CHAPTER VII.

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LIGHT.

Theories of the Nature of Light—Hypotheses of Newton and Huygens—Sources of Light—The Sun—Velocity of Light—Transparency—Dark Lines of the Spectrum—Absorption of Light—Colour—Prismatic Analysis—Rays of the Spectrum—Rainbow—Diffraction—Interference—Goethe’s Theory—Polarisation—Magnetisation of Light—Vision—The Eye—Analogy—Sound and Light—Influence of Light on Animals and Vegetables—Phosphorescence arising from several Causes—Artificial Light—Its Colour dependent on Matter.

Light, the first creation, presents to the enquiring mind a series of phenomena of the most exalted character. The glowing sunshine, painting the earth with all the brilliancy of colour, and giving to the landscape the inimitable charm of every degree of illumination, from the grey shadow to the golden glow;—the calm of evening, when, weary of the “excess of splendour,” the eye can repose in tranquillity upon the “cloud-land” of the west, and watch the golden and the ruddy hues fade slowly into the blue tincture of night;—and the pale refulgence of the moon, with the quiet sparkle of the sun-lit stars,—all tend to impress upon the soul, the great truth that, where there is light, organisation and life are found, and beyond its influence death and silence hold supreme dominion.[84] Through all time we have evidences that this has been the prevailing feeling of the human race, derived, of course, from their observation of the natural phenomena dependent upon luminous agency. In the myths of every country, impersonations of light prevail, and to these are referred the mysteries of the perpetual renewal of life on the surface of the earth.

This presentiment of a philosophic truth, in the instance of the poet sages of intellectual Greece, was advanced to the highest degree of refinement; and the sublime exclamation of Plato: “Light is truth, and God is light,” approaches nearly to a divine revelation.

As the medium of vision—as the cause of colour—as a power influencing in a most striking manner all the forms of organisation around us, light presented to the inquiring minds of all ages a subject of the highest interest.

The ancient philosophers, although they lost themselves in the metaphysical subtleties of their schools, could not but discover in light an element of the utmost importance in natural operations. The alchemists regarded the luminous principle as a most subtile fluid, capable of interpenetrating and mingling with gross matter: gold being supposed to differ from the baser metals only in containing a larger quantity of this ethereal essence.[85] Modern science, after investigating most attentively a greater number of the phenomena of light, has endeavoured to assist the inquiry by the aid of hypotheses. Newton, in a theory, which exhibits the refined character of that great philosopher’s mind, supposes luminous particles to dart from the surfaces of bodies in all directions—that these infinitely minute particles are influenced by the attracting and repelling forces of matter, and thus turned back, or reflected, from their superficies in some cases, and absorbed into their interstitial spaces in others.

Huyghens, on the contrary, supposes light to be caused by the waves or vibrations of an infinitely elastic medium—Ether—diffused through all space, which waves are propagated in every direction from the luminous body. In the first theory, a luminous particle is supposed actually to come from the sun to the earth; in the other, the sun only occasions a disturbance of the ether, which extends with great rapidity, in the same manner as a wave spreads itself over the surface of a lake.

Nearly all the facts known in the time of Newton, and those discovered by him, were explained most satisfactorily by his hypothesis; but it was found they could be interpreted equally as the effects of undulation, with the exception of the production of colour by prismatic refraction. Although the labours of many gifted minds have been given, with the utmost devotion, to the support of the vibratory theory, this simple fact has never yet received any satisfactory explanation; and there are numerous discoveries connected with the molecular and chemical disturbances produced by the sun’s rays, which do not appear to be explained by the hypothesis of emission or of undulation.

In both theories a wave motion is admitted, and every fact renders it probable that this mode of progression applies not only to light, but to the so-called imponderable forces in general. Admitting, therefore, the undulatory movement of luminous rays, we shall not stop to consider those points of the discussion which have been so ably dealt with by Young, Laplace, Fresnel, Biot, Fraunhofer, Herschel, Brewster, and others, but proceed at once to consider the sources of light, and its more remarkable phenomena.[86]

The sun is the greatest permanently luminous body we are acquainted with, and that orb is continually pouring off light from its surface in all directions at the rate, through the resisting medium of space and of our own atmosphere, of 192,000 miles in a second of time. It has been calculated, however, that light would move through a vacuum with the speed of 192,500 miles in the same period. We, therefore, learn that a ray of light requires eight minutes and thirteen seconds to come from the sun to us. In travelling from the distant planet Uranus, nearly three hours are exhausted; and from the nearest of the fixed stars each ray of light requires more than six years to traverse the intervening space between it and the earth. Allow the mind to advance to the regions of nebulÆ, and it will be found that hundreds of years must glide away during the passage of their radiations. Consequently, if one of those masses of matter, or even one of the remote fixed stars, was “blotted out of heaven” to-day, several generations of the finite inhabitants of this world would fade out of time before the obliteration could be known to man. Here the immensity of space assists us in our conception, limited though it be, of the for-ever of eternity.[87]

All the planets of our system shine with reflected light, and the moon, our satellite, also owes her silvery lustre to the sun’s radiations. The fixed stars are, in all probability, suns shining from the far distance of space, with their own self-emitted lights. By the photometric researches of Dr. Wollaston, we learn, however, that it would take 20,000 millions of such orbs as Sirius, the brightest of the fixed stars, to afford as much light as we derive from the sun. The same observer has proved that the brightest effulgence of the full moon is yet 801,072 times less than the luminous power of our solar centre.

The cultivators of modern science are a bold race; not contented with endeavouring to understand the physical earth, they are endeavouring to comprehend the condition of the solar surface. The mind of man can penetrate far into nature, and, as it were, feel out the mysteries of untraversed space. The astronomer learns of a peculiar condition of light, which is termed polarisation, and he learns by this, too, that he can determine if from a bright luminous disc the light is derived from a solid mass in a state of intense ignition, or from vapour in an incandescent condition. He adds a polarising apparatus to his telescopes, and he determines that the light we derive from the sun is due to an envelope of vapour—burning, in all probability—only with greater intensity, as the gas which we now employ. This Photosphere—as it has been called by the late French philosopher Arago, is found to be subjected to violent disturbances, and the dark spots seen on the sun’s disc are now known to be openings through this mysterious envelope of light, which enable us to look in upon the dark body of the sun itself.

Luminous phenomena may be produced by various means—chemical action is a source of light; and, under several circumstances in which the laws of affinity are strongly exerted, a very intense luminous effect is produced. Under this head all the phenomena of combustion are included. In the electric spark we have the development of light; and the arc which is formed between charcoal points at the poles of a powerful voltaic battery affords us the most intense artificial illumination with which we are acquainted. In addition to these, we have the peculiar phenomena of phosphorescence arising from chemical, calorific, electrical, actinic, and vital excitation, all of which must be particularly examined.

From whatever source we procure light, it is the same in character, differing only in intensity. In its action upon matter, we have the phenomena of transmission, of reflection, of refraction, of colour, of polarisation, and of vision, to engage our attention.

A beam of white light falls upon a plate of colourless glass, and it passes freely through it, losing but little of its intensity; the largest portion being lost by reflection from the first surface upon which the light impinges. If the glass is roughened by grinding, we lose more light by absorption and by reflection from the asperities of the roughened surface; but if we cover that face with any oleaginous fluid, as, for instance, turpentine, its transparency is restored. We have thus direct proof that transparency to light is due to molecular condition. This may be most strikingly shown by an interesting experiment of Sir David Brewster’s:—

If a glass tube is filled with nitrous acid vapour, which is of a dull red colour, it admits freely the passage of the red and orange rays with some of the others, and, if held upright in the sunshine, casts a red shadow on the ground; by gently warming it with a spirit-lamp, whilst in this position, it acquires a much deeper and blacker colour, and becomes almost impervious to any of the rays of light; but upon cooling it again recovers its transparency.

It has also been stated by the same exact experimentalist, that having brought a purple glass to a red heat, its transparency was improved, so that it transmitted green, yellow, and red rays, which it previously absorbed; but the glass recovered its absorptive powers as it cooled. A piece of yellowish-green glass lost its transparency almost entirely by being heated. Native yellow orpiment becomes blood-red upon being warmed, when nearly all but the red rays are absorbed; and pure phosphorus, which is of a pale yellow colour, and transmits freely all the coloured rays upon being melted, becomes very dark, and transmits no light.

Chemistry affords numerous examples of a very slight change of condition, producing absolute opacity in fluids which were previously diaphanous.[88]

Charcoal absorbs all the light which falls upon it, but in some of its states of combination, and in the diamond, which is pure carbon, it is highly transparent. Gold and silver beaten into thin leaves are permeated by the green and blue rays, and the metals in combination with acids are all of them more or less transparent. What becomes of the light which falls upon and is absorbed by bodies, is a question which we cannot yet, notwithstanding the extensive observations that have been made by some of the most gifted of men, answer satisfactorily. In all probability, as already stated, it is permanently retained within their substances; and many of the experiments of exciting light in bodies when in perfect darkness, by the electric spark and other means, appear to support the idea of light becoming latent or hidden.

No body is absolutely transparent; some light is lost in passing even through ethereal space, and still more in traversing our atmosphere.

Amongst the most curious instances of absorption is that which is uniformly discovered in the solar spectrum, particularly when we examine it with a telescope. We then find that the coloured rays are crossed by a great number of dark bands or lines, giving no light; these are generally called Fraunhofer’s dark lines, as it was to the indefatigable exertions of that experimentalist, and by the aid of his beautiful instruments, that most of them were discovered and measured, and enumerated, although they were previously noticed by Dr. Wollaston. It is quite clear that those lines represent rays which have been absorbed in their passage from the sun to the earth: although some of them have no doubt undergone absorption within the limits of the earth’s atmosphere, we have every reason to believe, with Sir John Herschel, that the principal absorption takes place in the atmosphere of the sun.[89]

It has been proved by Dr. Miller, that the number of those dark lines is continually varying with the alteration of atmospheric conditions;[90] and the evidences which have been afforded, of peculiar states of absorption by the gaseous envelope of the earth,—during the prosecution of investigations on the chemical agencies of the sun’s rays,—are of a sufficiently convincing character.

It has been calculated by Bouguer, that if our atmosphere, in its purest state, could be extended rather more than 700 miles from the earth’s surface instead of nearly 40, as it is at present, the sun’s rays could not penetrate it, and this globe would roll on in darkness and silence, without a vestige of vegetable form or of animal life. In the Hebrew version of the Mosaic History, the reading is, “Let light appear:” may not this really mean that the earth’s atmosphere was so cleared of obstructing vapours, that the solar rays were enabled to reach the earth? The same calculation supposes that sea-water loses all its transparency at the depth of 730 feet; but a dim twilight must prevail much deeper in the ocean.

The researches of Professor Edward Forbes have proved, that at the depth of 230 fathoms in the Ægean sea, the few shelled animals that exist are colourless: no plants are found within that zone; and that industrious naturalist fixes the zero of animal life of those waters at about 300 fathoms.[91] Since these zones mark the rapidly diminishing light, it is evident that where life ceases to be must be beyond the limits to which life can penetrate.

Our atmosphere, charged with aqueous vapour, serves to shield us from the intense action of the solar powers. By it we are protected from the destructive influences of the sun’s light and heat; enjoy those modified conditions which are most conducive to the healthful being of organic forms; to it we owe “the blue sky bending over all,” and those beauties of morning and evening twilight of which

—— Sound and motion own the potent sway.
Responding to the charm with its own mystery.

To defective transparency, or rather to the different degrees of it, we must attribute, in part, the colours of permeable media. Thus, a glass or fluid appears yellow to the eye, because it has the property of admitting the permeation of a larger quantity of the yellow rays than of any others;—red, because the red rays pass it with the greatest freedom; and so on for every other colour. In most cases the powers of transmission and of reflection are similar; but it is not so in all; a variety of fluor spar, which, while it transmits green light, reflects blue, and the precious opal, are striking instances to the contrary. Some glasses, which transmit yellow light have the singular power of dispersing blue rays from one surface; and a solution of quinine in water acidulated with sulphuric acid, although perfectly transparent and colourless when held between the eye and the light, exhibits, if viewed in a particular direction, a lively cerulean tint. These effects being supposed to be due to the conditions of the surface, have been called epipolic phenomena.[92]

The careful investigation of these phenomena has made us acquainted with some very interesting facts, and indeed discovered to us a set of luminous rays which were previously unknown. The dispersion of blue light from the surface of some yellow glasses—such as have been coloured by the oxide of silver—is of a different order from that which takes place with the solution of sulphate of quinine, or with the fluor spar. The first depends upon a peculiar condition of the surface, while the latter phenomena are due to a dispersion which takes place within the solid or fluid. In addition to the sulphate of quinine, and the fluor spar, we obtain the same results in a very marked manner by a canary yellow glass, coloured with the oxide of uranium, and by a decoction of the inner bark of the horse-chesnut tree. Mr. Stokes, who has investigated this class of phenomena, and proposes to call it Fluorescence, from its being naturally seen in fluor-spar, has shown that the peculiar internal dispersion, and the consequent alteration of the colour of the ray, is due to an alteration in its refrangibility. Whether this hypothesis prove to be the correct one or not, it is certain that there exists a set of rays of far higher refrangibility than those seen in the ordinary Newtonian spectrum. This may be shown in the following manner: taking either of the solutions named, or a block of uranium glass, throw upon one face, by means of a prism, a very pure spectrum. On looking into the glass or fluid there will be seen, commencing amidst the most refrangible rays, a new set of spectral rays, struggling to make their way through the absorbent medium. These are of a blue colour in the quinine or chesnut solution, and green in the uranium glass, and are seen extending themselves far beyond the most refrangible rays of the ordinary Newtonian spectrum. This is the space over which those rays which have the power of producing chemical changes, such as are rendered familiar by the practice of Photography, are detected in their greatest activity. It has, therefore, been supposed that these fluorescent rays are the chemical rays rendered luminous by the alteration of their refrangibility. This view has received much support from the fact that the extra spectral rays are crossed with numerous dark lines, and that in the chemical impressions these lines are marked by unchanged spaces which exactly coincide with them. There is, however, much doubt of the correctness of this, since, in the uranium glass of such a thickness that these visible rays are quite absorbed, the chemical rays still pass.

However, the whole question requires, and is receiving, the most searching investigation. The discovery of these phenomena, which are included under the term of Fluorescence, is of that interesting and important character, that it must be ranked as the most decided advance which has been made in physical optics since the days of Newton.

It is not improbable that those rays of such high refrangibility may, although they are under ordinary circumstances invisible to the human eye, be adapted to produce the necessary degree of excitement upon which vision depends in the optic nerves of the night-roaming animals. The bat, the owl, and the cat, may see in the gloom of night by the aid of rays which are invisible to, or inactive on the eyes of man, or of those animals which require the light of day for perfect vision.

It is a general law of the radiant forces, that whenever they fall upon any surface, a portion is thrown back or reflected at the same time as other portions are absorbed or transmitted. Upon this peculiarity appear to depend the phenomena of natural colour in bodies.

The white light of the sun is well known to be composed of several coloured rays. Or rather, according to the theory of undulations, when the rate at which a ray vibrates is altered, a different sensation is produced upon the optic nerve. The analytical examination of this question shows, that to produce a red colour the ray of light must give 37,640 undulations in an inch, and 458,000000,000000 in a second. Yellow light requires 44,000 undulations in an inch, and 535,000000,000000 in a second; whilst the effect of blue results from 51,110 undulations within an inch, and 622,000000,000000 of waves in a second of time.[93] The determination of such points as these is among the highest refinements of science, and, when contrasted with the most sublime efforts of the imagination, they must appear immeasurably superior.

If a body sends back white light unchanged, it appears white; if the surface has the property of altering the vibration to that degree which is calculated to produce redness, the result is a red colour: the annihilation of the undulations produces blackness. By the other view, or the corpuscular hypothesis, the beam of white light is supposed to consist of certain coloured rays, each of which has physical properties peculiar to itself, and thus is capable of producing different physiological effects. These rays falling upon a transparent or an opaque body suffer more or less absorption, and being thus dissevered, we have the effect of colour. A red body absorbs all the rays but the red; a blue surface, all but the blue; a yellow, all but the yellow; and a black surface absorbs the whole of the light which falls upon it.

That natural colours are the result of white light, and not innate properties of the bodies themselves, is most conclusively shown by placing coloured bodies in monochromatic light of another kind, when they will appear either of the colour of that light, or, by absorbing it, become black; whereas, when placed in light of their own character, the intensity of colour is greatly increasing.

Every surface has, therefore, a peculiar constitution, by which it gives rise to the diversified hues of nature. The rich and lively green, which so abundantly overspreads the surface of the earth, the varied colours of the flowers, and the numberless tints of animals, together with all those of the productions of the mineral kingdom, and of the artificial combinations of chemical manufacture, result from powers by which the relations of matter to light are rendered permanent, until its physical conditions undergo some change.

There is a remarkable correspondence between the geographical position of a region and the colours of its plants and animals. Within the tropics, where

“The sun shines for ever unchangeably bright,”

the darkest green prevails over the leaves of plants; the flowers and fruits are tinctured with colours of the deepest dye, whilst the plumage of the birds is of the most variegated description and of the richest hues. In the people also of these climes there is manifested a desire for the most striking colours, and their dresses have all a distinguishing character, not of shape merely, but of chromatic arrangement. In the temperate climates everything is of a more subdued variety: the flowers are less bright of hue; the prevailing tint of the winged tribes is a russet brown; and the dresses of the inhabitants of these regions are of a sombre character. In the colder portions of the earth there is but little colour; the flowers are generally white or yellow, and the animals exhibit no other contrast than that which white and black afford. A chromatic scale might be formed, its maximum point being at the equator, and its minimum at the poles.[94]

The influence of light on the colours of organized creation is well shown in the sea. Near the shores we find sea-weeds of the most beautiful hues, particularly on the rocks which are left dry by the tides; and the rich tints of the actiniÆ, which inhabit shallow water, must have been often observed. The fishes which swim near the surface are also distinguished by the variety of their colours, whereas those which live at greater depths are grey, brown, or black. It has been found that after a certain depth, where the quantity of light is so reduced that a mere twilight prevails, the inhabitants of the ocean become nearly colourless. That the sun’s ray alone gives to plants the property of reflecting colour is proved by the process of blanching, or etiolation, produced by artificially excluding the light.

By a triangular piece of glass—a prism,—we are enabled to resolve light into its ultimate rays. The white pencil of light which falls on the first surface of the prism is bent from its path, and coloured bands of different colours are obtained. These bands or rays observe a curious constancy in their positions: the red ray is always the least bent out of the straight path: the yellow class comes next in the order of refrangibility; and the blue are the most diverted from the vertex of the prism. The largest amount of illuminating power exists in the yellow ray, and it diminishes towards either end.[95] It is not uninteresting to observe something like the same variety of colour occurring at each end of the prismatic spectrum. The strict order in which the pure and mixed coloured rays present themselves is as follows:—

1. The extreme red: a ray which can only be discovered when the eye is protected from the glare of the other rays by a cobalt blue glass, is of a crimson character—a mixture of the red and the blue, red predominating.[96]

2. The red: the first ray visible under ordinary circumstances.

3. The orange: red passing into and combining with yellow.

4. The yellow: the most intensely luminous of the rays.

5. The green: the yellow passing into and blending with the blue.

6. The blue: in which the light very rapidly diminishes.

7. The indigo: the dark intensity of blue.

8. The violet: the blue mingled again with the red—blue being in excess.

9. The lavender grey: a neutral tint, produced by the combination of the red, blue, and yellow rays, which is discovered most easily when the spectrum is thrown upon a sheet of turmeric paper.

10. The fluorescent rays: which are either a pure silvery blue or a delicate green.

Newton regarded the spectrum as consisting of seven colours of definite and unvarying refrangibility. Brewster and others appear to have detected a great diffusion of the colours over the spectrum, and regard white light as consisting only of three rays, which in the prismatic images overlap each other; and from these—red, yellow, and blue—all the others can be formed by combination in varying proportions. The truth will probably be found to be, that the ordinary prismatic spectrum is a compound of two spectra:—that is, as we have the ordinary rainbow, and a supplementary bow, the colours of which are inverted, so the extraordinary may be somewhat masked by the intense light of the ordinary spectrum; and yet by overlapping produce the variations of colour in the rays. We have already examined the heating power found in these coloured bands, which, although shown to be in a remarkable manner in constant agreement with the colour of a particular ray, is not directly connected with it; that is, not as the effect of a cause, or the contrary. The chemical action of the solar rays, to which from its important bearings we shall devote a separate chapter, has, in like manner with heat, been confounded with the sun’s luminous power; but although associated with light and heat, and modified by their presence, it must be distinguished from them.

We find the maximum of heat at one end of the spectrum, and that of chemical excitation at the other—luminous power observing a mean point between them. Without doubt we have these powers acting reciprocally, modifying all the phenomena of each other, and thus giving rise to the difficulties which beset the inquirer on every side.

We have beautiful natural illustrations of luminous refraction in the rainbow and in the halo: in both cases the rays of light being separated by the refractive power of the falling rain drop, or the vesicles which form the moisture constituting a fog. In the simple toy of the child—the soap-bubble floating upon the air—the philosopher finds subjects for his contemplation; and from the unrivalled play of colours which he discovers in that attenuated film, he learns that the varying thicknesses of surfaces influence, in a most remarkable manner, the colours of the sunbeam. Films of oil floating upon water present similar appearances; and the colours developed in tempering steel are due entirely to the thickness of the oxidized surface produced by heat. There have lately been introduced some beautiful specimens of paper rendered richly iridescent by the following process:—A solution of a gum resin in chloroform is floated upon water, where it forms a film giving all the colours of Newton’s rings. A sheet of paper which has been previously sunk in the water is carefully lifted, and the film thus removed adheres with great firmness to the paper, and produces this rich and curious play of colour. The rich tints upon mother-of-pearl, in the feathers of many birds, the rings seen in the cracks of rock-crystal, or between the unequal faces of two pieces of glass, and produced by many chemical and indeed mechanical operations—are all owing to the same cause;—the refraction of the luminous pencil by the condition of the film or surface. If we take one of those steel ornaments which are formed by being covered with an immense number of fine lines, it will be evident that these striÆ present many different angles of reflection, and that, consequently, the rays thrown back will, at some point or another, have a tendency to cross each other. The result of this is, that the quantity of light is augmented at some points of intersection, and annihilated at others.[97] Out of the investigation of the phenomena of diffraction, of the effects of thin and thick plates upon light, and the results of interference, has arisen the discovery of one of the most remarkable conditions within the range of physical science.

Two bright lights may be made to produce darkness.—If two pencils of light radiate from two spots very close to each other in such a manner that they cross each other at a given point, any object placed at that line of interference will be illuminated with the sum of the two luminous pencils. If we suppose those rays to move in waves, and the elevation of the wave to represent the maximum of luminous effect, then the two waves meeting, when they are both at the height of their undulation, will necessarily produce a spot of greater intensity. If now we so arrange the points of radiation, that the systems of luminous waves proceed irregularly, and that one arrives at the screen half an undulation before the other, the one in elevation falling into the depression of the other, a mutual annihilation is the consequence. This fact, paradoxical as it may appear, was broadly stated by Grimaldi, in the description of his experiments on the inflection of light, and has been observed by many others. The vibratory hypothesis, seizing upon the analogy presented by two systems of waves in water, explains this plausibly, and many similar phenomena of what is called the interference of light; but still upon examination it does not appear that the explanation is quite free from objection.[98]

Another theory, not altogether new to us, it being indicated in Mayer’s hypothesis of three primary colours (1775), and to be found as a problem in some of the EncyclopÆdias of the last century, has been put forth, in a very original manner, by that master-mind of intellectual Germany, Goethe; and from the very comprehensive views which this poet-philosopher has taken of both animal and vegetable physiology (views which have been adopted by some of the first naturalists of Europe), we are bound to receive his theory of colours with every respect and attention.

Goethe regards colour as the “thinning” of light; for example, by obstructing a portion of white light, yellow is produced; by reducing it still farther, red is supposed to result; and by yet farther retarding the free passage of the beam, we procure a blue colour, which is the next remove from blackness, or the absence of light. There is truth in this; it bears about it a simplicity which will satisfy many minds; by it many of the phenomena of colour may be explained: but it is insufficient for any interpretation of several of those laws to which the other theories do give us some insight.

Newton may have allowed himself to be misled by the analogy presented between the seven rays of the spectrum and the notes in an octave. The mystic number, seven, may have clung like a fibre of the web of superstition to the cloak of the great philosopher; but the attack made by Goethe upon the Newtonian philosophy betrays the melancholy fact of his being diseased with the lamentable weakness of too many exalted minds—an overweening self-esteem.

The polarization of light, as it has been unfortunately called—unfortunately, as conveying an idea of determinate and different points or poles, which only exists in hypothetical analogy—presents to us a class of phenomena which promise to unclose the mysterious doors of the molecular constitution of bodies.

This remarkable condition, as produced by the reflection of light from glass at a particular angle, was first observed by Malus, in 1808,[99] when amusing himself by looking at the beams of the setting sun, reflected from the windows of the Luxembourg Palace through a double refracting prism. He observed that when the prism was in one position, the windows with their golden rays were visible; but that turned round a quarter of a circle from that position, the reflected rays disappeared although the windows were still seen.

The phenomenon of double refraction was noticed, in the first instance, by Erasmus Bartholin, in Iceland-spar, a crystal the primary form of which is a rhombohedron; who perceived that the two images produced by this body were not in the same physical conditions.[100] It was also studied by Huyghens and Sir Isaac Newton, and to our countryman we owe the singular idea that a ray of light emerging from such a crystal has sides. This breaking up of the beam of light into two,—which is shown by looking through a pin-hole on a card through a crystal of Iceland spar, when two holes become visible, is due to the different states of tension in which the different layers constituting the crystal exist.

In thus separating the ray of light into two rays, the condition called polarisation has been produced, and by experiment we discover that the single ray has properties different from those of the compound or ordinary ray.

It is somewhat difficult to explain what is meant by, and what are the conditions of, polarised light. In the first instance let us see by what methods this peculiar state may be brought about.

If we reflect a ray of light from the surface of any body, fluid or solid, but not metallic, at an angle between 53° and 68° it undergoes what has been called plane polarisation. It may also be produced by the refraction of light from several refracting surfaces acting upon the pencil of light in succession; as by a bundle of plates of glass. Each surface polarises a portion of the pencil, and the number of plates necessary to polarise a whole beam depends upon the intensity of the beam and the angle of incidence. Thus, the light of a wax candle is wholly polarised by forty-seven plates of glass at an angle of 40° 41'; while at an angle of 79° 11' it is polarised by eight plates. Again, plane polarisation may be produced by the double refraction of crystals. Each of the two pencils is polarised, like light reflected from glass at an angle of 56° 45', but in opposite planes.

Non-scientific readers will still ask,—What is this mysterious condition of light which is produced by reflection and refraction at peculiar angles to the incident ray. It is one of the most difficult of problems to express in popular language. The conditions are, however, these:—

An ordinary ray of light will be reflected from a reflecting surface at whatever angle that surface may be placed in relation to the incident beam.

A polarised ray of light is not reflected in all positions of the reflecting surface.

An ordinary ray of light is freely transmitted through a transparent medium, as glass, in whatever position it may be placed relative to the source of light.

A polarised ray of light is not transmitted in all the positions of the permeable medium.

Supposing a plate of glass is presented at the angle 56° to a polarised ray, and the plane of incidence or reflexion is at right angles to the plane of polarisation of the ray, no light is reflected. If we turn the plate of glass round through 90°, when the plane of reflexion is parallel to that of polarisation the light is reflected. If we turn the plate round another 90°, so that the plane of reflexion and of polarisation are parallel to each other, again no light is reflected; and if we turn it through another 90° the reflection of the ray again takes place.

Precisely the same result takes place when, instead of being reflected, the polarised ray is transmitted.

Some substances have peculiar polarizing powers: the tourmaline is a familiar example. If a slice of tourmaline is taken, and we look at a common pencil of light through it, we see it in whatever position we may place the transparent medium. If, however, we look at a pencil of polarised light, and turn the crystal round, it will be found that in two positions the light is stopped, and that in two other positions it passes freely through it to the eye.

By way of endeavouring to conceive something of what may be the conditions which determine this very mysterious state, let us suppose each ray of light to vibrate in two planes at right angles to each other: one wave being vertical and the other horizontal. We have many examples of this compound motion. The mast of a ship, by the force with which she is urged through the water, describes a vertical wave, while by the roll of the billows across which she sails, a lateral undulation is produced at the same time. We may sometimes observe the same thing when a field of corn is agitated by a shifting wind on a gusty day.

The hypothesis therefore is, that every ray of ordinary light consists of two rays vibrating in different planes; and that these rays, separated one from the other, have the physical conditions which we call polarized.

The most transparent bodies may be regarded as being made up of atoms arranged in certain planes. Suppose the plane of lamination of any substance to be vertical in position, it would appear that the ray which has a vertical motion passes it freely, whereas if we turn the body round so that the planes of lamination are at right angles to the plane of vibration of the ray, it cannot pass.

That some action similar to that which it is here endeavoured to express in popular language does take place, is proved by the correctness of the results deduced by rigid mathematical analyses founded on this hypothesis.

There are two other conditions of the polarization of light—called circular and elliptical polarization. The first is produced by light when it is twice reflected from the second surface of bodies at their angle of maximum polarization, and the second by reflexions from the surfaces of metals at angles varying from 70° 45' to 78° 30'. The motion of the wave in the first is supposed to be circular, or to be that which is represented by looking along the centre of a corkscrew as it is turned round. At every turn of the medium effecting circular polarization the colour of the ray of light is changed after a uniform order. If turned in one direction, they change through red, orange, yellow, green, and violet; and if in the other direction, the colours appear in the contrary order.

The variety of striking effects produced by the polarization of light; the unexpected results which have sprung from the investigation of the laws by which it is regulated; and the singular beauty of many of its phenomena, have made it one of the most attractive subjects of modern science.

Ordinary light passes through transparent bodies without producing any very striking effects in its passage; but this extraordinary beam of light has the power of insinuating itself between the molecules of bodies, and by illuminating them, and giving them every variety of prismatic hue, of enabling the eye to detect something of the structure of the mass. The chromatic phenomena of polarized light are so striking, that no description can convey an adequate idea of their character.

Spectra more beautiful and intense than the prismatic image,—systems of rings far excelling those of thin plates,—and forms of the most symmetric order, are constantly presenting themselves, as the polarized ray is passed through various transparent substances; the path of the ray indicating whether the crystal has been formed round a single nucleus or axis, or whether it has been produced by aggregation around two axes. The coloured rings, and the dark or luminous crosses which distinguish the path of the polarized ray, are respectively due to different states of tension amongst the particles, although those differences are so slight, that no other means is of sufficient delicacy to detect the variation.

The poetry which surrounds these, in every way, mysterious conditions of the solar beam, is such, that it is with difficulty that imagination is restrained by the stern features of truth. The uses of this peculiar property in great natural phenomena are not yet made known to us; but, since we find on every side of us the natural conditions for thus separating the beam of light, and effecting its polarization, there must certainly be some most important end for which it is designed by Him who said, “Let there be Light.”

It must not be forgotten that we have at command the means of showing that the chromatic phenomena of polarized light are due to atomic arrangement. By altering the molecular arrangement of transparent bodies, either by heat or by mere mechanical pressure, the unequal tension or strain of the particles is at once indicated by means of the polarized ray of light and its rings of colour. Differences in the chemical constitution of bodies, too slight to be discovered by any other mode of analysis, can be most readily and certainly detected by this luminous investigator of the molecular forces.[101]

Although we cannot enter into an examination of all the conditions involved in the polarization of, and the action of matter on, ordinary light, it will be readily conceived, from what has been already stated, that some most important properties are indicated, beyond those which science has made known.

Almost every substance in nature, in some definite position, appears to have the power of producing this change upon the solar ray, as may be satisfactorily shown by examining them with a polarizing apparatus.[102] The sky at all times furnishes polarized light, which is most intense where it is blue and unclouded, and the point of maximum polarization is varied according to the relative position of the sun and the observer. A knowledge of this fact has led to the construction of a “Solar Clock,[103] with which the hour can be readily determined by examining the polarized condition of the sky. It has been stated, that chemical change on the Daguerreotype plates and on photographic papers is more readily produced by the polarized than by the ordinary sunbeam.[104] If this fact be established by future investigations, we advance a step towards the discovery so much desiderated of the part it plays in natural operations.

The refined and accurate investigations of Dr. Faraday stand prominently forward amid those which will redeem the present age from the charge of being superficial, and they will, through all time, be referred to as illustrious examples of the influence of a love of truth for truth’s sake, in entire independence of the marketable value, which it has been unfortunately too much the fashion to regard. The searching examination made by this “interpreter of nature” into the phenomena of electricity in all its forms, has led him onward to trace what connexion, if any, existed between this great natural agent and the luminous principle.

By employing that subtile analyzer, a polarized ray, Dr. Faraday has been enabled to detect and exhibit effects of a most startling character. He has proved magnetism to have the power of influencing a ray of light in its passage through transparent bodies. A polarized ray is passed through a piece of glass or a crystal, or along the length of a tube filled with some transparent fluid, and the line of its path carefully observed; if, when this is done, the solid or fluid body is brought under powerful magnetic influence, such as we have at command by making a very energetic voltaic current circulate around a bar of soft iron, it will be found that the polarized light is disturbed; that, indeed, it does not permeate the medium along the same line.[105] This effect is most strikingly shown in bodies of the greatest density, and diminished in fluids, the particles of which are easily moveable over each other, and has not hitherto been observed in any gaseous medium. The question, therefore, arises,—does magnetism act directly upon the ray of light, or only indirectly, by producing a molecular change in the body through which the ray is passing? This question, so important in its bearings upon the connexion between the great physical powers, will, no doubt, before long receive a satisfactory reply. A medium is necessary to the production of the result, and, as the density of the medium increases, the effect is enlarged: it would therefore appear to be due to a disturbance by magnetic force of the particles which constitute the medium employed.

Without any desire to generalize too hastily, we cannot but express a feeling,—amounting to a certainty in our own mind,—that those manifestations of luminous power, connected with the phenomena of terrestrial magnetism, which are so evident in all the circumstances attendant upon the exhibition of Aurora Borealis, and those luminous clouds which are often seen, independent of the Northern Lights, that a very intimate, relation exists between the solar radiations and that power which so strangely gives polarity to this globe of ours.

In connexion with the mysterious subject of solar light, it is important that we should occupy a brief space in these pages with the phenomena of vision, which is so directly dependent upon luminous radiation.

The human eye has been rightly called the “masterpiece of divine mechanism;” its structure is complicated, yet all the adjustments of its parts are as simple as they are perfect. The eye-ball consists of four coats. The cornea is the transparent coat in front of the globe; it is the first optical surface, and this is attached to the sclerotic membrane, filling up the circular aperture in the white of the eye; the choroid coat is a very delicate membrane, lining the sclerotic, and covered with a perfectly black pigment on the inside; and close to this lies the most delicately reticulated membrane, the retina, which is, indeed, an extension of the optic nerve. These coats enclose three humours,—the aqueous, the vitreous, and the crystalline humours.

The eye, in its more superficial mechanical arrangements, presents exactly the same character as a camera obscura, the cornea and crystalline lens receiving the images of objects refracting and inverting them; but how infinitely more beautiful are all the arrangements of the organ of vision than the dark chamber of Baptista Porta![106] The humours of the eye are for the purpose of correcting the aberrations of light, which are so evident in ordinary lenses, and for giving to the whole an achromatic character. Both spherical and chromatic aberration are corrected, the latter not entirely, and by the agency of the cornea and the crystalline lens perfect images are depicted on the retina, in a similar way to those very charming pictures which present themselves in the table of the camera obscura.

The seat of vision has been generally supposed to be the retina; but Mariotte has shown that the base of the optic nerve, which is immediately connected with the retina, is incapable of conveying an impression to the brain. The choroid coat, which lies immediately behind the retina, is regarded by Mariotte and Bernoulli as the more probable seat of vision. The retina, being transparent, offers no obstruction to the passage of the light onward to the black surface of the choroid coat, from which the vibrations are, in all probability, communicated to the retina and conveyed to the brain. Howbeit, upon one or the other of these delicate coats a distinct image is impressed by light, and the communication made with the brain possibly by a vibratory action. We may trace up the phenomena of vision to this point; we may conceive undulations of light, differing in velocity and length of wave, occasioning corresponding tremors in the neuralgic system of the eye; but how these vibrations are to communicate correct impressions of length, breadth, and thickness, no one has yet undertaken to explain.

It has, however, been justly said by Herschel:—

“It is the boast of science to have been able to trace so far the refined contrivances of this most admirable organ, not its shame to find something still concealed from scrutiny; for, however anatomists may differ on points of structure, or physiologists dispute on modes of action, there is that in what we do understand of the formation of the eye, so similar, and yet so infinitely superior to a product of human ingenuity; such thought, such care, such refinement, such advantage taken of the properties of natural agents used as mere instruments for accomplishing a given end, as force upon us a conviction of deliberate choice and premeditated design, more strongly, perhaps, than any single contrivance to be found whether in art or nature, and renders its study an object of the greatest interest.”[107]

Has the reader ever asked himself why it is, having two eyes, and consequently two pictures produced upon the tablets of vision, that we see only one object? According to the law of visible direction, all the rays passing through the crystalline lenses converge to one point upon the retina,—and as the two images are coincident and nearly identical, they can only produce the sensation of one upon the brain.

When we look at any round object, as the ornamented moderator lamp before us, first with one eye, and then with the other, we discover that, with the right eye, we see most of the right-hand side of the lamp, and with the left eye more of the left-hand side. These two images are combined, and we see an object which we know to be round.

This is illustrated in a most interesting manner by the little optical instrument, the Stereoscope. It consists either of two mirrors placed each at an angle of 45°, or of two semi-lenses turned with their curved sides towards each other. To view its phenomena, two pictures are obtained by the camera obscura on photographic paper of any object in two positions, corresponding with the conditions of viewing it with the two eyes. By the mirrors or the lenses these dissimilar pictures are combined within the eye, and the vision of an actually solid object is produced from the pictures represented on a plane surface. Hence the name of the instrument; which signifies, Solid I see.

Analogy is often of great value in indicating the direction in which to seek for a truth; but analogical evidence, unless where the resemblance is very striking, should be received with caution. Mankind are so ready to leap to conclusions without the labour necessary for a faithful elucidation of the truth, that too often a few points of resemblance are seized upon, and an inference is drawn which is calculated to mislead.

There is an idea that the phenomena of sound bear a relation to those of light,—that there exists a resemblance between the chromatic and the diatonic scales. Sound, we know, is conveyed by the beating of material particles—the air—upon the auditory membrane of the ear, which have been set in motion by some distant disturbance of the medium through which it passes. Light has been supposed to act on the optic nerve in the same manner. If we imagine colour to be the result of vibrations of different velocities and lengths, we can understand that under some of these tremors, first established on the nerves, and through them conveyed to the brain, sensations of pain or pleasure may result, in the same way as sharp or subdued sounds are disagreeable or otherwise. Intensely coloured bodies do make an impression upon perfectly blind men; and those who, being born blind, know no condition of light or colour, will point out a difference between strongly illuminated red and yellow media. When the eyes are closed we are sensible to luminous influence, and even to differences of colour. We must consequently infer that light produces some peculiar action upon the system of nerves in general; this may or may not be independent of the chemical agency of the solar radiations; but certainly the excitement is not owing to any calorific influence. The system of nerves in the eye is more delicately organized, and of course peculiarly adapted to all the necessities of vision.

Thus far some analogy does appear to exist between light and sound; but the phenomena of the one are so much more refined than those of the other—the impressions being all of them of a far more complicated character, that we must not be led too far by the analogical evidence in referring light, like sound, to mere material motion.

It was a beautiful idea that real impressions of external objects are made upon the seat of vision, and that they are viewed, as in a picture, by something behind the screen,—that these pictures become dormant, but are capable of being revived by the operations of the mind in peculiar conditions; but we can only regard it as a philosophical speculation of a poetic character, the truth or falsehood of which we are never likely to be enabled to establish.[108]

That which sees will never itself be visible. The secret principle of sensation,—the mystery of the life that is in us,—will never be unfolded to finite minds.

Numerous experiments have been made from time to time on the influence of light upon animal life. It has been proved that the excitement of the solar rays is too great for the healthful growth of young animals; but, at the same time, it appears probable that the development of the functional organs of animals requires, in some way, the influence of the solar rays. This might, indeed, have been inferred from the discovery that animal life ceases in situations from which light is absolutely excluded. The instance of the Proteus of the Illyrian lakes may appear against this conclusion. This remarkable creature is found in the deep and dark recesses of the calcareous rocks of Adelsburg, at Sittich; and it is stated, also in Sicily, and in the Mammoth caves of Kentucky. Sir Humphry Davy describes the Proteus anguinus as “an animal to whom the presence of light is not essential, and who can live indifferently in air and in water, on the surface of the rock, or in the depths of the mud.” The geological character of rocks, however, renders it extremely probable that these animals may have descended with the water, percolating through fissures from very near the surface of the ground. All the facts with which science has made us acquainted—and both natural and physical science has been labouring with most untiring industry in the pursuit of truth—go to prove that light is absolutely necessary to organization. It is possible the influence of the solar radiations may extend beyond the powers of the human senses to detect luminous or thermic action, and that consequently a development of animal and vegetable forms may occur where the human eye can detect no light; and under such conditions the Proteus may be produced in its cavernous abodes, and also those creatures which live buried deep in mud. Some further consideration of the probable agency of light will occupy us, when we come to examine the phenomena of vital forces.

Light is essentially necessary to vegetable life; and to it science refers the powers which the plant possesses of separating carbon from the air breathed by the leaves, and secreting it within its tissues for the purpose of adding to its woody structure. As, however, we have, in the growing plant, the action of several physical powers exerted to different ends at the same time, the remarkable facts which connect themselves with vegetable chemistry and physiology are deferred for a separate examination.

The power of the solar rays to produce in bodies that peculiar gleaming light which we call phosphorescence, and the curious conditions under which this phenomenon is sometimes apparent, independent of the sun’s direct influence, present a very remarkable chapter in the science of luminous powers.

The phosphorescence of animals is amongst the most surprising of nature’s phenomena, and it is not the less so from our almost entire ignorance of the cause of it. Many very poetical fancies have been applied in description of these luminous creations; and imagination has found reason why they should be gifted with these extraordinary powers. The glow-worm lights her lamp to lure her lover to her bower, and the luminous animalcules of the ocean are employed in lighting up the fathomless depths where the sun’s rays cannot penetrate, to aid its monsters in their search for prey. “The lamp of love—the pharos—the telegraph of the night,—which scintillates and marks, in the silence of darkness, the spot appointed for the lover’s rendezvous,”[109] is but a pretty fiction; for the glow-worm shines in its infant state, in that of the larva, and when in its aurelian condition. Of the dark depths of the ocean it may be safely affirmed that no organized creation lives or moves in its grave-like silence to require this fairy aid. Fiction has frequently borrowed her creations from science. In these cases science appears to have made free with the rights of fiction.

The glow-worms (lampyris noctiluca), it is well known, have the power of emitting from their bodies a beautiful pale bluish-white light, shining during the hours of night in the hedge-row, like crystal spheres. It appears, from the observations of naturalists, that these insects never exhibit their light without some motion of the body or legs;—from this it would seem that the phosphorescence was dependent upon nervous action, regulated at pleasure by the insect; for they certainly have the power of obscuring it entirely. If the glow-worm is crushed, and the hands or face are rubbed with it, luminous streaks, similar to those produced by phosphorus, appear. They shine with greatly increased brilliancy in oxygen gas and in nitrous oxide. From these facts may we not infer that the process by which this luminosity is produced, whatever it may be, has a strong resemblance to that of respiration?

There are several varieties of flies, and three species of beetles of the genus Elater, which have the power of emitting luminous rays. The great lantern-fly of South America is one of the most brilliant, a single insect giving sufficient light to enable a person to read. In Surinam a very numerous class of these insects are found, which often illuminate the air in a remarkable manner. In some of the bogs of Ireland a worm exists which gives out a bright green light; and there are many other kinds of creatures which, under certain circumstances, become luminous in the dark. This is always dependent upon vitality; for all these animals, when deprived of life, cease to shine.

At the same time we have many very curious instances of phosphorescence in dead animal and vegetable matter; the lobster among the Crustacea, and the whiting among fishes, are striking examples; decayed wood also emits much light under certain conditions of the atmosphere. This development of light does not appear to be at all dependent upon putrefaction; indeed, as this process progresses, the luminosity diminishes. We cannot but imagine that this light is owing, in the first place, to direct absorption by, and fixation within, the corpuscular structure of those bodies, and that it is developed by the decomposition of the particles under the influence of our oxygenous atmosphere.

The pale light emitted by phosphorus in the dark is well known; and this is evidently only a species of slow combustion, a combination of the phosphorus with the oxygen of the air. Where there is no oxygen, phosphorus will not shine; its combustion in chlorine or iodine vapour is a phenomenon of a totally different character from that which we are now considering. This phosphorescence of animal and vegetable matter has been regarded as something different from the slow combustion of phosphorus; but, upon examination, all the chemical conditions are found to be the same, and it is certainly due to a similar chemical change.

The luminous matter of the dead whiting or the mackerel may be separated by a solution of common salt or of sulphate of magnesia; by concentrating these solutions the light disappears; but it is again emitted when the fluid is diluted. The entire subject is, however, involved in the mystery of ignorance, although it is a matter quite within the scope of any industrious observer. The self-emitted light of the carbuncle of the romancer is realized in these remarkable phenomena.

The phosphorescence of some plants and flowers is not, perhaps, of the same order as that which belongs to either of the conditions we have been considering. It appears to be due rather to an absorption of light and its subsequent liberation. If a nasturtium is plucked during sunshine, and carried into a dark room, the eye, after it has reposed for a short time, will discover the flower by a light emitted from its leaves.

The following remarkable example, and an explanation of it by the poet Goethe, is instructive:—

“On the 19th of June, 1799, late in the evening, when the twilight was deepening into a clear night, as I was walking up and down the garden with a friend, we very distinctly observed a flame-like appearance near the oriental poppy, the flowers of which are remarkable for their powerful red colour. We approached the place, and looked attentively at the flowers, but could perceive nothing further, till at last, by passing and repassing repeatedly, while we looked side-ways on them, we succeeded in renewing the appearance as often as we pleased. It proved to be a physiological phenomenon, and the apparent corruscation was nothing but the spectrum of the flower in the complementary blue-green colour. The twilight accounts for the eye being in a perfect state of repose, and thus very susceptible, and the colour of the poppy is sufficiently powerful in the summer twilight of the longest days to act with full effect, and produce a complementary image.”[110]

The leaves of the oenothera macrocarpa are said to exhibit phosphoric light when the air is highly charged with electricity. The agarics of the olive-grounds of Montpelier have been observed to be luminous at night; but they are said to exhibit no light, even in darkness, during the day. The subterranean passages of the coal mines near Dresden are illuminated by the phosphorescent light of the rhizomorpha phosphoreus, a peculiar fungus. On the leaves of the Pindoba palm, a species of agaric grows which is exceedingly luminous at night; and many varieties of the lichens, creeping along the roofs of caverns, lend to them an air of enchantment by the soft and clear light which they diffuse. In a small cave near Penryn, a luminous moss is abundant; and it is also found in the mines of Hesse. According to Heinzmann, the rhizomorpha subterranea and aidulÆ are also phosphorescent.

It is but lately that a plant which abounds in the jungles in the Madura district of the East Indies was sent to this country, which, although dead, was remarkably phosphorescent; and, when in the living state, the light which it emitted was extraordinarily vivid, illuminating the ground for some distance. Those remarkable effects may be due, in some cases, to the separation of phosphuretted hydrogen from decomposing matter, and, in others, to some peculiar electric manifestation.

The phosphorescence of the sea, or that condition called by fishermen brimy, when the surface, being struck by an oar, or the paddle-wheels of a steamer, gives out large quantities of light, has been attributed to the presence of myriads of minute insects which have the power of emitting light when irritated. The night-shining nereis (Nereis noctiluca) emits a light of great brilliancy, as do several kinds of the mollusca. The nereides attach themselves to the scales of fishes, and thus frequently render them exceedingly luminous. Some of the crustaceÆ possess the same remarkable property;—twelve different species of cancer were taken up by the naturalists of the Zaire in the Gulf of Guinea.[111] The cancer fulgens, discovered by Sir Joseph Banks, is enabled to illuminate its whole body, and emits vivid flashes of light. Many of the medusÆ also exhibit powerful phosphorescence.[112] These noctilucous creatures are, many of them, exceedingly minute, several thousands being found in a tea-cup of sea water. They float near the surface in countless myriads, and when disturbed they give out brilliant scintillations, often leaving a train of light behind them.[113] By microscopic examination no other fact has been elicited than that these minute beings contain a fluid which, when squeezed out, leaves a line of light upon the surface of water. The appearance of these creatures is almost invariably on the eve of some change of weather, which would lead us to suppose that their luminous phenomena must be connected with electrical excitation; and of this, the investigations of Mr. C. Peach, of Fowey, communicated to the British Association at Birmingham, furnish the most satisfactory proofs we have as yet obtained.

Benvenuto Cellini gave a curious account of a carbuncle which shone with great brilliancy in the dark.[114] The same thing has been stated of the diamond; but it appears to be necessary to procure these emissions of light, that the minerals should be first warmed near a fire. From this it may be inferred that the luminous appearance is of a similar character to that of fluor spar, and of numerous other earthy minerals, which, when exposed to heat, phosphoresce with great brilliancy. Phosphorescent glow can also be excited in similar bodies by electricity, as was first pointed out by Father Beccaria, and confirmed by Mr. Pearsall.[115] These effects, it must be remembered, are distinct from the electric spark manifested upon breaking white sugar in the dark, or scratching sulphuret of zinc.

In the instances adduced there is not necessarily any exposure to the sunshine required. It is probable that two, if not three, distinct phenomena are concerned in the cases above quoted, and that all of them are distinct from animal phosphorescence, or the luminous appearance of vegetables. They, however, certainly prove, either that light is capable of becoming latent, or that it is only a condition of matter, in which it may be made manifest by any disturbance of the molecular forces. We have, in answer to this, very distinct evidence that some bodies do derive this property from the solar rays. Canton’s phosphorus, which is a sulphuret of calcium, will, having been exposed to the sun, continue luminous for some time after it is carried into the dark; as will also the Bolognian stone,—a sulphuret of barium. This result appears to be due to a particular class of the solar rays; for it has been found, if these sulphurets, spread smoothly on paper, are exposed to the influence of the solar spectrum for some little time, and then examined in the dark, that luminous spaces appear, exactly corresponding with the most refrangible rays, or those which excite chemical change; and one very remarkable fact must not be forgotten—the dark rays of the spectrum beyond the violet produce a lively phosphorescence, which is extinguished by the action of the rays of least refrangibility, or the heat rays—whilst artificial heat, such as a warm iron, produces a very considerable elevation of the phosphorescent effect.[116] It is not improbable, that the fluorescent rays of Mr. Stokes may be materially concerned in producing the phenomena of phosphorescence: experiments are, however, required to prove this.

In these allied phenomena we have effects which are evidently dependent upon several dissimilar causes. The phosphorescence of the living animal is due, without doubt, to nervous excitation: that of the living vegetable to solar luminous influence; and in the case of the mosses of caverns, &c. to the chemical agency of the sun’s rays, which appears to be capable of conduction. In the dead organic matter we have a purely chemical action developing the light, and in the inorganic bodies we have peculiar molecular constitution, by which an absorption of light appears to take place.

The subject is one of the greatest difficulty; the torch of science is too dim to enable us to see the causes at work in producing these marvellous effects. The investigation leads, to a certain extent, to the elucidation of many of the secrets of luminous action; and the determination of the question, whether light is an emanation from the sun, or only a subtile principle diffused through all matter, which is excited by solar influence, is intimately connected with the inquiry.

It has been stated that matter is necessary to the development of light; that no luminous effect would be produced if it were not for the presence of matter. Of this we not only have no proof, but such evidence as we have is against the position. There is no loss of light in the most perfect vacuum we can produce by any artificial means, which should be the case if matter was concerned in the phenomena of light, as a cause.

Colour is certainly a property regulated by material bodies; or rather, the presence of matter is necessary to the production of colour. Chlorine gas is a pale yellow, and nitrous vapour a yellowish red. These and one or two other vapours, which are near the point of condensation into fluids, are the only coloured gaseous or vaporiform bodies. The sky is blue, because the material particles of the atmosphere reflect back the blue rays. But we have more practical illustrations than this. The flame of hydrogen burning with oxygen gives scarcely any light; allow it to impinge on lime, a portion of which is carried off by the heat of the flame, and the most intense artificial light with which we are acquainted is produced. Hydrogen gas alone gives a flame in which nearly all but the blue rays are wanting: place a brush of steel or asbestos in it, and many of the other rays are at once produced. An argand lamp, and more particularly the lamp in which camphine—a purified turpentine,—is burnt, gives a flame which emits most of the rays found in sunlight. Spirit of wine mixed with water, warmed and ignited, gives only yellow rays; add nitrate of strontian and they become red; but nitrate of barytes being mixed with the fluid, they are changed to green and yellow; salts of copper afford fine blue rays, and common salt intense yellow ones. Many of these coloured rays and others can be produced in great power by the use of various solid bodies introduced into flame. This has not been sufficiently pointed out by authors; but it is clear from experiments that light requires the presence of matter to enable it to diffuse its coloured glories. How is it that the oxygen and hydrogen flame gives so little light, and with a solid body present, pours forth such a flood of brilliancy?

The production of artificial light by electrical and chemical agencies will necessarily find some consideration under their respective heads. There are numerous phenomena which connect themselves with luminous power, or appear to do so, which, in the present state of our knowledge, cannot come immediately under our attention. We are compelled to reserve our limited space for those branches of science which we are enabled to connect with the great natural operations constantly going on around us. Many of these more abstruse results will, however, receive some incidental notice when we come to examine the operation of the combined physical forces on matter.

We see in light a principle which, if it has not its source in the sun, is certainly dependent upon that luminary for its manifestations and powers. From that “fountain of light” we find this principle travelling to us at a speed which almost approaches the quickness of thought itself; yet by the refinements of science we have been enabled to measure its velocity with the utmost accuracy. The immortal poet of our own land and language, in his creations of Ariel, that “tricksy spirit,” who could creep like music upon the waters, and of the fantastic Puck, who could girdle the earth in thirty minutes, appears to have approached to the highest point to which mere imagination could carry the human mind as to the powers of things ethereal. Science has, since then, shown to man that this “spirit, fine spirit,” was a laggard in his tasks, and a gross piece of matter, when compared with the subtile essences which man, like a nobler Prospero, has now subdued to do him service.

Light is necessary to life; the world was a dead chaos before its creation, and mute disorder would again be the consequence of its annihilation. Every charm which spreads itself over this rolling globe is directly dependent upon luminous power. Colours, and probably, forms, are the result of light; certainly the consequence of solar radiations. We know much of the mysterious influences of this great agent, but we know nothing of the principle itself. The solar beam has been tortured through prismatic glasses and natural crystals; every chemical agent has been tried upon it, every electrical force in the most excited state brought to bear upon its operations, with a view to the discovery of the most refined of earthly agencies; but it has passed through every trial without revealing its secrets, and even the effects which it produces in its path are unexplained problems, still to tax the intellect of man.

Every animal and every plant alike proclaim that life and health are due to light; and even the crystallizing forms of inorganic matter, by bending towards it, confess its all-prevailing sway. From the sun to each planet revolving around that orb, and to the remotest stars which gleam through the vast immensity of heaven, we discover this power still in its brightness, giving beauty and order to these unnumbered creations; no less completely than to this small island of the universe which we call our Earth. Through every form of matter we can mark its power, and from all, we can, under certain conditions, evoke it in lustre and activity. Over all and through all light spreads its ethereal force, and manifests, in all its operations, powers which might well exalt the mind of Plato to the idea of an omniscient and omnipresent God. Science, with her Ithuriel wand, has, however, shown that light is itself the effect of a yet more exalted cause, which we cannot reach.

Indeed, the attentive study of the fine abstractions of science lifts the mind from the grossness of matter, step by step, to the refinements of immateriality, and there appear, shadowed out beyond the physical forces which man can test and try, other powers still ascending, until they reach the Source of every good and every perfect gift.


FOOTNOTES:

[84] “These—oxygen, hydrogen, nitrogen, and carbon—are the four bodies, in fact, which, becoming animated at the fire of the sun, the true torch of Prometheus, approve themselves upon the earth the eternal agents of organisation, of sensation, of motion and of thought.”—Dumas, LeÇons de Philosophie Chimique, p. 100. Paris, 1837.

[85] It will be found in examining any of the works of the alchemists,—particularly those of Geber, De inveniendi arte Auri et Argenti, and his De AlchemiÂ; Roger Bacon’s Opus Majus, or Alchymia Major; Helvetius’ Brief of the Golden Calf; or Basil Valentine’s Currus Triumphalis,—that in the processes of transmutation the solar light was supposed to be marvellously effective. In Boyle’s Sceptical Chemist the same idea will be found pervading it.

Amid all their errors, the alchemists were assiduous workmen, and to them we are indebted for numerous facts. Of them, and of their age, as contrasted with our own, Gibbon remarks:—“Congenial to the avarice of the human heart, it was studied in China, as in Europe, with equal eagerness and equal success. The darkness of the middle ages ensured a favourable reception to every tale of wonder; and the revival of learning gave new vigour to hope, and suggested more specious arts of deception. Philosophy, with the aid of experience, has at length banished the study of alchemy; and the present age, however desirous of riches, is content to seek them by the humbler means of commerce and industry.”—Decline and Fall, vol. ii. p. 137.

[86] On the two theories the following maybe consulted:—Young, Supplement to EncyclopÆdia Britannica, article Chromatics; Fresnel, SupplÉment À la Traduction FranÇaise de la 5iÈme Édition du TraitÉ de Chimie de Thomson, par Riffault, Paris, 1822; Herschel’s Article, Light, in the EncyclopÆdia Metropolitana, and the French Translation of it by Quetelet and Verhulst; Airy’s Tract on the Undulatory Theory, in his Tracts, 2nd edition, Cambridge, 1831; Powel, The Undulatory Theory applied to Dispersion, &c. p. 184; Lloyd’s Lectures, Dublin, 1836–41; Cauchy, Sur le Mouvement des Corps Élastiques, MÉmoires de l’Institut, 1827, vol. ix. p. 114; ThÉorie de la LumiÈre, Ibid. vol. x. p. 293; M’Cullagh, On Double Refraction, Ibid., vol. xvi.; Geometrical Propositions applied to the Wave Theory of Light, Ibid., vol. xvii.; Sir David Brewster’s papers in the Transactions of the Royal Society of Edinburgh, and the Philosophical Magazine.

[87] Results of Astronomical Observations made during the years 1834–38, at the Cape of Good Hope, &c. By Sir John Herschel, Bart., K.H., D.C.L., F.R.S.—“In the contemplation of the infinite, in number and in magnitude, the mind ever fails us. We stand appalled before this mighty spectre of boundless space, and faltering reason sinks under the load of its bursting conceptions. But, placed as we are on the great locomotive of our system, destined surely to complete at least one round of its ethereal course, and learning that we can make no apparent advance on our sidereal journey, we pant with new ardour for that distant bourne which we constantly approach without the possibility of reaching it. In feeling this disappointment, and patiently bearing it, let us endeavour to realise the great truth from which it flows. It cannot occupy our mind without exalting and improving it.”—Sir D. Brewster: North British Review.

[88] For examples of this, consult Graham’s Elements of Chemistry; Brande’s Manual of Chemistry; or, indeed, any work treating of the science. The formation of ink, by mixing two colourless solutions, one of gallic acid and another of sulphate of iron, may be taken as a familiar instance.

[89] Sir John Herschel, in his paper On the Chemical Action of the Rays of the Solar Spectrum on Preparations of Silver, remarks that, “it may seem too hazardous to look for the cause of this very singular phenomenon in a real difference between the chemical agencies of those rays which issue from the central portion of the sun’s disc, and those which, emanating from its borders, have undergone the absorptive action of a much greater depth of its atmosphere; and yet I confess myself somewhat at a loss what other cause to assign for it. It must suffice, however, to have thrown out the hint; remarking only, that I have other, and, I am disposed to think, decisive evidence (which will find its place elsewhere) of the existence of an absorptive solar atmosphere, extending beyond the luminous one. The breadth of the border, I should observe, is small, not exceeding 0·5 or 1/7 part of the sun’s radius, and this, from the circumstances of the experiment, must necessarily err in excess.”—Philosophical Transactions, 1840.

[90] Experiments and Observations on some Cases of Lines in the Prismatic Spectrum, produced by the passage of Light through Coloured Vapours and Gases, and from certain Coloured Flames. By W. A. Miller, M.D., F.R.S., Professor of Chemistry in King’s College, London.—Philosophical Magazine, vol. xxvii.

[91] Report on the Mollusca and Radiata of the Ægean Sea, and on their distribution, considered as bearing on Geology. By Edward Forbes, F.R.S., &c.—Reports of the British Association, vol. xii. Professor Forbes remarks:—“A comparison of the testacea, and other animals of the lowest zones, with those of the higher, exhibits a very great distinction in the hues of the species, those of the depths being, for the most part, white or colourless, while those of the higher regions, in a great number of instances, exhibit brilliant combinations of colour. The results of an enquiry into this subject are as follows:—

“The majority of shells of the lowest zone are white or transparent; if tinted rose is the hue, a very few exhibit markings of another colour. In the seventh region, white species are also very abundant, though by no means forming a proportion so great as the eighth. Brownish red, the prevalent hue of the brachiopoda, also gives a character of colour to the fauna of this zone; the crustacea found in it are red. In the sixth zone the colours become brighter, reds and yellows prevailing,—generally, however, uniformly colouring the shell. In the fifth region many species are banded or clouded with various combinations of colours, and the number of white species has greatly diminished. In the fourth, purple hues are frequent, and contrasts of colour common. In the second and third, green and blue tints are met with, sometimes very vivid; but the gayest combinations of colour are seen in the littoral zone, as well as the most brilliant whites.

“The animals of Testacea, and the Radiata of the higher zones, are much more brilliantly coloured than those of the lower, where they are usually white, whatever the hue of the shell may be. Thus the genus Trochus is an example of a group of forms mostly presenting the most brilliant hues both of shell and animal; but whilst the animals of such species as inhabit the littoral zone are gaily chequered with many vivid hues, those of the greater depth, though their shells are almost as brightly covered as the coverings of their allies nearer the surface, have their animals, for the most part, of a uniform yellow or reddish hue, or else entirely white. The chief cause of this increase of intensity of colour as we ascend is, doubtless, the increased amount of light above a certain depth.”—p. 172.

[92] ???f?ta. On the Epipolic Dispersion of Light, being a paper entitled, On a case of Superficial Colour presented, by a homogeneous liquid internally colourless. By Sir J. F. W. Herschel, Bart, K.H., F.R.S., &c.—An epipolized beam of light (meaning thereby a beam which has once been transmitted through a quiniferous solution, and undergone its dispersing action) is incapable of further undergoing epipolic dispersion. In proof of this the following experiment may be adduced,—

A glass jar being filled with a quiniferous solution, a piece of plate glass was immersed in it vertically, so as to be entirely covered, and to present one face directly to the incident light. In this situation, when viewed by an eye almost perpendicularly over it, so as to graze either surface very obliquely, neither the anterior nor posterior face showed the slightest trace of epipolic colour. Now, the light, at its egress from the immersed glass, entered the liquid under precisely the same circumstances as that which, when traversing the anterior surface of the glass jar, underwent epipolic dispersion on first entering the liquid. It had, therefore, lost a property which it originally possessed, and could not, therefore, be considered qualitatively the same light.—Philosophical Transactions, vol. cxxxvi.

[93] In connection with this view, the Newtonian theory should be consulted, for which see—A Letter of Mr. Isaac Newton, Professor of the Mathematicks in the University of Cambridge; containing his new Theory about Light and Colors: sent by the Author to the Publisher, from Cambridge, Feb. 6, 1671–72, in order to be communicated to the Royal Society.

[94] In that admirable work, The Physical Atlas of Dr. Berghaus, of which a very complete edition by Alexander Keith Johnstone is published in this country, the following order of the distribution of plants is given:—

1. The region of palms and bananas Equatorial zone.
2. Tree ferns and figs Tropical zone.
3. Myrtles and laurels Sub-tropical zone.
4. Evergreen trees Warm temperate zone.
5. European trees Cold temperate zone.
6. Pines Sub-arctic zone.
7. Rhododendrons Arctic zone.
8. Alpine plants Polar zone.

Consult Humboldt, Essai sur la GÉographie des Plantes, Paris, 1807; De Distributione Geographic Plantarum, Paris, 1817. Schouw, GrundzÜge der Pflanzengeographie. Also his Earth, Plants, and Man; translated by Henfrey, in Bohn’s Scientific Library. Lamouroux, GÉographie Physique. The Plant, a Biography: by Schleiden; translated by Henfrey. Physical Geography: by Mrs. Somerville.

[95] Fraunhofer’s measure of illuminating power is as follows:—

At the 22nd degree of the red 0·032
" 34th degree of the red 0·094
" 22nd degree of the orange 0·640
" 10th degree of the yellow 1·000
" 42nd degree of the yellow 0·480
" 2nd degree of the blue 0·170
" 16th degree of the indigo 0·031
" 43rd degree of the violet 0·0056

[96] Herschel, On the Action of Crystallized Bodies on Homogeneous Light, and on the causes of the deviation from Newtons scale in the tints which many of them develope on exposure to a polarized ray.—Phil. Trans., vol. cx., p. 88.

[97] On the Nature of Light and Colours: Lecture 39, in Young’s Lectures on Natural Philosophy, Kelland’s Edition, p. 373, and the authorities there quoted.

[98] Brewster’s Optics: Lardner’s Cabinet CyclopÆdia. Herschel, On Light: EncyclopÆdia Metropolitana.

[99] Malus, Sur une PropriÉtÉ de la LumiÈre RÉflÉchie: MÉmoires d’Arcueil. Numerous memoirs by Sir David Brewster, in the Philosophical Transactions.

[100] Bartholin, On Iceland Crystals: Copenhagen, 1669. An Accompt of sundry Experiments made and communicated by that Learn’d Mathematician Dr. Erasmus Bartholin, upon a Chrystal like Body sent to him out of Island: in connection with which Dr. Matthias Paissenius writes:—The observations of the excellent Bartholin upon the Island Chrystal are, indeed, considerable, as well as painful. We have here, also, made some tryals of it upon a piece he presented me with, which confirm his observations. Mean time he found it somewhat scissile and reducible by a knife into thin laminas or plates, which, when single, shew’d the object single, but laid upon one another shew’d it double; the two images appearing the more distant from one another, the greater the number was of those thin plates laid on one another. With submission to better judgements I think it to be a kind of Selenites. Some of our curious men here were of opinion that the Rhomboid figure proper to this stone was the cause of the appearances doubled thereby. But having tryed whether in other transparent bodies of the like figure the like would happen, we found no such thing in them, which made us suspect some peculiarity in the very Body of the stone.—Phil. Trans. for 1670, vol. v.

[101] On the Application of the Laws of Circular Polarization to the Researches of Chemistry: by M. Biot.—Nouvelles Annales du MusÉum d’Histoire Naturelle, vol. iii., and Scientific Memoirs, vol. i. p. 600. On Circular Polarization: by Dr. Leeson.—Memoirs of the Chemical Society.

[102] In Sir David Brewster’s Treatise On Optics, chap, xviii., On Polarization, the best arrangements for a polarizing apparatus will be found described.

[103] This beautiful application was recently made by Professor Wheatstone, the particulars of which will be found in his interesting communication.—On a means of determining the apparent Solar Time by the diurnal changes of the Plane of Polarization at the Northern Pole of the Sky: Report of the Eighteenth Meeting of the British Association.

[104] On the Polarization of the Chemical Rays of Light: by John Sutherland, M.D., in which the author refers to the following experiment of M. J. E. BÉrard—“I received the chemical rays directed into the plane of the meridian on an unsilvered glass, under an incidence of 35° 61'. The rays reflected by the first glass were received upon a second, under the same incidence. I found that when this was turned towards the south, the muriate of silver exposed to the invisible rays which it reflected was darkened in less than half an hour; whereas, when it was turned towards the west, the muriate of silver exposed in the place where the rays ought to have been reflected, was not darkened, although it was left exposed for two hours. It is consequently to be presumed that the chemical rays can undergo double refraction in traversing certain diaphanous bodies; and lastly, we may say that they enjoy the same physical properties as light in general.”—Philosophical Magazine, vol. xx.

Dr. Leeson has stated that Daguerreotype pictures can be taken more readily under the influence of polarized light, than by ordinary radiation.

[105] On the Magnetization of Light, and the Illumination of Magnetic Lines of Force: by Michael Faraday, D.C.L., F.R.S.—Philosophical Transactions, vol. cxxxvii.—The following remarks are to the point of doubt referred to in the text.—“The magnetic forces do not act on the ray of light directly and without the intervention of matter, but through the mediation of the substance in which they and the ray have a simultaneous existence; the substances and the forces giving to and receiving from each other the power of acting on the light. This is shown by the non-action of a vacuum, of air or gases, and it is also further shown by the special degree in which different matters possess the property. That magnetic force acts upon the ray of light always with the same character of manner, and in the same direction, independent of the different varieties of substance, or their states of solid or liquid, or their specific rotative force, shows that the magnetic force and the light have a direct relation; but that substances are necessary, and that these act in different degrees, shows that the magnetism and the light act on each other through the intervention of the matter. Recognising or perceiving matter only by its powers, and knowing nothing of any imaginary nucleus abstract from the idea of these powers, the phenomena described must strengthen my inclination to trust in the views I have advanced in reference to its nature.”—Phil. Mag. vol. xxiv.

[106] The invention of the camera obscura certainly belongs to Giambattista Porta, and is described in his MagiÆ Naturalis, sive de Miraculis Rerum Naturalium, Libri Viginti; Antwerp, 1561. An English translation made in 1658 exists, but I have not seen it.

Hooke, in one of the earliest volumes of the Philosophical Transactions, describes as new many of the phenomena mentioned by Porta, and particularly the images of the dark chamber.

[107] Herschel, On Light,—EncyclopÆdia Metropolitana.

[108] “I would here observe that a consideration of many such phenomena (the obliteration and revival of photographic drawings) has led me to regard it as not impossible that the retina itself may be photographically impressed by strong light, and that some at least of the phenomena of visual spectra and secondary colours may arise from the sensorial perception of actual changes in progress in the physical state of that organ itself subsequent to the cessation of the direct stimulant.”—On the action of the Rays of the Solar Spectrum on Vegetable Colours, &c.: by Sir J. F. W. Herschel, Bart.

[109] Dumeril.

[110] Theory of Colours: by Goethe; translated by Eastlake.

[111] See Tuckey’s Narrative of the Expedition of the Zaire.

[112] The most complete examination of this subject will be found in two Memoirs:—

1. Experiments and observations on the light which is spontaneously emitted with some degree, of permanency from various bodies.—Phil. Trans., vol. xc.

2. A continuation of the above, with some experiments and observations on solar light, when imbibed by Canton’s phosphorus: by Nathaniel Hulm, M.D.—Phil. Trans., vol. xci.; and in the Monograph of the British Naked-eyed MedusÆ, by Professor Edward Forbes (published for the Ray Society). See Wilson’s note to the account of Pennalata phosphorea in Johnston’s Zoophytes, 2nd edition.

[113] A General Outline of the Animal Kingdom: by Thomas Rymer Jones, F.L.S.—AcalephÆ, p. 64. Lettre À M. Dumas sur la Phosphorescence des Vers luisants: par M. Ch. Matteucci.—Annales de Chimie, vol. ix. p. 71, 1843.

[114] Memoirs of Benvenuto Cellini—Bohn’s Standard Library. See also his Treatise on his Art as a Sculptor and Engraver. Florence, 1568. 4to.

[115] Phosphorescence of the Diamond: by M. Reiss (Revue Scientifique et Industrielle, vol. xxiii. p. 185).—“The diamond, phosphorescent by insulation, lost rapidly its phosphorescence when submitted to the action of the red rays of the solar spectrum. On the contrary, the blue rays are those which render the diamond the most luminous in the dark. It is probable that the phosphorescence produced by heat is equally diminished by the action of the red rays of the solar spectrum.” Giovanni Battista Beccaria published his experiments in 1769. See Priestley’s History of Electricity; and On the Effects of Electricity upon Minerals which are Phosphorescent by Heat; and Further Experiments on the communication of Phosphorescence and Colour to bodies of Electricity; by Thomas J. Pearsall.—Journal of the Royal Institution of Great Britain, Oct. 1830, Feb. 1831.—These two memoirs contain the most complete set of experiments on this subject which have yet been made; see Placidus Heinrich, Phosphorescenz der KÖrper, vol. iv.; Gmelin’s Handbuch der Chemie, part 1.;—On the Phosphorescence of Minerals, Brewster: Edinburgh Philosophical Journal, vol. i. p. 137.;—The AËrial Noctiluca, or some New Phenomena, and a process of a factitious self shining substance: Boyle’s Works, vol. iv.

[116] Des Effets produits sur les corps par les Rayons Solaires: par M. Edmond Becquerel.—Annales de Chimie, vol. ix. p. 257. 1843.

M. Becquerel has applied the term phosphorogÉnique to those rays producing phosphorescence.


                                                                                                                                                                                                                                                                                                           

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