CHAPTER XVII |
intensity of light transmitted | I | ||
Transparency = T = | | = | |
intensity of incident light | IO |
intensity of incident light | IO | 1 | |||
Opacity = O = | | = | | = | |
intensity of transmitted light | I | T |
Hurter and Driffield pointed out that a negative would give a true representation of the differences in the light and shade of the object if it reproduced these differences by equivalent differences in opacity. This is equivalent to stating that if the densities are plotted against the logarithms of the corresponding exposures, a straight line should be obtained at 45 degrees to the axis of exposure times. If the line is at another angle the opacities of the negative will be proportional to the brightness of the object photographed, but the contrast will be different.
A typical H & D plot is shown in Fig. 103. It will be noted that two curves are shown. These are obtained with different developments, and illustrate the fact that the contrast or proportionality between exposure differences and opacity differences is a matter of time of development. Each of these curves exhibits certain characteristics which are common to all made in this way. There is primarily a straight line portion, where opacities are proportional to illumination. This is commonly called the region of correct exposure. The slope of this straight line portion—the ratio of density
log exposure—is the development factor, commonly denoted by “?,” a gamma of unity denoting exact tone rendering. Below the region of correct exposure is a “toe,” or region of smaller contrast, called the region of under exposure. Above the correct exposure region is another where the opacity approaches constancy (afterwards decreasing or “reversing”), called the region of over exposure.
The speed of a plate on the H & D scale is given by the intersection of the straight line portion of the characteristic curve when produced, with the exposure axis. This intersection
If a plate is developed until no more density and contrast can be obtained, its development factor is then ?8, (gamma infinity), and the larger this is the more a plate can be forced in development. If the plate fogs in its unexposed portions this fog is measured and recorded in density units along with the other constants. The speed of development is represented by the velocity constant, commonly symbolized by ?.
Fig. 103.—Typical characteristic curves of photographic plate.
The length of the straight line portion determines the latitude of the plate, or the range of permissible exposures to secure a “perfect negative.” Thus if we assume that an
30 or 4. That is, the exposure could be as much as four times the necessary one, and still give the same result on a sufficiently exposed print. If the latitude of the plate is too small, the shadows will fall in the under exposure region, the high-lights in the over exposure portion of the characteristic curve, with consequent poor rendering of contrasts.
Criteria of Speed.—In airplane photography speed is of paramount importance, but great care must be exercised to insure that all the factors are considered which can contribute toward yielding the desirable pictorial quality in the brief exposure which alone is possible from the moving plane. A “fast” plate on the H & D scale is not necessarily suitable for aerial work, when we remember that accentuation of natural contrast is desirable, particularly under hazy conditions. For, as is shown in Fig. 104, it is a common characteristic of “fast” plates to have comparatively small latitude and low contrast at their maximum development.
It is to be noted that the Hurter and Driffield measure of speed is bound up with the idea of correct tone rendering and with the use of the straight line portion of the characteristic curve. Other criteria of speed exist. For instance, the exposure necessary to produce a just noticeable action (threshold value); and the exposure necessary to give a chosen useful density in the high-lights when development is pushed to the limit set by the growth of fog.
As has already been pointed out, correct tone rendering is not necessary or even indicated as desirable in aerial views. It is, moreover, a matter of experience that the majority of aerial exposures with existing plates fall in the “under exposure” period, where contrasts with normal development are less than in the subject. This being the case, the problem
Fig. 104.—Characteristic curves of fast and slow plates, developed to maximum contrast.
In addition to its capacity for developing density, the plate should have as low a threshold as possible, thus meeting to some extent the requirements of both the alternative criteria of speed given above. At the same time it is true that low threshold and good density for short exposures are not to be found in really slow plates. Consequently, while high speed, as ordinarily understood, is undoubtedly the first requirement, we may expect the complete specification for the best aerial plate to be a rather complicated thing, describing the characteristics of a workable “toe” of the curve, in terms of which several (e.g., contrast and speed) are derived from another and quite different exposure region.
Effect of Temperature on Plate Speed.—It has been found by Abney and Dewar that very low temperatures materially decrease the speed of photographic emulsions. This decrease may amount to as much as 50 per cent. in the temperature range from 30 degrees Centigrade above zero to 30 degrees below zero, which is the range over which aerial photographic operations will have to be carried on in war-time. This effect has not been at all fully studied, and it is not known whether it is general or only found in certain kinds of plates. The remedy indicated is to provide means for heating the plates or films when low temperatures are encountered. This is fairly easy in film cameras, or in plate cameras like the deRam, where the entire load of plates is carried in the camera body. Plates carried in magazines present a more difficult problem. The heating coil incorporated in the German cameras is perhaps partly for this purpose.
Roughly, two general types of color sensitive emulsions may be distinguished: first, those in which sensitiveness to green and yellow is added to the natural blue sensitiveness, and second, those sensitive in a useful degree to all colors of the spectrum. The former are called iso- or ortho-chromatic, the latter panchromatic emulsions. Spectrograms exhibiting the distribution of sensitiveness throughout the spectrum for several representative plates are shown in Fig. 105. Orthochromatic plates are adequate for use with light yellow filters and have the slight practical working advantage that they can be handled by red light. Panchromatic plates are necessary for use with dark orange or red filters. They must be handled in total darkness or in an exceedingly faint blue-green light, taking advantage of the common drop in sensibility
Fig. 105.—Spectrograms of representative photographic plates: a, ordinary plate; b, orthochromatic plate; c, specially green-sensitive plate; d, red sensitive plate, insensitive to green; e, panchromatic plate; f, specially red-sensitive panchromatic plate.
A rougher idea of color sensitiveness than is given by spectrograms is furnished by the tri-color ratio, which is the ratio of exposure times necessary with white light to give equal photographic action through a certain set of red, green and blue filters, expressed in terms of the blue exposure as unity. In an excellent panchromatic plate the three exposures would be equal. In an orthochromatic plate the red exposure will be too large to be figured. In interpreting either spectrograms or tri-color ratios care must be taken that the absolute exposures necessary are known. Thus a relatively high red sensitiveness may mean merely low absolute blue sensitiveness.
Two methods are used in imparting color sensitiveness. Either the sensitizing dye is incorporated in the plate emulsion before it is flowed; or the plate is bathed in a dye solution not long before using. The latter method gives higher color sensitiveness but poorer keeping quality, and is not a practical method for field operations. Greatly enhanced sensibility may be given by treatment with ammonia, but this again is a method for laboratory rather than field use.
Resolving Power.—A question which arises in connection with all photography of detail is the size of the grain of the photographic emulsion. Dependent on the size of the grain is the resolving power, or ability to separate images of closely adjacent objects. This varies with the speed, fast plates being of coarser grain than slow ones; with the exposure; and with the method and time of development. In general, it
Emulsion. | Resolving Power. |
---|---|
Seed Graflex | 25 |
Eastman Aerial Film | 37 |
Hammer Ortho | 44 |
Cramer Isonon | 48 |
Cramer Spectrum Process | 57 |
Eastman Portrait Film | 61 |
Tabulation of Requirements for Aerial Emulsions.—In terms of the sensitometric quantities just discussed the general requirements for aerial plates may be listed as follows:
1. Speed. The speed usually connected with the contrast and density required for the exposure times available is about 150 H & D. Faster plates in general have too low contrast, but the highest speed that will give the necessary contrast is desired.
2. Contrast. The contrast capable of development without fog should be from 1.5 to 2. This contrast should be produced by light of daylight quality, and, in orthochromatic and panchromatic plates, with the yellow or orange filters intended to be used with them. This contrast means a gamma infinity approaching 2.5.
3. Speed of development. A gamma of nearly 2 should be developed in 2½ minutes at 20 degrees C. in the developers recommended below.
5. Color sensitiveness. This should in general be as high as possible. In terms of certain representative filters (described in a subsequent chapter) color sensitiveness should be such that with the white light speed above specified the relative exposures through the filters shall not be greater than as follows:
No filter | Aero 1 | Aero 2 | #21 | #23a | #25 | |
---|---|---|---|---|---|---|
Panchromatic plate | 1 | 3 | 4.5 | 7 | 9 | 12 |
Ortho plate | 1 | 2.5 | 3.5 | 6 |
Relative Behavior of Plates and Films.—The advantages of film from the standpoint of weight and bulk have been discussed in connection with aerial cameras. Were there no other considerations film would unquestionably be the most appropriate medium for aerial photography. There is, however, the question of ease of handling, to be treated in a subsequent chapter, and the question whether the purely photographic characteristics of film are satisfactory. Can the same speed, contrast, and color sensitiveness be obtained on film as on glass? Is the picture so obtained as permanent or reliable as the plate image?
It must be confessed that up to the present emulsions on film have not proved the equal of those on glass. It has been found by emulsion manufacturers that the same emulsion flowed on film and on glass gives better quality on the glass. Emulsions specially prepared for film fall somewhat short of the best plate emulsions. It has also been found harder to color-sensitize film, and to insure good keeping quality in the color sensitized product.
In addition to the question of photographic quality there arises the matter of shrinkage and distortion. These are negligible with plates, but are a more or less unknown quantity in film. Irregular shrinkages of as much as two per cent.
Positype Paper.—The need sometimes arises in military operations to secure prints ready for examination within a few minutes after the receipt of the negatives. Even the 15 or 20 minutes within which a negative can be developed and a wet print taken may be considered too long. While such occasions are probably more apt to occur in popular magazine stories than in actual warfare, it is important to have available methods of producing prints with an absolute minimum of delay. This need is met to some degree by a direct print process, commercially exploited under the name of “Positype.”
In this process the exposure is made directly on a sensitized paper or card, which is developed, the image dissolved out, the residue exposed, and again developed; thus furnishing a positive picture (reversed right and left). The time necessary to develop a print ready for examination need not be more than three minutes. Only a single print is available, but this is all that would be called for under the extreme conditions suggested. If later, copies are desired they may be made by the same process.
Plates and Films Found Satisfactory for Aerial Work.—The following plates and films have been found particularly good for aerial photography. The list is not intended to be complete. Furthermore, it may be expected to be soon superseded, as the efforts of various manufacturers are directed toward developing special aerial photographic plates.
Among orthochromatic plates: The Cramer Commercial Isonon, the Jougla Ortho.
Among panchromatic plates: The Ilford Special Panchromatic, the Cramer Spectrum Process.
Film: Ansco Speedex, Eastman Aero.
CHAPTER XIX
FILTERS
The Function of Filters in Aerial Photography.—The use of color screens or filters has been very common in ordinary landscape photography, for the purpose of securing approximately correct renderings of the brightnesses of colored objects. Plates of the non-color-sensitive type have their maximum of sensitiveness in the blue of the spectrum (Fig. 105) and in consequence blue skies photograph as white, while other colors are likewise reproduced on a totally wrong scale. Filters for correct brightness rendering are calculated for a given color sensitive plate so that the resultant reaction to the light of the spectrum copies the sensitiveness of the eye, which is greatest in the yellow-green. Such filters for use with the common orthochromatic plates are of a general yellow color.
Filters for aerial work are meant to serve quite a different purpose. Correct tone or color rendering is of quite secondary importance to another use of filters, namely, to cut or pierce aerial haze. It is quite a matter of accident that the same general color of filter is called for both to give correct color rendering and to pierce aerial haze, namely, yellow. Yet on closer analysis it is found that quite different types of yellow filter are demanded, spectroscopically considered.
Figure 106 (K1 and K2) shows the spectral transmission curves of the Wratten K1 and K2 filters, intended for correct color rendering with orthochromatic plates. The absorption increases gradually toward the blue. In the same figure is shown on an arbitrary scale the spectroscopic character of typical haze illumination, increasing in brightness inversely
Fig. 106.—Characteristics of various filters.
Practical Filters.—Since the character of the absorption of the “K” filters is not all that could be desired, new filters, both of dyed gelatin and of glass, have been produced. The glass, a Corning product having a very sharp-cut absorption, has not yet been produced on a commercial scale with the high transparency in green, yellow and red that selected samples have shown. The United States Air Service has adopted filters of a new dye, called the EK, from the name of the company in whose laboratory it was produced. These filters are standardized in two depths of staining, called the “Aero No. 1” and “Aero No. 2.” Their spectral transmission curves appear in Fig. 106, along with those of certain darker filters useful only with panchromatic plates for exceptionally heavy haze. The characteristic of these Aero filters is their great transparency through all the spectrum except the blue, whereby the greatest haze-cutting action is attained together with a low filter factor. The filter factors of the Aero No. 1 and No. 2 with Cramer Isonon plates are 3 and 5, respectively.
Effects Secured by the Use of Filters.—The efficiency of yellow filters for haze-cutting is best shown by photographs taken at high altitudes with filters and without. Such illustrations are given in Figs. 107 and 108, where the first photograph is one taken at 10,000 feet without a filter, the second taken at the same altitude under the same conditions, but with an orange filter. Both are on panchromatic plates, and it will be seen that even with these plates the filter makes all the difference between a useless and a useful picture. But it must be clearly understood that the difference here lies between a plate sensitive chiefly in the blue and violet, and
Fig. 107.—A photograph taken at 10,000 feet, without a filter.
Filters are almost always necessary in photographing from high altitudes or in making distant obliques. At times, particularly after a heavy rain, the air is clear enough so
Fig. 108.—Photograph taken at same time and over same neighborhood as Fig. 107, but with an orange filter.
Filters for the Photographic Detection of Camouflage.—In the photographic as in the visual detection of camouflage, the problem is to differentiate colors which ordinarily look alike, but which are actually of different color composition. Particularly important are the differences between natural foliage greens and the paints used to simulate them. If these differ in their reflection spectra, a proper choice of filter will show up the two greens as markedly different. Two kinds of difference may be produced; either the two colors may be changed in relative brightness, or they may be altered in
Those same filters which have been worked out primarily for producing brightness differences in visual detection of camouflage could be used photographically, provided the plates employed were color sensitive, and were as well screened to imitate the sensibility of the eye. But the most useful visual filters are those causing color differences to appear; more than this, the visual camouflage detection filters as a class have low light transmissions, so that their usefulness in photography is doubtful. Little work has actually been done with camouflage detection filters for photography. Yet in spite of this photography has been of real service in this form of detective work. Its utility for the purpose comes from the fact that the natural sensitiveness of the plate to blue, violet and invisible ultra-violet acts to extend the range of the spectrum in which differences between identical and merely visually matched colors may be picked up. Consequently the plain unscreened plate has proved a very efficient camouflage detector—so efficient in fact that all camouflage materials have had to be subjected to a photographic test before acceptance. Fig. 171 shows how an ordinary photograph reveals the unnatural character of the camouflage over a battery.
Methods of Mounting and Using Filters.—The most primitive way of mounting a gelatin filter is to cut a disc from a sheet of dyed gelatin and insert it between the components of the lens. For this purpose the gelatin must be perfectly flat,
Glass filters, ground optically true, or gelatin filters, mounted between optically flat glass plates, are the most convenient and satisfactory. They may be mounted in circular cells to screw or attach by bayonet catches to the front of the lens. Or they may be mounted in rectangular frames to slide into transverse grooves in the camera body. Fig. 44 shows the mount of this latter form adopted in the larger United States Air Service cameras. This is particularly convenient if it is desired to insert or change the filter while in the air—a practice not generally considered feasible in war work with the photographically inexperienced observer, but likely to be common with the employment of skilled photographers for peace-time aerial photography.
German cameras are reported in which the glass filter is carried behind the lens, on a lever which also carries a clear glass plate of the same thickness, to be thrown in when no filter is needed, thus maintaining the focus. The performance of the lens will be impaired by this scheme, unless it is specially calculated to offset the effect of the glass introduced in the path of the rays behind the lens—optically true glass has no effect on definition if placed in front of the lens. Glass filters may also be placed in close contact with the plate or film, in which case they must be much larger, but do not need to be of as good optical quality.
Self-screening Plates.—Mention must be made of a quite different mode of realizing the filter idea, a method available where the sensitive plate is always to be used with
CHAPTER XX
EXPOSURE OF AERIAL NEGATIVES
The principal factors governing the length of exposure in the airplane camera have already been discussed under various headings. These are briefly, the nature of the aerial landscape, the practically attainable lens apertures, the form of the camera support, the speed of the plane, and the characteristics of plates, films and filters. It is convenient however, to re-assemble this information in one place, in such form as to apply to the practical problem of determining the exposure to be given in any specific case.
Limitations to Exposure.—In the ordinary photography of stationary objects, exposure is a variable entirely at the operator's command. Plates of any speed may be selected, so that attention may be focussed on latitude, color sensitiveness, and other tone rendering characteristics. The exposure may be made of a length sufficient to insure all the useful photographic action lying in the “correct exposure” portion of the sensitometric curve. The exposure ratio of any filter it is desired to use is a matter of indifference—its effect on color rendering need alone be considered.
Airplane photography is sharply distinguished from ground “still” photography by its severe limitations as to the amount of the exposure. The actual duration is definitely restricted by the high speed of the plane. In peace work this can be offset in part by using slower planes or by flying against the wind. The practical limitation to 1
100 second, set by war-time requirements as to definition of fine detail, may be increased to 1
50 of a second, or even more, where mapping of grosser features is the object. A common,
Broadly speaking, it may be said that all the demands made in reference to aerial photographic exposure work are to decrease the amount of light reaching the plate. Any surplus offered, as by the midsummer noon-day sun, must be immediately snapped up, either by decreasing the exposure to get greater sharpness, or by introducing filters to get greater photographic contrast. The absolute exposure of the plate tends to be kept at the irreducible minimum. As already stated, it lies, with present photographic materials, on the “toe” of the “H & D” curve, just reaching up into the straight line portion.
Estimation of Exposure.—According to the foregoing argument the problem of estimating an aerial exposure resolves itself largely into one of deciding how short this may be made. Or, if the light is strong, whether it is sufficient so that a filter may be introduced without demanding
100 second or thereabouts which is dictated by the motion of the plane.
Deciding upon exposures in the field has been largely a matter of experience and judgment. A majority of the cameras in use during the war were not furnished with shutters calibrated in definite speeds. Consequently, the sergeant upon whom the decision usually devolved became a storehouse of knowledge as to the slit widths and tensions appropriate to each individual camera. This knowledge had to be acquired from the results of actual photographic reconnaissances, or from special test flights, both of them wasteful methods. But the chief objection to this state of affairs lies in the fact that the knowledge thus acquired is of no use to anyone else, nor is it applicable to other types of camera.
The first essential to placing exposure estimation upon a sound basis is therefore an accurate knowledge of shutter performances. Either the shutter speeds should be placed upon the camera by the manufacturer and periodically checked, or a regular practice should be followed of calibrating shutters, either at a base laboratory or even in the field.
Assuming that the speeds of all shutters are accurately known, the process of estimating the requisite exposure becomes less a matter of mere guesswork and more nearly a matter of precision. For this purpose data on the variation of light intensity during the day and during the year (Figs. 101 and 102) should be taken as a guide. These data refer of course to visual and not to photographic light, but since it is always necessary to use color filters, which make the active light of approximately visual quality, this is no valid objection. The effects of clouds and mist must of course be learned largely by experience, but with the above daylight data at hand, anyone in possession of definite information on the correct exposure with a given plate for a known day
Fig. 109.—Chart showing aerial exposures for all times of the day and year. Data on basis of F/5.6 lens, Jougla orthochromatic plate, and clear sunlight, no filter. Exposures to be doubled and tripled for overcast and cloudy weather.
Exposure data charts. Fig. 109 shows a chart, prepared in the French service, indicating aerial exposures for all hours of the day throughout the year. These are for clear sunlight, for a lens of aperture F/5.6 and for “ortho” plates
Exposure meters. Aerial photography offers an excellent opportunity for the use of exposure meters, particularly those of the type in which a sensitive surface is exposed to the light for a measured time sufficient to darken a predetermined amount. The sensitive paper of the meter may either be exposed from the ground to the direct light of sun and sky, or from the plane to the light reflected from the ground. The first method will give figures subject to some correction for the character of the ground to be photographed—whether fields, forests, or snow. The second method is to be preferred where the shutter speed can be adjusted in the air, according to the indications of the meter, or where the filter can be selected and put in place during flight. Trials with a commercial Wynne exposure meter, used in the latter manner, give as a working figure an exposure of .001 second for each 4½ seconds taken to darken the sensitometer strip to match the darker comparison patch. This relation applies to a lens of aperture F/4.5, on Cramer Commercial Isonon plates without filter.
CHAPTER XXI
PRINTING MEDIA
Skilled photographers can examine a negative and can interpret its renderings with practically as much satisfaction as they get from a print, whereby a considerable amount of time can be saved in an emergency. The original glass negative should always be used when accurate measurements are to be made. These and a few other cases constitute the only use of a negative apart from its normal one, namely, for producing positive prints, usually in large numbers. The commonest form of print is on paper, although the most satisfactory print from the photographic standpoint is the transparency on glass or celluloid film.
Transparencies.—Transparencies are made by the regular photographic processes of exposure and development, on glass plates or films placed in contact with the negative, or in the appropriate position in an enlarging camera. The sensitometry and the terms used to describe the qualities of plate or film for this purpose are those already given in connection with the general discussion of plates and films. But the kind of emulsion to be selected is quite different from the aerial negative emulsion. There is here no practical limitation to the speed, contrast or latitude. Consequently, we can choose a positive emulsion on which the exposure through the aerial negative falls entirely on the straight line portion of the characteristic curve, thus reproducing all of its tones, and the contrast of the negative may be increased to any desired extent. The possibilities of positive emulsion are indeed rather greater than the usual aerial negative can utilize. A range of clearly graduated opacities of two or
Glass transparencies are of course impractical for general distribution, on account of their fragility. Heavy film transparencies are not open to this objection, and, especially in the form of stereos, constitute the most beautiful form of aerial photographic print.
Paper Prints.—Prints on paper suffer by comparison with transparencies, in the range of tones which they exhibit. This lies between the white of the paper, which never has more than 80 per cent. reflecting power, and its darkest black, which differs with the kind of paper. In dull or mat papers the blacks will reflect as much as 5 per cent.; in glossy papers, ordinarily used for aerial negatives, the reflection from the black may be as low as one per cent., but in order to get the benefit of this the paper must be so held as not to reflect any bright object to the eyes. This deficiency in the range of paper gradations is not so serious with aerial negatives as with ordinary properly exposed negatives because of the small range of brightness in the aerial view.
The sensitometry of papers is similar to that of plates, with the difference that reflecting powers take the place of transparency. As in the case of transparency emulsions there is in papers no dominating requirement for extreme speed, to which other characteristics must be subordinated. Yet
Fig. 110.—Characteristic curves of bromide paper.
The two principal types of rapid enlarging papers, the bromide and the “gas light,” exhibit certain characteristic differences which are important to bear in mind in seeking to obtain any particular quality of print. Bromide papers, of which “Nikko” is a good example, show sensitometric curves rather like those of plates. That is, they increase in contrast with continued development. At the same time, as is shown in Fig. 110, they increase somewhat in speed
Fig. 111.—Characteristic curves of gas light paper.
The sensitometric curves of a typical gas light paper “Contrast Enlarging Cyco,” are shown in Fig. 111. Here the contrast is a fixed characteristic of the paper, and the
Choosing a printing paper is a matter of deciding on the contrast required for the class of negative, and selecting a paper which will give this contrast with a good range of tones from a clear white to a deep black. The ideal paper would be one which was all straight line in the H & D plot. In such a paper there would occur no loss of contrast in the lighter tones when the high-lights were rendered by the clear white of the paper. Too great contrast with a short straight line portion, results in loss of detail at the ends of the scale. A negative possessing a very great range of tones cannot be correctly represented on one paper print—two printings are required, one for high-lights and one for shadows, but this difficulty is rarely to be faced in aerial views. The greatest demand for aerial printing papers has been for those of considerable contrast, because of the flat character of the negatives.
CHAPTER XXII
PHOTOGRAPHIC CHEMICALS
General Considerations.—Developing, fixing and other chemicals for aerial work differ in no essential respect from those used in ordinary photography. Full discussions of these are to be found in numerous texts and articles. The aerial photographic problem is to select those most suited for the under-exposed flat negatives characteristic of photographs from the air. At the same time selection from among the chemicals of appropriate quality must be governed by considerations of the conditions surrounding work in aerial photographic laboratories. These laboratories, especially in war-time, are apt to be most primitive in their facilities.
Characteristics of Developers for Plates and Films.—From the standpoint of practicability, aerial negative developers should have good keeping power, be slow to exhaust, and work well over a considerable range of temperatures. From the standpoint of the photographic quality desired in the negative, the developer should bring up the maximum amount of under-exposed detail. This means that it should impart the highest possible speed to the plate, with good contrast, and low fog or general reduction of unexposed silver bromide.
There are many characteristics to study in a developer: its effect on inertia or speed, gamma infinity, fog, time of appearance, “Watkins factor,” speed of development, temperature coefficient, dilution coefficient, keeping power, exhaustion, length of rinsing, stain, color coefficient and resolving power. These are defined and described as follows:
Effect on inertia. The meaning of inertia has already
Time-gamma relation. Contrast, symbolized by ?, has likewise been discussed under plate sensitometry. Viewed from the standpoint of the developer, the point of interest is the rate at which ? varies with development, and the maximum contrast which can be reached or ? infinity. Speed of development is commonly defined by the velocity constant, symbolized by ?, which is arrived at mathematically from a consideration of the time of development to produce two different contrast values. High ? infinity is desired for aerial negatives, and for rapid work ? must also be high.
Fog. The opacity due to chemical fog is to be kept at a minimum in aerial negatives, as it is chiefly prejudicial to under exposures.
Time of appearance and Watkins factor. The time of appearance is measured in seconds. The Watkins factor is a practical measure of the speed of development, and is determined by the ratio of the time of development required for a definite contrast, to the time of appearance. It is useful also as a guide to development time.
Temperature coefficient. This is the factor by which the time of development at normal temperature (20 Cent.) must be increased or decreased in order to obtain the same quality negative, for a change of seven degrees either side of normal.
Temperature limits are the temperatures between which development can be carried out with any degree of control or without serious damage to the negative. These factors are of great importance where climatic or seasonal changes have to be endured.
Dilution coefficient. This is the factor by which the
Keeping power. The keeping power of a developer, mixed ready for use, is determined by its ability to resist aerial oxidation. A developer of poor keeping power, which must be made up immediately before use, causes delay and waste of time whenever emergency work has to be done, whereas a developer of good keeping power may be left in its tank ready for instant use.
Exhaustion of a developer is the rate at which it becomes useless for developing, due both to aerial oxidation and to the using up of its reducing power by the work done in developing plates. It is conveniently measured by the area of plate surface developable before the solution must be renewed.
Length of rinsing. The time required for rinsing between development and fixing bath plays a not unimportant part in total development time. Dichroic fog is caused with some developers if, due to insufficient rinsing, any of the caustic alkali is carried over to the fixing bath. Stains develop also if the fixing bath is old, or if light falls on the unfixed plate while any developer remains in the film.
Color coefficient. The function of the sulphite, which forms a constituent of all developing solutions, is two-fold. It acts partly as a preservative, and partly to prevent the occurrence of a yellow color in the deposit. The yellow color, if present, increases the photographic contrast. This phenomenon has been purposely utilized, particularly in the British service, to give “stain” to negatives which otherwise would show insufficient printing density. The color index or coefficient of a negative (with a given printing medium) is the ratio of photographic to visual density. If we take a pyro developer containing five parts of pyro per thousand
Sulphite Parts per Thousand | Color Index |
---|---|
50 | 1.16 |
25 | 1.24 |
15 | 1.30 |
10 | 1.45 |
5 | 1.80 |
0 | 2.75 |
The color index is somewhat different with various kinds of printing media.
This staining effect is a variable one, depending upon length of development, dilution of the developer, length of rinsing, temperature, the fixing bath used (plain hypo being necessary for a maximum effect), the length of washing after fixation and the properties of the water used. Standardization of these conditions in the field is difficult; hence any developer which will give the same effective contrast without resorting to stain is to be preferred.
Resolving power. Some developing processes and conditions will introduce bad grain into the negative. Hence the resolving power which a developer brings up must be investigated among its other characteristics.
Practical Developers for Aerial Negatives.—In the English service a pyro metol developer was generally used, producing stained negatives. The French, American and Italian practice was to use metol-hydrochinon, without staining. A special chlor-hydrochinon developer, worked out by the Eastman Research Laboratory for the United States Air Service, has probably the greatest merit of any yet tried. A comparison, given below, between it and a pyro metol formula used on a representative plate, illustrates the use of the various bases of study given above.
Solution A | Solution B |
---|---|
Pyro, 3.75 grams | Sodium carbonate, 53 g |
Potassium metabisulphite, 3.75 g | |
Metol, 3.05 g | |
Potassium bromide, 1.5 g | |
Water, 500 c.c. | Water, 500 c.c. |
Solution A | Solution B |
---|---|
Chlorhydrochinon, 25 g | Sodium carbonate, 30 g |
Metol, 6 g | Sodium hydrate, 10 g |
Sodium bisulphite, 2.5 g | Potassium bromide, 3 g |
Sodium sulphite, 25 g | |
Water to 670 c.c. | Water to 330 c.c. |
Pyro | Chlorhydrochinon | |
---|---|---|
H & D speed | 150 | 180 |
Gamma infinity | 1.45 | 2.12 |
Fog (at maximum gamma) | .32 | .60 |
Time of appearance | 5 seconds | 5 seconds |
Watkins factor | 25 | 10 |
Velocity factor “?” | .320 | .400 |
Temperature coefficient | 1.40 | 2.0 |
Temperature limits | 4° to 32° C | 4° to 32° C |
Keeping power | 45 minutes | 8 days |
Exhaustion (100 c.c.) | 30 sq. in. | 300 sq. inches |
Dilution coefficient | 2 | 2 |
Color coefficient | 1.50 | 1.00 |
Resolving power | 47 | 53 |
Owing to the difficulty of securing pure chlor-hydrochinon a metol hydrochinon of very similar properties has been worked out. Its composition is
Metol | 16 | grams |
Hydrochinon | 16 | grams |
Sodium sulphite | 60 | grams |
Sodium hydroxide | 10 | grams |
Potassium bromide | 10 | grams |
Water to | 1 | litre |
To keep the ingredients in solution in cold weather, 50 c.c. of alcohol should be included in every litre of solution. All things considered this is probably the most practical and satisfactory developer for aerial negatives.
Metol | .9 | gram |
Hydrochinon | 3.6 | gram |
Sodium carbonate | 20.0 | gram |
Sodium sulphite | 14.0 | gram |
Potassium bromide | .5 to 1.0 | gram |
Water to | 1 | litre |
Fixing Baths.—For plates the following fixing and hardening bath is recommended:
Sodium thiosulphate (hypo) | 350 | grams |
Potassium chrome alum | 6 | grams |
Sodium bisulphite | 10 | grams |
Water to | 1000 | c.c. |
During hot weather, the above quantities of chrome alum and bisulphite are doubled.
For papers the following:
Hypo, 35 per cent. | 100 | volumes |
Acid hardener | 5 | volumes |
The acid hardener is constituted as follows:
Alum | 50 | grams |
Acid acetic 28° | 400 | c.c. |
Sodium sulphite | 100 | grams |
Water to | 1 | litre |
Intensification and Reduction.—These processes have been little employed in air work. Reduction is rarely necessary, for obvious reasons. Intensification would often be of value, but the common practice, which saves some time, is to use printing paper of strong contrast for those negatives which are deficient in density and contrast. When intensification is desirable or permissible, either the ordinary mercury or uranium intensifier may be used.
Water.—In the field it is found necessary in many cases to purify the water that is to be used in mixing up chemicals.
(a) Filter the water through a cloth into a barrel, add about one gram of alum for every four litres of water, and allow to settle over night. Draw off the clear liquid from a plug in the side as required.
(b) Boil the water and allow it to cool over night. If the water contains dissolved lime, boiling will often cause this to come out of solution.