NOTE XXXIV. VEGETABLE PERSPIRATION.

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And wed the enamoured Oxygene to Light.

CANTO IV. l. 34.

When points or hairs are put into spring-water, as in the experiments of Sir B. Thompson, (Philos. Trans. Vol. LXXVII.) and exposed to the light of the sun, much air, which loosely adhered to the water, rises in bubbles, as explained in note on Fucus, Vol. II. A still greater quantity of air, and of a purer kind, is emitted by Dr. Priestley's green matter, and by vegetable leaves growing in water in the sun-shine, according to Mr. Ingenhouze's experiments; both which I suspect to be owing to a decomposition of the water perspired by the plant, for the edge of a capillary tube of great tenuity may be considered as a circle of points, and as the oxygene, or principle of vital air, may be expanded into a gas by the sun's light; the hydrogene or inflammable air may be detained in the pores of the vegetable.

Hence plants growing in the shade are white, and become green by being exposed to the sun's light; for their natural colour being blue, the addition of hydrogene adds yellow to this blue, and tans them green. I suppose a similar circumstance takes place in animal bodies; their perspirable matter as it escapes in the sun-shine becomes decomposed by the edges of their pores as in vegetables, though in less quantity, as their perspiration is less, and by the hydrogene being retained the skin becomes tanned yellow. In proof of this it must be observed that both vegetable and animal substances become bleached white by the sun-beams when they are dead, as cabbage-stalks, bones, ivory, tallow, bees-wax, linen and cotton cloth; and hence I suppose the copper-coloured natives of sunny countries might become etiolated or blanched by being kept from their infancy in the dark, or removed for a few generations to more northerly climates.

It is probable that on a sunny morning much pure air becomes separated from the dew by means of the points of vegetables on which it adheres, and much inflammable air imbibed by the vegetable, or combined with it; and by the sun's light thus decomposing water the effects of it in bleaching linen seems to depend (as described in Note X.): the water is decomposed by the light at the ends or points of the cotton or thread, and the vital air unites with the phlogistic or colouring matters of the cloth, and produces a new acid, which is either itself colourless or washes out, at the same time the inflammable part of the water escapes. Hence there seems a reason why cotton bleaches so much sooner than linen, viz. because its fibres are three or four times shorter, and therefore protrude so many more points, which seem to facilitate the liberation of the vital air from the inflammable part of the water.

Bee's wax becomes bleached by exposure to the sun and dews in a similar manner as metals become calcined or rusty, viz. by the water on their surface being decomposed; and hence the inflammable material which caused the colour becomes united with vital air forming a new acid, and is washed away.

Oil close stopped in a phial not full, and exposed long to the sun's light, becomes bleached, as I suppose, by the decomposition of the water it contains; the inflammable air rising above the surface, and the vital air uniting with the colouring matter of the oil. For it is remarkable, that by shutting up a phial of bleached oil in a dark drawer, it in a little time becomes coloured again.

The following experiment shews the power of light in separating vital air from another basis, viz. from azote. Mr. Scheel inverted a glass vessel filled with colourless nitrous acid into another glass containing the same acid, and on exposing them to the sun's light, the inverted glass became partly filled with pure air, and the acid at the same time became coloured. Scheel in Crell's Annal. 1786. But if the vessel of colourless nitrous acid be quite full and stopped, so that no space is left for the air produced to expand itself into, no change of colour takes place. Priestley's Exp. VI. p. 344. See Keir's very excellent Chemical Dictionary, p. 99. new edition.

A sun-flower three feet and half high according to the experiment of Dr. Hales, perspired two pints in one day (Vegetable Statics.) which is many times as much in proportion to its surface, as is perspired from the surface and lungs of animal bodies; it follows that the vital air liberated from the surfaces of plants by the sunshine must much exceed the quantity of it absorbed by their respiration, and that hence they improve the air in which they live during the light part of the day, and thus blanched vegetables will sooner become tanned into green by the sun's light, than etiolated animal bodies will become tanned yellow by the same means.

It is hence evident, that the curious discovery of Dr. Priestley, that his green vegetable matter and other aquatic plants gave out vital air when the sun shone upon them, and the leaves of other plants did the same when immersed in water, as observed by Mr. Ingenhouze, refer to the perspiration of vegetables not to their respiration. Because Dr. Priestley observed the pure air to come from both sides of the leaves and even from the stalks of a water-flag, whereas one side of the leaf only serves the office of lungs, and certainly not the stalks. Exper. on Air, Vol. III. And thus in respect to the circumstance in which plants and animals seemed the furtherest removed from each other, I mean in their supposed mode of respiration, by which one was believed to purify the air which the other had injured, they seem to differ only in degree, and the analogy between them remains unbroken.

Plants are said by many writers to grow much faster in the night than in the day; as is particularly observable in seedlings at their rising out of the ground. This probably is a consequence of their sleep rather than of the absence of light; and in this I suppose they also resemble animal bodies.

                                                                                                                                                                                                                                                                                                           

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