Voltaic Electricity—The Voltaic Battery—Intensity—Quantity—Static Electricity, and Electricity in Motion—Luminous Effects—Mr. Grove on the Electric Arc and Light—Decomposition of Water—Formation of Crystals by Voltaic Electricity—Photo-galvanic Engraving—Conduction—Heat of Voltaic Electricity—Electric Fish. Voltaic or Dynamic electricity is elicited by the force of chemical action. It is connected with some of the most brilliant periods of British science, from the splendid discoveries to which it led Sir Humphry Davy and Dr. Faraday. In 1790, while Galvani, Professor of Anatomy in Bologna, was making experiments on electricity, he was surprised to see convulsive motions in the limbs of a dead frog accidentally lying near the machine during an electrical discharge. Though a similar action had been noticed long before his time, he was so much struck with this singular phenomenon, that he examined all the circumstances carefully, and at length found that convulsions take place when the nerve and muscle of a frog are connected by a metallic conductor. This excited the attention of all Europe; and it was not long before Volta, Professor at Pavia, showed that the mere contact of different bodies is sufficient to disturb electrical equilibrium, and that a current of electricity flows in one direction through a circuit of three conducting substances. From this he was led, by acute reasoning and experiment, to the construction of the Voltaic pile, which, in its early form, consisted of alternate discs of zinc and copper, separated by pieces of wet cloth, the extremities being connected by wires. This simple apparatus, perhaps the most wonderful instrument that has been invented by the ingenuity of man, by divesting electricity of its sudden and uncontrollable violence, and giving in a continued stream a greater quantity at a diminished intensity, has exhibited that force under a new and manageable form, possessing powers the most astonishing and unexpected. The expression current has no relation to a fluid, which is now considered to be as inconsistent with the phenomena of dynamic as with static electricity. The disturbance of electric equilibrium, and a development of electricity, invariably accompany the chemical action of a fluid on metallic substances, and the electricity is most plentiful when that action occasions oxidation. Metals vary in the quantity of electricity afforded by their combination with oxygen. But the greatest abundance is developed by the oxidation of zinc by weak sulphuric acid. And, in conformity with the law that one kind of electricity cannot be evolved without an equal quantity of the other being brought into activity, it is found that the acid is positively, and the zinc negatively electric. It has not yet been ascertained why equilibrium is not restored by the contact of these two substances, which are both conductors, and in opposite electrical states. However, the electrical and chemical changes are so connected, that, unless equilibrium be restored, the action of the acid will go on languidly, or stop as soon as a certain quantity of electricity is accumulated in it. Equilibrium, nevertheless, will be restored, and the action of the acid will be continuous, if a plate of copper be placed in contact with the zinc, both being immersed in the fluid; for the copper, not being acted upon by the acid, will serve as a conductor to convey the positive electricity from the acid to the zinc, and will at every instant restore the equilibrium, and then the oxidation of the zinc will go on rapidly. Thus three substances are concerned in forming a Voltaic circuit, but it is indispensable that one of them should be a fluid. The electricity so obtained will be very feeble in overcoming resistances offered by imperfect conductors interposed in the circuit, or by very long wires, but it may be augmented by increasing the number of plates. In the common Voltaic battery, the electricity which the fluid has acquired from A battery charged with water alone, instead of acid, is constant in its action, but the quantity of electricity it develops is comparatively very small. Mr. Cross, of Broomfield in Somersetshire, kept a battery of this kind in full force during twelve months. M. Becquerel had invented an instrument for comparing the intensities of the different kinds of electricity by means of weights; but, as it is impossible to make the comparison with Voltaic electricity produced by the ordinary batteries, on account of the perpetual variation to which the intensity of the current is liable, he has constructed a battery which affords a continued stream of electricity of uniform power, but it is also of very feeble force. The current is produced by the chemical combination of an acid with an alkali. Metallic contact is not necessary for the production of Voltaic electricity, which is entirely due to chemical action. The intensity of the Voltaic electricity is in proportion to the intensity of the affinities concerned in its production, and the quantity produced is in proportion to the quantity of matter which has been chemically active during its evolution. Dr. Faraday considers this definite production to be one of the strongest proofs that electricity is of chemical origin. Galvanic or Voltaic electricity is manifested by two continuous forces or currents passing in opposite directions through the circuit: the zinc is the positive end or pole of the battery, and the copper the negative. Voltaic electricity is distinguished by two marked characters. Its intensity increases with the number of plates, its quantity with the extent of their surfaces. The most intense concentration of force is displayed by a numerous series of large plates: light and heat are copiously evolved, and chemical decomposition is accomplished with extraordinary energy; whereas the electricity from one pair of plates, whatever their size may be, is so feeble The action of Voltaic electricity differs in some respects materially from that of the ordinary kind. When a quantity of common electricity is accumulated, the restoration of equilibrium is attended by an instantaneous violent explosion, accompanied by the development of light, heat, and sound. The concentrated power of the electricity forces its way through every obstacle, disrupting and destroying the cohesion of the particles of the bodies through which it passes, and occasionally increasing its destructive effects by the conversion of fluids into steam from the intensity of the momentary heat, as when trees are torn to pieces by a stroke of lightning. Even the vivid light which marks the path of the electricity is probably owing in part to the sudden compression of the air and the rapidity of its passage. But the instant equilibrium is restored by this energetic action the whole is at an end. On the contrary, when an accumulation takes place in a Voltaic battery, equilibrium is restored the moment the circuit is completed. But so far is the electric stream from being exhausted, that it continues to flow silently and invisibly in an uninterrupted current supplied by a perpetual reproduction. And, although its action on bodies is neither so sudden nor so intense as that of common electricity, yet it acquires such power from constant accumulation and continued action, that it ultimately surpasses the energy of the other. The two kinds of electricity differ in no circumstance more than in the development of heat. Instead of a momentary evolution, the circulation of the Voltaic electricity is accompanied by a continued development of heat, lasting as long as the circuit is complete, without producing either light or sound. Its intensity from a very powerful battery is greater than that of any heat that can be obtained by artificial means, so that it fuses substances which resist the action of the most powerful furnaces. The temperature of every part of a Voltaic battery itself is raised during its activity. With the greater number of metals Mr. Grove According to Mr. Joule, the quantity of heat generated in a unit of time is proportional to the strength of the current, and when a galvanic current is employed in chemical analysis, the heat in the entire circuit generated in a unit of time is equal to the work expended in producing it, minus that employed in the analysis. In fact, a current of electricity cannot pass through a homogeneous conductor without generating heat in overcoming resistance, an effect proved by Mr. Joule to be proportional to the square of the force of the current, and the same in whatever direction the current may be flowing. Any other thermal action that can take place must depend upon the heterogeneousness of the circuit, and must be reversible with the current. For example, if a semicircle of bismuth be joined to a semicircle of antimony, an electric current in passing through it produces cold where it passes from the bismuth to the antimony by absorption, and heat where it passes from the antimony to the bismuth. The transit of the electricity from pole to pole is accompanied by light, and in consequence of the continuous current sparks occur every time the contact of the wires is either broken or renewed; but considerable intensity is requisite to enable the electricity to force its way through atmospheric air or gas. Both its length and colour are affected by the density of the medium through which it passes. If the medium be gradually rarefied the discharge increases from a spark to a luminous glow, differing in colour in different gases, but white in air. When very much attenuated a discharge may be made to pass across 6 or 7 feet of space, while in air of the ordinary density it will not pass through an inch. In rarefied gas it resembles the Aurora by its continuous flashes. When the battery is powerful the luminous effects are very brilliant. The most splendid artificial light known is produced by fixing pencils of charcoal at the extremities of the wires, and bringing them into contact. This light is the more remarkable as it is independent of combustion, since the charcoal suffers no apparent change, and, likewise, because it is equally vivid in such gases as do not contain oxygen. It depends upon the molecular arrangement of the charcoal; for Mr. Grove observes that “carbon in a transparent crystalline Professor Wheatstone, by fixing metallic points at the extremities of the wires or poles, has found that the appearance of the spectrum of the voltaic arc or vivid flame that is seen between the terminals of a battery, depends, as in static electricity, upon the metal from whence it is taken. The spectrum of that from mercury consists of seven definite rays, separated from each other by dark intervals; these visible rays are two orange lines close together, a bright green line, two blueish-green lines near each other, a very bright purple line, and, lastly, a blue line. It is the same when it passes through carbonic acid gas, oxygen gas, air, or vacuum. The light from zinc, cadmium, tin, bismuth, and lead, in a melted state, gives similar results; but the number, position, and colour of the lines vary so much in each case, and the appearances are so different, that the metals may easily be distinguished from one another by this mode of investigation. The electric spark is considered by M. AngstrÖm to be the overlapping of two spectra, one of which belongs to the metal, and the other to the gas through which the spark passes, and that the bright lines vary with the gas as well as with the metal. In an oxygen spectrum the greatest number of bright lines occur in the blue and violet, in nitrogen in the green and yellow, and in hydrogen in the red. These effects must necessarily be connected with the chemical and thermal properties of the gases. Mr. Grove considers that the colour of the voltaic arc, or flame, Another strong evidence that the Voltaic discharge consists of the material itself of which the terminals are composed, is the peculiar rotation which is observed in the light when iron is employed, the magnetic character of this metal causing its particles to rotate by the influence of the Voltaic current. In short, Mr. Grove concludes that, although it would be hasty to assert that the electrical disruptive discharge can in no case take place without the terminals being affected, yet he had met with no instance of such a result, provided the discharge had been sufficiently prolonged, and the terminals in such a state as could be expected to render manifest slight changes! Some years ago Mr. Grove discovered that the electrical discharge possesses certain phases or fits of an alternate character, forming rings of alternate oxidation and deoxidation on metallic surfaces. A highly polished silver plate in an air-pump was connected with the pole of a powerful inductive battery, while a fine metallic wire, or even a common sewing needle, was fixed at the other pole, and so arranged as to be perpendicular to the silver plate, and very near, but not touching it. By means of this apparatus the electrical discharge could be sent through any kind of rarefied media. In some of the experiments a series of concentric coloured rings of oxide alternating with rings of polished or unoxidated silver were formed on the plate under the point of the needle or wire. When the plate was previously coated with a film of oxide, the oxide was removed in concentric spaces by the discharge, and increased on the alternate ones, showing an alternate positive and negative electricity, or electricity of an opposite character in the same discharge. When the silver plate was polished the centre of the rings formed on it was yellow-green surrounded by blue-green; then a ring of polished silver, followed by a crimson ring with a slight orange tint on the inner side and deep purple on the outer; When the silver plate was connected with the negative pole of the battery a polished point appeared upon it opposite the needle, surrounded by a dusky ill-defined areola of a brown colour tinged with purple when viewed in one direction, and greenish-white when seen in another. In the present year Mr. Gassiot, Vice-President of the Royal Society, has shown that the stratified character of the electric discharge is remarkably developed in the In a closed glass tube about an inch internal diameter and 38 inches long, in which a vacuum had been made, two platinum wires were hermetically sealed, 32 inches apart, and connected with the poles of an inductive battery. The luminous appearance at the two poles was very different when electricity passed through the wires. A glow surrounded the negative pole, and in close approximation to the glow a well-defined dark space appeared, while from the positive pole or wire the light proceeded in a stream; but unless the charge be great or the tube short, the stream will not extend to the black band, which is totally different from the intervening space. When discharges of electricity were sent through this vacuum tube a series of bands or stratifications were formed which were concave towards the positive pole; and as in the changes in making and breaking the circuit the electricity emanates from the different terminals or wires, their concavities were in opposite directions. When instead of platinum wires narrow tinfoil coatings were placed round the exterior of the glass tube and connected with the wires of the battery, brilliant stratifications filled the interior of the tube between the foil coatings, but no dark band appeared. At present Mr. Gassiot is inclined to believe that the dark band is due to interference; but that the stratifications arise from pulsations or impulses of a force acting in a highly attenuated but Voltaic electricity is a powerful agent in chemical analysis. When transmitted through conducting fluids, it separates them into their constituent parts, which it conveys in an invisible state through a considerable space or quantity of liquid to the poles, where they come into evidence. Numerous instances might be given, but the decomposition of water is perhaps the most simple and elegant. Suppose a glass tube filled with water, and corked at both ends; if one of the wires of an active Voltaic battery be made to pass through one cork, and the other through the other cork, into the water, so that the extremities of the two wires shall be opposite and about a quarter of an inch asunder, chemical action will immediately take place, and gas will continue to rise from the extremities of both wires till the water has vanished. If an electric spark be then sent through the tube, the water will reappear. By arranging the experiment so as to have the gas given out by each wire separately, it is found that water consists of two volumes of hydrogen and one of oxygen. The hydrogen is given out at the positive wire of the battery, and the oxygen at the negative. The oxides are also decomposed; the oxygen appears at the positive pole, and the metal at the negative. The decomposition of the alkalies and earths by Sir Humphry Davy formed a remarkable era in the history of science. Soda, It had been observed that, when metallic solutions are subjected to galvanic action, a deposition of metal, sometimes in the form of minute crystals, takes place on the negative wire. By extending this principle, and employing a very feeble Voltaic action, M. Becquerel has succeeded in forming crystals of a great proportion of the mineral substances, precisely similar to those produced by nature. The electric state of metallic veins makes it possible that many natural crystals may have taken their form from the action of electricity bringing their ultimate particles, when in solution, within the narrow sphere of molecular attraction. Both light and motion favour crystallization. Crystals which form in different liquids are generally more abundant on the side of the jar exposed to the light; and it is well known that still water, cooled below 32°, starts into crystals of ice the instant it is agitated. A feeble action is alone necessary, provided it be continued for a sufficient time. Crystals formed rapidly are generally imperfect and soft, and M. Becquerel found that even years of constant Voltaic action were necessary for the The deposition of metal from a metallic solution by galvanic electricity has been most successfully applied to the arts of plating and gilding, as well as to the more delicate process of copying medals and copper plates. Indeed, not medals only, but any object of art or nature, may be coated with precipitated metal, provided it be first covered with the thinnest film of plumbago, which renders a non-conductor sufficiently conducting to receive the metal. Photo-galvanic engraving depends upon this. Gelatine mixed with bichromate of potash, nitrate of silver, and iodide of potassium, is spread over a plate of glass, and when dry a positive print is laid upon it with its face downwards, which, when exposed to the sun, leaves its impression. When soaked in water the gelatine swells around all those parts where the light had fallen, thus forming an intaglio, a cast of which is taken in gutta-percha, which is then coated with copper by the electro process, whence a copper plate in relief is obtained. Static electricity, on account of its high tension, passes through water and other liquids as soon as it is formed, whatever the length of its course may be. Voltaic electricity, on the contrary, is weakened by the distance it has to traverse. Pure water is a very bad conductor; but ice absolutely stops a current of Voltaic electricity altogether, whatever be the power of the battery, although static or common electricity has sufficient power to overcome its resistance. Dr. Faraday has discovered that this property is not peculiar to ice; that, with a few exceptions, bodies which do not conduct electricity when solid acquire that property, and are immediately decomposed, when they become fluid, and, in general, that decomposition takes place as soon as the solution acquires the capacity of conduction, which has led him to suspect that the power of conduction may be only a consequence of decomposition. Heat increases the conducting power of some substances for Voltaic electricity, and of the gases for both kinds. Dr. Faraday has given a new proof of the connexion between heat and electricity, by showing that, in general, when a solid, which is not a metal, becomes fluid, it almost entirely loses its power of conducting The galvanic current affects all the senses: nothing can be more disagreeable than the shock, which may even be fatal if the battery be very powerful. A bright flash of light is perceived with the eyes shut, when one of the wires touches the face, and the other the hand. By touching the ear with one wire, and holding the other, strange noises are heard; and an acid taste is perceived when the positive wire is applied to the tip of the tongue, and the negative wire touches some other part of it. By reversing the poles the taste becomes alkaline. It renders the pale light of the glow-worm more intense. Dead animals are roused by it, as if they started again into life, and it may ultimately prove to be the cause of muscular action in the living. Several fish possess the faculty of producing electrical effects. The most remarkable are the gymnotus electricus, found in South America; and the torpedo, a genus of ray, frequent in the Mediterranean. The electrical action of the torpedo depends upon an apparatus apparently analogous to the Voltaic pile, which the animal has the power of charging at will, consisting of membranous columns filled throughout with laminÆ, separated from one another by a fluid. The absolute quantity of electricity brought into circulation by the torpedo is so great, that it effects |