CHAPTER XLIV STORAGE BATTERIES

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Introduction.—The practical development of the storage battery is comparatively recent, although a knowledge of the phenomena upon which its actions are based, dates back to 1801. In 1800, the year made memorable by Volta's discovery of the galvanic battery, Nicholson and Carlisle found that a current from Volta's cell could decompose water.

In 1801, Gautherot discovered that if two plates of platinum or silver, immersed in a suitable electrolyte, be connected to the terminals of an active primary cell and current be allowed to flow, a small current could be obtained on an outside circuit connecting these two electrodes as soon as the primary battery had been disconnected.

Erman found that the positive pole of such a cell, was the pole which had been connected to the positive pole of the battery.

In 1803, Ritter observed, with gold wire, the same phenomenon as Gautherot, and constructed the first secondary battery, by superposing plates of gold, separated by cloth discs, moistened with ammonia.

Volta, Davy, Marianini, and others added somewhat to the knowledge on the subject, and in 1837, Schoenbein found that peroxide of lead could be used in secondary batteries.

Sir William Grove next came forward with the discovery that metal plates, with a layer of oxide on them, acted better than the plain metallic plates, and Wheatstone and Siemens found still later that peroxide of lead was the best for such purposes.

In 1842, Grove constructed a gas battery, in which the electromotive force came from the oxygen and hydrogen evolved in the electrolysis of water acidulated with sulphuric acid. By means of fifty such cells, he obtained an arc light.

Michael Faraday, when electrolyzing a solution of lead acetate, found that peroxide was produced at the positive, and metallic lead at the negative pole, and in his "Experimental Researches," he comments on the high conductivity of lead peroxide, and its power of readily giving up its oxygen. Although he made no apparent use of this discovery, it may be considered as the next important step in the development of the storage battery.

According to Niblett, Wheatstone, de la Rue, and Niaudet were well aware that peroxide of lead was a powerful depolarizer, but nobody appears to have made use of this fact until 1860, when M. Gaston Plante constructed his well known cell with coiled plates. Plante's researches extended up to 1879, and practically determined the state of the art.


Fig. 1,046.—One plate or "grid" of a type of storage cell constructed by inserting buttons or ribbons of the proper chemical substances in perforations. Some such cells use crimped ribbons of metallic lead for inserting in the perforations, others pure red lead or other suitable material.

As to the theory at this time, it may be stated that Clerk Maxwell, although the leading electrician of his time, speaks of the storage battery as storing up a quantity of energy in a manner somewhat analogous to the ordinary condenser; hence the use of the word "accumulator" for storage battery.

In 1879, R. L. Metzer did away with the tedious forming process, by mechanically applying the active material. This important discovery was not, however, generally known, until 1881, when Camille Faure obtained important patents concerning the method of shortening the time of formation.

Charles F. Brush, working independently of either Faure or Metzer, arrived at the same result, and the United States courts have decided, after long litigation, that to him belongs the priority of invention in this country.


Figs. 1,047 to 1,050.—Electric Storage Battery Co. plates. Fig. 1,047, "Manchester" positive plate; fig. 1,048, box negative plate; fig. 1,049, "Tudor" positive plate; fig 1,050, pasted negative plate.

Ques. To what use is the storage battery sometimes put in electric lighting or power stations?

Ans. To carry the "peak" of the load; that excessive portion of the load which, for instance, in electric lighting stations has to be carried only for two or three hours a day. To carry the entire load at minimum hours. To act as equalizer or reservoir. Also for equipment of annex or substations.


Fig. 1,051.—"Unformed" plate of one pattern of Gould storage cell. The particular plate shown has total outside dimensions of 6×6 inches. The clear outline of the grooves indicates absence of oxides, due to action of "forming" solutions, or charging current.

Theory of the Storage Battery.—The action of the storage battery is practically the same as that of the primary battery and it is subject to the same general laws. The cells of a storage battery are connected in the same way as primary cells, and when charged is capable of generating a current of electricity in a manner similar to that of a primary battery. It differs, however, from the primary battery in that it is capable of being recharged after exhaustion by passing an electric current through it in a direction opposite to that of the current on discharge. This difference constitutes the principal advantage of the storage battery over the primary battery.


Figs. 1,052 and 1,053.—Electric Storage Battery Co., type H "exide" plates. This form of plate is used for large "stand by" batteries. Fig. 1,052, positive plate; fig. 1,053, negative plate.

Ques. Describe a storage cell.

Ans. A storage cell consists of plates or of grids in an electrolyte, of such a character that the electrical energy supplied to it is converted into chemical energy (a process called charging). The chemical energy can be reconverted into electrical energy (a process called discharging).

Ques. Describe the electrolyte generally used.

Ans. It consists of a weak solution of sulphuric acid which permits ready conduction of the current from the primary battery, the greater the proportion of acid within certain limits, the smaller the resistance offered.


Fig. 1,054.—Elements of 6 volt 40 ampere hour "Aplco" portable (3 cell) storage battery. The grids are made from an alloy of lead and antimony; hard lead straps which are burned together, are used for joining the plates. Specially treated separators are used.

Ques. What is the effect of the current passing through the electrolyte?

Ans. It decomposes the water into oxygen and hydrogen; this is indicated by the formation of bubbles upon the exposed surfaces of both plates, these bubbles being formed by oxygen gas on the plate connected to the positive pole of the primary battery, and hydrogen on the plate connected to the negative pole.

Because, however, the oxygen is unable to attack either platinum or silver under such conditions, the capacity of such a device to act as an electrical accumulator is practically limited to the point at which both plates are covered with bubbles. After this point the gases will begin to escape into the atmosphere.

Ques. What is the prime condition for operation of a storage battery?

Ans. The resistance of the electrolyte should be as low as possible in order that the current may pass freely and with full effect between the electrodes. If the resistance of the electrolyte be too small, the intensity of the current will cause the water to boil rather than to occasion the electrolytic effects noted above.

Ques. What happens when the charging current is discontinued, and the two electrodes joined by an outside wire?

Ans. A small current will flow through the outside circuit, being due to the recomposition of the acid and water solution. The process is in a very definite sense a reversal of that by which the current is generated in a primary cell.

Hydrogen collected upon the negative plate, which was the cathode, so long as the primary battery was in circuit, is given off to the liquid immediately surrounding it, uniting with its particles of oxygen and causing the hydrogen, in combination with them, to unite with the particles of oxygen next adjacent. The process is continued until the opposite positive plate is reached, when the oxygen collected there is finally combined with the surplus hydrogen, going to it from the surrounding solution.

This chemical process causes the current to emerge from the positive plate, which was the anode, so long as the primary battery was in circuit. The current thus produced will continue until the recomposition of the gases is complete; then ceasing because these gases, as before stated, do not combine with the metal of the electrodes.

Types of Storage Battery.—There are three classes of storage cell which are commercially important:

1. Plante cells;
2. Faure cells;
3. Alkaline cells.

According to construction secondary cells may be classified as follows:

1. Lead sulphuric acid cells;
2. Lead copper cells;
3. Lead zinc cells;
4. Alkaline zincate cells.

The lead sulphuric acid type includes all those cells belonging to the Plante and Faure groups.

Lead copper cells consist of sheets of metal coated with lead oxide, serving as the positive electrode, and copper plates for the negative electrodes. These plates are immersed in a solution of copper sulphate. Cells belonging to this class are not employed in commercial practice, being useful only for laboratory experiments.

Lead zinc cells are similar to the preceding type, but differ by having zinc for the negative electrode, and zinc sulphate for the electrolyte. The voltage of these cells is slightly higher than that of the ordinary cell, and their capacity per unit of total weight is high, but they are apt to lose their charge on open circuit, besides they possess most of the disadvantages of the Plante cells.

Alkaline zincate cells have copper for the positive, and iron for the negative electrode. The electrolyte is composed of sodium, or potassium, zincate. Cells of this type are used to some extent for traction purposes.

In addition to the above there are some special forms of cell which do not belong to the four preceding types.

Ques. Describe the Plante type.

Ans. In the Plante type the lead is chemically attacked and finally converted into lead peroxide, probably after it has gone through several intermediate changes. The plates are all formed as positive plates first and then all that are intended for negative plates are reversed, the peroxide being changed into sponge lead.


Figs. 1,055 and 1,056.—Willard plates; fig. 1,055, negative plates; fig. 1,056, positive plates. Both positive and negative plates are of the PlantÉ type, made from one integral piece of rolled lead. These are grooved plates. The projections are tapered, that is, they are wider at the base than at the surface, for strength. The center web of each positive plate is tapered from the top of the plate downward to secure uniform distribution of the current all over the surface of the plate.


Fig. 1,057.—Wood separator for spacing the plates, as used in the Willard storage cells.


Fig. 1,058.—Positive plate.

Fig. 1,059.—Perforated rubber separator.

Fig. 1,060.—Wood separator.

Fig. 1,061.—Negative plate.

Fig. 1,062.—Hard rubber cover.

Fig. 1,063.—Vent plug.

Fig. 1,064.—Pillar connecting strap.

Fig. 1,065.—Hard rubber jar.

Fig. 1,066.—Complete element.

Figs. 1,058 to 1,066.—Parts of the Willard "Autex" automobile cells.

Ques. What is done to make the Plante plate more efficient?

Ans. The surfaces are finely subdivided, the following methods being those common: scoring, grooving, casting, laminating, pressing, and by the use of lead wool.

Ques. Describe the Faure or pasted type.

Ans. This form of plate is constructed by attaching the active material by some mechanical means to a grid proper. The active material first used for this purpose was red lead, which was reduced in a short time to lead peroxide when connected as the positive or anode, or to spongy metallic lead when connected as the cathode or negative, thus forming plates of the same chemical compound as in the Plante type.

The materials used at the present time by the manufacturers for making this paste are largely a secret with them, but in general they consist of pulverized lead or lead oxide mixed with some liquid to make a paste.

Ques. How do Faure plates compare with those of the Plante type?

Ans. They are usually lighter and have a higher capacity, but have a tendency to shed the material from the grid, thus making the battery useless.

Many ways have been tried for mechanically holding the active material on the grid, the general method involving a special design in the shape of the grid. Some of these designs are: 1, solid perforated sheets of lattice work; 2, corrugated and solid recess plates not perforated; 3, ribbed plates with projecting portions; 4, grid cast around active material; 5, lead envelopes, and 6, triangular troughs as horizontal ribs.

The Electrolyte.—Sulphuric acid is generally used as electrolyte; the acid should be made from sulphur and not from pyrites, as the latter is liable to contain injurious substances.

Ques. How is the electrolyte prepared?

Ans. One part of chemically pure concentrated sulphuric acid is mixed with several parts of water. The proportion of water differs with several types of cell from three to eight parts, as specified in the directions accompanying the cells.


Figs. 1,067 to 1,079.—Willard connecting straps and connectors.

Ques. What test is necessary in preparing the electrolyte?

Ans. In mixing the water and acid, the hydrometer should be used to test the specific gravity6 of both the acid and the solution. The most suitable acid should show a specific gravity of about 1.760 or 66° BaumÉ.

Ques. In preparing the electrolyte, how should the water and acid be mixed?

Ans. The mixture should be made by pouring the acid slowly into the water, never the reverse. As cannot be too strongly stated, in mixing, the liquid should be stirred with a clean wooden stick, the acid being added to the water slowly; the latter is corrosive and will painfully burn the flesh.

Distilled or rain water should be used in preparing the electrolyte. When made, the solution should be allowed to cool for several hours or until its temperature is approximately that of the atmosphere (60 being the average). At this point it should have a specific gravity of about 1.200 or 25° BaumÉ. If the hydrometer show a higher reading, water may be added until the correct reading is obtained; if a lower reading, dilute acid may be added with similar intent.

The electrolyte should never be mixed in jars containing the battery plates, but preferably in stone vessels, specially prepared for the purpose. Furthermore, it should never be placed in the cell until perfectly cool.

Ques. What is the effect of mixing the acid and the water?

Ans. The mixture becomes hot.

Before using, the mixture should be allowed to cool.

Ques. What kind of a vessel should be used?

Ans. The vessel should be of glass, glazed earthenware, or lead.

Ques. At what density is the resistance of dilute sulfuric acid at a minimum?

Ans. At 1.260.

The percentage of concentrated sulphuric acid and of water per 100 parts of the electrolyte for various specific gravities is given by the following table:

SPECIFIC GRAVITY TABLE
Sulphuric acid
(Per cent.).
Water
(Per cent.).
Specific gravity
of Mixture.
50 50 1.398
47 53 1.370
44 56 1.342
41 59 1.315
38 62 1.289
35 65 1.264
32 68 1.239
29 71 1.215
26 74 1.190
23 77 1.167
20 80 1.144
17 83 1.121
14 86 1.098
10 90 1.068

The electrolyte of the desired specific gravity may be purchased ready for use, but in cases where it is desirable to save freight, the acid may be diluted at the point of installation.

Ques. What is the effect of a deep containing vessel?

Ans. Parts of the plate surface may do more than their share of the work due to the difference in the density of the electrolyte at the top and bottom. The containing vessel should, therefore, never be deeper than about 20 inches unless some artificial means of acid circulation be used.

Ques. What is the effect of changes in temperature on the electrolyte?

Ans. The resistance of the electrolyte is changed, being less for increase of temperature.


Figs. 1,080 to 1,084—Acid hydrometers for liquids heavier than water. Fig. 1,080, standard storage battery hydrometer with guiding points designed for "hydrometer syringe," shot bulb, with red line at 25 BaumÉ, 5 inches long, double scale 10 to 40 BaumÉ, 1.050 to 1.400 specific gravity. Fig. 1,081, plain hydrometer with shot bulb, 5 inches long, double scale 10 to 40 BaumÉ, 1.050 to 1.400 specific gravity. Figs. 1,082 and 1,083, hydrometer with small flat bulb, used in car lighting batteries, shot bulb, 4½ inches long, single scale, reading from 1.100 to 1.250 specific gravity. Fig. 1,084 jar for hydrometers.

Ques. How should the cells be filled?

Ans. Enough of the electrolyte should be poured into the jars to completely cover the plates, or to within about a half inch of the top edge of the jar. Large cells should be filled by means of an acid proof pump and rubber hose.

Ques. What change takes place after filling the jars?

Ans. The specific gravity of the electrolyte will fall considerably, but will rise again when the battery is charged.

Ques. What may be said with respect to the density of the electrolyte?

Ans. It should never exceed 1.200 when the battery is fully charged.

Ques. How much electrolyte is used per 100 ampere hours battery capacity, on an 8 hour rating?

Ans. About ten pounds; in automobile batteries, about four pounds is sufficient.


Fig. 1,085.—The hydrometer syringe; a convenient device for testing electric vehicle cells. By slightly compressing the bulb and inserting the slender tube through the vent hole in the cover of the cell sufficient acid may be drawn up to float the hydrometer within the large glass tube, and the reading can be made at once. The acid is returned to the cell by again compressing the bulb, and the reading of the next cell taken. The laborious and uncleanly method of drawing out sufficient acid by a syringe is thus avoided.

Ques. What may be said with respect to impurities in the electrolyte?

Ans. The electrolyte should be free from chlorine, nitrates, acetates, iron, copper, arsenic, mercury, and the slightest trace of platinum.

Mercury alone has no injurious effect unless it be present in sufficient quantity to amalgamate the plates, but in combination with any other metal, may cause local action.


Figs. 1,086 to 1,089.—The "Champion" Accumulator; views showing parts and assembly. Fig. 1,086, empty plate; fig. 1,087, filled plate; fig. 1,088, complete element, small type; fig 1,089, cell assembled. The plates are of the envelope type and are made thick. The active material is held firmly in place by a covering of lead. A few thick plates are used instead of many thin ones.

The following tests should be made for impurities before the electrolyte is poured in the cells:

Chlorine.—To a small sample of the electrolyte add a few drops of silver solution (20 grains of silver dissolved in 1,000 cu. cm. of water). A white precipitate indicates chlorine.

Nitrates.—Place some of the electrolyte in a test tube, and add 10 grains of strong ferrous sulphate solution. Carefully pour down the side of the test tube a small amount of chemically pure concentrated sulphuric acid. A brown stratum between the electrolyte and the concentrated acid indicates the presence of nitric acid.

Acetic acid.—Neutralize the electrolyte with ammonia, then add ferric chloride. If the solution turns red, and is afterwards bleached by the addition of hydrochloric acid, acetic acid is present.

Iron.—Neutralize a sample of the electrolyte with ammonia; boil a small portion with hydrogen peroxide, and add ammonia or caustic potash solution until the mixture becomes alkaline. If a brownish red precipitate forms, it indicates iron.

Copper.—If copper be present, a bluish white precipitate will be formed when ammonia solution is added to the electrolyte.


Fig. 1,090.—One cell of the Gould storage battery for electric vehicle use. According to the data given by the manufacturers, this cell, containing four negative and three positive plates, has a normal charging rate of 27 amperes; a distance rate of 22 amperes for four hours; a capacity of 81 ampere hours at 3 hours discharge, and of 90 ampere hours at 4 hours discharge. Forty such cells are generally used for an average light vehicle battery.

Mercury.—This is indicated by an olive green precipitate when a solution of potassium iodide is added to the electrolyte, or by a black precipitate when lime water is added.

Platinum.—A rough test for traces of platinum is made by pouring the electrolyte into a cell in which the battery plates are immersed. If gassing take place for some time on open circuit, it is an indication of the presence of platinum.

Ques. What should be done with old electrolyte?

Ans. When a battery is taken down the electrolyte may be saved and used when re-assembling the battery, providing great care be exercised when pouring it out of the jar, so as not to draw off with it any of the sediment. It should be stored in convenient receptacles, preferably carboys, which have been thoroughly washed and never used for any other purpose.


Fig. 1,091.—Phantom view of an "Exide" sparking or ignition battery. It contains three cells. In this type, the terminal lug has been designed to obviate the creeping of the electrolyte with its accompanying corrosion. The positive and negative terminals are for identification.

The electrolyte saved in this manner will not, however, be sufficient to refill the battery, and as some new electrolyte will be required, in general it is recommended that the old supply be thrown away and all new electrolyte (1.200 specific gravity) be used when re-assembling.

Voltage of a Secondary Cell.—This depends on the density of the electrolyte, the character of the electrodes and condition of the cell; it is independent of the size of the cell.

The voltage of a lead sulphuric acid cell when being charged is from 2 to 2.5 volts. While the cell is being discharged, it decreases from 2 to 1.7 volts. The voltage due to the density of the electrolyte may be calculated from the following formula:

V = 1.85 + .917 (S - s)

in which

V = voltage;
S = specific gravity of the electrotype;
s = specific gravity of water at the temperature of observation.


Fig. 1,092.—The Exide storage cell. The positive and negative plates are separated by thin sheets of perforated hard rubber, placed on both sides of each positive plate. The electrolyte and plates are contained in a hard rubber jar.

Fig. 1,093.—An Exide battery of five cells. The box which holds the cells is usually made of oak, properly reinforced, with the wood treated to render it acid proof. The terminals as shown, consist of metal castings attached to the side of the box and plainly marked.

Connection for Charging.—The dynamo cable connections may be made either before or after filling the cells. In making these connections great care should be taken to be sure that the positive terminal of the battery is connected to the positive lead of the dynamo, and that the negative terminal of the battery is connected to the negative lead of the dynamo. In order to insure that the reverse connections are not made accidentally, the dynamo leads should be tested by a pole tester, and the positive and negative poles marked red and black respectively.


Figs. 1,094 to 1,109.—Parts of the "Exide" sparking battery. A, positive plate; B, negative plate; C, wood separator; D, positive strap; E, negative strap; F, terminal lug; H, connector; I, terminal bolt connector, stud, thumb nut and hexagonal nut; J, copper washer for bolt connector; L, hard rubber jar; M, hard rubber cover; N, hard rubber cylinder vent; O, vent plug for cylinder vent; R, wood case; S, strap handle; T, fitting for strap handle. The "Exide" sparking battery is also adapted for electric lighting of automobiles, for head lights, tail lights, side and interior lights.

The polarity of the dynamo wires being determined, they may be joined to the proper terminals by means of suitable clamps or by solder.

Wherever possible the dynamo should be of the direct current, shunt wound, or special compound type, but in cases where only alternating current can be obtained, suitable rectifiers or converters should be used for changing it to direct current.

Charging.—Before beginning to charge a storage battery, it should be gone over carefully, and any cell that is not up to the standard should be disconnected and put in working order before being replaced. In general, if the current used in charging be too large, it will waste energy by evolving an excess of heat and gas; if too small, an insulating deposit of white lead sulphate will be formed on the positive plate, thereby preventing the formation of the proper amount of lead peroxide.


Figs. 1,110 and 1,111.—Switchboard and motor dynamo circuit connections for charging a battery from direct current mains.

Ques. How should a battery be charged for the first time?

Ans. It is essential that the current be allowed to enter at the positive pole at about one-half the usual charging rate prescribed, but after making sure that all necessary conditions have been fulfilled, it is possible to raise the rate to that prescribed by the manufacturers of the battery.

Ques. What is the usual period for charging a new battery?

Ans. With several of the best known makes of storage battery the prescribed period for the first charge varies between twenty and thirty hours.


Figs. 1,112 and 1,113.—Switchboard and motor generator circuit connections for charging a battery from alternating current mains. The connections of a third wire are shown, for use in case a three phase circuit is available.

Ques. How is the electrolyte affected by the first charge?

Ans. A change of specific gravity occurs. The specific gravity should be about 1.200 when the solution is poured into the cells.

At the completion of the first charge, it should, on the same scale be about 1.225. If it be higher than this, water should be added to the solution until the proper figure is reached, if it be lower, dilute sulphuric acid should be added until the hydrometer registers 1.225.

At the first charging of a cell, when the pressure has reached the required limit, the cell should be discharged until the voltage has fallen to about two-thirds normal pressure, when the cell should again be recharged to the normal voltage (2.5 or 2.6 volts).

The manufacturers of a well known cell of the Plante genus prescribe for the first charge, half rate for four hours, after which the current may be increased to the normal power and continued for twenty hours successively.


Fig. 1,114.—Plates of Edison storage battery. The positive or nickel plate consists of one or more perforated steel tubes, heavily nickel plated, filled with alternate layers of nickel hydroxide and pure metallic nickel in excessively thin flakes. The tube is drawn from a perforated ribbon of steel, nickel plated, and reinforced with eight steel bands, equidistant apart, which prevent the tube expanding away from and breaking contact with its contents. The tubes are flanged at both ends and held in perfect contact with a steel supporting frame or grid made of cold rolled steel, nickel plated. The negative or iron plate consists of a grid of cold rolled steel, nickel plated, holding a number of rectangular pockets filled with powdered iron oxide. These pockets are made up of very finely perforated steel, nickel plated. After the pockets are filled they are inserted in the grid and subjected to great pressure between dies which corrugate the surface of pockets and force them into good contact with the grid.

Ques. What strength of current should be used in charging a cell?

Ans. It should be in proportion to the ampere hour capacity of the cell.

Thus, as given by several manufacturers, the normal charging rate for a cell of 40 ampere hours should be five amperes, or one-eighth of its ampere hour rating in amperes of charging current.

Ques. What should be the voltage of the charging current before closing the charging circuit?

Ans. The voltage should be at least ten per cent. higher than the normal voltage of the battery when charged.


Fig. 1,115.—Complete element of Edison storage battery with insulators. After the plates are assembled into a complete element, narrow strips of treated hard rubber are inserted between the plates, thereby separating and insulating them from each other. The side insulator is provided with grooves that take the edges of the plates, thereby performing the dual function of separating the plates and insulating the complete elements from the steel container. At the ends of the element, that is between the outside negative plates and container, are inserted smooth sheets of hard rubber. At the bottom, the element rests upon a hard rubber rack or bridge, insulating the plates from the bottom of container.

Fig. 1,116.—Four Edison cells (type A-4) in wooden tray.

Ques. What indicates the completion of a charge?

Ans. When a cell is fully charged the electrolyte apparently boils and gives off gas freely. The completion of a charge may be determined by the voltmeter, which will show whether the normal pressure has been attained.

Ques. How should the voltage be regulated during the first charge?

Ans. It should be allowed to rise somewhat above the point of normal pressure.

Electrical Data Edison Cell
B-2 B-4 B-6
Normal output, ampere hours 40 80 120
Maximum output, ampere hours 48 95 142
Normal rate of discharge, amperes for five hours 8 16 24
Average voltage on normal discharge 1.2 1.2 1.2
Normal rate of charge, amperes for seven hours 8 16 24
Maximum rate of "boosting charge" (for short time only) 50 100 140
Length of containing can (determined by number of plates) 2? 313/16
Width of containing can 5? 5? 5?
Height " " " 715/16 713/16
Height over all 8?
Weight of each cell alone, lbs. 4.6 7.4 10.5
Average weight per cell of battery, assembled in trays 5.5 8.7 11.8

Fig. 1,117.—Cell of Edison storage battery. The jar or container is of nickel plated sheet steel with welded seams; the walls are corrugated to give strength. The cell cover, of sheet steel, has four mountings, two being pockets to contain stuffing boxes about the terminal posts. One of the other two is a separator which separates spray from the escaping gas while the battery is charging. The fourth mounting is for filling with electrolyte. The electrolyte consists of a 21% solution of potash in distilled water with a small per cent. of lithia. The density of the electrolyte does not change on charge or discharge.

Ques. How often should a battery be charged?

Ans. At least once in two weeks, even if the use be only slight in proportion to the output capacity.

In charging a storage battery, it is essential to remember the fact that the normal charging rate is in proportion to the voltage of the battery.

Thus, a 100 ampere hour battery, charged from a 110 volt circuit at the rate of ten amperes per hour, would require ten hours to charge, and would consume in that time an amount of electrical energy represented by the product of 110 (voltage) by 10 (amperes) which would give 1,100 watts, or 11/10 kw.


Fig. 1,118.—Diagram illustrating method of charging storage battery of stationary gas engine ignition system; the system is simple to install and will give satisfactory results. Two storage batteries are used, one being charged while the other is operating the sparking coil. Where charging current is available at the point where the batteries are used, the following diagram shows the system of connections, which can be easily followed, A represents the source of charging current and B the bank of lamps (or other resistance, such as an ordinary rheostat) sufficient to cut down the charging voltage to that required by the battery. C and D are two double pole double throw knife switches connected at their hinges to two batteries, E and F, each consisting of a group of cells. G represents the leads to the sparking coil terminals. From the diagram, it will readily be seen that by throwing the switches in opposite directions one battery will be charging while the other battery is discharging to the engine, thus giving a constant source of supply, and insuring that the spare battery will be full and ready for service by the time the other is discharged. The method of determining the necessary resistance for cutting down the line voltage for charging the battery is illustrated by the following example: If a battery require about 3 amperes for charging, how is this current obtained from a 110 volt circuit? Each 16 candle power carbon filament lamp in the lamp bank would give approximately 1/3 ampere with the cells in series in the lamp circuit. Therefore, 3 x 3 or 9 lamps should be used in parallel to give 3 amperes.

Ques. If in charging a battery, one or more of the cells do not boil at the completion of the charge, or fail to show the proper voltage, what should be done?

Ans. The charging must be continued until the cadmium test shows the required voltage, but if the prolonging of the charge be liable to damage the plates in the other cells, the defective cell or cells should be cut out of circuit when the battery discharges and then placed in circuit again when the battery is recharged. If the desired result cannot be attained by this method, the plates which require additional charging may be charged in a separate cell.


Figs. 1,119 and 1,120.—Emergency connections for weak ignition battery. It sometimes occurs through carelessness or neglect, that the storage battery is discharged so low that the engine explosion will not take place, and it is necessary to run somehow or other for a short time. In such cases the following suggestion may be followed: If there be two storage batteries, connect them in series. If there be one storage battery and a set of dry cells, connect the positive terminal of the storage battery to the negative or outside terminal of the dry cell; set and connect to the coil leads as if they were one battery. The above suggestions should only be followed in emergency, for it may injure the coils, and is harmful to the battery.

Ques. How is the cadmium test made?

Ans. A plate of cadmium is mounted in a hard rubber frame and immersed in the electrolyte. The test consists in taking voltage readings between the cadmium plate and the positive or negative plates of the cell. During charge the cadmium plate reads negative to the negative plate, until the cell is about full, when the reading should be zero; the charge should be continued until the cadmium reads 0.2 volt positive to the negative while charging at the normal rate.

Ques. Name some portable instruments that should be provided for testing batteries.

Ans. 1, a hydrometer syringe (specific gravity tester); 2, an acid testing set (can be used instead of the syringe); 3, a low reading voltmeter; 4, suitable prods, and 5, a thermometer.

Ques. What precaution should be taken in charging a battery?

Ans. Care should be taken not to have a naked flame anywhere in its vicinity.

To either charge or discharge a battery at too rapid a rate involves the generation of heat. Thus, while this is not liable to result in a flame under usual conditions, the battery may take fire, if it be improperly connected or improperly used.

Ques. What is the effect of varying the charging current?

Ans. In charging a storage cell, particularly for the first time, a weaker current than that specified may be used with the same result, provided the prescribed duration of the charge be proportionally lengthened. The battery may also be occasionally charged beyond the prescribed voltage, ten or twenty per cent. overcharge effecting no injury, although if frequently repeated, it shortens the life of the battery.

Ques. What are the charge indications?

Ans. The state of the charge is not only indicated by the density of the electrolyte and the voltage of the cell, but also by the color of the plates, which is considered by many authorities as one of the best tests for ascertaining the condition of a battery.


Figs. 1,121 and 1,122.—Two methods of charging from a direct current lighting system. The simplest method of charging is from an incandescent light circuit, using lamps connected in parallel to reduce the voltage to that of the battery, the current being adjusted by varying the number of lamps in circuit. The group of lamps is in series with the battery to be charged, and the combination is connected across the circuit furnishing the current. If the charging source be a 110-120 volt circuit, and the rate required be 6 amperes, twelve 16 c. p. or six 32 c. p. lamps, in parallel, and the group in series with the battery, will give the desired charging rate, unless high efficiency lamps be used, when more will be required. In case a lower charging rate, say 2 amperes be used, then a proportionately fewer number of lamps will be needed; but the length of time required to complete the charge will be correspondingly increased. Instead of lamps, as in fig. 1,121, a rheostat is sometimes used, as shown in fig 1,122. Its resistance should be such as to produce, when carrying the normal charging current, a drop in volts equal to the difference between the pressure of the charging source and that of the battery to be charged; thus, if a battery of three cells, giving 6 volts, is to be charged from a 110 volt circuit at a 6 ampere rate, the resistance would be, according to Ohm's law,
(110 - 6) ÷ 6 = 17.3 ohms.
The carrying capacity of the rheostat should be slightly in excess of the current required for charging. An ammeter with suitable scale should be inserted in the battery circuit to indicate the current. For charging more than one battery at a time from a 110 volt circuit, the batteries should be connected in series (positive terminal of one battery to the negative of the next, and so on). The charging rate should be that of the battery with the lowest rate. The resistance to be inserted will be less than if only one battery is being charged; where lamp resistance is used, this means more lamps in parallel. Care should be taken to remove each battery from the circuit as it becomes charged, inserting additional resistance to take its place.

Ques. What are the colors of the plates?

Ans. In the case of formed plates, and before the first charging, the positives are of a dark brown color with whitish or reddish gray spots, and the negatives are of a yellowish gray. The whitish or reddish gray spots on the positive plates are small particles of lead sulphate which have not been reduced to lead peroxide during the process of forming, and represent imperfect sulphation.

As a general rule, the first charging should be carried on until these spots completely disappear. After this the positive plates should be of a dark red or chocolate color at the end of the discharge, and of a wet slate or nearly black color when fully charged. A very small discharge is sufficient, however, to change them from black to the dark red or chocolate color.

If the battery has been discharged to a pressure lower than 1.8 volts, the white sulphate deposits will reappear, turning the dark red color to a grayish tint in patches or all over the face of the plate, or in the form of scales of a venetian red color.

The formation of these scales while charging indicates that the maximum charging current is too large and should be reduced until the scales or white deposits fall off or disappear, after which the current can be increased again.

During charging, the yellowish gray color of the negatives changes to a pale slate color which grows slightly darker at the completion of the charge. The color of the negatives always remains, however, much lighter than that of the positives.

Ques. How are the best results obtained in charging?

Ans. The rate of charge should be normal, except in cases of emergency. At such a rate, unless the constant voltage method be employed, the cell may be considered full when the voltmeter reads 2.5 volts during charge. The electrolyte should be kept at uniform density throughout the cell; when water is added, because of evaporation, it should be added by means of a funnel reaching to the bottom of the cell. Care should be taken never to add acid after evaporation; otherwise the electrolyte will be too heavy. Hydrometer readings should be taken regularly; the reading is an excellent indication of the amount of charge in the battery. Hydrometer readings are useless, however, unless the precaution be taken to keep the electrolyte of uniform density.

Ques. What voltage should be used in charging?

Ans. At the beginning of the charge the voltage should be about 5 per cent. higher than the normal voltage of the battery, unless the latter has been overdischarged, in which case the difference of pressure should not exceed 2 per cent., otherwise the current might be too large.


Fig. 1,123.—Diagram showing charging connections for "Exide" duplex sparking battery. C, charging source; D, double pole single throw switch; E, single pole single throw switch; M, lamp resistance "main" battery; R, lamp resistance "reserve" battery.

Ques. In what two ways may batteries be charged?

Ans. They may be charged either at constant current or at constant voltage.

Although the latter method is considered the better one by many authorities, it is a fact, nevertheless, that if the charging current be normal at the beginning of the charge, and no means be provided for keeping it constant, it will diminish as the charging progresses, thereby greatly increasing the length of the time required for charging, and resulting in serious injury to the plates.

Ques. How may the charging current be kept constant?

Ans. Its voltage should be gradually increased, first to about 10 or 15 per cent. above the voltage of the battery, and kept at that point nearly to the end of the charge, where in consequence of the rapid rise of pressure in the battery it might become necessary to increase the voltage of the current to 30 or 40 per cent. above the normal of the battery.


Figs. 1,124 to 1,126.—Electric Storage Battery Co. chloride cells. The voltage of cells of all capacities is slightly above 2 volts on open circuit, and during discharge at the 8 hour rate it varies from that point at the beginning to 1.75 volts at the end.

Ques. What tests should be made while charging?

Ans. Occasional voltage and cadmium readings of each cell should be taken for the purpose of ascertaining their condition and the behavior of the separate plates.

Ques. What tests should be made after charging?

Ans. Each cell should be tested with a low reading voltmeter and hydrometer about once a week. If any cell read low, it should be cut out and examined to see if any material has been introduced which would cause a short circuit. If this trouble do not exist, the cell should be given an independent charge.

Charge Indications.—The state of the charge is not only indicated by the density of the electrolyte and the voltage of the cell, but also by the color of the plates, which is considered by many authorities as one of the best tests for ascertaining the condition of a battery.

In the case of formed plates, and before the first charging, the positives are of a dark brown color with whitish or reddish gray spots and the negatives are of a yellowish gray. The whitish or reddish gray spots on the positive plates are small particles of lead sulphate which have not been reduced to lead peroxide during the process of forming, and represent imperfect sulphation.

As a general rule the first charging should be carried on until these spots completely disappear. After this, the positive plates should be of a dark red or chocolate color at the end of a discharge and of a wet slate or nearly black color when fully charged. A very small discharge is sufficient, however, to change them from black to the dark red or chocolate color.

If the battery has been discharged to a pressure lower than 1.8 volts, the white sulphate deposits will reappear turning the dark red color to a grayish tint in patches or all over the surface of the plate, or in the form of scales of a venetian red color.

The formation of these scales during charging indicates that the maximum charging current is too large and should be reduced until the scales or white deposits fall off or disappear, after which the current can be increased again.

Ques. Describe the behavior of the electrolyte during discharge.

Ans. There is a definite change in the density of the electrolyte for a given amount of discharge.

The density of the electrolyte is, therefore, one of the best indications of the state of charge, provided, of course, no internal discharge due to local action takes place. If, when the cell is charged, it show a density of 1.200, and when discharged 1.130, the difference .07 represents the total charge. If at any time the density be 1.165, then just one half the amount of capacity has been taken from the cell.

It is necessary to stir the electrolyte well, in order for these observations to be reliable.

If the discharge has taken place at a high rate, the cell must stand for an hour or more before the electrolyte will completely diffuse so that the density readings are correct.


Fig. 1,127.—Electric Storage Battery Co., arc lead burning outfit. In assembling a storage battery element, a negative plate is laid down with a separator on it, then a positive plate, separator, negative plate, etc. The plates are so placed that all the lugs of the positive plates are on one side and all the lugs of the negative plates are on the other side. A strip, consisting of flat strips of lead or lead alloy, having rectangular openings in it of the same dimensions as the cross section of the lug of the plates, these openings being spaced to register with the lugs, is then placed over the plate lugs of the positive plates and a similar strap is placed over the lugs of the negative plates. The lugs are then burned into integral union with the straps.

Ques. Define the term "boiling."

Ans. Boiling means the rapid evolution of gas when a cell is nearly charged.

Ques. What causes boiling?

Ans. The amount of sulphate to be converted into peroxide becomes less and less as the charge progresses and the plates therefore become virtually smaller, so that the current becomes too large for the work demanded of it. The result is, that part of the current not actually used in the formation of peroxide decomposes the electrolyte into its constituent elements.

Ques. Why do the gases evolved produce a less milky appearance of the electrolyte when a battery has been in use for a considerable time?

Ans. The plates are better formed; consequently a larger charging current can be used without producing "boiling".


Fig. 1,128.—Hydrogen gas generator for lead burning. A complete lead burning outfit consists of the following parts: 1, hydrogen gas generator; 2, trap for cleaning the gas and for preventing the flame getting back in the generator; 3, air pump; 4, air tank; 5, blow pipe; 6, lead burner's mixing tee; 7, length of 150 feet 5/16 inch soft rubber tubing. When the generator is to be used for lead burning, connect up the different parts of the apparatus as shown. Fill the trap 2/3 full with water and be sure to connect the gas generator to the nipple on the bottle marked B. The stop cocks N and C must be closed. See that the rubber plug at D is secured in place. Put the required amount of zinc in the opening at H. (No. 1 generator requires: 15 lbs. zinc, 9 gals, water, 3 gal. vitriol. No. 2 generator requires: 20 lbs. zinc, 15 gals. water, 5 gals. vitriol). After putting in the zinc, add the water and then the sulphuric acid, and note that the water must always be put in before the acid. When making the connection be sure that there are no low points in the hose between E and N, as water is liable to accumulate at these low places, which will make the gas damp which is detrimental to the burning. If water get into the line, kink the hose between F and B, detach the hose at E and blow out the water with air by opening the cocks, N, C and V. The length of the hose between T and X must not be longer than five feet as the cocks N and C must always be within the reach of the man who is using the flame. When ready to use the flame, open N which allows the hydrogen gas to escape. Light the same with a match and adjust the air cock C until the desired flame is obtained. Different classes of work require different flames, which can be obtained by changing the tips and by varying the amount of gas and air with the cocks N and C. When the generator is laid up for the night, or when the charge is exhausted, pull the hose off at F and draw off the solution by removing the plug at D. The generator should then be thoroughly washed by pouring water in A.

Ques. What may be said of charging a battery as quickly as possible?

Ans. As a general rule, such a procedure should not be adopted unless the battery be thoroughly discharged.

Ques. What precaution should be taken?

Ans. The danger to be avoided in rapidly charging a cell is its tendency to heat.

Ques. What apparatus is necessary in charging a battery?

Ans. The battery may be charged from direct current mains having the proper voltage. A current as near uniform as possible is required, and existing conditions must be met in each separate case. Sometimes a motor dynamo set with a regulating switchboard is used. Such an apparatus consists of a direct current dynamo, driven direct from the shaft of a motor, which, in turn, is energized by current from the line circuit.

With a direct current on the line, a direct current dynamo may be used; but with an alternating current an induction motor is required. The speed of the motor is governed by a rheostat, and the output of the dynamo is thus regulated as desired.

Charging Through the Night.—If an electric vehicle, after a late evening run, is to be used in the morning, the battery may be charged during the night without an attendant being present; but in doing this great care must be taken not to excessively overcharge.

A careful estimate of the amount of current required should be made and the rate of charge based on this estimate.

If, say, 72 ampere hours be required to recharge, and the time available is nine hours, the average rate of charge must be 8 amperes.

If charging from a 110-volt circuit, the rate at the start should be about 10 amperes; if from a 500-volt circuit, about 9 amperes; as, in charging from a source with constant voltage, such as a lightning or trolley circuit, the rate into the battery will fall as the charge progresses. This also applies if the charging be done from a mercury arc rectifier without attendance.

Ques. What precautions should be taken in charging a battery out of a vehicle?


Fig. 1,129.—Interior view Northwestern storage battery. The positive plate is of double grid construction, and the negative plate consists of a special staggered grid. The separators used between the plates are hard rubber, ribbed on one side so as to prevent the positive plate from buckling. It is perforated so as to allow a free circulation of the electrolyte and to decrease the internal resistance. Rubber separators are better than the commonly used wood or paper separators because they prevent local action. The flat side of each separator is placed against a positive plate, preventing shedding or jolting of the active material of the plate. This checks deterioration. The jars are made of rubber composition; the walls are thick and the covers well fitted to avoid spilling the electrolyte. All Northwestern batteries are contained in rubber composition jars. The walls are thick and the covers fit tightly to prevent spilling the acid. A hard wood box, treated with a moisture repellant is used for the outer case. These batteries are made in any voltage desired, the ampere capacity ranging from 25 amp. hrs. to 300 amp. hrs.

Ans. When a battery is being overhauled, the cells must be connected together in series and to the charging source in relatively the same manner as if they were in the vehicle; that is, the positive (+) terminal of one group of cells must be connected to the negative (-) terminal of the next group, and the two free terminals, one positive and the other negative, must be connected respectively to the positive and negative terminals of the charging circuit, but not until all of the groups have been connected in series. Great care must always be taken to have the polarities correct and the wire or cable for the connections of ample size to carry, without heating, the heaviest current used in charging.

Charging Small Cells.—For cells of the portable type, having capacities from 10 to 100 ampere hours, the normal charging and discharging rate should be about one-tenth the stated capacity, but the discharging rate may be increased to double this value, in case of necessity.

If the cells be provided with formed plates and not charged, the jars should be filled with the proper electrolyte, and then charged for at least 10 hours steady, or until they boil, then they may be discharged.

In the case of unformed plates, the charging should be from 30 to 40 hours, until the cells boil, and the plates assume their proper color.

Ques. How are small cells easily charged from 110 or 220 volt circuits?

Ans. This may be conveniently done by inserting in one of the charging leads an incandescent lamp which will pass the required quantity of current. If the current required be as large as 10 amperes, a suitable resistance or 10 lamps in parallel, each passing one ampere, may be used. Great care should be taken to see that the battery is connected properly.

Period of Charging a New Battery.—In the case of batteries provided with formed plates, the first charge should extend over a period of not less than 30 consecutive hours, without stopping, if possible, or for periods of not less than 10 hours a day for three consecutive days. The electrolyte will then commence to "boil" or "gas," assuming a milky appearance due to the ascending bubbles of gas. At this stage the density of the electrolyte as shown by the hydrometer placed in each cell should be at least 1.200; it is essential that the charging should be continued until every cell boils equally. From this point the charging should be prolonged until the pressure, as determined by a voltmeter or a cadmium tester, rises to about 2.55 volts.


Fig. 1,130.—The Willard underslung battery box for automobiles. The general tendency in automobile design, is to keep everything off the running board as far as possible, and to get tool boxes, battery boxes, etc., placed somewhere under cover. To meet these conditions the box here illustrated is arranged so that it can be underslung beneath the rear footboard or supported on auxiliary cross members made of strap iron and attached to the side members of the chassis. It is usually suspended under the rear footboard or the rear seat. The box has a chemically treated wood lining to make it acid proof. The lining is so made that there is air space between the battery and the sides of the box, except at the corners. Ventilation is thus obtained and the battery kept dry. Accumulation of water or spilled electrolyte in the bottom of the box is prevented by grooves in the bottom board, extending downward from the corners to an outlet at the center of the board. The box is also fitted with rubber bushings in the holes where wire leaves the battery box.

The charging of unformed plates is similar in all respects to that of formed plates, except that the first charging should extend over a period of at least 70 consecutive hours without stopping, at the end of which time the plates should have the characteristic colors of those of a fully charged battery. If they do not, the charging should be prolonged and the cell tested for density of electrolyte, and voltage, as already described until the desired conditions are attained. Then the battery may be discharged and recharged.

It is probable that a total of 300 to 400 hours of charging with intervening discharges will be required to form the plates until they acquire a good color, and the density of the electrolyte becomes stable.

In regular charging, the rate should be rapid when the battery is nearly exhausted, but it should be greatly reduced at the end of the charge after passing the point of boiling. Charging at too low a rate is always injurious.

Ques. What may be said with respect to the capacity of a new battery?

Ans. A new battery will never give its full capacity till after about twenty discharges. During this time it should be given about 25% overcharge. After that, 10% overcharge, that is, 10% more charge than was taken out, will be sufficient for ordinary work.

High Charging Rates.—Occasionally it is desirable to charge a battery as quickly as possible. As a general rule, such a procedure should not be adopted unless the battery be thoroughly discharged, and not then, unless done by a person who thoroughly understands what he is about; battery makers will always furnish data and directions to meet emergencies.

In charging a battery at a high rate, the danger to be avoided is the tendency of the cells to heat. The troubles that might arise from this cause may be prevented by immediately reducing the current strength. The proper rate of charge for a given battery of cells may be thus discovered by experiment. A battery should never be charged at a high rate unless it be completely exhausted, since it is a fact that the rate of charge that it will absorb is dependent upon the amount of energy already absorbed.


Fig. 1,131.—Instructions for taking voltage readings ("National" batteries). The batteries are made up of several cells, usually two or three, each cell representing approximately 2 volts when battery is on "open circuit" (neither charging nor discharging). It is sometimes advisable to take individual readings of the cells, both to determine on charge if all the cells be evenly charged, and also on discharge to be sure that the cells are evenly discharged. To do this, a low-reading voltmeter must be used with prods attached to the voltmeter leads that can be forced into the terminals so as to insure good contacts. To test the positive end cell, put the positive prod on the positive terminal of the battery and the negative prod into small hole back of positive terminal in hard rubber cover. Middle cell (in 6 volt, type "Y" batteries) is tested by inserting the positive prod in the small hole back of the positive terminal, and the negative prod in small hole back of negative terminal. In the 120 ampere hour, Auto type of battery, the middle cell is tested by inserting the positive prod in the small hole back of the positive terminal and the negative prod on the middle terminal. The negative end cell is tested by putting the negative prod on the negative terminal and the positive in the small hole in rubber cover back of the negative terminal. A charging cell at end of charge should read about 2.55 volts. A fully charged cell on open circuit should read about 2.1 volts. Since open circuit readings vary under different conditions, as to age, acid, etc., little significance should be attached to them. A discharged cell voltage will vary considerably with the many different coils, engines, etc., but in the majority of cases should read between 1.8 to 1.9 volts, while motor is in operation.

For rapid charging, when a battery has to be charged in four hours, the current should vary about as follows:

40 per cent. of total 1st hour
25 " " " " 2nd "
20 " " " " 3rd "
15 " " " " 4th "

For quick charging in three hours the rates should be: 50 per cent. 1st hour; 331/3 per cent. 2nd hour; 162/3 per cent. 3rd hour.

Mercury Arc Rectifier.—This is a device for obtaining direct current from alternating current for use in charging storage batteries. The transformation is obtained at a low cost, because the regulation is obtained from the alternating side of the rectifier, while the current comes from the direct current side.


Figs. 1,132 to 1,134.—Mercury arc rectifier outfit, or charging set. The cuts show front, rear, and side views of the rectifier, illustrating the arrangement on a panel, of the rectifier tube with its connection and operating devices.

The theory is as follows: In an exhaust tube having one or more mercury electrodes, ionized vapor is supplied by the negative electrode or cathode, when the latter is in a state of "excitation." This condition of excitation can be kept up only as long as there is current flowing toward the negative electrode.

If the direction of the voltage be reversed, so that the formerly negative electrode is now positive, the current ceases to flow, since in order to flow in the opposite direction it would require the formation of a new negative electrode, which can be accomplished only by special means. Therefore, the current is always flowing toward one electrode—the cathode, which is kept excited by the current itself. Such a tube would cease to operate on alternating current voltage after half a cycle if some means were not provided to maintain a flow of current continuously towards the negative electrode.


Fig. 1,135.—Elementary diagram of mercury arc rectifier connections. A, A´, graphite anodes; B, mercury cathode; C, small starting electrode; D, battery connection; E, and F reactance coils; G and H, transformer terminals; J, battery.

Ques. Describe the construction and operation of a mercury arc rectifier.

Ans. Fig. 1,135 is an elementary diagram of connections. The rectifier tube in an exhausted glass vessel in which are two graphite anodes A, A´, and one mercury cathode B. The small starting electrode C is connected to one side of the alternating circuit, through resistance; and by rocking the tube a slight arc is formed, which starts the operation of the rectifier tube. At the instant the terminal H of the supply transformer is positive, the anode A is then positive, and the arc is free to flow between A and B. Following the direction of the arrow still further, the current passes through the battery J, through one-half of the main reactance coil E, and back to the negative terminal G of the transformer. When the impressed voltage falls below a value sufficient to maintain the arc against the reverse voltage of the arc and load, the reactance E, which heretofore has been charging, now discharges, the discharge current being in the same direction as formerly. This serves to maintain the arc in the rectifier tube until the voltage of the supply has passed through zero, reversed, and built up such a value as to cause the anode A to have a sufficiently positive value to start the arc between it and the cathode B. The discharge circuit of the reactance coil E is now through the arc A'B instead of through its former circuit. Consequently the arc A'B is now supplied with current, partly from the transformer, and partly from the reactance coil E. The new circuit from the transformer is indicated by the arrows enclosed in circles.

Ques. How is a mercury arc rectifier started?

Ans. A rectifier outfit with its starting devices, etc., is shown in figs. 1,132 to 1,134. To start the rectifier, close in order named line switch and circuit breaker; hold the starting switch in opposite position from normal; rock the tube gently by rectifier shaker. When the tube starts, as shown by greenish blue light, release starting switch and see that it goes back to normal position. Adjust the charging current by means of fine regulation switch on the left; or, if not sufficient, by one button of coarse regulation switch on the right. The regulating switch may have to be adjusted occasionally during charge, if it be desired to maintain the charging current approximately constant.

Capacity.—The unit of capacity of a storage cell is the ampere hour, that is, the ability to discharge one ampere continuously for one hour. For instance, a 100 ampere hour battery will give a continuous discharge of 12½ amperes for eight hours. It should theoretically give a discharge of 25 amperes continuously for four hours, or 50 amperes for two hours, but in reality, the ampere hour capacity decreases with an increase of discharge rate.

It requires, theoretically .135 ounces of metallic lead on either element reduced to sponge lead or to lead peroxide to produce one ampere hour; in practice, from four to six times this amount is required.

The reason for this is because it is impossible to reduce all the active material, to bring every particle in contact with the electrolyte, or to cause every part to be penetrated by the current.

Experiments show that from .5 to .8 ounces of sponge lead, and from .53 to .86 ounces of metallic lead converted into peroxide, are required on their respective elements to produce a discharge of one ampere hour at ordinary commercial rates.

The capacity increases with the temperature, being about one per cent. for each degree Fahr. increase in temperature.

Battery capacity depends on the size and number of plates; the quantity of active material present, and the quantity of electrolyte.

For an eight hour rate of discharge and 60 degrees temperature, the capacity of American batteries varies from 40 to 60 ampere hours per square foot of positive plate surface ( = 2 × number of positive plates in parallel × length × breadth).

The following table gives the variation of capacity for different rates of discharge:

Capacity Variation for Different Discharge Rates
Discharge rate Per cent of capacity
at 8 hour rate
Plante Faure
8 hour 100% 100%
6 hour 96% 96%
4 hour 80% 88%
2 hour 61% 70%
1 hour 56% 48%

Fig. 1,136.—"Exide" connector puller for removing connectors.

Ques. How may the capacity of a battery be increased?

Ans. By mixing organic materials with the lead oxide, but any such mixture is always accompanied by a rapid deterioration of the plates.

Discharging.—In discharging a battery its voltage should never be allowed to fall below 1.8 volts, under load, thus leaving about 30 per cent. of the total capacity unused. The normal discharging current may be equal to the normal charging current, but a discharge equal to 3 or 4 times the normal may be given without injury to the plates. Some types may be discharged at even six or seven times the normal rate. In such cases, however, the capacity will be reduced in the same proportion, as before explained in the paragraph dealing with battery capacities.


Figs. 1,137 to 1,151.—Parts of the Witherbee battery. 1, jar; 2, inside cover; 3, cover; 4, handle; 5, vent cap; 6, cover, screws, nuts and washers; 7, handle eyes, nuts and washers; 8, rubber covered nut; 9, spannernut; 10, plate strap for positive plates; 11, plate strap for negative plates; 12, rubber separator; 13, wood separator; 14, positive group of plates; 15, negative group of plates; 16, positive plate; 17, negative plate; 18, cell connector. An element consists of a complete set of plates bound together on strap, with wood and rubber separators for a single cell. Positive plates are brown, negative plates, gray.

Ques. What is the effect of discharging too rapidly?

Ans. It tends to break the plates, and in the case of pasted plates, a very sudden discharge will dislodge the paste.

Ques. How is the discharge capacity of a storage battery stated?

Ans. In ampere hours. This, unless otherwise specified, refers to its output of current at the eight hour rate. Most manufacturers of automobile batteries specify only the amperage of the discharge at three and four hours. Thus, at the eight hour rate, a cell which will discharge at ten amperes for eight hours is said to have a capacity of eighty ampere hours. It does not follow that eighty amperes would be secured if the cell were discharged in one hour. It is safe to say that not more than forty amperes would be the result with this rapid discharge.

As a general rule, the one hour discharge rate is four times that of the normal, or eight hour discharge, and considerations of economy and prudence suggest that it should never be exceeded, if, indeed, it ever be employed. The three hour discharge, which is normally twice that of the eight hour, is usually the highest that is prudent, while the four hour discharge is the one most often employed in vehicles for the average high speed riding.

Ques. What should be the maximum rate of discharge?

Ans. The one-hour rate; this when used, should not extend over fifteen or twenty minutes. In the case of regulating batteries a forty-five minute rate of discharge may be allowed for one or two minutes during great fluctuations of load.

Ques. How does the capacity decrease?

Ans. It decreases with the increase in current output.

An 80 ampere hour cell, capable of delivering 10 amperes for 8 hours, would, when discharged at 14 amperes, have a capacity of 70 ampere hours; when discharged at 20, its capacity would be 60; and when discharged at 40, its capacity will have decreased from 80 to 40 ampere hours.


Fig. 1,152.—The Edison alternating current rectifier. It consists of an electro-mechanically operated valve which allows current waves of only one polarity to pass through it from the alternating current circuit to the battery which is to be charged. An indicating snap switch of the usual form controls the starting and stopping of the charging current. The rectifier gives any desired charging rate within its capacity. The illustration shows the rectifier connected up and charging an ignition battery of five Edison cells. The connections consist of the usual connecting cord and plug and a charging lead running from the plus side of the charging terminals on the rectifier to the plus pole of the battery, and another lead connecting the negative terminals as shown. In turning the snap switch to the "on" position, the proper charging current will flow into the battery. When charging is completed, the switch is turned to the "off" position and the battery leads disconnected.

Ques. What, in general, are the indications of the quantity of electricity remaining within a cell?

Ans. The voltage, and the density of the electrolyte.

Ques. What should be done after discharging?

Ans. Whenever possible the battery should be immediately charged.

The Battery Room.—Precautions should be taken to prevent any direct sunlight falling on the battery cells in glass jars, as the breakage of such jars due to unequal expansion of the different portions of the glass, is a source of constant trouble and danger.


Fig. 1,153.—Permanent connections for Edison rectifier. As shown, the rectifier is connected to a small switch and cutout.

The exclusion of direct sunlight also tends to keep the evaporation of the electrolyte at a minimum.


Fig. 1,154.—Edison Alternating Current rectifier; view with cover open showing parts. B, primary circuit cord; C, condenser; E, primary relay; F, secondary switch; S, alternating circuit switch; T, transformer.


Fig. 1,155.—Vibrating unit of Edison alternating current rectifier. M, permanent magnet; N, carbon vibrating contact; O, comb radiator; P, primary circuit coil; Q, vibrator adjustment screw.


Fig. 1,156.—Elementary diagram of connections.

Operation of Edison Rectifier

The operation of the Edison rectifier may be explained as follows with the aid of figs. 1,154 to 1,156 (the parts being uniformly lettered in the figures): The primary circuit taken from the alternating current mains by the cord B, embraces the primary winding of the transformer T, a condenser C, and the coils P, of the vibrating units, fig. 1,155.

The secondary circuit from the transformer embraces the massive carbon and copper contacts (N and O, fig. 1,156) which pass only the positive waves of the alternating current, for charging batteries or other duty.

An ammeter and rheostat may be placed in this charging circuit if the current is to be varied, or a fixed connection may be substituted on the base of the rectifier if it is to be used for the maximum duty of 8 or 16 amperes.

The vibrating unit (fig. 1,155), which operates in a manner similar to the well known action of a polarized relay, includes a permanent magnet M; the coil in the primary circuit P; the vibrating armature of steel with removable carbon contact N; the stationary copper contact with comb top for heat radiation O, and the screw Q for adjusting the amplitude of the armature vibration.

The vibrating armature of each unit is divided into two parts, which gives flexibility, affords increased current capacity and minimizes sparking, the two leads shown being connected together in one circuit.

A primary relay and a secondary switch (E and F, figs. 1,154 and 1,156), close their contacts when current is flowing.

Upon failure of the main alternating current line they operate to open the charging circuit. A storage battery is thus prevented discharging through the rectifier.

Upon resumption of the main alternating current, the rectifier starts automatically.

Every battery room should be provided with a water tap and sink. The floor should be paved with vitrified brick, preferably blue or yellow in color, of diamond pattern and sloping in all directions toward suitable drains. A floor of this type can be easily washed by flooding with water, and its patterns tend to keep it dry under foot at all times. Wooden floors are rotted very quickly by acid spillings and by the spray.

The room should be kept absolutely clear of everything, which may be injured, by the sulphuric acid fumes and it should be well ventilated to insure the safety and good health of the attendants.

A battery, even at rest, gives off hydrogen which when diluted with air forms a mixture which is very liable to explode if brought in contact with any kind of flame. Unless proper ventilation be provided, the breaking of the connection when a current is flowing, or the lighting of a bare flame lamp in the battery room would be dangerous.

Battery Attendants and Workmen.—Those employed in setting up batteries are liable to suffer from soreness of hands and the destruction of clothing unless proper precautions be taken to prevent the same. In order to avoid these troubles, the boots should be painted with paraffine mixed with an equal quantity of beeswax.

The clothing should be of woolen material, which, unlike cotton, is practically unaffected by the acid. If cotton shirts be worn, they should be dipped in a strong solution of washing soda and then rough dried.

An apron of sacking, backed with flannel should be worn over all the other clothes. A bottle of strong ammonia should be kept in the battery room at all times, and in case of an accidental splash of acid on the clothes, the immediate application of a small quantity of the ammonia, by means of the stopper, will at once neutralize the acid and prevent it burning a hole in the material. A pail containing water made strongly alkaline with washing soda should also be kept conveniently at hand during all operations in the battery room. The hands should be dipped occasionally in this water in order to prevent the skin smarting and becoming sore under the action of the acid.


Fig. 1,157.—Interior of storage battery room showing arrangement of cells. A, are the cell insulators; B, wooden stringers; C, supporting pieces.

If a splash of acid should happen to enter the eye, it should be washed at once with clean water, warm water preferably, and then put one or two drops of olive oil into the eye. If olive oil be not immediately available, any kind of engine oil is better than none at all.

Points on Care and Management.—In setting up storage cells, they should be placed in as few tiers as possible, and in such a manner that the direct rays of the sun are not allowed to fall upon the cells. The rays of the sun are likely to crack the glass. This is probably due to the unequal expansion of the glass, for it has been found that jars which are carefully annealed never crack in this manner. Of course, the latter precaution does not apply to large batteries, where lead lined wooden tanks or solid lead boxes are used.

In installing plants where expert attendance is not to be had, it is well to place in the circuit two magnetic cut outs, one set for maximum current, and the other for minimum voltage, so that the battery cannot be discharged too low.

Ques. How should the cells be placed?

Ans. They should be placed as shown in fig. 1,151, on insulators A, resting on wooden stringers B, and supporting pieces C placed on the floor. The insulators are usually of glass or porcelain, which in certain patterns may be filled with oil, to insure better insulation as shown in figs. 1,165 and 1,166.

In setting up a battery, it should be remembered that plates deteriorate on standing exposed to the air. They should, therefore, be unpacked and set up immediately on arrival. When they are entirely connected up, they are ready for the addition of the electrolyte, and for the forming charge, which they should receive immediately.

Ques. How should the wooden stringers, shelves, cell boards, and trays be treated?

Ans. They should be thoroughly varnished to insure cleanliness as well as good insulation.

Outside of each cell and close to the mouth, melted paraffine should be applied by means of a brush, so as to form a band about an inch wide, for the purpose of preventing the electrolyte creeping over the top of the jar, wetting the outside, and thereby impairing the insulation.

Ques. What should be done to avoid waste of current by leakage?

Ans. Each cell of the battery must be thoroughly insulated.

Ques. What is the effect of verdigris which forms on the terminals?

Ans. It is a poor conductor and should therefore be removed and the terminals kept bright and clean to insure the proper flow of the current.


Fig. 1,158.—Charging "Champion" battery with charging plug. Where direct lighting current is available, recharging may be done by means of the charging plug. First insert the plug in a regular socket. Then screw a 50 c.p. lamp into the plug and turn on. To tell the positive from the negative, lay both wires on a small piece of red litmus or test paper moistened. The negative wire makes a mark on the paper. This wire must go to the negative post of battery. This will fully charge the "6-25-G" battery in 15 to 20 hours.

Ques. What precautions should be taken in unpacking cells?

Ans. The plates should be handled carefully. When they are sent out from the factory already built into sections, they should be unpacked without disturbing a single plate. In all cases, every particle of packing, straw, hay and any chips and bits of parts should be carefully removed, and all the dust should be blown out of the spaces between the plates by means of a bellows or other similar device.

NOTE.—Champion directions for repairs. To replace broken jars in a battery remove the lid and lift out elements bodily. Empty the good jars with a syringe or by tilting the battery over. Never put the acid in any vessel except glass, stone or lead. Put new jars in place same as others and run melted paraffine around the edges. The wax must be broken off the elements that are to go into new jars and be poured on again. Fill the jars with acid to ¾" from tops. Melt the broken wax in a tin ladle and pour over the acid about ½" thick. Do not fill with wax to tops of jars. When the wax gets cold it will be found to have shrunk away from the edges of the jars. Fill up the opening with a little melted paraffine wax by means of a squirt can. Cut a small hole in the middle of the wax seal for a vent. Smear the brass posts and terminals and inside of case with vaseline to prevent creeping of the acid. The "6-25-G" requires one-half gallon of acid and the "6-50-G" one gallon.

Although such particles are good non-conductors, the action of the sulphuric acid electrolyte carbonizes them, giving them conducting properties which tend to produce leakage.


Figs. 1,159 to 1,161.—"Champion" electric light equipment designed especially for use on launches, yachts, and country residences. The outfit consists of three essential parts: 1, a dynamo run by belt from main engine; 2, a storage battery, and 3, a switchboard to regulate, measure and control the current.

Ques. How should the cells be assembled?

Ans. In placing the plates or plate sections in the containing jars or tanks, care should be taken to see that the supporting frame of paraffined wood bears evenly on the bottom of the jar. If they do not, wedges of paraffined wood should be placed under the frame, so as to distribute the weight of the section equally. Each section should be lowered gently into the jar until it rests fairly upon the frame, and care should be taken to see that none of the plates have shifted, and that the section is situated centrally in the jar, with a small clear space all around.

Ques. How should the cells be arranged?

Ans. They should be so placed that the battery attendant can see the edges of the plates and consequently the spaces between them at the same time.

Ques. Describe the method of connecting the cells.

Ans. This is accomplished by means of solder, bolts and nuts, or clamps, according to circumstances. The use of solder is not essential if there be a good surface of the lead strip of one cell in contact with that of the next, and provided these contact surfaces have been well cleaned. Usually, the ends of the lead strips are turned up so that the junction of two cells takes the form of an inverted T as shown in fig. 1,162.


Fig. 1,162.—Two storage cells; view showing the inverted T form of connection.

Ques. What precaution should be taken in joining the terminals of the cells?

Ans. The contact at the junctions should be very thorough, otherwise they will become heated when a current is flowing, and it is desirable that the connections should include as little lead strip in the circuit as possible, thereby reducing the amount of useless resistance.

Brass or gun metal clamps may be kept clean by brushing them over with melted paraffin after they have been screwed up tightly. When thus treated they serve to indicate points of bad contact by heat, generated at such points, when the current is flowing, softening the paraffin and changing its normal color. Vaseline and different kinds of anti-sulphuric acid varnishes, or preparations that are not attacked by the electrolyte, may also be used for this purpose. It is a good plan to color the varnish with vermillion or lamp black and paint the positive connections red and the negative connections black, and also other parts of the installation for distinguishing the polarities.

Cell Connections.—The cells may be connected together either in series or parallel, or in parallel-series or series-parallel combinations, according to the requirements, but in all cases it is best to use the simplest arrangement practicable.

For instance: if the cells employed in an installation requiring 110 volts, have only half the capacity required, and 55 cells give the desired voltage, then the number of cells must be increased to 110, and theoretically the required number of amperes hours at 110 volts may be obtained in one of two ways: 1, by connecting the cells in pairs in parallel and then coupling the pairs together in series, and 2, by arranging the 110 cells in two complete batteries of 55 cells each connected in series, then coupling the two batteries in parallel.

The first method is quite impracticable, however, as the slightest difference between the voltages of the two cells of any pair will result in the one having the greater pressure discharging into the other, thereby causing the entire battery to quickly deteriorate.

NOTE.—To determine the positive wire. Without a voltmeter, the positive terminal of the charging circuit can be determined by attaching a piece of clean lead to each wire which is to be connected to the battery, and immersing them, without touching each other, in a glass or other insulating vessel containing water to which is added a drop or two of sulphuric acid. After the current has passed through the circuit for a short time, the positive lead will commence to discolor, and, if left long enough, will turn brown. Bubbles will arise from the two terminals immersed, the larger and more frequent ones being from the negative, the smaller ones from the positive.

NOTE.—Method of disconnecting "National" cells. There are two methods of disconnecting the cells employing link connectors. First a ? inch bit or twist drill may be used, boring down into the top of the posts about ¼ inch. The link will then be loosened and can be removed. This leaves the link, as well as the post, in good condition for reburning. Second the link may be cut in the center. A flame should be played on the top of the post, at the same time grasping the end of the half link firmly with pliers. When the connection has become warmed (care being taken not to melt the lead) the half link can be twisted loose from the port. New links may be used if desired in re-assembling the cells. It is not necessary to remove the covers from the element, the links may be cut in the center and the plates removed from the jars without removing the links from the ports. The links can be afterwards reburned together in the center. When the cells are equipped with "T" or "L" straps, they should be cut apart with hack saw or chisel midway between the cells, and in re-assembling, burned together at this point.

Battery Troubles.—To successfully cope with faults in storage batteries, there are two requisites: 1, a thorough knowledge of the construction and principle of operation of the battery, and 2, a well ordered procedure in looking for the source of trouble. The faults which are usually encountered by those who operate storage batteries are here given.


Fig. 1,163.—Arrangement of battery cells and stand. A, cable lugs; B, bus bars; C, glass tanks; D, plate; E, glass insulators; Q, vitrified brick; O, lead washers. Battery cells are set up on stands; the one shown being built for a 100 ampere battery. Larger sizes would, of course, require heavier stands, and if space be limited, the cells may be set in rows, one above the other. However, it is evidently much better to place the cells in single rows, where they will be convenient for inspection and repairs or any work that has to be done on them. There are several other ways of setting a battery, one of which is to place the stringers on the floor, on vitrified brick or some other insulator, and then place trays filled with sand on the stringers, setting the cells in the trays on glass insulators. The battery room should be dry, clean, well ventilated and free from metal work, also neither too hot nor too cold. Too high a temperature in the battery will shorten the life of the plates, and although there is no danger of the battery freezing, a low temperature, while it is maintained, reduces the capacity; otherwise cold has no ill effect on the battery. A good temperature for the battery room is about 60° F. A damp, dirty room is conductive to grounds and surface leakage, and there is danger of impurities getting into the cells. If the room be very damp the electrolyte may absorb enough moisture to cause the cells to overflow. Strong floors are necessary to support a battery, as one of a 100 ampere, 125 volt capacity weighs from 12 to 13 tons. A wood floor may be used, but a cement floor is better, and a glazed vitrified brick floor is better still. Wooden floors will rot quickly from the acid, which is sure to get onto it more or less; a cement floor will be disintegrated if too much acid get onto it. This kind of floor forms a first class ground if there be any chance for one; the glazed brick floor is not affected by the acid and is an insulator.

Short Circuiting.—A form of derangement that may occasionally affect storage batteries is short circuiting. It may be caused by some of the active material—if the cell be of the pasted variety—scaling off and dropping between the plates, or by an over collection of sediment in the bottom of the cell.

Should the operator suspect trouble with his battery he may discover a short circuited cell by the marked difference in color of the plates or of the specific gravity of the electrolyte, as compared with the other cells. No particular damage will be caused, if the trouble be discovered and removed before these symptoms become too marked.

If a foreign substance has become lodged between the plates, it may be removed by a wood or glass instrument.

If some of the active material has scaled off, it may be forced down to the bottom of the jar. If excessive sediment be found, the jar and plates should be washed carefully, and reassembled.

A cell that has been short circuited may be disconnected from the battery and charged and discharged several times separately which may remedy the trouble.

Ques. How are internal short circuits indicated?

Ans. Short circuits in a cell are indicated by short capacity, low voltage and low specific gravity, excessive heating and evaporation of the electrolyte.

Ques. How are internal short circuits located?

Ans. If the trouble cannot be located by the eye, the battery should be connected in series and discharged at the normal rate through suitable resistance. If a suitable rheostat be not available, a water resistance may be used.

This consists of a receptacle (which must not be of metal) filled with very weak acid solution, or with salt water in which are suspended two metal plates, which are connected by wires through an ammeter. The current may be regulated by altering the distance between the plates, or by varying the strength of the solution. As the discharge progresses the voltage will gradually decrease, and it should be frequently read at the battery terminals; as soon as it shows a sudden drop, the voltage of each cell should be read with a low reading voltmeter.

While the readings are being taken, the discharge rate should be kept constant and the discharge continued until the majority of the cells read 1.70 volts; those reading less should be noted. The discharge should be followed by a charge until the cells which read 1.70 volts are up, then the low cells should be cut out, examined, and the trouble remedied.

Overdischarge: Buckling.—On account of unequal expansion of the two sides of a plate, or certain portions thereof, the strains thus set up may distort it and cause it to assume a buckled shape, that is, bent so one side is concave.


Fig. 1,164.—Method of straightening a buckled plate. Buckling is caused by the unequal expansion of the plates which is due to the sulphate lodging on the plates, thus preventing action taking place at that point; and by excessive charging. If the plates be not badly buckled, they can be placed between 2 boards and with a little pressure, can be straightened out.

Buckling is due always to over discharge on either the whole, or some portion of the plate. Occasional buckling may occur with too rapid charge and discharge.

Sulphation of Plates.—During discharge a storage cell deteriorates on account of the formation of lead sulphate over the surface of the plates. This lead sulphate is the product of the chemical combination of active material with the electrolyte. It is a non-conductor, white in color and of greater volume, in proportion than the active material. When the discharge is over prolonged, sulphation is evidenced by the electrodes becoming lighter in color, because of the sulphate which lessens the active surface.


Figs. 1,165 and 1,166.—Oil Insulator; fig. 1,165, general view; fig. 1,166, sectional view. Whenever a number of open cells are in use, unless precautions be taken, electrical leakage between the cells invariably occurs. This leakage is due chiefly to the semi-conducting nature of the thin layer of moisture which frequently covers not only the glass containing cells, but the unimmersed parts of the elements, and even the shelves on which the cells rest. To prevent this waste of energy, the outside of the cells should occasionally be well cleaned and thoroughly dried. A little vaseline or tallow may then be rubbed over them to advantage. The shelves or supports for the cells, should either be well varnished or coated with paraffin wax. Electrical leakage is greatly reduced if each cell be mounted on a glass or earthenware insulator, as shown in the illustrations. The insulator here shown is in two parts and of a mushroom shape. The lower cup contains a small quantity of some non-evaporating oil, and as the conducted moisture cannot bridge across this, a nearly perfect insulating medium is obtained. These insulators are made in various sizes and may be obtained in earthenware or glass. Those made of glass are found to give the best results.

Ques. Name some causes of sulphation.

Ans. It is sometimes caused by a too weak or too strong acid solution, but more generally by continued over discharging, or too rapid discharging of the batteries, or by allowing them to remain uncharged for long periods of time.

Ques. What is the effect of sulphation?

Ans. It tends to cause shedding of the active material, buckling of plates, loss of capacity, increase of resistance and consequent reduction of efficiency, and increase of temperature with flow of current. A sufficient amount of lead peroxide and sponge lead must be retained on the plates to reduce this resistance, otherwise the charging current cannot flow through the active material and regenerate the battery.


Fig. 1,167.—Illustrating method of placing plates in glass jars.

Ques. What should be done in case of sulphation?

Ans. Charge the battery below the maximum rate, necessarily prolonging the charge, until the plates assume the proper color. This is a tedious task, but it must not be hastened, as rapid charging will cause serious buckling.


NOTE.—How to destroy acid vapor in storage battery rooms: The best remedy is a good system of thorough and rapid ventilation; failing this the evil effect of the acid may be minimized by the fumes of a powerful alkali such as ammonia, which will readily combine with the sulphuric acid to form sulphate of ammonia, an inert and harmless salt. If the use of liquid ammonia be objectionable, the granulated carbonate of ammonia will do equally well. The ammonia fumes are best obtained by placing dilute ammonia in shallow dishes, so that an extensive evaporating surface is obtained. In the same way the corroding dew which is so frequently deposited on the lugs and connectors of storage battery elements may readily be neutralized by the application of a solution of ammonia, or even common washing soda. A good method of protecting metal work in battery rooms is to smear it over evenly with vaseline.

The charging should be done at low rates. Discharge should not be carried below 1.8 volts per cell, and the charging current should be stopped when each cell shows 2.4 volts.

If the plates be in a very bad condition, a little of the white sulphate deposit on each of the positive plates may be removed with a stick, thus exposing a part of the good surface to the action of the electrolyte.

If the positive plates cannot be restored to their proper color as directed, it is cheaper to replace them by a new set, rather than to attempt their recovery by means of reversals.

Electrical Data on "National" Cells
(Size of plate 4?" × 8?")
Number of Plates per cell 5 7 9 11
Discharge in amperes {for 4 hours 12 18 24 30
{for 5 hours 10¼ 15¼ 20½ 25½
{for 6 hours 13¾ 18½ 23
Ampere hour capacity {at 4 hour rate 48 72 96 120
{at 5 hour rate 51 76 102 127
{at 6 hour rate 55 83 110 138
Outside measurements of rubber jar, in inches {Length 1? 2? 3? 43/16
{Width 55/16 55/16 55/16 55/16
{Height 11¾ 11¾ 11¾ 11¾
Weight of cell complete, in lbs 14¼ 19¼ 24¼ 29¾
Weight of electrolyte, in lbs 1 2 5

Lack of Capacity.—This is usually due to the clogging of the pores in the plate with sulphate which is invisible because the surface of the plate is maintained in proper condition but the interior portions of the active material have not been thoroughly reduced. To correct this condition, the battery should be given a prolonged overcharge at low current rates, say about one fourth the normal 8 hour charging rate.

NOTE.—Oxide of lead, litharge, or plumbic oxide is sometimes found native as lead ochre, and may be artificially made by heating the carbonate or nitrate. It is usually prepared on a larger scale by heating the lead in air. When the metal is only moderately heated, the oxide forms a yellow powder which is known as massicot, but at a higher temperature the oxide melts, and on cooling, it forms a brownish scaly mass, which is called flake litharge. The scaly pieces are afterwards ground between stones under water, forming buff or levegated litharge. The litharge of commerce often has a reddish yellow color, due to the presence of some of the red oxide of lead, and frequently from one to three per cent. of finely divided metallic lead is found mixed with it. When heated to dull redness litharge assumes a dark brown color, and becomes yellow again on cooling. At a bright red heat it fuses and readily attacks clay crucibles, forming silicate of lead. Litharge is a most powerful base, and has a strong tendency to form basic salts. Hot solution of alkalies, as potash or soda, readily dissolve it, and on cooling, it crystalizes out in the form of beautiful pink crystals.

Falling off in the capacity may be caused by a dry cell, due to a leaking jar; some or all of the cells may be in a state of incomplete charge, due to the battery having been run too low and not sufficiently charged; or the plates may be short circuited, either by the sediment (deposit in the bottom of the jar) getting up to the bottom of the plates or by something that has fallen into the cell.


Electrical Data on "American" Cells
Normal
Capacity
Number of 30 volt Tungsten lamps that can be run with 16 cells in series for 2, 4, 6 or 8 hours
Ampere
hours
2 hours 4 hours 6 hours 8 hours
40 14 9 8 7
60 17 14 12 10
80 28 18 15 14
120 42 27 24 21
160 57 37 31 28
20 71 45 40 35
250 88 56 50 44
300 106 70 60 52
350 124 81 71 62
400 142 91 81 71

Fig. 1,168.—"American" cell.

Ques. What action takes place when a battery stands idle for some time?

Ans. It loses part of its charge, due to local losses in the cells.

Ques. How should batteries be treated, when used but occasionally?

Ans. If a battery is not to be used for several days, it should first be fully charged before standing; if it continue idle, a freshening charge should be given every two weeks, continuing the charge when the cells begin to gas freely.

Ques. What should be done in case of lack of capacity?

Ans. If the current consumption be normal, there may be poor connections or trouble in the battery; there may be a dry cell, due to a leaking jar; some or all of the cells may be in a state of incomplete charge, due to the battery having been run too low and not sufficiently charged, or the plates may be short circuited, either by the sediment (deposit in the bottom of the jar) getting up to the bottom of the plates or by something that has fallen into the cell.

Electrical Data on "Autex" Cells
(Standard plates; size, 5¾" x 8?")
Number of Plates 7 9 11 13 15 17 19 21
Discharge in Amperes for 4 hours 21 28 35 42 49 56 63 70
Outside Measurements
Rubber Jars in inches.
{Length 5 8
{Width 6? 6? 6? 6? 6? 6? 6? 6?
{Height 12? 12? 12? 12? 12? 12? 12? 12?
Weight in Pounds {Element 15¾ 20¼ 24¼ 29¾ 34 38½ 43 47½
{Electrolyte 5 7
{Complete Cell 22 28 34¼ 40½ 47 53¼ 59½ 66

NOTE.—Peroxide of lead, pure oxide or plumbic dioxide is the true active material in all forms of lead storage cell. This lead salt is found native as the mineral plattnerite. It is a heavy lead ore, forming black, lustrous, six sided prisms. It may be prepared from the red oxide by boiling it in fine powder, with nitric acid diluted with five parts of water, or by treating the carbonate when suspended in water with a stream of chlorine gas, and then thoroughly washing and drying it. It is reduced to a lower oxide on heating or by exposure to bright sunlight. This salt readily imparts oxygen to other substances; it becomes heated to redness when thrown into sulphuric dioxide, and takes fire when triturated with sulphur—hence this oxide is a common ingredient in lucifer match composition. When used in primary or secondary batteries it readily imparts its oxygen to nascent hydrogen, forming water, and thus it acts as a powerful depolarizer. When robbed of its oxygen, it readily becomes reoxidized, if subjected to the action of nascent oxygen liberated by the electrolytic decomposition of water.

If the trouble cannot be located by the eye, connect the battery in series, and discharge it at the normal rate, through suitable resistance. If a suitable rheostat be not available, a water resistance may be used.

This consists of a receptacle (which must not be of metal) filled with very weak acid solution or salt water in which are suspended two metal plates, which are connected, by wires through an ammeter.

Electrical Data on "Autex" Cells
(Light weight plates; size, 5¾" × 8?")
Number of Plates 7 9 11 13 15 17 19 21 23 25
Discharge in Amperes for 5 hours 15¾ 21 26¼ 31½ 36¾ 42 47¼ 52½ 57¾ 63
Outside Measurements Rubber Jars in in. {Length 129/32 27/16 331/32 41/32 49/16 53/32 5? 65/32 611/16
{Width 6? 6? 6? 6? 6? 6? 6? 6? 6? 6?
{Height 12? 12? 12? 12? 12? 12? 12? 12? 12? 12?
Weight in Pounds {Element 11½ 14¾ 18 21¼ 24½ 27¾ 31 34¼ 37¼ 40½
{Electrolyte 3 6
{Comp. Cell 15¾ 20 24¼ 28½ 33¼ 38 42 46¼ 51½ 56

The current may be regulated by altering the distance between the plates or by varying the strength of the solution. As the discharge progresses, the voltage will gradually decrease and it should be frequently read at the battery terminals. When it shows a sudden drop, the voltage of each cell should be read with a low reading voltmeter.

While the readings are being taken, the discharge rate should be kept constant and the discharge continued until the majority of the cells read 1.70 volts; those reading less should be noted. The discharge should be followed by a charge until the cells which read 1.70 volts are up; then the low cells should be cut out, examined and the trouble remedied.

NOTE.—How to prevent lead poisoning. Workmen employed in the manufacture of lead or lead salts are always liable to lead poisoning, both by inhaling the dust and by contact of the materials with the hands. Various preventives for this have been employed, and of these, the most simple seems to be a careful washing of the hands in petroleum. It is said that three washings a day are sufficient to prevent all serious danger of poisoning. The benzole in the petroleum appears to scour the skin and remove the loose lead dust, and the fatty substance in the oil fills up the pores of the skin and prevents the absorption of the deleterious salts. The employment of petroleum has given such good results that it has been proposed to use this material as a guard against poisoning in other industries where the salts of copper or mercury are employed.

Ques. What causes low specific gravity when there are no short circuits?

Ans. 1, sloppage or a leaky jar (the loss having been replaced with water alone), 2, insufficient charge, 3, over discharge, or 4, a combination of these abuses. Any of these mean that there is acid in combination with the plates.

In this case the acid should be brought out into the electrolyte by a long charge at a quarter of the normal discharge rate.


Figs. 1,169 and 1,170.—The "National" storage battery; views showing methods of assembling cells. Fig 1,169, end assembling; fig 1,170, side assembling.

Ques. How should weak cells be treated?

Ans. They should be grouped by themselves and charged as a separate battery, care being taken that the positive strap of one cell, is connected to the negative strap of the adjoining cell and that the charging connections are properly made. If there be not sufficient resistance in the charging rheostat to reduce the current to the proper point, a water resistance should be used.

NOTE.—Pole testing paper. Make a thin solution of white starch and soak strips of thin white blotting paper in it, and set aside in a clean, dry place to dry. Dissolve ½ oz. of potassium iodide in one pint of water. Immerse the strips in the solution for a few seconds and again dry. This paper, when moistened and used in the usual way, turns violet at the positive pole.

While a cell is being treated, when possible, the cover should be removed (if sealed, the compound can be loosened by using a hot putty knife).


Figs. 1,171 to 1,177.—"National" battery bolt connector and parts. The connector is equipped with grease cups and antimonious lead washers.

Disconnecting Cells.—The best method of disconnecting cells assembled with pillar straps, for the purpose of replacing broken jars, cleaning or taking out of commission, is to use a five-eighth inch twist drill, in a carpenter's brace, boring down into the top of the pillar about one-quarter inch; then pull off the connector sleeve from the pillar. By following this method, all parts may be used again.

When cells are equipped with top straps, the straps should be cut with a sharp knife or chisel midway between the cells.

Taking Batteries out of Commission.—Where a battery is to be out of service for several months, and it is not convenient to give it the freshening charge every two weeks, it should be taken out of commission.

COMPARISON OF THE BAUMÉ AND SPECIFIC GRAVITY
SCALES AT 60° FAHRENHEIT
Degrees
Baume
Specific
Gravity
Degrees
Baume
Specific
Gravity
Degrees
Baume
Specific
Gravity
Degrees
Baume
Specific
Gravity
0 1.000 17 1.133 34 1.306 51 1.542
1 1.007 18 1.142 35 1.318 52 1.559
2 1.014 19 1.151 36 1.330 53 1.576
3 1.021 20 1.160 37 1.342 54 1.593
4 1.028 21 1.169 38 1.355 55 1.611
5 1.036 22 1.179 39 1.368 56 1.629
6 1.043 23 1.188 40 1.381 57 1.648
7 1.051 24 1.198 41 1.394 58 1.666
8 1.058 25 1.208 42 1.408 59 1.686
9 1.066 26 1.218 43 1.421 60 1.707
10 1.074 27 1.229 44 1.436 61 1.726
11 1.082 28 1.239 45 1.450 62 1.747
12 1.090 29 1.250 46 1.465 63 1.768
13 1.098 30 1.261 47 1.479 64 1.790
14 1.107 31 1.272 48 1.495 65 1.812
15 1.115 32 1.283 49 1.510 66 1.835
16 1.124 33 1.295 50 1.526

NOTE.—The characteristic properties of concentrated sulphuric acid are very marked. Its freedom from odor, oily appearance, and its great weight, distinguish it from other liquids. The pure concentrated commercial acid has a density which usually reaches 1.842, and its boiling point is about 640° F. The absolutely pure acid is perfectly colorless, but usually even that used in laboratories has a peculiar grayish color, due to slight traces of organic matter. Sulphuric acid is exceedingly hydroscopic, and when exposed to the air it rapidly increases in bulk, owing to absorption of atmospheric moisture.

NOTE.—Clamps not made of metal similar to that of the connecting strips, frequently give trouble from the galvanic action due to the contact of dissimilar metals in the presence of moisture which causes the destruction of either the connecting strip or the clamp. Such troubles can be avoided by placing a thin strip of sheet zinc between the lead strip and the clamp. Under these circumstances the zinc will crumble away, and can be replaced without much inconvenience and very little expense, while the clamps and connecting strips will remain uninjured.

Strength of Dilute Sulphuric Acid
of
Different Densities at 59° Fahr.
Per cent.
of
Sulphuric Acid
Specific
Gravity
Per cent.
of
Sulphuric Acid
Specific
Gravity
100 1.842 23 1.167
40 1.306 22 1.159
31 1.231 21 1.151
30 1.223 20 1.144
29 1.215 19 1.136
28 1.206 18 1.129
27 1.198 17 1.121
26 1.190 16 1.116
25 1.172 15 1.106
24 1.174 14 1.098

Ques. Describe the method of taking a battery out of commission.

Ans. The battery is charged in the usual manner, until the specific gravity of the electrolyte of every cell has stopped rising over a period of one hour (if there be any low cells, due to short circuits or other cause, they should be put in condition before the charge is started, so that they will receive the full benefit of it). The cells may now be disconnected and covers and elements removed from the jars, (if sealed, the compound is loosened with a hot putty knife). The elements are placed on their sides with the plates slightly spread apart at the bottom, the separators withdrawn, and the positive and negative groups pulled apart. The electrolyte is washed off with a gentle stream of water and the plates allowed to drain and dry.7 The positive plates are ready to be put away. When dry, the negatives are completely immersed in electrolyte (of about 1.275 specific gravity), and allowed to soak for three or four hours. The jars may be used for this purpose. After rinsing and drying, they are ready to be put away; wash also the rubber separators.

Wood separators, after having been in service, will not stand much handling and had better be thrown away. If it be thought worth while to keep them, they must be immersed in water or weak electrolyte, and in re-assembling, the electrolyte must be put into the cells immediately, as wet wood separators must not stand exposed to the air.


Fig. 1,178.—The "Witham" charging board, for charging from any electric outlet on a direct current system. The instrument shows the direction of the current, and the candle power of the lamps used as resistance indicates approximately the strength of the current passing. Operation: From any convenient electric light fitting remove one of the lamps, replacing it by the plug attached to the flexible cord. Screw the lamp into one of the sockets on the charging board. Connect a wire to each binding post, and before joining up to the battery, hold the ends of the two wires together. The lamp will then light up and the indicator needle will point to that binding post which must be connected to the positive (+) terminal of the battery. The other binding post must, of course, be connected to the negative (-) of the battery. The charging current can be increased by inserting another lamp into the second socket on the charging board and by using lamps of higher candle power. If, when the lamp lights up, the indicator needle do not point to one of the binding posts, but retain its position midway, then the current is an alternating one and will not charge the battery.

Ques. What precaution should be taken with the jars?

Ans. They should be thoroughly cleaned with fresh water, no sediment being allowed to remain.

Putting Batteries into Commission.—When re-assembling a battery, it should be treated in the same manner as if it were new and the regular instructions for assembling and putting a new battery into commission followed.

Cleaning Jars.—The jars should be thoroughly cleaned with fresh water, no sediment being allowed to remain.

Table of Voltage Change as Affected by Discharge Rate8
8 hour rate .05 volt
6 " " .065 "
4 " " .09 "
3 " " .11 "
2 " " .14 "
" " .18 "
1 " " .21 "

Condensed Rules for the Proper Care of Batteries.—The following general instructions should be followed in the care and maintenance of batteries:

1. A battery must always be charged with "direct" current and in the right direction.

2. Be careful to charge at the proper rates and to give the right amount of charge; do not undercharge or overcharge to an excessive degree.

3. Do not bring a naked flame near the battery while charging or immediately afterwards.

4. Do not overdischarge.

5. Do not allow the battery to stand completely discharged.

6. Voltage readings should be taken only when the battery is charging or discharging; if taken when the battery is standing idle they are of little or no value.

7. Do not allow the battery temperature to exceed 110° Fahr.

8. Keep the electrolyte at the proper height above the top of the plates and at the proper specific gravity. Use only pure water to replace loss by evaporation. In preparing the electrolyte never pour water into the acid.

9. Keep the cells free from dirt and all foreign substances, both solid and liquid.

10. Keep the battery and all connections clean; keep all bolted connections tight.

11. If there be lack of capacity in a battery, due to low cells, do not delay in locating and bringing them back to condition.

12. Do not allow sediment to get up to the plates.


                                                                                                                                                                                                                                                                                                           

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