Smear'd her huge dragons with metallic hues, With golden purples, and cobaltic blues; CANTO II. l. 287. The fine bright purples or rose colours which we see on china cups are not producible with any other material except gold, manganese indeed gives a purple but of a very different kind. In Europe the application of gold to these purposes appears to be of modern invention. Cassius's discovery of the precipitate of gold by tin, and the use of that precipitate for colouring glass and enamels, are now generally known, but though the precipitate with tin be more successful in producing the ruby glass, or the colourless glass which becomes red by subsequent ignition, the tin probably contributing to prevent the gold from separating, (which it is very liable to do during the fusion; yet, for enamels, the precipitates made by alcaline salts answer equally well, and give a finer red, the colour produced by the tin precipitate being a bluish purple, but with the others a rose red. I am informed that some of our best artists prefer aurum fulminans, mixing it, before it has become dry, with the white composition or enamel flux; when once it is divided by the other matter, it is ground with great safety, and without the least danger of explosion, whether moist or dry. The colour is remarkably improved and brought forth by long grinding, which accordingly makes an essential circumstance in the process. The precipitates of gold, and the colcothar or other red preparations of iron, are called tender colours. The heat must be no greater than is just sufficient to make the enamel run upon the piece, for if greater, the colours will be destroyed or changed to a different kind. When the vitreous matter has just become fluid it seems as if the coloured metallic calx remained barely intermixed with it, like a coloured powder of exquisite tenuity suspended in water: but by stronger fire the calx is dissolved, and metallic colours are altered by solution in glass as well as in acids or alcalies. The Saxon mines have till very lately almost exclusively supplied the rest of Europe with cobalt, or rather with its preparations, zaffre and smalt, for the exportation of the ore itself is there a capital crime. Hungary, Spain, Sweden, and some other parts of the continent, are now said to afford cobalts equal to the Saxon, and specimens have been discovered in our own island, both in Cornwall and in Scotland; but hitherto in no great quantity. Calces of cobalt and of copper differ very materially from those above mentioned in their application for colouring enamels. In those the calx has previously acquired the intended colour, a colour which bears a red heat without injury, and all that remains is to fix it on the piece by a vitreous flux. But the blue colour of cobalt, and the green or bluish green of copper, are produced by vitrification, that is, by solution in the glass, and a strong fire is necessary for their perfection. These calces therefore, when mixed with the enamel flux, are melted in crucibles, once or oftener, and the deep coloured opake glass, thence resulting, is ground into unpalpable powder, and used for enamel. One part of either of these calces is put to ten, sixteen, or twenty parts of the flux, according to the depth of colour required. The heat of the enamel kiln is only a full red, such as is marked on Mr. Wedgwood's thermometer 6 degrees. It is therefore necessary that the flux be so adjusted as to melt in that low heat. The usual materials are flint, or flint-glass, with a due proportion of red-led, or borax, or both, and sometimes a little tin calx to give opacity. Ka-o-lin is the name given by the Chinese to their porcelain clay, and pe-tun-tse to the other ingredient in their China ware. Specimens of both these have been brought into England, and found to agree in quality with some of our own materials. Kaolin is the very same with the clay called in Cornwall [Transcriber's note: word missing] and the petuntse is a granite similar to the Cornish moorstone. There are differences, both in the Chinese petuntses, and the English moorstones; all of them contain micaceous and quartzy particles, in greater or less quantity, along with feltspat, which last is the essential ingredient for the porcelain manufactory. The only injurious material commonly found in them is iron, which discolours the ware in proportion to its quantity, and which our moorstones are perhaps more frequently tainted with than the Chinese. Very fine porcelain has been made from English materials but the nature of the manufacture renders the process precarious and the profit hazardous; for the semivitrification, which constitutes porcelain, is necessarily accompanied with a degree of softness, or semifusion, so that the vessels are liable to have their forms altered in the kiln, or to run together with any accidental augmentations of the fire. |