Spreading of Oil on the Surface of Water.—If a small drop of oil be placed on the surface of water it will be observed to spread immediately until it forms a thin layer covering the surface. If a further addition of the oil be made, globules will be formed, which, as you now see upon the screen, remain floating on the surface. The spreading of the oil in all directions from the place on which the small quantity of oil was dropped is due to the superior surface tension of water, which pulls the oil outwards. The surface tension of the oil opposes that of the water, and would prevent the drop from spreading were it not overcome by a greater force. The result is the same as would be observed if the centre or any other part of a stretched rubber disc were weakened; the weak part would be stretched in all directions, and the rest of the disc would shrink towards the sides. When the oil has spread out, however, and contaminated, as it were, the surface of the water, the surface tension is reduced, and is not sufficiently strong to stretch out a further quantity of oil, which, if added, remains in the form of a floating globule.

Let us study the forces at work on the floating globule a little more closely. Its upper surface is in [pg 61] contact with air, and the surface tension tends, as usual, to reduce the area to a minimum. The top of the globule is not flat, but curved (Fig. 35), and its surface meets that of the water at an angle; and the counter-pull exerted against the stretching-pull of the water surface is not horizontal, but inclined in the direction of the angle of contact, as shown by the line B. The under part of the globule is also curved, and meets the water surface from below at an angle; and here also is exerted a pull in opposition to that of the water surface, different in magnitude to the force at the upper surface, but also directed at the angle of contact as shown by the line C. This tension at the joining surface of two liquids is called the “interfacial” tension, to distinguish it from that of a surface in contact with air. Acting against these two tensions is that of the water, which is directed horizontally along the surface, as shown by the line A. The lines A, B, and C indicate the forces acting at a single point; but the same forces are at work at every point round the circle of contact of the globule and the surface of the water. And therefore the tendency on the part of the water [pg 62] tension is to cause the globule to spread out in all directions, whereas the other two tensions tend to prevent any enlargement of its surface. The result depends upon the magnitudes and directions of the conflicting forces. We can imagine a kind of tug-of-war taking place, in which one contestant, A, is opposed to two others, B and C, all pulling in the directions indicated in Fig. 35. Although A is single-handed, he has the advantage of a straight pull, whereas B and C can only exert their strength at an angle, and the larger the angle the more they are handicapped. If A be more powerful than B and C, the globule will spread; but the result of the spreading is to diminish the angles at which the pulls of B and C are inclined to the surface, and hence their effective opposition to A will be increased. Moreover, the spreading of the liquid diminishes the surface tension of the water—that is, weakens A—and hence it becomes possible for B and C to prevail and draw back the surface of the globule which A had previously stretched. If, in spite of these disabilities, A should still be the stronger, the globule will be stretched until it covers the whole surface; whereas if B and C overcome A, the globule will shrink, increasing the angles at which B and C operate, and therefore reducing their effective pulls, until their combined strength is equal to that of A, when the globule will remain at rest. Bearing these facts in mind, we can understand why a small drop of oil placed on a clean water surface spreads across; for in this case A is stronger than B and C combined. But when the surface of the water is covered with a layer of oil, A is weakened, and can no longer overcome the opposing pulls of B and C. Hence [pg 63] a further drop of oil poured on to the surface remains in the form of a globule.

Movements due to Solubility.—When small fragments of camphor are placed on the surface of water some remarkable movements are seen.³ The bits of camphor move about with great rapidity over the surface, and generally, in addition, show a rapid rotary motion. The explanation usually given is that the camphor dissolves in the water at the points of contact forming a solution which possesses a less surface tension than pure water. This solution is in consequence stretched by the tension of the rest of the surface, and the camphor floating on its solution is therefore made to move in the direction of the line along which the stretching force happens to be the greatest. But the camphor continues to dissolve wherever it goes, and is therefore continuously pulled about as a result of this interplay of tensions. Touching the surface with a wire which has been dipped in oil immediately arrests the movements, owing to the tension of the water being diminished to such an extent by the skin of oil that it is no longer competent to stretch the part on which the camphor floats. No doubt this explanation is correct so far as it goes, but it is highly probable that when the floating substance dissolves, other forces are called into action in addition to the tensions.

Movements of Aniline Globules on a Water Surface.—If we allow a small quantity of aniline to run on to the surface of water, it forms itself into a number of floating globules. I now project on the screen a [pg 64] water surface on which a little aniline has been poured, and we are thus enabled to watch the movements which occur. All the globules appear to be twitching or shuddering; and if you observe closely you will notice the surface of each globule stretching and recoiling alternately. The recoil is accompanied by the projection of tiny globules from the rim, which becomes scalloped when the globule is stretched. The small globules thrown off appear to be formed from the protuberances at the edge (Fig. 36), and after leaving the main globule they spread out over the surface, or dissolve. This process continues for a long time, gradually diminishing in vigour, until small stationary globules are left floating on the surface, which is now covered with a skin of aniline. This action is in [pg 65] striking contrast to the tranquil formation of floating globules of oil, and calls for some special comment.

Let us recall again the three forces at work at the edge of a floating globule (Fig. 35). The surface tension of the water, acting horizontally, tends to stretch the globule, and is successful momentarily in overcoming the opposing tensions, each of which pulls at an angle to the surface. Enlargement of the upper surface of the globule, however, reduces the angles at which the tensions B and C act, and in consequence their effective strength is increased. The spreading of the aniline over the water surface diminishes the pull A, which B and C combined now overcome, and hence the surface of the globule shrinks again. For some unexplained reason both the stretching and recoil of the globule occur suddenly, there being an interval of repose between each, and these jerky movements result in small portions of the rim being detached, each of which forms a separate small globule. The aniline which spreads over the surface of the water dissolves, and the water tension A, which had been enfeebled by the presence of the aniline skin, recovers its former strength, and again stretches the globule; and so the whole process is repeated. When the surface of the water becomes permanently covered with a skin, which occurs when the top layer is saturated with aniline, the globule remains at rest, and has such a shape that the tensions B and C act at angles which enable them just to balance the weakened pull of A. Why the edge of the globule becomes indented during the movements, and why these movements are spasmodic instead of gradual, has not been clearly made out. It [pg 66] is interesting to recall that a spheroid of liquid on a hot plate also possesses a scalloped edge, and it may be that the two phenomena have something in common.

Movements of Orthotoluidine and Xylidine 1-3-4 on a Water Surface.—We will now observe, by the aid of the lantern, movements of globules more striking, and certainly more puzzling, than those of aniline. I place on the surface of the water a quantity of a special sample of orthotoluidine, and you see that immediately a number of globules are formed which are endowed with remarkable activity. They become indented at one side, and then dart across the surface at a great speed, usually breaking into two as a result of the violent action (Fig. 37). Then follows a short period of rest, when suddenly, as if in response to a [pg 67] signal, all the larger globules again become indented, forming shapes like kidneys, and again shoot across the surface, breaking up into smaller globules. Notice that the very small globules remain at rest; it is only those above a certain size that display this remarkable activity. A film of the liquid forms on the water, and the action gradually becomes more intermittent, ceasing altogether when a skin is well established, and the large globules have sub-divided into very small ones. My sample of orthotoluidine is somewhat unique, as other specimens of the liquid, obtained from the same and other sources, do not show the same lively characteristics. As in the case of camphor, touching the surface with a drop of oil arrests the movements immediately. The organic liquid xylidine 1-3-4, however, exhibits the same movements, as you now see on the screen; and, if anything, is even more active than the orthotoluidine previously shown. It may be added that occasional samples of aniline show similar movements, but of less intensity.

Now if I am asked to explain these extraordinary movements, I am bound to confess my inability to do so at present. Why should the globules become indented on one side only? The two tensions acting at the edge in opposition to the water tension are at work all round the globule, and it is not easy to see why they should prevail to such a marked degree at one spot only. The movement across the surface, if we followed our previous explanations, would be due to the superior pull of the water tension behind the globule, opposite the indented part; although to look at it would seem as if some single force produced the indentation and [pg 68] pushed the globule along bodily. Are there local weaknesses in the tension of the water, and, if so, why should such weak spots form simultaneously near each globule, causing each to move at the same moment? Any explanation we may give as to the origin of the cavity in the side of the globule does not suffice to account for the intermittent character of the movement, and its simultaneous occurrence over the whole surface. We must therefore leave the problem at present, and trust to future investigation to provide a solution.

Production of Globules from Films.—When a film of oil spreads over a water surface it sometimes remains as such indefinitely. Certain other liquids, however, form films which after a short interval break up into globules, and the process of transition [pg 69] is at once striking and beautiful. In order to show it, I project a water surface on the screen, and pour on to it a very small quantity of dimethyl-aniline—an oily liquid related to but distinct from ordinary aniline. It spreads out into a film of irregular outline, which floats quietly for a short time. Soon, however, indentations are formed at the edges, which penetrate the film, and from the sides of the indentations branches spread which in turn become branched; and shortly the whole film becomes ramified, resembling a mass of coral, or, to use a more homely illustration, a jig-saw puzzle (Fig. 38). The various branches join in numerous places, cutting off small islands from the film; and immediately each island becomes circular in outline—and the resolution into globules is complete. We have witnessed one of the beauty-sights of Nature.

The same method of globule formation is shown by nitro-benzol and quinoline, and as the action is more gradual in the case of the latter substance, I show it in order that we may study the process in greater detail. Notice the formation of the indentations and their subsequent branching; and also that holes form in the skin from which branchings also proceed. In this instance the film is broken up in sections, but the action continues until nothing but globules remain on the surface.⁴

It is not easy to see why the canals of water penetrate the film and split it up into small sections, nor why entry takes place at certain points on the edge in [pg 70] preference to others. Some orderly interplay of forces, not yet properly understood, gives rise to the action; and a satisfactory explanation has yet to be given.

Network formed from a Film.—A further example of the breaking up of a film is furnished by certain oils derived from coal-tar, the result in this case being the formation of a network or cellular structure. I place on the surface of water in a glass dish a small quantity of tar-oil, and project it on the screen. It spreads out at first into a thin film, which, by reflected light, shows a gorgeous display of colours. After a short time, little holes make an appearance in the film, and these holes gradually increase in size until the whole of the film is honeycombed (Fig. 39), the oil having been heaped up into the walls which divide the separate compartments. Here again the accepted views on surface tension do not appear competent to explain the action. It appears to be the case that most films on the surface of water show this tendency to [pg 71] perforation, which may be due to inequalities in the thickness of the film, or in the distribution of the strain to which it is subjected.⁵

Quinoline Rings.—Reference has already been made to the breaking-up of a quinoline film into globules. But if we examine the surface about half an hour after the formation of these globules, we find that each has been perforated in the centre, forming a ring or annulus (Fig. 40). Some of the larger globules have undergone perforation in several places, forming honeycombed plates. These rings and plates, which you now see projected on the screen, remain unchanged, and apparently represent the final stage of equilibrium under the action of the various forces. Quinoline, so far as observations have been made, appears to be unique in respect to the formation of stable rings from globules.

Expanding Globules.—I now wish to show, by an [pg 72] experiment, how sensitive a floating globule is to disturbances in the existing tensions, which maintain it at rest. On the screen is projected a globule of dimethyl-aniline, floating tranquilly on the surface of water. I now allow a small drop of quinoline to fall upon it, and immediately it spreads out over the surface, forming a hole in its centre (Fig. 41), after which it gradually resumes its former shape. Sometimes the action is so violent that the globule is split up into several portions, which, however, join together again after a short time. In order to explain this action, we must again refer to the three tensions operating on the globule (Fig. 35). When in equilibrium, A is balanced by the joint pull of B and C; and hence if either of the latter be weakened, A will predominate and stretch the globule. In our experiment it is the interfacial tension, C, which has been diminished in strength, as we may now prove by a second experiment. In this [pg 73] instance I float on the water surface a globule of lubricating oil, with which quinoline does not readily mix, and which does not act so immediately as dimethyl-aniline. On allowing the drop of quinoline to fall into it, no action is observed until the drop has rested on the junction of the oil and water for a short time; but when it has penetrated the interface the oil globule suddenly spreads over the water surface, and with such violence as to detach several portions from the main globule. Merely touching the upper surface of the oil with a rod moistened with quinoline has no effect, and hence the result is due to the weakening of the interfacial tension. A similar effect is obtained when quinoline is dropped into a globule of aniline, and may be obtained with various other liquids.

Attraction between Floating Globules.—The “Devouring” Globule. When globules of different liquids are floating on the same water surface, a tendency to coalesce is sometimes noticed, but is by no means general. I will show one example which possesses striking features, showing as it does the remarkable results which may be brought about by surface forces. First of all, we form a number of active orthotoluidine globules on the surface of a dish of water, which you see wriggling about in their characteristic fashion. After their activity has subsided somewhat, I float on to the surface a large globule of dimethyl-aniline. Attraction of some kind is at once apparent, for the nearest globule of orthotoluidine immediately approaches the intruder. And now comes the process of absorption. The large globule of dimethyl-aniline develops a protuberance in the direction [pg 74] of its victim (Figs. 42 and 43), and the small globule of orthotoluidine coalesces with this “feeler,” which then shrinks back into the large globule, conveying with it the entangled orthotoluidine. This, however, by no means satisfies the devouring globule, as a second victim is at once appropriated in the same manner; and you will notice a nibbling process at work round the edges continuously, which is due to the absorption of the smaller globules of orthotoluidine. The action continues until the whole of the surface has been cleared of orthotoluidine, after which the large globule floats tranquilly in the centre of the vessel, apparently resting after its heavy meal. The interaction [pg 75] of the forces which gives rise to this phenomenon is difficult to fathom; there are no doubt several tensions, constantly changing in magnitude, which in the result cause the liquids of the large and small globules to intermingle. Separate globules of a single liquid sometimes unite in this manner, but this is not common, it being more usual for the scattered units to remain apart.

Analogies of Surface Tension Phenomena with Life.—When we watch the movements of globules on the surface of water, the resemblance to the antics of the lower forms of life immediately occurs to our [pg 76] minds. Now I do not intend here to intrude any opinion on the much-discussed subject of the Origin of Life, but merely to point out that certain phenomena, usually supposed to be associated only with living things, may result from the interplay of surface tensions. In our experiments we have witnessed expansive and contractile motion (aniline globules on water); movement of translation, of a very vigorous kind (xylidine and orthotoluidine globules); incorporation of external matter, or feeding (dimethyl-aniline absorbing orthotoluidine)—we are getting quite familiar with these long names now—, splitting up of masses, or division (skins of quinoline, etc., breaking up into branched portions, and sub-division of large globules); and formation of cellular structure (tar-oil on water). And the conclusion we may legitimately draw is this: that mechanical forces may account for many observed phenomena in connexion with life which formerly were attributed to the action of “vital” forces. Modern biological research all points in the same direction, and it seems probable that the operations of the animate and inanimate are controlled by the same forces. But the mystery of Life still remains.

Conclusion.—I have endeavoured in these lectures to bring to your notice some of the remarkable results which may be produced by the use of water and a few other liquids, and the scientific conclusions which may be drawn from them. It may be that the phenomena we have considered have little or no commercial application; but science has other uses in addition to its fruitful alliance with commerce. The study of the [pg 77] methods by which Nature achieves her ends stimulates the imagination and quickens the perceptions, and is therefore of the highest educational value. It is a great scientific achievement to run a railway to the summit of the Jungfrau, but we should not envy the mental condition of the individual to whom that glorious mountain appealed only through the railway dividends. And I trust that we shall never become so imbued with the industrial aspects of science, as to lessen our appreciation of the works of Nature, whether manifested in the snow-clad peak or the equally wonderful drop of water.

[pg 78]