We encourage you to keep this file, exactly as it is, on your own disk, thereby keeping an electronic path open for future readers. Please do not remove this. This header should be the first thing seen when anyone starts to view the etext. Do not change or edit it without written permission. The words are carefully chosen to provide users with the information they need to understand what they may and may not do with the etext. To encourage this, we have moved most of the information to the end, rather than having it all here at the beginning. **Etexts Readable By Both Humans and By Computers, Since 1971** *****These Etexts Were Prepared By Thousands of Volunteers!***** Title: The Story Of Electricity Author: John Munro Release Date: December, 2003 [Etext #4710] Edition: 10 Language: English Produced by Robert Rowe, Charles Franks and the Online Distributed Proofreading Team. The "legal small print" and other information about this book may now be found at the end of this file. Please read this important information, as it gives you specific rights and tells you about restrictions in how the file may be used. THE STORY OF ELECTRICITYBY JOHN MUNROAUTHOR OF ELECTRICITY AND ITS USES, PIONEERS OF ELECTRICITY, HEROES OF THE TELEGRAPH, ETC., AND JOINT AUTHOR OF MUNRO AND JAMIESON'S POCKET-BOOK OF ELECTRICAL RULES AND TABLESPREFACE.A work on electricity needs little recommendation to stimulate the interest of the general reader. Electricity in its manifold applications is so large a factor in the comfort and convenience of our daily life, so essential to the industrial organization which embraces every dweller in a civilized land, so important in the development and extension of civilization itself, that a knowledge of its principles and the means through which they are directed to the service of mankind should be a part of the mental equipment of everyone who pretends to education in its truest sense. Let anyone stop to consider how he individually would be affected if all electrical service were suddenly to cease, and he cannot fail to appreciate the claims of electricity to attentive study. The purpose of this little book is to present the essential facts of electrical science in a popular and interesting way, as befits the scheme of the series to which it belongs. Electrical phenomena have been observed since the first man viewed one of the most spectacular and magnificent of them all in the thunderstorm, but the services of electricity which we enjoy are the product solely of scientific achievement in the nineteenth century. It is to these services that the main part of the following discussion is devoted. The introductory chapters deal with various sources of electrical energy, in friction, chemical action, heat and magnetism. The rest of the book describes the applications of electricity in electroplating, communication by telegraph, telephone, and wireless telegraphy, the production of light and heat, the transmission of power, transportation over rails and in vehicles, and the multitude of other uses. July, 1915. PUBLISHERS' NOTE.For our edition of this work the terminology has been altered to conform with American usage, some new matter has been added, and a few of the cuts have been changed and some new ones introduced, in order to adapt the book fully to the practical requirements of American readers. CONTENTS.I. THE ELECTRICITY OF FRICTION II. THE ELECTRICITY OF CHEMISTRY III. THE ELECTRICITY OF HEAT IV. THE ELECTRICITY OF MAGNETISM V. ELECTROLYSIS VI. THE TELEGRAPH AND TELEPHONE VII. ELECTRIC LIGHT AND HEAT VIII. ELECTRIC POWER IX. MINOR USES OF ELECTRICITY X. THE WIRELESS TELEGRAPH XI. ELECTRO-CHEMISTRY AND ELECTRO-METALLURGY XII. ELECTRIC RAILWAYS APPENDIXTHE STORY OF ELECTRICITY.CHAPTER I.THE ELECTRICITY OF FRICTION.A schoolboy who rubs a stick of sealing-wax on the sleeve of his jacket, then holds it over dusty shreds or bits of straw to see them fly up and cling to the wax, repeats without knowing it the fundamental experiment of electricity. In rubbing the wax on his coat he has electrified it, and the dry dust or bits of wool are attracted to it by reason of a mysterious process which is called "induction." Electricity, like fire, was probably discovered by some primeval savage. According to Humboldt, the Indians of the Orinoco sometimes amuse themselves by rubbing certain beans to make them attract wisps of the wild cotton, and the custom is doubtless very old. Certainly the ancient Greeks knew that a piece of amber had when rubbed the property of attracting light bodies. Thales of Miletus, wisest of the Seven Sages, and father of Greek philosophy, explained this curious effect by the presence of a "soul" in the amber, whatever he meant by that. Thales flourished 600 years before the Christian era, while Croesus reigned in Lydia, and Cyrus the Great, in Persia, when the renowned Solon gave his laws to Athens, and Necos, King of Egypt, made war on Josiah, King of Judah, and after defeating him at Megiddo, dedicated the corslet he had worn during the battle to Apollo Didymaeus in the temple of Branchidas, near Miletus. Amber, the fossil resin of a pine tree, was found in Sicily, the shores of the Baltic, and other parts of Europe. It was a precious stone then as now, and an article of trade with the Phoenicians, those early merchants of the Mediterranean. The attractive power might enhance the value of the gem in the eyes of the superstitious ancients, but they do not seem to have investigated it, and beyond the speculation of Thales, they have told us nothing more about it. Towards the end of the sixteenth century Dr. Gilbert of Colchester, physician to Queen Elizabeth, made this property the subject of experiment, and showed that, far from being peculiar to amber, it was possessed by sulphur, wax, glass, and many other bodies which he called electrics, from the Greek word elektron, signifying amber. This great discovery was the starting-point of the modern science of electricity. That feeble and mysterious force which had been the wonder of the simple and the amusement of the vain could not be slighted any longer as a curious freak of nature, but assuredly none dreamt that a day was dawning in which it would transform the world. Otto von Guericke, burgomaster of Magdeburg, was the first to invent a machine for exciting the electric power in larger quantities by simply turning a ball of sulphur between the bare hands. Improved by Sir Isaac Newton and others, who employed glass rubbed with silk, it created sparks several inches long. The ordinary frictional machine as now made is illustrated in figure i, where P is a disc of plate glass mounted on a spindle and turned by hand. Rubbers of silk R, smeared with an amalgam of mercury and tin, to increase their efficiency, press the rim of the plate between them as it revolves, and a brass conductor C, insulated on glass posts, is fitted with points like the teeth of a comb, which, as the electrified surface of the plate passes by, collect the electricity and charge the conductor with positive electricity. Machines of this sort have been made with plates 7 feet in diameter, and yielding sparks nearly 2 feet long. The properties of the "electric fire," as it was now called, were chiefly investigated by Dufay. To refine on the primitive experiment let us replace the shreds by a pithball hung from a support by a silk thread, as in figure 2. If we rub the glass rod vigorously with a silk handkerchief and hold it near, the ball will fly toward the rod. Similarly we may rub a stick of sealing wax, a bar of sulphur, indeed, a great variety of substances, and by this easy test we shall find them electrified. Glass rubbed with glass will not show any sign of electrification, nor will wax rubbed on wax; but when the rubber is of a different material to the thing rubbed, we shall find, on using proper precautions, that electricity is developed. In fact, the property which was once thought peculiar to amber is found to belong to all bodies. ANY SUBSTANCE, WHEN RUBBED WITH A DIFFERENT SUBSTANCE, BECOMES ELECTRIFIED. The electricity thus produced is termed frictional electricity. Of course there are some materials, such as amber, glass, and wax, which display the effect much better than others, and hence its original discovery. In dry frosty weather the friction of a tortoise-shell comb will electrify the hair and make it cling to the teeth. Sometimes persons emit sparks in pulling off their flannels or silk stockings. The fur of a cat, or even of a garment, stroked in the dark with a warm dry hand will be seen to glow, and perhaps heard to crackle. During winter a person can electrify himself by shuffling in his slippers over the carpet, and light the gas with a spark from his finger. Glass and sealing-wax are, however, the most convenient means for investigating the electricity of friction. A glass rod when rubbed with a silk handkerchief becomes, as we have seen, highly electric, and will attract a pithball (fig. 2). Moreover, if we substitute the handkerchief for the rod it will also attract the ball (fig. 3). Clearly, then, the handkerchief which rubbed the rod as well as the rod itself is electrified. At first we might suppose that the handkerchief had merely rubbed off some of the electricity from the rod, but a little investigation will soon show that is not the case. If we allow the pithball to touch the glass rod it will steal some of the electricity on the rod, and we shall now find the ball REPELLED by the rod, as illustrated in figure 4. Then, if we withdraw the rod and bring forward the handkerchief, we shall find the ball ATTRACTED by it. Evidently, therefore, the electricity of the handkerchief is of a different kind from that of the rod. Again, if we allow the ball to touch the handkerchief and rub off some of its electricity, the ball will be REPELLED by the handkerchief and ATTRACTED by the rod. Thus we arrive at the conclusion that whereas the glass rod is charged with one kind of electricity, the handkerchief which rubbed it is charged with another kind, and, judging by their contrary effects on the charged ball or indicator, they are of opposite kinds. To distinguish the two sorts, one is called POSITIVE and the other NEGATIVE electricity. Further experiments with other substances will show that sometimes the rod is negative while the rubber is positive. Thus, if we rub the glass rod with cat's fur instead of silk, we shall find the glass negative and the fur positive. Again, if we rub a stick of sealing-wax with the silk handkerchief, we shall find the wax negative and the silk positive. But in every case one is the opposite of the other, and moreover, an equal quantity of both sorts of electricity is developed, one kind on the rod and the other on the rubber. Hence we conclude that EQUAL AND OPPOSITE QUANTITIES OF ELECTRICITY ARE SIMULTANEOUSLY DEVELOPED BY FRICTION. If any two of the following materials be rubbed together, that higher in the list becomes positively and the other negatively electrified:— POSITIVE (+). Cats' fur. NEGATIVE (-).The list shows that quality, as well as kind, of material affects the production of electricity. Thus polished glass when rubbed with silk is positive, whereas rough glass is negative. Cork at ordinary temperature is positive when rubbed with hot cork. Black silk is negative to white silk, and it has been observed that the best radiator and absorber of light and heat is the most negative. Black cloth, for instance, is a better radiator than white, hence in the Arctic regions, where the body is much warmer than the surrounding air, many wild animals get a white coat in winter, and in the tropics, where the sunshine is hotter than the body, the European dons a white suit. The experiments of figures 1, 2, and 3 have also shown us that when the pithball is charged with the positive electricity of the glass rod it is REPELLED by the like charge upon the rod, and ATTRACTED by the negative or unlike charge on the handkerchief. Again, when it is charged with the negative electricity of the handkerchief it is REPELLED by the like charge on the handkerchief and ATTRACTED by the positive or unlike charge on the rod. Therefore it is usual to say that LIKE ELECTRICITIES REPEL AND UNLIKE ELECTRICITIES ATTRACT EACH OTHER. We have said that all bodies yield electricity under the friction of dissimilar bodies; but this cannot be proved for every body by simply holding it in one hand and rubbing it with the excitor, as may be done in the case of glass. For instance, if we take a brass rod in the hand and apply the rubber vigorously, it will fail to attract the pithball, for there is no trace of electricity upon it. This is because the metal differs from the glass in another electrical property, and they must therefore be differently treated. Brass, in fact, is a conductor of electricity and glass is not. In other words, electricity is conducted or led away by brass, so that, as soon as it is generated by the friction, it flows through the hand and body of the experimenter, which are also conductors, and is lost in the ground. Glass on the other hand, is an INSULATOR, and the electricity remains on the surface of it. If, however, we attach a glass handle to the rod and hold it by that whilst rubbing it, the electricity cannot then escape to the earth, and the brass rod will attract the pith-ball. All bodies are conductors of electricity in some degree, but they vary so enormously in this respect that it has been found convenient to divide them into two extreme classes—conductors and insulators. These run into each other through an intermediate group, which are neither good conductors nor good insulators. The following are the chief examples of these classes:— CONDUCTORS.—All the metals, carbon. INTERMEDIATE (bad conductors and bad insulators).—Water, aqueous solutions, moist bodies; wood, cotton, hemp, and paper in any but a dry atmosphere; liquid acids, rarefied gases. INSULATORS.—Paraffin (solid or liquid), ozokerit, turpentine, silk, resin, sealing-wax or shellac, india-rubber, gutta-percha, ebonite, ivory, dry wood, dry glass or porcelain, mica, ice, air at ordinary pressures. It is remarkable that the best conductors of electricity, that is to say, the substances which offer least resistance to its passage, for instance the metals, are also the best conductors of heat, and that insulators made red hot become conductors. Air is an excellent insulator, and hence we are able to perform our experiments on frictional electricity in it. We can also run bare telegraph wires through it, by taking care to insulate them with glass or porcelain from the wooden poles which support them above the ground. Water, on the other hand, is a partial conductor, and a great enemy to the storage or conveyance of electricity, from its habit of soaking into porous metals, or depositing in a film of dew on the cold surfaces of insulators such as glass, porcelain, or ebonite. The remedy is to exclude it, or keep the insulators warm and dry, or coat them with shellac varnish, wax, or paraffin. Submarine telegraph wires running under the sea are usually insulated from the surrounding water by india-rubber or gutta-percha. The distinction between conductors and non-conductors or insulators was first observed by Stephen Gray, a pensioner of the Charter-house. Gray actually transmitted a charge of electricity along a pack-thread insulated with silk, to a distance of several hundred yards, and thus took an important step in the direction of the electric telegraph. It has since been found that FRICTIONAL ELECTRICITY APPEARS ONLY This is well shown by a device of Faraday resembling a small butterfly net insulated by a glass handle (fig. 5). If the net be charged it is found that the electrification is only outside, and if it be suddenly drawn outside in, as shown by the dotted line, the electrification is still found outside, proving that the charge has shifted from the inner to the outer surface. In the same way if a hollow conductor is charged with electricity, none is discoverable in the interior. Moreover, its distribution on the exterior is influenced by the shape of the outer surface. On a sphere or ball it is evenly distributed all round, but it accumulates on sharp edges or corners, and most of all on points, from which it is easily discharged. A neutral body can, as we have seen (fig. 4), be charged by Thus if we electrify a glass rod positively (+) and bring it near a neutral or unelectrified brass ball, insulated on a glass support, as in figure 6, we shall find the side of the ball next the rod no longer neutral but negatively electrified (-), and the side away from the rod positively electrified (+). If we take away the rod again the ball will return to its neutral or non-electric state, showing that the charge was temporarily induced by the presence of the electrified rod. Again, if, as in figure 7, we have two insulated balls touching each other, and bring the rod up, that nearest the rod will become negative and that farthest from it positive. It appears from these facts that electricity has the power of disturbing or decomposing the neutral state of a neighbouring conductor, and attracting the unlike while it repels the like induced charge. Hence, too, it is that the electrified amber or sealing-wax is able to attract a light straw or pithball. The effect supplies a simple way of developing a large amount of electricity from a small initial charge. For if in figure 6 the positive side of the ball be connected for a moment to earth by a conductor, its positive charge will escape, leaving the negative on the ball, and as there is no longer an equal positive charge to recombine with it when the exciting rod is withdrawn, it remains as a negative charge on the ball. Similarly, if we separate the two balls in figure 7, we gain two equal charges—one positive, the other negative. These processes have only to be repeated by a machine in order to develop very strong charges from a feeble source. Faraday saw that the intervening air played a part in this action at a distance, and proved conclusively that the value of the induction depended on the nature of the medium between the induced and the inducing charge. He showed, for example, that the induction through an intervening cake of sulphur is greater than through an equal thickness of air. This property of the medium is termed its INDUCTIVE CAPACITY. The Electrophorus, or carrier of electricity, is a simple device for developing and conveying a charge on the principle of induction. It consists, as shown in figure 8, of a metal plate B having an insulating handle of glass H, and a flat cake of resin or ebonite R. If the resin is laid on a table and briskly rubbed with cat's fur it becomes negatively electrified. The brass plate is then lifted by the handle and laid upon the cake. It touches the electrified surface at a few points, takes a minute charge from these by contact. The rest of it, however, is insulated from the resin by the air. In the main, therefore, the negative charge of the resin is free to induce an opposite or positive charge on the lower surface and a negative charge on the upper surface of the plate. By touching this upper surface with the finger, as shown in figure 8, the negative charge will escape through the body to the ground or "earth," as it is technically called, and the positive charge will remain on the plate. We can withdraw it by lifting the plate, and prove its existence by drawing a spark from it with the knuckle. The process can be repeated as long as the negative charge continues on the resin. These tiny sparks from the electrophorus, or the bigger discharges of an electrical machine, can be stored in a simple apparatus called a Leyden jar, which was discovered by accident. One day Cuneus, a pupil of Muschenbroeck, professor in the University of Leyden, was trying to charge some water in a glass bottle by connecting it with a chain to the sparkling knob of an electrical machine. Holding the bottle in one hand, he undid the chain with the other, and received a violent shock which cast the bottle on the floor. Muschenbroeck, eager to verify the phenomenon, repeated the experiment, with a still more lively and convincing result. His. nerves were shaken for two days, and he afterwards protested that he would not suffer another shock for the whole kingdom of France. The Leyden jar is illustrated in figure 9, and consists in general of a glass bottle partly coated inside and out with tinfoil F, and having a brass knob K connecting with its internal coat. When the charged plate or conductor of the electrophorus touches the knob the inner foil takes a positive charge, which induces a negative charge in the outer foil through the glass. The corresponding positive charge induced at the same time escapes through the hand to the ground or "earth." The inner coating is now positively and the outer coating negatively electrified, and these two opposite charges bind or hold each other by mutual attraction. The bottle will therefore continue charged for a long time; in short, until it is purposely discharged or the two electricities combine by leakage over the surface of the glass. To discharge the jar we need only connect the two foils by a conductor, and thus allow the separated charges to combine. This should be done by joining the OUTER to the INNER coat with a stout wire, or, better still, the discharging tongs T, as shown in the figure. Otherwise, if the tongs are first applied to the inner coat, the operator will receive the charge through his arms and chest in the manner of Cuneus and Muschenbroeck. Leyden jars can be connected together in "batteries," so as to give very powerful effects. One method is to join the inner coat of one to the outer coat of the next. This is known as connecting in "series," and gives a very long spark. Another method is to join the inner coat of one to the inner coat of the next, and similarly all the outer coats together. This is called connecting "in parallel," or quantity, and gives a big, but not a long spark. Of late years the principle of induction, which is the secret of the Leyden jar and electrophorus, has been applied in constructing "influence" machines for generating electricity. Perhaps the most effective of these is the Wimshurst, which we illustrate in figure 10, where PP are two circular glass plates which rotate in opposite directions on turning the handle. On the outer rim of each is cemented a row of radial slips of metal at equal intervals. The slips at opposite ends of a diameter are connected together twice during each revolution of the plates by wire brushes S, and collecting combs TT serve to charge the positive and negative conductors CC, which yield very powerful sparks at the knobs K above. The given theory of this machine may be open to question, but there can be no doubt of its wonderful performance. A small one produces a violent spark 8 or 10 inches long after a few turns of the handle. The electricity of friction is so unmanageable that it has not been applied in practice to any great extent. In 1753 Mr. Charles Morrison, of Greenock, published the first plan of an electric telegraph in the Scots Magazine, and proposed to charge an insulated wire at the near end so as to make it attract printed letters of the alphabet at the far end. Sir Francis Ronalds also invented a telegraph actuated by this kind of electricity, but neither of these came into use. Morrison, an obscure genius, was before his age, and Ronalds was politely informed by the Government of his day that "telegraphs of any kind were wholly unnecessary." Little instruments for lighting gas by means of the spark are, however, made, and the noxious fumes of chemical and lead works are condensed and laid by the discharge from the Wimshurst machine. The electricity shed in the air causes the dust and smoke to adhere by induction and settle in flakes upon the sides of the flues. Perhaps the old remark that "smuts" or "blacks" falling to the ground on a sultry day are a sign of thunder is traceable to a similar action. The most important practical result of the early experiments with frictional electricity was Benjamin Franklin's great discovery of the identity of lightning and the electric spark. One day in June, 1792, he went to the common at Philadelphia and flew a kite beneath a thundercloud, taking care to insulate his body from the cord. After a shower had wetted the string and made it a conductor, he was able to draw sparks from it with a key and to charge a Leyden jar. The man who had "robbed Jupiter of his thunderbolts" became celebrated throughout the world, and lightning rods or conductors for the protection of life and property were soon brought out. These, in their simplest form, are tapes or stranded wires of iron or copper attached to the walls of the building. The lower end of the conductor is soldered to a copper plate buried in the moist subsoil, or, if the ground is rather dry, in a pit containing coke. Sometimes it is merely soldered to the water mains of the house. The upper end rises above the highest chimney, turret, or spire of the edifice, and branches into points tipped with incorrosive metal, such as platinum. It is usual to connect all the outside metal of the house, such as the gutters and finials to the rod by means of soldered joints, so as to form one continuous metallic network or artery for the discharge. When a thundercloud charged with electricity passes over the ground, it induces a charge of an opposite kind upon it. The cloud and earth with air between are analogous to the charged foils of the Leyden jar separated by the glass. The two electricities of the jar, we know, attract each other, and if the insulating glass is too weak to hold them asunder, the spark will pierce it. Similarly, if the insulating air cannot resist the attraction between the thundercloud and the earth, it will be ruptured by a flash of lightning. The metal rod, however, tends to allow the two charges of the cloud and earth to combine quietly or to shunt the discharge past the house. CHAPTER II.THE ELECTRICITY OF CHEMISTRY.A more tractable kind of electricity than that of friction was discovered at the beginning of the present century. The story goes that some edible frogs were skinned to make a soup for Madame Galvani, wife of the professor of anatomy in the University of Bologna, who was in delicate health. As the frogs were lying in the laboratory of the professor they were observed to twitch each time a spark was drawn from an electrical machine that stood by. A similar twitching was also noticed when the limbs were hung by copper skewers from an iron rail. Galvani thought the spasms were due to electricity in the animal, and produced them at will by touching the nerve of a limb with a rod of zinc, and the muscle with a rod of copper in contact with the zinc. It was proved, however, by Alessanjra Volta, professor of physics in the University of Pavia, that the electricity was not in the animal but generated by the contact of the two dissimilar metals and the moisture of the flesh. Going a step further, in the year 1800 he invented a new source of electricity on this principle, which is known as "Volta's pile." It consists of plates or discs of zinc and copper separated by a wafer of cloth moistened with acidulated water. When the zinc and copper are joined externally by a wire, a CURRENT of electricity is found in the wire One pair of plates with the liquid between makes a "couple" or element; and two or more, built one above another in the same order of zinc, copper, zinc, copper, make the pile. The extreme zinc and copper plates, when joined by a wire, are found to deliver a current. This form of the voltaic, or, as it is sometimes called, galvanic battery, has given place to the "cell" shown in figure II, where the two plates Z C are immersed in acidulated water within the vessel, and connected outside by the wire W. The zinc plate has a positive and the copper a negative charge. The positive current flows from the zinc to the copper inside the cell and from the copper to the zinc outside the cell, as shown by the arrows. It thus makes a complete round, which is called the voltaic "circuit," and if the circuit is broken anywhere it will not flow at all. The positive electricity of the zinc appears to traverse the liquid to the copper, from which it flows through the wire to the zinc. The effect is that the end of the wire attached to the copper is positive (+), and called the positive "pole" or electrode, while the end attached to the zinc is negative (-), and called the negative pole or electrode. "A simple and easy way to avoid confusion as to the direction of the current, is to remember that the POSITIVE current flows FROM the COPPER TO the ZINC at the point of METALLIC contact." The generation of this current is accompanied by chemical action in the cell. Experiment shows that the mere CONTACT of dissimilar materials, such as copper and zinc, electrifies them—zinc being positive and copper negative; but contact alone does not yield a continuous current of electricity. When we plunge the two metals, still in contact, either directly or through a wire, into water preferably acidulated, a chemical action is set up, the water is decomposed, and the zinc is consumed. Water, as is well known, consists of oxygen and hydrogen. The oxygen combines with the zinc to form oxide of zinc, and the hydrogen is set free as gas at the surface of the copper plate. So long as this process goes on, that is to say, as long as there is zinc and water left, we get an electric current in the circuit. The existence of such a current may be proved by a very simple experiment. Place a penny above and a dime below the tip of the tongue, then bring their edges into contact, and you will feel an acid taste in the mouth. Figure 12 illustrates the supposed chemical action in the cell. On the left hand are the zinc and copper plates (Z C) disconnected in the liquid. The atoms of zinc are shown by small circles; the molecules of water, that is, oxygen, and hydrogen (H2O) by lozenges of unequal size. On the right hand the plates are connected by a wire outside the cell; the current starts, and the chemical action begins. An atom of zinc unites with an atom of oxygen, leaving two atoms of hydrogen thus set free to combine with another atom of oxygen, which in turn frees two atoms of hydrogen. This interchange of atoms goes on until the two atoms of hydrogen which are freed last abide on the surface of the copper. The "contact electricity" of the zinc and copper probably begins the process, and the chemical action keeps it up. Oxygen, being an "electro-negative" element in chemistry, is attracted to the zinc, and hydrogen, being "electro-positive," is attracted to the copper. The difference of electrical condition or "potential" between the plates by which the current is started has been called the electromotive force, or force which puts the electricity in motion. The obstruction or hindrance which the electricity overcomes in passing through its conductor is known as the RESISTANCE. Obviously the higher the electromotive force and the lower the resistance, the stronger will be the current in the conductor. Hence it is desirable to have a cell which will give a high electromotive force and a low internal resistance. Voltaic cells are grouped together in the mode of Leyden jars. Figure 13 shows how they are joined "in series," the zinc or negative pole of one being connected by wire to the copper or positive pole of the next. This arrangement multiplies alike the electromotive force and the resistance. The electromotive force of the battery is the sum of the electromotive forces of all the cells, and the resistance of the battery is the sum of the resistances of all the cells. High electromotive forces or "pressures" capable of overcoming high resistances outside the battery can be obtained in this way. Figure 14 shows how the zincs are joined "in parallel," the zinc or negative pole of one being connected by wire to the zinc or negative pole of the rest, and all the copper or positive poles together. This arrangement does not increase the electromotive force, but diminishes the resistance. In fact, the battery is equivalent to a single cell having plates equal in area to the total area of all the plates. Although unable to overcome a high resistance, it can produce a large volume or quantity of electricity. Numerous voltaic combinations and varieties of cell have been found out. In general, where-ever two metals in contact are placed in a liquid which acts with more chemical energy on one than on the other, as sulphuric acid does on zinc in preference to copper, there is a development of electricity. Readers may have seen how an iron fence post corrodes at its junction with the lead that fixes it in the stone. This decay is owing to the wet forming a voltaic couple with the two dissimilar metals and rusting the iron. In the following list of materials, when any two in contact are plunged in dilute acid, that which is higher in the order becomes the positive plate or negative pole to that which is lower:— POSITIVE Iron Silver There being no chemical union between the hydrogen and copper in the zinc and copper couple, that gas accumulates on the surface of the copper plate, or is liberated in bubbles. Now, hydrogen is positive compared with copper, hence they tend to oppose each other in the combination. The hydrogen diminishes the value of the copper, the current grows weaker, and the cell is said to "polarise." It follows that a simple water cell is not a good arrangement for the supply of a steady current. The Daniell cell is one of the best, and gives a very constant current. In this battery the copper plate is surrounded by a solution of sulphate of copper (Cu SO4), which the hydrogen decomposes, forming sulphuric acid (H2SO4), thus taking itself out of the way, and leaving pure copper (Cu) to be deposited as a fresh surface on the copper plate. A further improvement is made in the cell by surrounding the zinc plate with a solution of sulphate of zinc (Zn SO4), which is a good conductor. Now, when the oxide of zinc is formed by the oxygen uniting with the zinc, the free sulphuric acid combines with it, forming more sulphate of zinc, and maintaining the CONDUCTIVITY of the cell. It is only necessary to keep up the supply of zinc, water, and sulphate of copper to procure a steady current of electricity. The Daniell cell is constructed in various ways. In the earlier models the two plates with their solutions were separated by a porous jar or partition, which allowed the solutions to meet without mixing, and the current to pass. Sawdust moistened with the solutions is sometimes used for this porous separator, for instance, on board ships for laying submarine cables, where the rolling of the waves would blend the liquids. In the "gravity" Daniell the solutions are kept apart by their specific gravities, yet mingle by slow diffusion. Figure 15 illustrates this common type of cell, where Z is the zinc plate in a solution of sulphate of zinc, and C is the copper plate in a solution of sulphate of copper, fed by crystals of the "blue vitriol." The wires to connect the plates are shown at WW. It should be noticed that the zinc is cast like a wheel to expose a larger surface to oxidation, and to reduce the resistance of the cell, thus increasing the yield of current. The extent of surface is not so important in the case of the copper plate, which is not acted on, and in this case is merely a spiral of wire, helping to keep the solutions apart and the crystals down. The Daniell cell is much employed in telegraphy. The Bunsen cell consists of a zinc plate in sulphuric acid, and at carbon plate in nitric acid, with a porous separator between the liquids. During the action of the cell, hydrogen, which is liberated at the carbon plate, is removed by combining with the nitric acid. The Grove cell is a modification of the Bunsen, with platinum instead of carbon. The Smee cell is a zinc plate side by side with a "platinised" silver plate in dilute sulphuric acid. The silver is coated with rough platinum to increase the surface and help to dislodge the hydrogen as bubbles and keep it from polarising the cell. The Bunsen, Grove, and Smee batteries are, however, more used in the laboratory than elsewhere. The Leclanche is a fairly constant cell, which requires little attention. It "polarises" in action but soon regains its normal strength when allowed to rest, and hence it is useful for working electric bells and telephones. As shown in figure 16, it consists of a zinc rod with its connecting wire Z, and a carbon plate C with its binding screw, between two cakes M M of a mixture of black oxide of manganese, sulphur, and carbon, plunged in a solution of sal-ammoniac. The oxide of manganese relieves the carbon plate of its hydrogen. The strength of the solution is maintained by spare crystals of sal-ammoniac lying on the bottom of the cell, which is closed to prevent evaporation, but has a venthole for the escape of gas. The Bichromate of Potash cell polarises more than the Leclanche, but yields a more powerful current for a short time. It consists, as shown in figure 17, of a zinc plate Z between two carbon plates C C immersed in a solution of bichromate of potash, sulphuric acid (vitriol), and water. The zinc is always lifted out of the solution when the cell is not in use. The gas which collects in the carbons, and weakens the cell, can be set free by raising the plates out of the liquid when the cell is not wanted. Stirring the solution has a similar effect, and sometimes the constancy of the cell is maintained by a circulation of the liquid. In Fuller's bichromate cell the zinc is amalgamated with mercury, which is kept in a pool beside it by means of a porous pot. De la Rue's chloride of silver cell (fig. 18) is, from its constancy and small size, well adapted for medical and testing purposes. The "plates" are a little rod or pencil of zinc Z, and a strip or wire of silver S, coated with chloride of silver and sheathed in parchment paper. They are plunged in a solution of ammonium chloride A, contained in a glass phial or beaker, which is closed to suppress evaporation. A tray form of the cell is also made by laying a sheet of silver foil on the bottom of the shallow jar, and strewing it with dry chloride of silver, on which is laid a jelly to support the zinc plate. The jelly is prepared by mixing a solution of chloride of ammonium with "agar-agar," or Ceylon moss. This type permits the use of larger plates, and adapts the battery for lighting small electric lamps. Skrivanoff has modified the De la Rue cell by substituting a solution of caustic potash for the ammonium chloride, and his battery has been used for "star" lights, that is to say, the tiny electric lamps of the ballet. The Schanschieff battery, consisting of zinc and carbon plates in a solution of basic sulphate of mercury, is suitable for reading, mining, and other portable lamps. The Latimer Clark "standard" cell is used by electricians in testing, as a constant electromotive force. It consists of a pure zinc plate separated from a pool of mercury by a paste of mercurous proto-sulphate and saturated solution of sulphate of zinc. Platinum wires connect with the zinc and mercury and form the poles of the battery, and the mouth of the glass cell is plugged with solid paraffin. As it is apt to polarise, the cell must not be employed to yield a current, and otherwise much care should be taken of it. Dry cells are more cleanly and portable than wet, they require little or no attention, and are well suited for household or medical purposes. The zinc plate forms the vessel containing the carbon plate and chemical reagents. Figure 19 represents a section of the "E. C. C." variety, where Z is the zinc standing on an insulating sole I, and fitted with a connecting wire or terminal T (-), which is the negative pole. The carbon C is embedded in black paste M, chiefly composed of manganese dioxide, and has a binding screw or terminal T (+), which is the positive pole. The black paste is surrounded by a white paste Z, consisting mainly of lime and sal-ammoniac. There is a layer of silicate cotton S C above the paste, and the mouth is sealed with black pitch P, through which a waste-tube W T allows the gas to escape. The Hellesen dry cell is like the "E. C. C.," but contains a hollow carbon, and is packed with sawdust in a millboard case. The Leclanche-Barbier dry cell is a modification of the Leclanche wet cell, having a paste of sal-ammoniac instead of a solution. All the foregoing cells are called "primary," because they are generators of electricity. There are, however, batteries known as "secondary," which store the current as the Leyden jar stores up the discharge from an electrical machine. In the action of a primary cell, as we have seen, water is split into its constituent gases, oxygen and hydrogen. Moreover, it was discovered by Carlisle and Nicholson in the year 1800 that the current of a battery could decompose water in the outer part of the circuit. Their experiment is usually performed by the. apparatus shown in figure 20, which is termed a voltameter, and consists of a glass vessel V, containing water acidulated with a little sulphuric acid to render it a better conductor, and two glass test-tubes OH inverted over two platinum strips or electrodes, which rise up from the bottom of the vessel and are connected underneath it to wires from the positive and negative poles of the battery C Z. It will be understood that the current enters the water by the positive electrode, and leaves it by the negative electrode. When the power of the battery is sufficient the water in the vessel is decomposed, and oxygen being the negative element, collects at the positive foil or electrode, which is covered by the tube O. The hydrogen, on the other hand, being positive, collects at the negative foil under the tube H. These facts can be proved by dipping a red-hot wick or taper into the gas of the tube O and seeing it blaze in presence of the oxygen which feeds the combustion, then dipping the lighted taper into the gas of the tube H and watching it burn with the blue flame of hydrogen. The volume of gas at the CATHODE or negative electrode is always twice that at the ANODE or positive electrode, as it should be according to the known composition of water. Now, if we disconnect the battery and join the two platinum electrodes of the voltameter by a wire, we shall find a current flowing out of the voltameter as though it were a battery, but in the reverse direction to the original current which decomposed the water. This "secondary" or reacting current is evidently due to the polarisation of the foils—that is to say, the electro- positive and electro-negative gases collected on them. Professor Groves constructed a gas battery on this principle, the plates being of platinum and the two gases surrounding them oxygen and hydrogen, but the most useful development of it is the accumulator or storage battery. The first practicable secondary battery of Gaston Plante was made of sheet lead plates or electrodes, kept apart by linen cloth soaked in dilute sulphuric acid, after the manner of Volta's pile. It was "charged" by connecting the plates to a primary battery, and peroxide of lead (PbO2) was formed on one plate and spongy lead (Pb) on the other. When the charging current was cut off the peroxide plate became the positive and the spongy plate the negative pole of the secondary cell. Faure improved the Plante cell by adding a paste of red lead or minium (Pb204) and dilute sulphuric acid (H2SO4), by which a large quantity of peroxide and spongy lead could be formed on the plates. Sellon and Volckmar increased its efficiency by putting the paste into holes cast in the lead. The "E. P. S." accumulator of the Electrical Power Storage Company is illustrated in figure 21, and consists of a glass or teak box containing two sets of leaden grids perforated with holes, which are primed with the paste and steeped in dilute sulphuric acid. Alternate grids are joined to the poles of a charging battery or generator, those connected to the positive pole being converted into peroxide of lead and the others into spongy lead. The terminal of the peroxide plates, being the positive pole of the accumulator, is painted red, and that of the spongy plates or negative pole black. Accumulators of this kind are highly useful as reservoirs of electricity for maintaining the electric light, or working electric motors in tramcars, boats, and other carriages. |