SOME INTERESTING FACTS ABOUT EXPLOSIVES

An explosive material consists of a combustible and of an oxidizing agent for burning the combustible. Hence it contains within its own substance the necessary oxygen for its combustion, so that it will burn without atmospheric air and therefore in a confined space.

There are two main kinds of explosive materials—high explosives and gunpowder. There are also two main kinds of high explosives—dynamites and military high explosives. Lastly there are two main kinds of gunpowders—black, smoky gunpowder and smokeless gunpowder.

Dynamite is used mostly for commercial blasting purposes, such as blasting rock in the construction of railways, and so forth. Military high explosives are mostly employed for submarine mines, warheads for torpedoes, and as bursting charges for high explosive projectiles.

A high explosive is consumed almost instantly by what is called a detonative wave; hence it is said to detonate. When gunpowder explodes, it is not consumed by a detonative wave, but burns from the surface, and the more strongly it is confined, that is to say, the higher the pressure under which it is burned, the more rapid is its combustion. Although the action is rapid, it is yet much slower than is the action of detonation of high explosives.

The name gunpowder is a misnomer, for gunpowder is no longer a powder, but is made in the form of hard and dense grains or sticks, according to the use for which it is intended.

A gunpowder is smoky when its products of combustion are not all gaseous. Only about forty-four per cent. of the products of combustion of black gunpowder is gaseous. The rest is inert solid matter, which makes the smoke.

The products of combustion of smokeless powder, however, are practically all gaseous. Consequently, weight for weight, it is much more powerful than black powder.

Black gunpowder is a mechanical mixture of charcoal, sulphur and saltpeter, the charcoal and sulphur being the combustible elements, and the saltpeter the oxidizing element or the element that supplies the oxygen.

In smokeless powder the oxygen is held in chemical union with nitrogen and hydrogen, but the bond between the nitrogen and the other elements is weak, so that when ignited the other more active elements are enabled easily to unite at the expense of the nitrogen.

In the combustion of all explosive materials, great heat is generated, and the force of the explosion is dependent upon the volume of gases and the high temperature to which they are raised.

The smokeless powder used in the United States is made by dissolving a special kind of guncotton or nitrocellulose in ether and alcohol, just sufficient of the solvent being used to gelatinate the nitrocellulose, which is then stuffed through a forming die into rods. The rods are cut into sections of about three diameters long. The die, the invention of the writer, contains seven mandrels arranged in such wise that when the material is forced through the die the bar is multi-perforated with seven holes at equal distances apart. The grains or rods of smokeless powder are then dried for use.

When burned in a cannon, all of the surfaces of the material are practically instantly ignited by a small flash charge of black rifle powder used for the purpose of setting fire to the charge of smokeless powder. The combustion in the perforations causes them to become larger and larger until the grain is all consumed. This form of grain tends better to maintain the pressure behind the projectile in its flight through the gun, and enables the use of larger charges of powder with lower pressures than could otherwise be employed. In fact, it would be impossible to use a smokeless powder made of pure nitrocellulose in big guns without the multi-perforations.

In certain European countries where the multi-perforated powder has not been adopted, nitroglycerin is employed, combined with the nitrocellulose, which causes the material to burn through a greater thickness in a given time. Thus a smokeless powder may be made without the multi-perforations, but smokeless powders containing nitroglycerin erode the guns and destroy them very quickly, while guns employing pure nitrocellulose smokeless powders last much longer.

When one of our big army or navy cannon is fired, the time which elapses from the instant of complete ignition of the powder charge to the instant that the projectile leaves the muzzle of the gun is about the fiftieth or the sixtieth of a second, and in that time the hard and horn-like smokeless powder material is burned through only about a sixteenth of an inch; hence the rate of combustion or rate of explosion of smokeless powder in a cannon is about four inches per second, while it has been ascertained by actual experiments that the rate of combustion or rate of explosion of dynamite and other high explosives is about four miles per second, so that the rate of consumption of smokeless powder, as compared to that of a high explosive, is as are four inches to four miles.

As the time required for the projectile to be thrown from a twelve-inch cannon is only about the sixtieth of a second, sixty of these huge guns could be placed side by side and fired by electricity one after the other, while grandfather’s clock is making but one tick.

Our ideas of duration are but relative. We have seen that the combustion in a cannon, though very rapid to our senses, is actually very slow indeed as compared with the much more rapid combustion of a high explosive; and great as is the speed of the detonative wave, yet the speed of the earth in its orbit is four times as great.

If a celestial giant with a huge dynamite bomb the size of the earth itself were to approach the earth in its flight through space, and detonate the bomb immediately behind the earth, it would take half an hour for the bomb to explode, that is to say, it would take half an hour, or thirty minutes, for the explosive wave to pass through the eight thousand miles of its diameter. As the speed of the earth in its orbit is four times as great as that of the explosive wave, the earth would rush away, leaving the bomb about thirty thousand miles behind by the time it had completely exploded. If the interstellar ether were a high explosive mixture and were to be set off by the bomb, the earth would pass on clear around the sun, and while coming back, about six months later, would meet the explosive wave still going. It would require nearly a year for such a detonative wave to reach our sun from the earth.

We have seen that if the earth were a ball of dynamite, it would require half an hour to explode. If the sun were a mass of dynamite it would require about two and a half days to explode.

We frequently hear the theory advanced that planets and suns sometimes explode from pent-up forces within them, and that our earth might possibly blow up. Now, the force exerted by a high explosive is dependent entirely upon the pressure capable of being exerted by the gases liberated by the explosion. The pressure exerted by the most powerful high explosives has been estimated to be about 500,000 pounds to the square inch. Consequently, were the whole molten interior of the earth to be replaced with dynamite and detonated, the explosion that would follow would not lift the earth’s crust. The superincumbent weight of the earth’s crust is greater than would be the pressure exerted by the dynamite.

If it were possible to throw a projectile from the earth to the nearest fixed star, Alpha Centauri, it would take about four years for the light of the flash to reach that star. The sound, if it could travel through ether, would reach there about four million years later. The projectile, traveling more than twice as fast as sound, would reach there in about two million years.

When one of our big twelve-inch cannon is fired, the projectile, weighing a thousand pounds, has a muzzle energy, stated in mechanical terms, of about 50,000 foot tons, that is to say, its energy is equal to 50,000 tons falling from a height of one foot—energy enough to lift two 25,000-ton battleships to the height of a foot.

As the projectile weighs half a ton, the energy is equal to that which would be developed by dropping the projectile from a height of more than twenty miles, making no account of the resistance of the atmosphere.

Dropping upon a piece of armorplate too hard and thick for the projectile to penetrate, the heat developed would be sufficient to melt 750 pounds of cast iron.

When one of these projectiles is fired from the gun directly against twelve-inch armorplate, which the projectile is capable of penetrating, the hard-tempered steel plate in front of the projectile is fuzed or rendered plastic from the heat generated by the energy of the impact, and is forced like wax from the path of the projectile.

There are many popular errors regarding the action of explosive materials. One of the most notable is the opinion that the action of dynamite is downward, and that if a body of high explosive be detonated on the surface of the earth the main effect is downward.

The exact opposite is the truth. When a mass of explosive is detonated, it is converted practically instantly into a ball of incandescent gases and vapors under very high pressure. When confined the gases act to disrupt their container.

When a large steel projectile is charged with a high explosive, like picric acid, and the explosive detonated, the walls of the projectile are not only broken but they are also torn, twisted and shredded, and so quick is the action that the inner surface of the metal is compressed and densified against the outer metal.

For this reason it is easy to tell from the character of the fragments of a projectile whether or not a high explosive or an explosive of inferior power was employed, that is to say, whether or not the explosion was of high order or of low order.

There is one false belief about the action of high explosives that has been about the hardest of any to kill, and the cost of killing it has been very expensive. Furthermore, it possesses more lives than the proverbial nine-lived cat. This belief is that five hundred pounds or so of dynamite exploded upon a warship or upon coast fortifications would destroy ship or fortifications, and that a few of such large bombs of dynamite dropped in a city would lay the city in ruins.

Upon the advent of the aeroplane and the dirigible balloon, it was confidently believed that the aerial bomb would quickly become the most destructive implement of warfare. It was prophesied that should war come between England and Germany, London would soon be reduced to a heap of ruins by bombs dropped from the German Zeppelins.

Several years before the European War broke out, I predicted that Zeppelin bombs would not and could not by any possibility work very wide destruction, and events have since vindicated my prediction. I pointed out the fact that should a hundred Zeppelins visit the city of London, once a day, for a year, returning to their base without mishap, and each Zeppelin succeed in destroying two buildings, the destruction would just about keep up with the growth of that city, for they build in London sixty thousand houses a year.

We all remember the destructive powers that were predicted for the fifteen-inch Zalinski pneumatic dynamite guns that were mounted at Sandy Hook and at San Francisco at enormous Government expense. These guns were capable of throwing with compressed air about six hundred pounds of nitrogelatin to a distance of from a mile-and-a-half to two miles. It was popularly believed that one of these bombs striking upon a huge armorclad warship would utterly destroy it.

Also two of these guns were mounted in a sort of cruiser called the Vesuvius. During the Spanish War the Vesuvius was taken down to Cuba, and in one action several of the huge bombs were thrown upon the earthworks and fortifications of the Spanish. They succeeded merely in mussing up the green, grassy effect. They did no material damage, for the reason that the action of the explosive was nearly all upward into the air.

When the pneumatic dynamite gun was promulgated, it was popularly believed that all high explosives were exceedingly sensitive, and that it was necessary to get them out of the gun very gently if they were to be thrown from ordnance.

The writer was the first to dispel this folly, through the invention of Maximite, a high explosive which will stand not only the shock of being fired from heavy guns at high velocities, but which will also, without exploding, stand the far greater shock of penetrating the heaviest armorplate—armorplate as heavy as the projectile will stand to pass through without breaking up.

While I was working upon Maximite and trying to get the Government to adopt it, Congress appropriated the money for building an eighteen-inch gun for testing a shell invented by Louis Gathmann, which was intended to destroy battleships by exploding the shell on the outside of their heavy armorplate, it being believed that if five hundred pounds of guncotton were to be fired against the side of an armored ship and exploded, the whole side of the ship would be blown in and the vessel destroyed.

The gun employed by Gathmann was essentially the same type of gun as that previously designed by me, and explained in a lecture by me before the Royal United Service Institution of Great Britain in 1897, and illustrated in a book of mine published the same year by Eyre & Spottiswoode, British Government printers, except that the bore of my gun, which was of the same weight as that of the Gathmann gun, was greater. With my gun, however, I proposed to throw armor-piercing projectiles, or projectiles capable of penetrating an object struck and exploding inside of it. I did not believe that a quantity of high explosive that could be thrown in a shell and exploded on the outside of a heavily armored ship would destroy it, but believed it necessary that the explosive should penetrate and explode inside the ship, and within earthworks and fortifications in order to destroy them.

Maximite was adopted by the United States Army in 1901. It was during that same year that the experiments were conducted with the Gathmann shell at Sandy Hook. I attended those experiments.

Two Kruppized armorplates, each eleven-and-a-half inches thick, sixteen feet long, and seven-and-a-half feet wide, and each weighing 47,000 pounds, were set up, one as a target for the Gathmann shell and the other as a target for the regular United States twelve-inch Army Rifle. Each of the plates was backed by supports to represent the same strength as though mounted on a battleship.

The Gathmann shell weighed about eighteen hundred pounds, and carried about five hundred pounds of guncotton, while the Government twelve-inch shell weighed a thousand pounds and carried only twenty-three pounds of Maximite. The Gathmann shell had a soft nose, which collapsed on the plate at the instant before the explosion of the shell, so that the guncotton might explode fairly against the side of the plate.

At the first shot of the Gathmann gun, the projectile struck the plate squarely and exploded, but the only effect upon the plate was to leave a great yellow smudge on its face. The plate was neither cracked nor pushed back. Several more shots of the Gathmann gun were fired, and although, under the heavy pummeling, the plate was pushed back and broken through, up and down, it was not otherwise injured.

Then the Government twelve-inch gun was fired at the other plate. The first shell contained nineteen pounds of high explosive, and it passed through the plate, leaving a clean round hole, and exploded behind the plate without breaking it. The next shell contained twenty-three pounds of Maximite, and the fuze was timed to go off a little quicker. This shell exploded in the plate when about two-thirds through, with the result that a hole was blown in the plate as big as a barrel, and the plate shattered into fragments.

One would think that these tests would suffice forever to seal the doom of the Gathmann type of shell. Nevertheless, it matters not what Army and Navy officers may learn by experience, or know without experience, Congress does not know and does not understand, and depends far more upon think-so than upon experience. The result is that Government officers are often compelled, as in the case of the Zalinski dynamite gun and the Gathmann shell, to waste large sums of money while they know very well beforehand exactly what the results will be, and that the tests will prove the devices to be abject failures. Even after the failure of the Gathmann shell, another shell of almost identical conception and purpose was made and tested under a Congressional appropriation, to be relegated to the scrap-heap of failures.

It is very fortunate that things happen to be as they are in the cosmos and that the action of a high explosive when exploding against a massive body is to rebound from that body on the line of least resistance. It is for this reason that more damage is not done by great explosions.

One of the biggest explosions in the history of gunpowder manufacture occurred at Pleasant Prairie, Wisconsin, on the 9th of March, 1911, when it was estimated that a thousand tons of black blasting powder blew up. Glass was broken over a very wide area. Some glass was broken in Chicago, about fifty miles distant.

But neither the walls nor the foundations of buildings were greatly disturbed even but a few miles from the explosion. In the village of Pleasant Prairie, at a distance of but two miles, although the buildings were very much damaged the inhabitants continued to occupy them.

Early in the morning of July 30, 1916, a very large quantity, certainly several hundred tons, of high explosive materials blew up in New York Harbor, not far from Ellis Island. A large quantity of shrapnel ammunition and other ammunition went up in the blast, their fragments raining all over the surrounding water. There was but very little loss of life, and the actual material damage to buildings in Jersey City, Manhattan and Brooklyn was astonishingly small, except the loss from broken glass.

Why is it, then, that so much glass is broken and at such long distances, while the foundations and walls of buildings suffer but little injury? Let me explain. When a quantity of high explosive detonates, a wave of atmospheric compression is sent outward in all directions by the explosion. It is, in fact, a huge sound wave, and moves exactly at the speed of sound—about eleven hundred feet per second. Of course, buildings or other structures or objects near enough to the explosion to be struck by the expanding gases themselves, or by the atmosphere immediately propelled forward by them like a projectile, may be destroyed, but the area over which this action occurs is so circumscribed that no great damage is apt to result at distances beyond a few hundred feet.

However, the great sound wave may travel to a distance of many miles. Consequently, as a result of the explosion just referred to, about a million dollars’ worth of glass was broken in New York City alone. One would naturally suppose that the fragments of window glass broken in this manner would fall inside a building, but they do not. Almost always they fall outside into the street. The reason for this is that the wave of compression, striking a pane of glass, forces it inward nigh to the breaking point, and then as the wave of compression moves on, followed by a partial vacuum, the glass, springing outward to fill the void, breaks, and falls into the street.

An interesting incident of this great explosion was staged at Ellis Island. There were a goodly number of immigrants on the Island at the time, congregated from the four corners of the earth, some of whom had come to America to seek their fortunes in this land of freedom-from-everything-except-freedom, but many had come to find quiet and security from war’s alarums. Few of them, indeed, had ever felt the comfort of an overcoat, but many had dreamed of some happy day when they would sport a veritable fur-lined overcoat.

When the great explosion came it sounded like the crack of doom, and most of the immigrants believed it to be the real thing and proceeded with agitated precipitation to get their souls ready for rapid transit over the Great Divide.

All eyes naturally were averted to the celestial concave, aglare with the great conflagration, when suddenly, to the confounding amaze of all, a large flock of fur-lined overcoats began tumbling down out of the heavens all over the Island. It is true they were lined merely with sheep’s fur, but even such a garment is as much the pride of the Northern European peasant as is the broad, glad-colored sombrero the pride of the Mexican peon.

As the Government statute books and rules and regulations governing immigrants contain no provision for the disposal of such species of manna as heaven-sent overcoats, the immigrants were the beneficiaries.

Great as are such explosions as that at Pleasant Prairie and that in New York Harbor, they are but little things indeed compared with the explosions that sometimes accompany volcanic eruptions. Mother Earth is the greatest of all explosive manufacturers.

Water seeping down into the earth’s crust and trapped in large quantities in the neighborhood of volcanoes sometimes becomes heated to high incandescence—heated until it is no longer water or steam, but mingled oxygen and hydrogen, far above the temperature of their dissociation—under a pressure so great that they occupy a space no larger than the original water; consequently the entrapped waters exert a pressure as great as the strongest dynamite.

The most notable volcanic explosion that ever occurred in historic time was when that old extinct volcano, Krakatoa, in the Straits of Sunda, that had been sleeping for thousands of years, was literally blown into the sky by the pressure of the pent-up gases beneath it.

This great eruption occurred in 1883. More than sixty thousand persons were killed. The captain of a tramp steamer, who happened to be passing in the vicinity of Krakatoa at a distance of some miles, a short time before the explosion occurred, saw a very strange disturbance in the sea in the direction of the old mountain. Taking his glass he saw a perfect Niagara of water pouring into an enormous fissure that had opened in the earth. He was struck with consternation and rightly imagining that something very serious was likely soon to happen, he put on all steam to escape, and luckily he had reached a point which enabled him to survive the effects of the awful blast when it came.

The vast mass of water which had tumbled into the bowels of the earth was immediately trapped by the closing of the great fissure down which it had poured. The water was quickly converted by the intense heat into a veritable high explosive, with the result that the massive mountain was literally blown bodily skyward, and fell in huge fragments into the surrounding sea. The shock was so great that it was felt clear through the earth, and an immense tidal wave was set going which encircled the earth. The opposing portions of the great wave, meeting in the lower Atlantic, flowed up even to the coast of France. An atmospheric wave passed around the earth three times. It is estimated that the amount of volcanic mud that was discharged from the mountain during the eruption was more than the muddy Mississippi discharges into the Gulf of Mexico in two hundred years.

There was so much impalpably fine volcanic dust blown into the upper atmosphere that it did not entirely settle out of the air for more than two years, which period was noted for its beautiful glowing sunsets, due to the illumination of the fine dust suspended in the upper air.

As the ax is to the woodsman, so are high explosives to the engineer. With dynamite he hews down the hills, fills the valleys and tunnels the mountain-range to make a straight and even way for the locomotive. He cuts canals through the width of the land, uniting rivers and seas.

Always in the van of civilization, there is heard the churn of the rock-drill and the echoing crash and roar of the dynamite blast.

Also it is the huge high explosive shell that makes way for the march of modern armies, and high explosive mines and torpedoes are the terror of the underseas.

All forms of dynamite are high explosives, and all high explosives may fairly be called dynamite.

Smokeless gunpowder is actually but a modified form of high explosive. It is dynamite that has been chained and tamed by the chemist’s cunning, so that it will burn without detonation, and thus permit the utilization of its awful energy to hurl shot and shell from war’s great guns.

Thus it is that dynamite in its varied forms deserves the high place with steam and electricity as one of the great triumvirs that have been the architects of the modern world.