Conclusion.

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The principal results relating to s.fluoresceÏn which have been reached in this work may be briefly summarized as follows. Orthosulphobenzoic acid acts on resorcin at a temperature of about 180° giving off water and forming a substance analogous to fluoresceÏn but having the CO group replaced by SO2. This substance sulphonfluoresceÏn crystallizes from water in light yellow monoclinic crystals having the composition C19H12O6S + 2H2O. It is very soluble in alcohol and water and with difficulty in ether. It does not melt under 250° but above 300° melts with decomposition. It shows in alkaline solution a clear green fluorescence. It acts as an acid, decomposing carbonates and forming salts, the Ba salt having the composition C19H13O7SBa. It forms an acetyl compound when boiled with acetic anhydride. It forms substitution products with Br, probably the dibrom-product most easily. It forms a compound with H2SO4, probably a substitution product, whose composition was not determined. It is reduced by zinc dust and KOH to a colorless substance analogous to fluoresceÏn.

Finally in terms of the prevalent theory the substance itself may be represented thus—

H H
C O C
? ? ? ? ? ?
(HO ) C C C C (OH)
H C C C C H
? ? ? ? ? ?
C C C =
H H ? ? H
C ? ?
? ? ? O
HC C ?
?
HC C S O 2
? ?
C
H
? OH
?
C6H3
?
O
?
C ? C6H3
?
OH
C6H4SO2
?
? O

[1]
Annalin. No. 183. S. 1. No. 202. S. 36 & S. 153.
Berichte. No. IV. S. 457. 555. 658. 662.
VIII. S. 66. 146.

Transcriber's Notes:


Illustration has been moved so it does not break up the paragraph.

As this was a hand-written thesis, the spelling, punctuation and hyphenation is very inconsistent.

The original spelling, hyphenation and punctuation have been left unchanged.





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