CHAPTER XX. DIA-MAGNETISM.

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At the end of the chapter devoted to the subject of light, will be found an experiment devised and carried out by Dr. Faraday, in which it is shown that if a bar of a peculiar glass (called after the inventor, Faraday's heavy glass, or silicated borate of lead) is subjected to the inductive action of a very powerful electro-magnet, that it has the power of changing the direction of a ray of polarized light transmitted through it. This effect is not confined to the poles of an electro-magnet, but is also perceptible (though in a diminished degree) with ordinary magnets.

The result of this important experiment was communicated to the Royal Society by Dr. Faraday on the 27th November, 1845, the enunciation of the fact by this learned philosopher being, "that when 'the line of magnetic force' is made to pass through certain transparent bodies parallel to a ray of polarized light traversing the same body, the ray of polarized light experiences a rotation." Now, "the line of magnetic force" means that continual flow of the magnetic current which passes from pole to pole, and is indicated by iron filings sprinkled on paper placed above the poles of a magnet, and usually termed magnetic curves, or the curved lines of magnetic force. (Fig. 241.)

Fig. 241. Fig. 241.

The curved lines of magnetic force.

The heavy glass already alluded to, upon which the magnet exerts a certain influence, is called

THE DIA-MAGNETIC;

and by this term is meant a body through which the lines of magnetic force are passing without affecting it like iron or steel. At page 211 is a picture representing (at Figs. 201 and 202) the direction of the electricity and that of the magnetic current or whirl at right angles to it. If, then, Fig. 202 be considered as a piece of glass, the arrow a b will show "the line of magnetic force," the point b being the north pole, and the shaft a the south pole of the magnet, and the arrows traced round will represent direction. This simple drawing expresses the whole of the law of the action of the magnet on the glass, and if kept in view, will give every position and consequence of direction resulting from it.

The phenomenon of the affection of the beam of polarized light is immediately connected with the magnetic force, and this is supposed to be proved by the brightness of the polarized ray being developed gradually, as the iron coiled with wire requires about two seconds to acquire its greatest power after being connected with the battery.

In another experiment of Faraday's, where a beam of polarized light was sent through a long glass tube containing water, and introduced as a core inside a powerful electro-magnetic coil, the image of a candle viewed with a proper eye-piece, appeared or disappeared as the battery connexion was made or broken with the coil; but this result is not considered by many philosophers to be conclusive of the action of magnetism on light, but rather as an alteration of the refracting power of the medium through which the light passes. These experiments were the precursors of the other effects of magnetism upon different kinds of matter which Faraday discovered, and he commenced his examination with a small bar of heavy glass suspended by a filament of silk between the poles of an electro-magnet, and when the twisting or effects of torsion had ceased, the battery was connected. Directly the current passed, Faraday's keen eye detected a movement of the glass, and on repeating the experiment, he discovered that the movement was not accidental, but always took place in a certain fixed direction—viz., a direction at right angles to a line drawn across and touching the two poles of a horse-shoe-shaped magnet—i.e., supposing the feeder or bit of soft iron usually placed in contact with the poles of the horse-shoe-magnet to represent the "axial line," any line drawn across it at right angles would be called the equatorial line, whilst the general space included between the poles of the magnet is called "the magnetic field." The movement of the heavy glass was therefore equatorial, and it pointed east and west instead of north and south, like iron and steel.

Fig. 242. Fig. 242.

A cube of copper suspended between the poles of a powerful electro-magnet.

By the use of the apparatus (Fig. 242) Faraday proved that every substance, whether solid, fluid, or gaseous, was subject to magnetic influences, assuming either the axial or equatorial position. The apparatus consists of a prolongation of the poles of a powerful electro-magnet, between which the cube of copper, weighing from a quarter to half a pound, suspended by a thread, may be set spinning or rotating. If the electro-magnet is connected with the battery, the cube stops immediately, and whilst still in the same position or in the magnetic field, with the magnet in full action, it is impossible to set it spinning or twisting round again. (Fig. 242.)

A large number of other substances, solid, liquid, and gaseous, were submitted to the action of the magnet, the liquids and gases being hermetically sealed in glass tubes, and some of the results are detailed in the following list:

Bodies that point axially, or are paramagnetic, like a suspended needle.

Iron.
Nickel.
Cobalt.
Manganese.
Chromium.
Cerium.
Titanium.
Palladium.
Platinum.
Osmium.
Paper.
Sealing-wax.
Fluor spar.
Peroxide of lead.
Plumbago.
China ink.
Berlin Porcelain.
Red-lead.
Sulphate of zinc.
Shell-lac.
Silkworm-gut.
Asbestos.
Vermilion.
Tourmaline.
Charcoal.
All salts of iron,
when the latter is basic.
Oxide of titanium.
Oxide of chromium.
Chromic acid.
Salts of manganese.
Salts of chromium.
Oxygen, which stands
alone as a paramagnetic gas.

Bodies that point equatorially, or are diamagnetic, like Faraday's heavy glass.

Bismuth.
Antimony.
Zinc.
Tin.
Cadmium.
Sodium.
Mercury.
Lead.
Silver.
Copper.
Gold.
Arsenic.
Uranium.
Rhodium.
Iridium.
Tungsten.
Rock crystal.
The mineral acids.
Alum.
Glass.
Litharge.
Common salt.
Nitre.
Phosphorus.
Sulphur.
Resin.
Spermaceti.
Iceland spar.
Tartaric acid.
Citric acid.
Water.
Alcohol.
Ether.
Sugar.
Starch.
Gum-arabic.
Wood.
Ivory.
Dried mutton.
Fresh beef.
Dried beef.
Apple.
Bread.
Leather.
Fresh blood.
Dried blood.
Caoutchouc.
Jet.
Turpentine.
Olive oil.
Hydrogen.
Carbonic acid.
Carbonic oxide.
Nitrous oxide (moderately).
Nitric oxide (very slightly).
Olefiant gas.
Coal gas.

Nitrogen is neither paramagnetic nor diamagnetic, and is equivalent to a vacuum. Magnetically considered, it is like space itself, which may be considered as zero.

The term magnetic Faraday proposes should be a general one, like that of electricity, and include all the phenomena and effects produced by the power, and he proposes that bodies magnetic in the sense of iron should be called paramagnetic, so that the division would stand thus:

Magnetic ......... { Paramagnetic,
{ Diamagnetic;

All space above and within the limits of our atmosphere may be regarded as traversed by lines of force, and amongst others are the lines of magnetic force which affect bodies, as shown in the table of paramagnetic and diamagnetic bodies, which have the same relation to each other as positive and negative, or north and south, in electricity and magnetism.

The lines of magnetic force are assumed to traverse void space without change; but when they come in contact with matter of any kind they are either concentrated upon it or scattered according to the nature of the matter.

The power which urges bodies to the axial or equatorial lines is not a central force, but a force differing in character in the axial or radial directions. If a liquid paramagnetic body were introduced into the field of force, it would dilate axially, and form a prolate spheroid like a lemon, while a liquid diamagnetic body would dilate equatorially, and form an oblate spheroid like an orange. PlÜcker has demonstrated that if magnetic solutions are placed in watch glasses across the poles of the electro-magnet, they are heaped up in a very curious manner. The poles of the electro-magnet are pieces of soft iron, which may be drawn away or approached at pleasure, and according as the poles are nearer or further asunder, the magnetic liquids, such as solution of iron, are heaped up in one or two directions, as shown at b and c in Fig. 243.

Fig. 243. Fig. 243.

Glass dish holding magnetic solution of iron, and placed in the magnetic field.

"The diamagnetic power, doubtless," says Faraday, "has its appointed office, and one which relates to the whole mass of the globe. For though the amount of the power appears to be feeble, yet, when it is considered that the crust of the earth is composed of substances of which by far the greater portion belongs to the diamagnetic class, it must not be too hastily assumed that their effect is entirely overruled by the action of the magnetic matters, whilst the great mass of waters and the atmosphere must exert their diamagnetic action uncontrolled."

PlÜcker has also announced—what at the time he believed to be true—the highly interesting and important fact that the optic axis of Iceland or calcareous spar is repelled by the magnet and placed equatorially—a fact which PlÜcker thought true of many other crystals when the magnetic axis is parallel to the longer crystallographic axis. A piece of kyanite, which is a mineral composed of sand, clay, often lime, iron, water, and is used in India, being cut and polished as a gem, and sold frequently as an inferior kind of sapphire, will, it is said, even under the influence of the earth's magnetism, arrange itself like a magnetic needle.

PlÜcker believed that he had discovered an existing relation between the forms of the ultimate particles of matter and the magnetic forces, and he imagined that the results he obtained would lead gradually to the determination of crystalline form by the magnet. The experiments of Tyndal and Knoblauch lead, however, to a very opposite series of conclusions, and by ingeniously powdering the crystals with water, and making them into a paste, which was afterwards dried and suspended as a model in "the magnetic field;" also by taking a slice of apple about as thick as a penny-piece, with some bits of iron wire through it, in a direction perpendicular to its flat surface, they were found to set equatorially not by repulsion but by the attraction of the iron wires; or instead of the iron by placing bismuth wires, the apple now settled axially, not by attraction but by the repulsion of the bismuth. Ipecacuanha lozenges, Carlisle biscuits also, suspended in the magnetic field, exhibited a most striking directive action. The materials in these two cases were diamagnetic; but owing to the pressure exerted in their formation their largest horizontal dimensions set from pole to pole, the line of compression being equatorial; and it is a universal law "that in diamagnetic bodies the line along which the density of the mass has been induced by compression sets equatorial, and in magnetic bodies axial." Hence they assume, from these and many other conclusive experiments, that crystallized bodies, such as Iceland spar, take their position in the magnetic field without reference to the existence of an "optic axis."

At the conclusion of a brilliant lecture at the Royal Institution by Dr. Tyndal "On the influence of material aggregation upon the manifestations of force," in which PlÜcker's experiments respecting the repulsion of the optic axis were gracefully discussed and his theory refuted, the learned doctor said: "This evening's discourse is in some measure connected with this locality; and thinking thus, I am led to inquire wherein the true value of a scientific discovery consists? Not in its immediate results alone, but in the prospect which it opens to intellectual activity—in the hopes which it excites—in the vigour which it awakens. The discovery which led to the results brought before us to-night was of this character. That magnet[E] was the physical birthplace of these results; and if they possess any value they are to be regarded as the returning crumbs of that bread which in 1846 was cast so liberally upon the waters. I rejoice, ladies and gentlemen, in the opportunity here afforded me of offering my tribute to the greatest workman of the age, and of laying some of the blossoms of that prolific tree which he planted at the feet of the great discoverer of diamagnetism."[F]

[E] Alluding to a splendid magnet made by Logeman, which was sent to the Exhibition in Hyde-park in 1851. It could sustain a weight of 430 pounds, and was purchased by the Royal Institution for Dr. Faraday.

[F] Dr. Faraday.

It was first observed by Father Bancalari, of Genoa, that when the flame of a candle is placed between the poles of a magnet it is strongly repelled. The flames of combustible gases from various sources are differently affected, both by the nature of the combustible and by the nearness of the poles. Faraday repeated Bancalari's experiments, and by a certain arrangement of the poles of this magnet he obtained a powerful effect in the magnetic field, and having the axial line of the magnetic force horizontal, he found that when the flame of a wax taper was held near the axial line (but on one side or the other), and about one-third of the flame rising above the level of the upper surface of the poles, as soon as the magnetic force was exerted the flame receded from the axial line, moving equatorially until it took an inclined position, as if a gentle wind was causing its deflection from the upright position.

When the flame was placed so as to rise truly across the magnetic axis, the effect of the magnetism was very curious, and is shown at a, Fig. 244.

On raising the flame a little more the effect of the magnetic force was to intensify the results already mentioned, and the flame actually became of a fish-tailed shape, as at c, Fig. 244; and when the flame was raised until about two-thirds of it were above the level of the axial line, and the poles approached very close, the flame no longer rose between the poles, but spread out right and left on each side of the axial line, producing a double flame with two long tongues, as at b, Fig. 244.

Fig. 244. Fig. 244.

Effect of magnetism on candle-flame between the poles of the magnet.

It was these experiments that led to the important discovery of the paramagnetic property of oxygen, and proved in a decided manner that gaseous bodies when heated became more highly diamagnetic. Oxygen, which (tried in the air) is powerfully magnetic, becomes diamagnetic when heated. A coil of platinum wire heated by a voltaic current, and placed beneath the poles of Faraday's apparatus, occasioned a strong upward current of air; but directly the magnetic action commences the ascending current divides, and a descending current flows down between the upward currents.

The discovery, says Silliman, of the highly paramagnetic character of oxygen gas, and of the neutral character of nitrogen, the two constituents of air, is justly esteemed a fact of great importance in studying the phenomena of terrestrial magnetism. We thus see that one-fifth of the air by volume consists of an element of eminent magnetic capacity, after the manner of iron, and liable to great physical changes of density, temperature, &c., and entirely independent of the solid earth. In this medium hang the magnetic needles used as tests, and as this magnetic medium is daily heated and cooled by the sun's rays, its power of transmitting the lines of magnetic force is then affected, influencing undoubtedly the diurnal changes of the magnetic needle.

For a complete digest of Faraday's discoveries in diamagnetism the reader is referred to the second edition of Dr. Noad's comprehensive and learned work entitled "A Manual of Electricity."

Coming always from the highest walks of philosophy to lower and "common things" one cannot help being reminded of the old-fashioned method of drawing up a sluggish fire, and the natural query is suggested whether the poker is to be considered as a weak magnet, and does influence and draw towards the fire a greater supply of magnetic oxygen gas? (Fig. 245.)

Fig. 245. Fig. 245.
interior of the optical box

The interior of the optical box at the Polytechnic—looking towards the screen. The assistants are supposed to be showing the dissolving views.


                                                                                                                                                                                                                                                                                                           

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