling. When galls and sumach are both prescribed, their baths should be separately made and mixed together.

2. Aluming. Alum is a salt which serves to prepare cotton for receiving an indefinite variety of dyes. Its bath is made as follows: For 100 pounds of scoured cotton, about 30 gallons of water being put into the copper, are heated to about 122° F., when 4 ounces of alum, coarsely pounded, are thrown in for every pound of cotton, and instantly dissolved. Whenever the heat of the bath has fallen to about 98° F., the cotton is well worked in it, in order that the solution may thoroughly penetrate all its pores. It is then taken out, wrung at the peg or squeezed in the press, and dried in the shade. The solution of alum is of such constant employment in this kind of dyeing, that it should be made in large quantities at a time, kept in the alum tun, where it can suffer no deterioration, and drawn off by a spigot or stop-cock as wanted.

There are certain colours which require alum to be deprived of a portion of its acid excess, as a supersalt; which may be done by putting 1 ounce of crystals of soda into the tun for every pound of alum. But so much soda should never be used as to cause any permanent precipitation of alumina. When thus prepared, it is called saturated alum, though it is by no means neutral to litmus paper; but it crystallizes differently from ordinary alum.

Cotton does not take up at the first aluming a sufficient quantity of alum; but it must receive a second, or even a third immersion. In every case the stuff should be thoroughly dried, with an interval of one or two days between each application; and it may even be left for 10 or 12 hours moist with the alum bath before being hung in the air. When the cotton is finally dry, it must be washed before being plunged into the dye bath; otherwise, the portion of alum, not intimately combined with the cotton, but adhering externally to its filaments, would come off by the heat, mix with the bath, alter the colour by dissolving in it, and throw it down to the bottom of the copper, in the form of a lake, to the great loss of the dyer. Madder reds, weld yellows, and some other colours, are more brilliant and faster when acetate of alumina, prepared with acetate of lead, alum, and a little potash, is used, than even saturated alum. This mordant is employed cold, and at 4° BaumÉ.

3. Mordants. See this article in its alphabetical place.

4. Dye baths, are distinguished into two classes; the colouring bath, and the dyeing bath. The former serves to extract the colouring matters of the different substances, with the exception of madder, which is always used in substance, and never as an extract, infusion, or decoction. In all these cases, when the colour is extracted, that is, when the dye bath is completed by the degree of heat suited to each substance, it is then allowed to cool down a certain way, and the cotton is worked or winced through it, to get the wished-for tint. This is what is called the dye bath. Several colouring baths are made in the cold; and they serve to dye also in the cold; but the greater part require a heat of 90° or 100° to facilitate the penetration of the stuffs by the colouring particles. The description of the several dye baths is given under the individual dyes.

5. Of the washing after the dyeing.—The washing of the cottons after they have received the dyes, is one of the most important operations in the business. If it is not carefully performed, the excess of colour not combined with the fibres, is apt to stain whatever it touches. This inconvenience would be of little consequence, if the friction carried off the colour equally from all the points; but it does not do so, and hence the surface appears mottled. A well-planned dye house should be an oblong gallery, with a stream of water flowing along in an open conduit in the middle line, a series of dash wheels arranged against the wall, at one side, and of dyeing coppers, furnished with self-acting winces or reels, against the other. In such a gallery, the washing may be done either by hand, by the rinsing machine, or by the dash wheel, according to the quality of the dye, and the texture of the stuffs. And they may be stripped of the water either by the jack and pin, by the squeezing roller, or by the press. Wooden pins are placed in some dye-houses on each side of the wash cistern or pool. They are somewhat conical, 1¹/₂ foot high, 3¹/₂ inches in diameter at the base, 1¹/₂ at the top, are fixed firmly upright, and at a level of about 3 feet above the bottom of the cistern, so as to be handy for the workmen. See Brazil wood, Fustic, Madder, Black Dye, Brown Dye, &c., as also Bleaching, Bran, Calico Printing, Dunging, Dyeing, &c.