12. The Natural Object Water.One of the commonest of common natural objects is water; everybody uses it in one way or another every day; and consequently everybody possesses a store of loose information—of common knowledge—about it. But, in all probability, a great deal of this knowledge has never been attended to by its possessor; and certainly, those who have never tried to learn how much may be known about water, will be ignorant of a great many of its powers and properties and of the laws of nature which it illustrates; and consequently will be unable to account for many things of which the explanation is very easy. So we may as well make a beginning of science by studying water. 13. A Tumbler of Water.Suppose we have a tumbler half-full of water. The tumbler is an artificial object (§ 5); that is to say, certain natural objects have been brought together and heated till they melted into glass, and this glass has been shaped by a workman. The water, on the other hand, is a natural object, which has come from some river, pond, or spring; or it may be from a water-butt into which the rain which has fallen on the roof of a house has flowed. Now the water has a vast number of peculiarities. For example, it is transparent, so that you can see through it; it feels cool; it will quench thirst and dissolve sugar. But these are not the characters which it is most convenient to begin with. 14. Water occupies Space; it offers Resistance; it has Weight; and is able to transfer Motion which it has acquired; it is therefore a form of Matter.The water, we see, fills the cavity of the tumbler for half its height, therefore it occupies that much space, or has that bulk or volume. If you put the closed end of another tumbler of almost the same size into the first, you will find that when it reaches the water, the latter offers a resistance to its going down, and unless some of the water can get out, the end of the second tumbler will not go in. Any one who falls from a height into water will find that he receives a severe shock when he reaches it. Water therefore offers resistance. If the water is emptied out, the tumbler feels much And, finally, if you throw the water out of the tumbler at any slightly supported object, the water hitting against it would knock it over. That is to say, the water being put in motion is able to transfer that motion to something else. All these phenomena, as things which happen in nature are often called, are effects of which water, under the conditions mentioned, is the cause, and they may therefore be said to be properties (§ 4) of water. All things which occupy space, offer resistance, possess weight and transfer motion to other things when they strike against them, are termed material substances or bodies, or simply matter. Water, therefore, is a kind, or form, of matter. 15. Water is a liquid.You will easily observe that, though water occupies space, it has no definite shape, but fits itself exactly to the figure of the vessel which holds it. If the tumbler is cylindrical, the contour of the surface of the water will be circular when the tumbler is held vertically, and will change, without the least break or interruption, to more and more of an oval when the tumbler is inclined, and whatever the shape of the vessel into which you pour it, the sides of the water always exactly fit against the sides of the vessel. If you put your finger into the water you can move it in all directions with scarcely any feeling of obstacle. If you pull your finger out there is no hole left, the water on all sides rushing together to fill up the space that was occupied by the finger. You cannot take up a handful of Nevertheless, although the parts of the water thus loosely slip and slide upon one another, yet they hold together to a certain extent. If the surface of the water is just touched with the finger, a little of it will adhere; and if the finger is then slowly and carefully raised, the adjacent water will be raised up into a slender column which acquires a noticeable length before it breaks. So, in the early morning, after heavy dew, you may see the water upon cabbage-leaves and blades of grass in spherical drops, the parts of which similarly hold together. Material substances, the parts of which are so movable that they fit themselves exactly to the sides of any vessel which contains them, and which flow when they are not supported, are called fluids, and fluids the parts of which do not fly off from one another, but hold together as those of water do, are called liquids. Water therefore is a liquid. 16. Water is almost incompressible.It has been seen that water, like every other 17. The Meaning of Weight.Let us next consider the property of weight. We say that anything has weight when, on trying to lift it from the ground, or on holding it in the hand, we have a feeling of effort. Or again, if anything which is supported at a certain height above the ground, falls when the support is taken away, we say that it has weight. Now the ground merely means the surface of the earth; and, as all bodies which possess weight fall directly towards the surface of the earth when they are not kept away from it by some support, we may say that all bodies which have weight tend to fall in this way. And it does not matter on what part of the surface of the earth you make the experiment. Rain consists of drops of water, and it does not matter whether we watch a shower in calm weather here, or in New Zealand; the drops fall perpendicularly towards the ground. But we know that the earth is a globe, and that New Zealand is at our antipodes, or on the opposite side of the globe to England. Hence if two showers are falling at the same time, one in New Zealand and one here—the drops must be falling in opposite directions, towards one another; that is, towards the centre of the earth which lies between them. In fact, all bodies which have weight tend to fall towards the centre of the earth—that is to say they fall in this way if there is nothing to prevent them; and when we speak of weight we mean this tendency to fall. To call anything heavy, is the same as saying that we fully expect that, if there is nothing to support it, it will fall to the ground; or that if we support it ourselves we shall be conscious of effort. 18. Gravity and Gravitation.The word gravity, when it was first used, had exactly the same meaning as weight; and a body which has weight is said to gravitate towards the center of the earth. But gravity has now acquired a much wider sense than weight. For an immense number of careful observations and experiments have established the general rule, or law of nature, that every material substance, tends to approach every other material substance, just in the same way as a drop of rain falls towards the earth; and, in fact, that any two portions of matter, whatever the nature of that matter may be, will move towards one another if there is nothing to prevent them from doing so. To make this clear, let us suppose that the only material bodies in the universe were two spherical drops of water, each a tenth of an inch in diameter. Each of these drops would have the same bulk as the other, and would be a quantity of matter exactly equivalent to the other. Then, however great the distance which separated these two drops, they would begin to approach one another; and, each moving with gradually increasing swiftness, they would at length meet in a point exactly half-way between the positions which they at first occupied. But if the bulk of one drop were greater than that of the other drop, then the larger would move more slowly, and the point of meeting would be by so much nearer the larger drop. It follows that, if the one body of water were as big as the earth and the other remained of its original size, no bigger than a rain-drop—the motion of the large mass towards the small one would be an inconceivably minute fraction of the total This is just what happens when a single drop of water falls from a cloud, say through a distance of a mile, to the earth. The earth really moves towards it, just as it moves towards the earth, on the straight line which joins the centres of the two. But the length of this line which each travels over is inversely proportional to the quantity of matter in each, that is to say is the less the bigger the quantity. So that we have a rule-of-three sum. As the quantity of matter in the earth is to that in a rain-drop, so is a mile to the distance travelled over by the earth. And if any one worked out this sum, he would find that the fourth term of the proportion would be an inconceivably minute fraction of an inch. For all practical purposes, therefore, we may consider the earth to be at rest in relation to all falling bodies, inasmuch as the quantity of matter in any falling body is insignificant, in comparison with that contained in the earth. What is true of water is true, so far as we know, of all kinds of matter, and we therefore say that it is a law of nature that all kinds of matter possess gravity; that is to say, that of any two, each tends to move towards the other, at a speed which is the slower the greater the quantity of matter it contains in proportion to that which the other contains; and this speed gradually becomes quicker as the two bodies approach. What is usually called the law of gravitation is a statement of the same observed facts in another and more complete fashion. (See Physics Primer.) 19. The cause of Weight: Attraction: Force.We know nothing whatever of the reason why bodies possess weight. Bodies do not fall on account of the law of gravitation (§ 9); nor does their gravity explain why they fall. Gravity, as we have seen, is only a name for weight, and the law of gravitation is only a statement of how bodies approach one another, not why they do so. It is often said that gravitation is attraction, and that bodies fall to the earth because the earth attracts them. But the word “attract” simply means to “draw towards,” and “attraction” means nothing but “drawing towards;” and to say, when two bodies move towards one another, that they are “drawn towards” one another, is simply to describe the fact and makes us no whit wiser than we were before. On the contrary, unless we take great care, it may make us a little less wise. For the words “drawing towards” are so closely associated with ropes and hooks and the act of pulling, that we are easily led to fancy the existence of some analogous invisible machinery in the case of mutually attractive bodies. Again, gravitation is spoken of as a force; and as the word force is in very common use, let us try to make out what we mean by it. A man is said to exert force when he pushes or pulls anything so as either to exert pressure upon it or to put it in motion. A wrestler’s force is proved by his hug; a bowler’s force is shown by the swiftness of motion of the ball. Force, then, is the name which we give to that which causes or, in the case of pressure, tends to cause, motion. The force of gravity therefore means A good deal of mischief is done by the inaccurate use of such words as attraction and force, as if they were the names of things having an existence apart from natural objects, and from the series of causes and effects which are open to our observation; while they are, in reality, merely the names of the unknown causes of certain phenomena. And it is worth while to take pains to get clear ideas on this head at the outset of the study of science. Let us remember then that, so far as we know, it is a law of nature, that any two material bodies, if they are free to move, approach one another with gradually increasing swiftness; and that the space over which each travels before the two meet, is inversely proportional to the quantity of matter which it contains. Attraction of gravitation is a name for this general fact; weight is the name for the fact in the case of terrestrial bodies; force is a name which we give to the unknown cause of the fact. The fact is that which it is important to know. The names are of no great consequence so long as we recollect that they are merely names and not things. 20. The Weight of Water is Proportioned to its Bulk.We must next consider, not weight in general, but the weight of water. We say that a tumbler full of 21. The Measuring of Weights. The Balance.Such an instrument is the balance or scales, which you may see in every grocer’s shop. It is composed of a beam which moves easily on a pivot fixed to its middle, and which has a scale-pan attached to each end. So long as both scale-pans are empty the beam is horizontal; but if you put anything which has Suppose that, instead of pressing down the empty scale, you put something that has weight into it; then, as soon as this weight is equal to that in the other scale, the beam will become horizontal. In fact, one scale has just as much tendency to move towards the centre of the earth as the other has, and as neither can go down without pulling the other up, they neutralise one another. It comes to the same thing, as if two boys of equal strength were pulling one against the other; so long as the pulls in opposite directions are equal, of course neither boy can stir; while the smallest addition of strength to one enables him to pull the other over. 22. The Weight of the same Bulk or Volume of Water is Constant under the same conditions. Mass. Density.Now let two graduated thin glass measures be put into the two scales, and made to counterpoise one another exactly. Then, if even a single drop of In § 18 it was said that bodies tend to move towards one another with a relative velocity 1. Velocity, or swiftness, is measured by the distance over which a body travels, in a given time. Of two bodies, one of which travels through one foot in a second, while the other travels through two feet, the latter has the greater relative velocity. Now what is true of water is true of all other bodies or material substances. Suppose that one of the measures is emptied and replaced, the beam may be brought to the horizontal position again by means of a piece of lead cut to exactly the right size. The piece of lead will thenceforth furnish an exactly corresponding or equivalent weight for so much water; and pieces of iron or brass, which counterpoise the lead, will also be equivalents of the weight of the water, or of the lead, or of one another. But the pieces of lead, iron, or brass will obviously be of much less volume or bulk than the water which they counterpoise. Here it follows that the densities of these metals, or the quantity of matter contained in the same volume, must be much greater than in the case of water. What are called weights in commerce are pieces of lead, or iron, or brass exactly equivalent in weight to a certain bulk of water under certain conditions. An imperial gallon of water thus weighs ten pounds, and therefore an imperial pint weighs a pound and a quarter. 23. Equal Volumes of Different Things under the same circumstances, have Different Weights: the Density of Different Bodies is Different.The important fact which has just been alluded to must be considered more fully. We have seen that an imperial pint measure gives us the space which is taken up by as much water as weighs a pound and a quarter; and this space is the bulk or volume of that 24. The Meaning of Heavy and Light—Specific Gravity.We are in the habit of using the words heavy and 25. Things of greater Specific Gravity than Water sink in Water; Things of less Specific Gravity float.Here are two tumblers of water. Throw some sand into one and some sawdust into the other. What happens? The sand sinks to the bottom, the sawdust floats at the top. We may stir them up as we like, but the sand will tumble to the bottom and the sawdust, as obstinately, rise to the top. Thus that which is lighter than the water floats, and that which is heavier (bulk for bulk) sinks. So, if we pour We saw that the iron-filings sank, because iron is heavier than water. Here is a piece of the thin tinned sheet-iron that they make tin boxes of. What will happen if we drop it into the water? It is heavier than water, bulk for bulk, and therefore it will sink as you see it does. But now here is a “tin” canister made of this very same tinned sheet-iron. We drop that into the water, and you see it does not sink at all, but floats at the top as if it were made of cork. Here is a perplexity. We were sure just now that iron is heavier than water, and here is an iron box floating! Is this an exception to the law? Not at all; for what we said was that a thing would float if it were lighter, bulk for bulk, than water. Now let us weigh the tin box, and having weighed it let us next try to find out how much the same bulk of water weighs. This may be done very simply, for the walls of the box are very thin, so that the inside of the box is very nearly as large as the whole box. Consequently, if we fill the box with water, and then weigh the water, we shall find out, very nearly, what is the weight of a bulk of water as great as that of the box. But if we do this, we shall find that the water which was contained in the box, weighs very much more than the box does. So that, bulk for bulk, the box, although it is made of iron, is really lighter than water, and that is why it floats. You will all have heard of the iron ships which are now so common, and you may have wondered how it It is because of this property of water to bear up things lighter than itself, and because of that other property of being easily moved which the particles of water have, that the sea, and rivers, and canals, are such great highways for mankind. For there is nothing so heavy that it may not be made to float in water, if the box which holds it is large enough to make the weight of the whole less than the weight of the same bulk of water. And then, having once got the weight to float, the particles of water are so easily moved, that the force of the winds, or of oars, or of paddles, readily causes it to slip through the water from one place to another. 26. A Body which Floats in Water always occupies as much Space beneath the level of the Surface of the Water as is equal to the Volume of Water which weighs as much as that Body; in other words, it displaces its own Weight of Water.A cubic inch of water weighs about 252 grains and a half. Suppose that the tin box in the previous experiment was square, and had the bulk of 100 cubic inches, then the weight of a corresponding volume of water would be 25,250 grains. If the box weighed 8,416 grains, just a third of its bulk would be immersed; if 27. Water presses in all Directions.Thus water presses in all directions upon things which are immersed in it. If a long wooden or metal pipe, placed vertically, has its lower end stopped with a cork which does not fit very tightly, and water is poured into the top of the tube, the water will at first fill the part of the tube above the cork, and its weight will exert a certain pressure on the cork. In fact, if the end of the tube is stopped by applying the palm of the hand closely against it, the downward pressure of the water will have to be overcome by a certain amount of effort. As the water accumulates, this downward Suppose the tube to be square, and that the inside of the square measures exactly one inch each way. Then an inch of height of the tube will hold exactly one cubic inch of water. Since one cubic inch of water weighs 252 grains and a half, as much water as will fill the tube about two feet three inches and a half high, will weigh a pound (7,000 grains), and fifteen pounds of water will fill such a tube between thirty-three and thirty-four feet high. And these respective weights measure the pressure of two columns of water, one twenty-seven and a half inches high, and the other nearly thirty-four feet high, on a square inch of the surface on which they rest. The specific gravity (§ 24) of lead is 11·45; in other words it is about eleven and a half times denser than water. Therefore if a bar of lead cut square and one inch in the side, and rather less than 1 And now comes a difference between the lead and the water, which depends on the fluidity of the latter. The lead exerts no pressure on the sides of the tube, but the water does. If a small hole is cut in the side of the tube close to the bottom, and stopped with a cork, the lead will not press upon the cork. But if the column of water is high enough If a glass tube is bent into the shape of a U, and water is poured into it, the water will always stand at the same level in the two legs of the tube, whatever the shape of the bend may be, or the relative capacities of the two legs, or the inclination of the tube. And this must needs be so, for the force with which the water tends to flow out of the one half of the arrangement depends on the vertical height 2. Vertical height is the height measured along a line drawn from the surface of the water perpendicularly to the surface of the earth. A plumb-line is a string to one end of which a weight is attached and thus hangs suspended. If the other end of the line is brought opposite the surface of the water the direction of the string answers to the line of vertical height. That a column of water will stand at exactly the same level as any other with which it communicates, may be seen still more simply by placing a glass tube, open at each end, in a basin of water. However the tube may be inclined or bent, whether its lower end is In a well-ordered town, water is supplied to every house and can be drawn from taps placed in the highest stories. These are fed by pipes which lead from a cistern at the top of the house. This water is brought from a large pipe, or main, in the street, by a smaller house-pipe, which is often made to twist about in various directions before it reaches the cistern at the top of the house into which it delivers the water. If you followed the main, you would find that it took a long course up and down, beneath the pavement of the streets, until at last it reached the water-works. Here you would find that the main was connected with a reservoir; and either this reservoir is at a greater height than any of the cisterns into which the water is delivered, or there is some means of pumping the water from it to that height on its way to the main. Thus the reservoir, the main, and the house-pipe form one immense U-tube, and the water in the house-pipe tends to rise to the same level as that of the water in the reservoir, and hence flows into the cistern when the supply-pipe is open. 28. The Transference of Motion by Moving Water: the Momentum of Moving Water.Suppose a wooden vat with a horizontal tap, the sectional area 3. The sectional area of a tube is the surface occupied by its cavity when it is cut across. It would be represented by the surface of a piece of cardboard, like the wad of a gun, just large enough to go into the tube. If the tap is now turned, the water nearest to it being unsupported on its outer side, the pressure on the inner side sets it in motion, and it flows out in a stream. At first the stream shoots out violently and the water is carried to a long distance. That is to say, the weight of the column of water 100 inches high acts as a force, or cause of motion, upon the water nearest the tap, and this water is forced out with a velocity depending on that force in a horizontal direction. Now suppose that you take a common toy cup-and-ball and bring the ball into the way of the stream of water. The stream will at once strike the ball and drive it in the same direction as that which it is itself taking. The power which the moving water has of transferring or communicating motion to a body which is at rest, but free to move as the ball is, is due to its momentum. The greater the mass of the stream and the more rapidly it moves, the more motion will it communicate to the ball, or the heavier the ball it will move. Close to the mouth of the tap the direction of the stream is horizontal; but it very soon begins to bend downwards, and describing a rapid curve, comes to the ground. It does this for just the same reasons that a stone thrown horizontally describes a curve; and at These reasons are two: firstly, as soon as the water has left the tap it is an unsupported heavy body; and, as such, it begins to fall to the ground. Secondly, the momentum of the water is continually being diminished by the resistance of the air through which it passes. For, although the air which surrounds us is so thin and movable a body that we ordinarily take no notice of it—the fact that it offers resistance to bodies which move through it is easily observed; as, for example, in using a fan. The water has to overcome this resistance, and its momentum is proportionally diminished. If, when the water leaves the tap, the air and gravitation were alike abolished, the water, keeping its momentum, would travel for ever in the same direction. As the water runs out, it will be observed that the velocity of the stream becomes less and the curve which it describes sharper, so that it comes to the ground sooner; and finally, when the vat is nearly empty, the stream falls nearly vertically downwards. The reason of this is that the level of the top of the water is gradually lowered; consequently, the height of the column which presses on the water close to the tap is gradually lessened, and therefore its weight is diminished. But this weight or pressure is the cause of the motion of the water, and as the cause diminishes the effect of that cause must diminish. Therefore the momentum of the water is gradually lessened and it is carried less and less far horizontally in the time which it takes to fall to the ground: 29. The Energy of Moving Water.If a short pipe bent at right angles like the letter L is fitted by one arm on to the end of the tap, while the other is turned vertically upwards, and the vat is full as before; when the tap is turned, the water will shoot up into the air, and after rising for a certain distance will stop, and then fall. In fact we shall have a fountain. Observe the difference between the vertical jet of water and the horizontal jet. If we leave the resistance of the air out of consideration, the water in the horizontal jet has no obstacle to overcome; and it might go on for ever, if its weight did not gradually cause its path to become more and more bent towards the earth, against which it eventually strikes. When the jet is vertical the case is altered. The water thrown up vertically constantly tends to fall down vertically, as any other heavy body would do, and its momentum has to overcome the obstacle of its gravity. Any given portion of the water is, in fact, acted upon by two opposite tendencies, momentum urging it up, and gravity pulling it down. Now if two equal tendencies exactly oppose one another, the body upon which they act does not move at all; while, if one is stronger than the other, the body moves in the direction of the stronger. Thus a portion of water which has just left the spout shoots up, because the velocity with which it is impelled upwards is sufficient to carry it through a But the distance which the water will travel during this second will be the difference between the distance which it would have ascended if there had been no gravity forcing it down, and the distance which it would have descended if there had been no momentum driving it up; and, at the end of the second, the rate of its motion upwards, or its velocity, will be proportionally slower. Thus, at the end of the first second, the water has spent a certain portion of its momentum in overcoming its gravity. And as there is nothing to make good the loss, it would, if left to itself, travel more slowly, or over a less distance, in the second second than it tended to do in the first. But though the momentum of the water is diminished, its gravity, weight, or tendency to fall downwards, for a given distance in a second, remains exactly what it was, and operates in the course of the second second to exactly the same extent as in the first. Hence, at the end of the second second, the distance through which the water travels upwards is still smaller, and its velocity is still more diminished. It is obvious that, however great the disproportion between momentum and gravity to start with, gravity must gain the day in the long run under these circumstances. The store of momentum will be used up; and, after a momentary rest, the water, reduced to the condition of a body without support, will begin to be carried downwards by the unopposed action of gravity. The case is similar to that of a boy sculling a boat, the bows of which are suddenly seized and the boat We call people who possess much muscular or other power energetic; and we estimate their energy by the obstacles they overcome, or, in other words, by the work they do. In the present illustration the man’s energy would be measured by the distance to which the boat was propelled before it stopped. It is easy to transfer this conception of energy, as the power of doing work, to inanimate things; and thus when a body in motion overcomes any kind of obstacles in its way, parting with its momentum and more or less coming to rest in the process, we say that it has energy and that it does work. The energy of moving water is thus measured by the intensity of the opposing forces which it can overcome multiplied into the distance which it can travel before that energy is exhausted; that is to say, by the work it does before it is itself reduced to a state of rest. In the case under consideration, the energy by which gravity is overcome, for a greater or less time, depends upon the velocity of the stream; and this again depends upon the height of the water in the vat The energy of moving water makes it, under some circumstances, one of the most destructive of natural agents; and, under others, one of the most useful servants of man. A stream is water falling down hill with a velocity depending upon the inclination of its bed. As it falls it acquires momentum and, hence, energy; and thus a mountain stream, suddenly swollen by rain or melting snow, will tear away masses of rock and sweep everything before it. Nothing can look softer or more harmless than a calm sea, but if the wind sweeping over its surface puts the water in motion, it strikes upon the shore with terrific force; and its energy is expended in throwing up great waves, which lift vast blocks or drive masses of shingle up the beach. In all kinds of watermills it is the energy of more or less rapidly falling water which is turned to account. The water is made to flow against buckets or floats attached to the circumference of a wheel. Each bucket or float is therefore an obstacle to which the water transfers some of its own motion; it moves away and thus makes the wheel to which it is fastened turn. But the turning of the wheel brings a new obstacle in the way of the stream. This is treated in the same fashion, and the wheel turns still further, thus introducing another obstacle in the way of the stream upon which the same effect is produced. Thus each float, or bucket, is a means by which some of the momentum But this water-wheel is now a mass of matter in motion, and therefore itself contains a store of energy or power doing work. If a cord with a weight at the end of it were fastened to the axle of the wheel, the cord would be wound upon the axle, and the weight could be raised, or, in other words, so much work would be done by the turning of the wheel and we should thus have a rough measure of the amount of energy which had been given up by the stream to the wheel. The machinery of the mill is simply a set of contrivances for transferring the energy stored up in the water-wheel to the place in which work has to be done. In a flour-mill, for example, a series of wheels carries it from the water-wheel to the grindstones, which it sets in motion. 30. The Properties of Water are Constant.If, whenever there is a shower, you catch some rain-water, you will find that it possesses all the properties which have been described. It will be found to be an almost incompressible liquid, an imperial pint of which weighs about a pound and a quarter. It would make no difference if the rain-water were collected in Africa or in New Zealand; or if it had been obtained centuries ago and kept bottled up ever since. And there is every reason to believe that rain-water will have exactly the same properties a hundred or a thousand years hence. So far as the properties of This, however, is by no means the same thing as saying that the properties of water are always the same. In fact the properties of the substance, water, vary immensely according to the conditions to which it is exposed; but, under the same conditions, they are the same, so that we may still say that so far as water is concerned, the order of nature is constant. 31. Increase of Heat at first causes Water to Increase in Volume.It has been seen that a certain weight of water always has the same volume under the same conditions. The most important of these conditions is the heat or cold to which it is exposed. Water which has stood for some time in a warm room becomes less in volume, or contracts, if it is taken into a cool place; while its volume increases, or it expands, if it is made hot. The same thing is true of quicksilver, of spirit, and of liquids in general. A thermometer is simply a small flask—the bulb—with a long and narrow neck—the tube—filled with as much mercury or spirit as will rise a short distance into the neck. If the liquid in the bulb is warmed, its volume is increased and it overflows into the tube, increasing the height of the column of liquid in the tube. If, on the other hand, the liquid in the bulb is cooled, its volume is diminished; and, as it shrinks, the column of liquid in the tube flows back into the bulb, and the level of the top of the column is lowered. If a mark is made on the tube, or on a scale fixed to it, at the point which the liquid reaches when the That hot water is lighter than cold is easily seen when a bath is filled from two taps, one of hot and one of cold water, which run at the same time. Unless care is taken to stir the water, the top of the bath will be very much hotter than the bottom. Thus, an imperial pint of water weighs a pound and a quarter only at a certain temperature or degree of warmth, namely at 62°; if it is made hotter its volume increases, and therefore its specific gravity diminishes. It was for this reason that in § 22 the weight of the same volume of water was said to be constant under the same conditions; and, of course, the same qualification must be borne in mind when we speak of the weight of a cubic inch of water being about 252 and a half grains. Its weight is in fact 252·45 grains only when Fahrenheit’s thermometer stands at 62°—but as this is the temperature of ordinary mild weather, and the expansion or contraction of water for a degree about this temperature amounts to less than 1 Thus a change is effected in the properties of water by heating it ever so little. If it is more strongly heated a still greater change takes place. You know what happens when a saucepan containing water is put on the fire. The water gets hotter and hotter, then it begins to simmer, and finally, when it reaches 212°, it boils away into steam, which passes into the air and disappears. If the boiling is carried on long enough all the water vanishes. It looks at first as if the water had been destroyed by the heat. In reality, however, not a particle of water has been destroyed. It has merely changed its state. The heat has altered it from the state of liquid water into that of gaseous water, vapour or steam. Try the same experiment with a tea-kettle instead of a saucepan, but only put a little water in the tea-kettle, and shut the lid well down. Then, as soon as the water begins to boil, the steam will shoot out of the spout in a jet; and this will go on as long as any water remains in the kettle. The steam, as it comes out of the spout, is so hot that it will scald you if you put your finger in it. But you may satisfy yourself that it is very hot, without scalding your fingers, by holding a stick of sealing-wax in it. The wax will soften, just as if you held it before the fire. Moreover, if you look through the steam, just where it leaves the spout, you will see that it is quite transparent; it is only at some little distance from the spout that it loses its transparency, changes into a white opaque cloud, and rapidly vanishes in the air. 33. The taking away of Heat from Steam causes the steam to change into Hot Water.Now take a cold spoon, or a cold plate, and hold it against the jet of steam, for a moment or two. When you take it away, you will find that it is quite wet, being covered with drops of warm water, and, moreover, the cold spoon, or plate, has become warm. And if you fit a long cold metal pipe to the nozzle of the tea-kettle, you will find that no steam at all issues from the end of the pipe, but only water, while the pipe becomes warmed. Thus the heat passes from the fire into the saucepan, or kettle, and thence to the water which they contain; the water gets hotter and hotter, and, when it has taken in a certain quantity of heat, it becomes steam, or vapour of water. When the steam comes against the cold plate, or passes through the cold pipe, it gives up the heat it has taken in to the plate, or the metal of the pipe. They carry off the heat which kept the water in a condition of a vapour, and so it passes back into the condition of liquid. Thus steam and water are two conditions of the same thing, water; they are effects of the quantity of heat which the water has taken in. 34. When Water is changed into Steam, its Volume becomes about 1,700 times greater that it was at first.If you could measure and weigh the water in your kettle to begin with, and then measure and weigh all the steam into which the heat of the fire changes it, you would find that the bulk of the steam was nearly 1,700 times as great as the bulk of the water, though The power with which water expands when it is converted into steam is very great. If you were to stop up the nozzle of the tea-kettle, the steam, inside the kettle, in trying to expand, would burst open the lid; and if you were to fasten down the lid, it would pretty soon burst the kettle itself. You sometimes hear of the strong boilers of steam-engines being burst in this way. 35. Gases or Elastic Fluids. Air.Here is a glass flask with a long neck and an open mouth. If we pour water in at the mouth until it rises to the lip we say that the flask is full of water. If we now pour the water out we say that the flask is empty. But is it empty? Press the flask mouth Air therefore has all the characters of a material substance. Moreover it is a fluid, for it fits itself exactly to the shape of any vessel which contains it; its parts are very easily moved, or we should feel its resistance every time we move a limb; that it “flows” is seen in every breeze and every time you use a pair of bellows, when the air is driven in a stream out of the nozzle; and it presses on all sides anything contained in it. But though air is a fluid it is not a liquid. In the first place it is very compressible. We saw that the water entered a little way into the tube or the neck of 36. Steam is an Elastic Fluid or Gas.In all the properties which have been mentioned water in the form of steam is an elastic fluid or gas like air. If a little water is placed in the flask mentioned in the preceding section all the “empty” part of the space will contain air. If the flask is now made hot the water will at length boil, bubbles of steam forming in the water and breaking at its surface. By degrees, the air, which at first lay above the water, will be driven out; and if the whole flask is kept hot, the “empty” part of it will be full of the gaseous water, which is transparent and colourless like air. The steam flows out of the mouth of the flask still a clear and colourless gas; but it soon cools and becomes condensed as a cloud of small particles of fluid water. Steam is lighter than air, and hence it rises in the air, just as bodies which are lighter than water rise in water. 37. Gases and Vapours.Air is as much a gas in the coldest winter as it is in the hottest summer. But air can be liquefied by exposing it to a very low temperature, while, at the same time, it is subjected to an extremely great pressure. Thus, the difference between gases like air, which are condensed with extreme difficulty, and gases like steam, which are condensed easily, is only one of degree. Nevertheless there is a certain convenience in distinguishing those gases, which, like steam, are easily condensed as vapours. In what we ordinarily call steam, all the water of which it is composed remains gaseous only at and above the temperature of boiling water (212° Fahrenheit). Cooled ever so little below this point, most of it becomes condensed into hot liquid water. However, it must be recollected that though that particular form of gaseous water which we call steam exists only at and above the temperature of boiling water, yet water is capable of existing in the gaseous state down to the freezing-point. Suppose that when our boiling flask contained nothing but water and steam, the mouth were stopped and the lamp removed. Then, so long as the temperature of the whole remained at that of boiling water, every cubic inch of steam above the water in the flask would weigh about ?th of a grain, since 100 cubic inches weigh about 15 grains. Suppose the capacity of the flask, exclusively of the fluid water in it, to be 100 cubic inches. Then, to begin with, the gaseous water which it contains will weigh 15 grains. If the flask is now allowed to cool, more and more of the gaseous water condenses into the Suppose an elastic bag were to be tied on to the nozzle of a kettle full of boiling water. If the bag were kept as hot as the boiling water it would become fully distended, and maintain its shape in spite of the pressure of the air upon all sides of it. If the bag were taken away it would retain its shape so long as it was kept as hot as boiling water; but, if it were allowed to cool, it would gradually become flattened by the outside air squeezing up the less and less resisting gaseous water of the lower temperatures. Hence, when the stopped flask has been allowed to cool, the air rushes in with great violence if it is opened. 38. The Evaporation of Water at ordinary Temperatures.If some water is poured into a saucer and is Air is said to be moist when the weight of water in a given quantity, say 100 cubic inches, is as much, or nearly as much, as can exist in the state of gas at the temperature. Under these circumstances, if the temperature is lowered even a very little, some of the gaseous water is converted into liquid water. We see this in hot moist weather, when the outside of a tumbler of fresh drawn cold spring water immediately becomes bedewed. The gaseous water in immediate contact with the tumbler, in fact, is cooled down below the point at which it can all exist as gas, and the superfluity is deposited as dew. In such days wet clothes do not dry well, because there is, already, nearly as much gaseous water in the atmosphere as the amount of heat marked by the thermometer can maintain in that state. 39. When Hot Water is cooled, it Contracts to begin with, but after a time Expands.We have now seen what a wonderful change is On the other hand, if warm water is allowed to cool, it gradually contracts till it reaches the ordinary temperature of the air in mild weather; but, if the weather is very cold, or if the water is cooled artificially, it goes on contracting only down to a certain temperature (39°), and then begins to expand again. In this peculiarity water is unlike all other bodies which are fluid at ordinary temperatures. Hence the temperature of 39° is that at which pure water has its greatest density or specific gravity, and water at this temperature is heavier, bulk for bulk, than the same water at any other temperature. Therefore if water at the top of a vessel is cooled down to this temperature, it falls to the bottom, and if the water at the bottom of a vessel is cooled below this temperature it rises to the top. 40. Water cooled still further becomes the transparent brittle solid Ice.Our tumbler of water, if put out of doors on a cold winter’s night, would gradually cool until it assumed a temperature of 39° throughout. Cooling below this temperature, the water so cooled would gradually accumulate at the surface by reason of its less density, and its temperature would fall till the thermometer placed in it marked 32°. As soon as this upper water cooled ever so little below 32°, a film like glass would form on its surface by the conversion of the coldest fluid water into solid water or ice. And if all the In this condition water is solid. It occupies space, offers resistance, has weight and transmits motion as the water did, but if you shake it out of the tumbler in a cold place it retains its form without the least change. If you press it, it proves to be exceedingly hard and unyielding; and, if the pressure is increased, it becomes crushed and breaks like glass. It may thus be crushed to powder, and the ice powder can be formed into heaps as if it were sand. Just as any quantity of steam has exactly the same weight as the water which was converted into it by heat; so the ice has exactly the same weight as the water which has been converted into it by taking away heat. 41. Ice has less Specific Gravity than the Water from which it was formed.But though the ice in the tumbler has the same weight as the water had, it has not the same volume. The expansion which began at 39° goes on, and when water passes into the solid state its volume is about 1 But although water in freezing expands only to this small amount, it resembles steam in the tremendous force with which it expands. If you fill a hollow iron shell quite full of water, screw down the opening tight, and then put it in a cold place where the water may freeze, the water as it freezes will burst the iron walls of the shell. You know that when the winter is severe, the pipes by which water is brought 42. Hoar Frost is the Gaseous Water which exists in the Atmosphere, condensed and converted into Ice Crystals.In the winter-time you often notice, on a clear sharp night, that the tops of the houses and the trees are covered with a white powder called hoar frost; and, on the windows of the room when you wake up, you see most beautiful figures, like delicate plants. Take a little of the hoar-frost, or scrape off some of the stuff that makes the window look like ground glass, and you find that it melts in your hand and turns to water. It is in fact ice. And if you look at the figures on the window pane with a magnifying glass you will see that they are made up bits of ice which have a definite shape, and are arranged in a regular pattern. Each of these definitely shaped bits of ice has been formed in the following way. The air in the room is much warmer than that outside, and there is mixed with it nearly as 43. When Ice is warmed it begins to change back into Water as soon as the Temperature reaches 32°.A lump of ice brought out of the open air in very cold weather may have a temperature of 30°, or 20°, or lower. If such a lump is brought into a warm room it gradually becomes warmer, but remains unchanged otherwise, until it has risen to 32°. Then it begins to melt, and remains at 32° as long as it is melting; and the water which proceeds from it is at first also at 32°. If you were to throw a lump of ice into the middle of a hot fire, so long as a particle of ice remained as such, it would have a temperature of 32° and no more. This is a fact exactly parallel to that which is observed 44. Ice the solid, Water the liquid, and Steam the gas, are three states of one natural object; the Condition of each State being a certain Amount of Heat.Ice, liquid water, and steam, are three things as unlike as any three things can well be. What do we mean then by saying that they are states of one substance, water? What we really mean is that if we take a given quantity of water, say a cubic inch, and change it first into ice and then into steam, there is something which remains identically the same through all these changes. This something is, in the first place, the weight of the material substance. The water weighs 252½ grains, the ice into which it is converted weighs 252½ grains, and the steam produced from it weighs 252½ grains. In the second place, the same force would cause the ice, the water, and the steam, to move with the same rapidity; and, when set in motion, they would produce the same effect upon anything movable against which they struck. In the third place, when you study chemistry, you will learn that the ice, the steam, and the liquid water, would yield the same weight of the same two gases, oxygen and hydrogen, and nothing else. Every one cubic inch of water, 1,700 cubic inches of steam, and 1 As there is not the slightest difference in weight between a given quantity of water and the ice, or the steam, into which it may be converted, it is clear that the heat which is added to or taken from the water to give rise to these several states, can possess no weight. If then heat is a material body, it must be devoid of weight—and hence, in former times, heat was called an imponderable substance. It was thought to be a kind of fluid, called caloric, which had no weight, and which drove the particles of bodies asunder, when it entered them as they were heated, and let them come together as it left and they grew cool. 45. The Phenomena of Heat are the Effects of a rapid Motion of the Particles of Matter.This much, however, is certain: that heat can be caused by motion. Every boy knows that a metal button may be made quite hot by rubbing it. A skilful smith will hammer a piece of iron red hot. The axles of wheels become red hot by rubbing against their bearings, if they are not properly lubricated; and even two pieces of ice may be melted by the heat evolved when they are rubbed together. And there are abundant other reasons, as you will find when you study physics, for the belief that the sensation we call heat, and all the phenomena which we ascribe to heat, are the effects of the rapid motion of matter. However, a quiescent body may be made hot without exhibiting the least appearance of motion. The The answer to this question is that the motion which causes the phenomena of heat, is not a visible motion of the whole mass of the hot body, but a motion of the individual particles of which it is composed. And each particle moves, not straight forward, but backwards and forwards in the same space, so that its motion may be roughly compared to that of a pendulum, or to that of the balance-wheel of a watch. It is in fact a sort of vibratory movement; each vibration taking place through a very short distance and with extreme rapidity. The sensation of heat is caused by the vibratory movements of the particles of matter, just as sound is so caused. The prongs of a tuning-fork which has been struck, certainly vibrate, for you can see them do so if the note is low. If you now put your ear at one end of a long piece of timber and the handle of the vibrating tuning-fork is placed upon the other end, the vibratory motion of the tuning-fork will be communicated to the particles of the wood and will be loudly heard. All the time the sound is heard the particles of the wood are vibrating. Nevertheless, the wood as a whole does not move, but its particles swing backwards and forwards through such a minute space that their motion is imperceptible. But what are these particles of matter which by their vibration give rise to the phenomena of heat? 46. The Structure of Water.We have seen that pure water is perfectly clear and transparent. The naked eye can discern no difference between one part and another. In other words, it has no visible texture or structure. It does not follow that it really possesses none, however, for there are many things which seem to be the same throughout, or homogeneous, which yet show structure if they are examined with a magnifying glass. Thus the surface of a sheet of fine white paper looks perfectly even and smooth to the eye; but a magnifying glass of no great power will show the minute woody fibres of which it is made up; while, under a powerful microscope, the paper looks like a coarse matting. But if we put a small drop of water on a slide, such as is used for microscopic objects, and cover it over with a thin glass so as to spread it out into a film, perhaps not more than 1 It is certain that solid bodies may be divided into particles so minute that the best microscopes show no trace of them. Common gum-mastic cannot be dissolved by water, but it readily dissolves in strong spirit or alcohol, and mastic varnish is an This milkiness arises from the presence of solid particles of mastic diffused through the water; and yet, if the experiment has been properly managed, a drop of the fluid may be spread out as before and examined with the highest magnifying powers, and nothing can be seen of such particles. So far as vision goes it might be a drop of pure water. Now our best microscopes are able to show us anything solid which has a diameter of 1 47. Suppositions or Hypotheses; their Uses and their Value.When our means of observation of any natural fact fail to carry us beyond a certain point, it is perfectly legitimate, and often extremely useful, to make a supposition as to what we should see, if we could carry direct observation a step further. A supposition of this kind is what is called a hypothesis, and the value of any hypothesis depends upon the extent to which reasoning upon the assumption that it is true, enables us to explain or account for the phenomena with which it is concerned. Thus, if a person is standing close behind you, and you suddenly feel a blow on your back, you have no direct evidence of the cause of the blow; and if you two were alone, you could not possibly obtain any; but you immediately suppose that this person has struck you. Now that is a hypothesis, and it is a legitimate hypothesis, first, because it explains the fact; and, secondly, because no other explanation is probable; probable meaning in accordance with the ordinary course of nature. If your companion declared that you fancied you felt a blow, or that some invisible spirit struck you, you would probably decline to accept his explanation of the fact. You would say that both the hypotheses by which he professed to explain the phenomenon were extremely improbable; or in other words, that in the ordinary course of nature fancies of this kind do not occur, nor spirits strike blows. In fact, his hypotheses would be illegitimate, and yours would be legitimate; and, in all probability, you would act upon your own. In daily life, nine-tenths of our actions are based Thus, everybody invents, and, indeed, is compelled to invent, hypotheses in order to account for phenomena of the cause of which he has no direct evidence; and they are just as legitimate and necessary in science as in common life. Only the scientific reasoner must be careful to remember that which is sometimes forgotten in daily life, that a hypothesis must be regarded as a means and not as an end; that we may cherish it so long as it helps us to explain the order of nature; but that we are bound to throw it away without hesitation as soon as it is shown to be inconsistent with any part of that order. 48. The Hypothesis that Water is composed of Separate Particles (Molecules).It has been pointed out that we cannot see, and indeed that there is not much hope of our ever being able to see, the separate particles of water, even if water is composed of such particles. But it is perfectly legitimate to suppose that water is made up of such particles, if that hypothesis will enable us to explain the properties of water. Let us suppose then that any portion of fluid water is really composed of a prodigious number of particles less (and probably much less) than a millionth of an inch in diameter. We may call these particles molecules. 4. Diminutive of moles, a mass. What is it that keeps the molecules apart? We have seen that great mechanical pressure brings them but slightly nearer to one another; hence there is an equivalent resistance of some kind which keeps them apart. This resistance must have the same origin as the sensation which we know as heat, for it has been seen that diminution of heat diminishes the bulk of water; that is, allows the molecules to come closer together; that is, diminishes their tendency to keep asunder. Increase of heat, on the other hand, increases the volume of water; that is to say, drives the molecules further apart, or increases their tendency to keep asunder. Suppose we call the cause of the tendency of the molecules of water to come together an attractive force; and the cause of their keeping apart, which manifests itself to us as the sensation of heat and is, as we have seen, in all probability, a rapid vibratory or whirling motion of the molecules, a repulsive force; then, in the liquid state, these forces are so adjusted that the molecules are quite free to move, and yet hold together. By adding heat the repulsive force is increased, until the molecules are about twelve times as far apart as they were in each direction; while the attractive It is probable that the expansion of fluid water, at a temperature below 39°, depends upon the molecules taking up a peculiar arrangement as they approach one another. If sixteen men are formed into a column, four deep, and each man a foot from the other, the same men may stand closer together and yet form a hollow square, which occupies a larger space. That the molecules of water do take up a particular order in assuming the solid condition, is shown by the crystalline form of ice. Each crystal of hoar-frost owes its shape to the arrangement of its molecules, according to a definite geometrical pattern. Thus the hypothesis that water is composed of separate molecules, is useful, for it helps us to some extent to explain the properties of water. And, when you study physics and learn the laws of motion, you will find that there is no end to the number of the truths established by observation and experiment, which can be explained by this hypothesis. Hence it may fairly be adopted and employed as a means of picturing to ourselves the order of nature, so long as no facts are discovered which are inconsistent with it. 49. All Matter is probably made up either of Molecules or of Atoms.The same reasons which lead to the adoption of the hypothesis that water is composed of separate The metal mercury or quicksilver, for instance, may be supposed to be made up of distinct particles of mercury of extreme minuteness, and according to the temperature, these associate themselves in the solid (frozen mercury), liquid (ordinary quicksilver), or gaseous form (vapour of mercury). To whatever treatment pure mercury may be subjected, we cannot get anything but mercury out of it. The particles of mercury have never been broken up. Hence they are generally termed atoms, or particles that cannot be divided; and mercury is said to be an element, or a substance which is not compounded of any other substances. Here is a case in which it is very useful to distinguish between fact and hypothesis. The matter of fact is that, up to the present time, no one has been able to get out of pure mercury anything but pure mercury. The statement that mercury is a simple substance, and therefore never can be broken up into any other substances, is a hypothesis which future observation and experiment may or may not confirm. A hundred and fifty years ago it was universally believed that water was as much an element as mercury. But water is now well known to be a compound. In fact, as has already been said, the particles of water may be very readily broken up or decomposed (in what way, you will learn when you study chemistry) into two totally distinct substances, oxygen and hydrogen, which are gaseous at all known temperatures, though by combining vast pressure with extreme cold they have recently been Nine parts by weight of pure water always yield eight of oxygen and one of hydrogen. The hypothetical particle, or molecule of water, therefore, must be composed of atoms of oxygen and hydrogen having this relative weight; and chemists have grounds for believing that one atom of oxygen and two atoms of hydrogen exist in each molecule of water. If this be so, the structure of water must be more complicated than we thought at first; and each particle of water (the molecule) must be a system composed of three separate atoms. 50. Elementary Bodies are neither destroyed nor is their Quantity increased in Nature.It has been seen that when a cubic inch of water is dissipated by heat, it is not destroyed, but that it merely changes its form from the fluid to the gaseous state, while its weight remains unaltered. If the same cubic inch of water is decomposed into oxygen and hydrogen gases, the water is indeed destroyed, but the matter of which it consisted remains unchanged in weight. If the water weighed 252·5 grains, the oxygen gas will weigh 224·45 grains and the hydrogen gas will weigh 28·05 grains. And nothing that man has been able to do has affected the weight of a given quantity of either of these gases. So far as we know, elementary bodies retain their weight under all Hence it follows that natural things and artificial things resemble one another in one respect. It is true of both that the matter of which they are composed is never destroyed and never increased; and therefore the order of events in nature as much consists in the joining together and putting apart of natural bodies by natural agencies, as the order of events in the artificial world consists in the joining together and the putting apart of natural bodies by human agencies. 51. Simple Mixture.In order to learn the manner in which water may be broken up into its elements or decomposed, you must turn to the Primer on Chemistry. But as a preliminary to the study of that science, it may be useful to consider some simple cases of composition and decomposition which are exemplified by water. If half a pint of water, coloured by putting a little ink into it, is added to the same quantity of clean water, the two will readily mingle; the total quantity of water will be a pint; and its colour will be just half as dark as that of the coloured half-pint. This is a case of simple mixture. The volume of the mixture equals the sum of the volumes of the things mixed, and there is no change in the properties of these things. So when water evaporates, the gaseous water or vapour mixes with the air in the same way, the molecules of the one body dispersing themselves between On the other hand, oil and water will not mix, however much you may stir the two together; and the oil, being the lighter, rises to the top as soon as the fluid is quiet. Nor will quicksilver and water mix, but the quicksilver, being very much heavier than the water, rushes to the bottom of the vessel into which the two are put. Neither will sand nor iron filings mix with water; as heavier bodies, they also sink to the bottom. Nor does powdered ice, though it is water in another shape, mix with ice cold water; as a lighter body it floats at the top. 52. Mixture followed by Increase of Density; Alcohol and Water.Strong spirit, or alcohol, is a clear transparent fluid which looks like water, but is a very different substance. For example, it boils at a much lower temperature, it burns with a blue flame, it has intoxicating properties, and, like oil, it is very much lighter than water. Hence, if coloured spirit is poured gently upon the surface of water the spirit rests upon the water. Suppose, now, that we take a tall measure graduated into ten equal parts. Fill the lower five with water, and then, very gently, pour in the strongest alcohol, coloured in some way, until the tenth mark is reached. We shall have five volumes of water below, and an equal quantity, or five volumes, of coloured alcohol above. Where the two are in contact, the colour will be Thus far, nothing further than simple mixture, as when coloured water was added to pure water, seems to have occurred; but, in reality, something more has happened. In the first place, the mixture is a good deal warmer than either of its components; that is to say, heat has been generated. In the second place, if you measure the volume of the whole fluid after it has cooled, it no longer stands at the mark ten, but distinctly lower, or about nine and three-quarters. As the volume of the mixture is less than the sum of the volumes of its two components, it follows that the density of the mixture must be greater than a density midway between that of the water and that of the alcohol. In other words, the molecules in the mixture do not occupy the same space as they did when they were separate. The result is the same as if the ten volumes had been compressed until they occupied only nine and three-quarters; so that the effect is a contraction similar to that which would be brought about by taking away heat from the mixture. In fact, as we have seen, the mixture gives out a quantity of heat. There is another respect in which the mixture is unlike both its constituents. It both boils and Thus alcohol and water, mingled together, give rise to a fluid which is not a mere mixture, the properties of which are known if we know the properties of its components; it is, in strictness, a new body, in which the molecules of the water and those of the alcohol affect one another to a certain extent and modify the pre-existing properties of each. This effect of different bodies upon one another becomes much more manifest when water is brought into contact with certain solids. 53. Solution; Water Dissolves Salt.If a spoonful of salt is put into a tumbler of cold water and the water is stirred, the salt swiftly vanishes from view; and, after a time, so far as our sense of vision goes, the water appears to be just what it was before. But if the water in the tumbler at first weighed five ounces and the salt weighed two ounces, the water in the tumbler will now weigh seven ounces; the water will now taste salt, the salt is said to be Thus, contact with water has had a very singular effect upon the salt. It appears to have changed one of the properties of the salt, namely, its solidity, but to have left all the rest unaltered. We saw just now that powdered ice does not mix with ice-cold water, but that the fragments of ice remain solid. The moment, however, that the temperature rises, the cohesion, or sticking together of the molecules, which is the characteristic of the solid state, comes to an end; they become loose and free to move, and they mingle with the surrounding water. Or we may say that the ties which held the molecules of the solid together are dissolved, so that the solid water becomes fluid. The resemblance of this process to the dissolving of salt in water is so obvious that, in common language, it is often said that a lump of salt or of sugar melts away in water; but if you try to make salt fluid by heat, you will have to expose it to a very high If brine is allowed to evaporate slowly, the molecules of the salt arrange themselves, as the water leaves them, in beautifully regular cubical crystals. You may see them form easily enough if you watch a drop of brine gradually dry up under a microscope. The salt crystals contain nothing but salt. If they are heated till they become red-hot they pass into the fluid state; and when still further heated, the fluid salt becomes a vapour or gas and, as such, flies off into the air, or volatilizes. Thus we see that when salt and water are brought into contact, the salt undergoes a certain amount of change, while the water does not remain wholly unchanged. For brine no longer boils at 212°, but requires a considerably higher temperature. The salt, as it were, holds the water back, and prevents it from assuming the gaseous state under the same conditions as if it were pure, just as, in the previous case, the water held the alcohol back; or we may say that the force of heat which drives the molecules of liquid water apart, when If we mean by attraction that which opposes any force which tends to separate bodies, then we may say that the molecules of salt and those of water attract one another. And such attraction between molecules of matter of different kinds is called chemical attraction. 54. Quicklime and Water: Plaster of Paris and Water: Combination.Quicklime is a substance obtained by heating chalk or limestone to redness. When pure, it is a white hard solid which can be made to pass into the liquid and gaseous states only at enormously high temperatures. If a lump of fresh quicklime be placed in a saucer and about one-third of its weight of water poured upon it, there will be a great turmoil, heat will be evolved, the water will disappear, and the lime will crumble down into a soft white powder. This operation is what bricklayers call slaking lime. And if no more water has been added than the proportion mentioned, the pure white powder which results will be solid and dry, the water having, to all appearance, vanished. In the solution of salt we saw a solid become fluid under the influence of water; in the slaking of lime the fluid water enters into the structure of a solid. The water thus bound up with the lime into a new solid holds on so firmly to the lime that it requires a red heat to separate the two. The lime and the water are said to be chemically combined; and as the proportion of lime and water in slaked lime, or lime crystals, is always the same, they are said to be combined in definite proportions; and the slaked lime receives the special name of hydrate of lime. Gypsum or Plaster of Paris is a dry white powder. If mixed with a little water it does not slake after the fashion of quick lime, but the mixture soon sets or becomes hard; and, at the same time, the greater part of the water disappears. In fact, it has combined with the plaster of Paris and forms part of another hydrate, in which, when the superfluous moisture dries, not a trace of water is to be seen. It is this property which is taken advantage of when plaster of Paris is used in making casts and moulds. The fluid plaster is poured over and round the body to be cast; as a fluid, it applies itself conveniently to all the inequalities of its surface; and, when it sets, it retains the shape which it has thus acquired. Set plaster of Paris may be perfectly dry; but it nevertheless contains Gypsum is found abundantly in nature, in the shape of beautiful transparent crystals which are called selenite. These crystals have the same composition as set plaster, that is to say, they are hydrates. A thin flake of such a crystal viewed with the highest powers of the microscope appears perfectly homogeneous. Nevertheless, there is good reason for the conclusion that it consists of molecules of water and molecules of gypsum which hold together so strongly that they form a hard brittle glassy solid. Moreover, the molecules of the hydrate itself hold together more strongly in some directions than in others. It is very easy to split the crystals lengthwise; while much more force is needed to cut them crosswise and then they do not split, but break. Glauber’s salts and Epsom salts are other examples of solids which dissolve in water and separate in the crystalline form as the water evaporates; and which, like lime and gypsum, combine with a definite proportion of water to form crystalline compounds. In fact, each of these glassy brittle solids contains more than half its weight of water. Thus we see that two bodies, of which water is one, may combine together to give rise to something different from either. And we are thus led to the science of chemistry, which tells us exactly how bodies combine, what comes of their combination, and how compounds may be separated into their constituents. Water and all the other natural bodies which have hitherto been mentioned, are what are called mineral bodies, although, in common use, the term mineral is usually restricted to ores and metals. Now we have repeatedly had occasion to remark that, under certain circumstances, not only water, but many other mineral bodies, assume regular shapes. The most familiar example is that of the beautiful imitation of leaves and foliage which is presented by the ice which forms on a window in winter. But we have also seen that common salt, lime, gypsum, Glauber’s salts and Epsom salts, also assume the crystalline form as they or their compounds with water are deposited from their solutions. And if a drop of solution of Glauber’s salts or of Saltpetre, is allowed to evaporate under the microscope, a wonderful spectacle will be presented. As the salt assumes the solid state, the crystals suddenly appear in the field of view as needles and plates disposed in beautiful patterns, which rival those of hoar frost, though they are quite different from them. In fact, as you will learn if you study crystallography, every crystallizable substance has its proper crystalline forms and never departs from certain strictly related geometrical figures. A crystal of any of these substances will grow if placed under proper conditions. Thus, if a crystal of common salt is hung by a thread in a saturated solution of salt, which is exposed to the air, so as to allow the water to evaporate slowly, the molecules of the salt which is left behind and can no longer be held |