CHAPTER XIII. ON THE SECONDARY, PURPLE.

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Purple, the third and last of the secondary colours, is composed of red and blue, in the proportions of five of the former to eight of the latter; proportions which constitute a perfect purple, or one of such a hue as will neutralize and best contrast a perfect yellow, in the ratio of thirteen to three, either of surface or intensity. When mixed with its co-secondary colour, green, purple forms the tertiary olive; and, when compounded with the remaining secondary, orange, it constitutes in like manner the tertiary russet. Of the three secondary colours it is the coolest, as well as the nearest in relation to black or shade; in which respect, and in never being a warm colour, it resembles blue. In other respects also, purple partakes of the properties of blue, which is its archeus, or ruling colour; hence it is to the eye a retiring colour, that reflects light little, and loses rapidly in power in a declining light, and according to the distance at which it is viewed. By reason of its being the mean between black and blue it becomes the most retiring of all positive colours. Nature employs this hue beautifully in landscape, as a sub-dominant, in harmonizing the broad shadows of a bright sunshine ere the light sinks into deep orange or red. Girtin, who saw Nature as she is, and painted what he saw, delighted in this effect of sunlight and shadow. As a ruling colour, whether in flesh or otherwise, purple is commonly too cold, or verges on ghastliness, a fault which is to be as much avoided as the opposite extreme of viciousness in colouring, stigmatized as foxiness.

Yet, next to green, purple is the most generally pleasing of the consonant colours; and has been celebrated as a regal or imperial colour, as much perhaps from its rarity in a pure state, as from its individual beauty. Romulus wore it in his trabea or royal mantle, and Tullus Hostilius, after having subdued the Tuscans, assumed the pretexta or long robe, broadly striped with purple. Under the Roman emperors, it became the peculiar emblem or symbol of majesty, and the wearing of it by any who were not of the Imperial family, was deemed a "treasonable usurpation," punishable by death. At the decline of the empire, the Tyrian purple was an important article of commerce, and got to be common in the clothing of the people. Pliny says, "Nepos Cornelius, who died in the reign of Augustus CÆsar, when I was a young man, assured me that the light violet purple had been formerly in great request, and that a pound of it usually fetched 100 denaria (about £4 sterling): that soon after the tarentine or reddish purple came into fashion; and that this was followed by the Tyrian dibapha, which could not be bought for less than 1000 denaria (nearly £40 sterling) the pound; which was its price when P. Lentulus Spinter was Ædile, Cicero being then Consul. But afterwards, the double-dyed purple became less rare, &c." The Tyrian purple alluded to was obtained from the purpurÆ, a species of shell-fish adhering to rocks and large stones in the sea adjoining Tyre. On account, probably, of its extreme costliness, it was frequently the custom to dye the cloth with a ground of kermes or alkanet, previous to applying the Tyrian purple. This imparted to the latter a crimson hue, and explains doubtless the term, double-dyed. The Greeks feigned the ancient purple to be the discovery of Hercules Tyrius, whose dog, eating by chance of the fish from which it was produced, returned to him with his mouth tinged with the dye. Alexander the Great is said to have found in the royal treasury, at the taking of Susa, purple to the enormous value of 5000 talents,[A] which had lain there one hundred and ninety-two years, and still preserved its freshness and beauty.

When inclining to red, purple takes the name of crimson, &c.; and when leaning to blue, the names of violet, lilac, mauve, &c. Blue is a colour which it serves to mellow, or follows well into shade. The contrast or harmonizing colour of purple is yellow on the side of light and the primaries; while purple itself is the harmonizing contrast of the tertiary citrine on the side of shade, and less perfectly so of the semi-neutral brown. As the extreme primaries, blue and yellow, when either compounded or opposed, afford, though not the most perfect harmony, yet the most pleasing consonance of the primary colours; so the extremes, purple and orange, yield the most pleasing of the secondary consonances. This analogy extends likewise to the extreme tertiary and semi-neutral colours, while the mean or middle colours furnish the most agreeable contrasts or harmonies.

In nature pure purple is not a common colour, and on the palette purple pigments are singularly few. They lie under a peculiar disadvantage as to apparent durability and beauty of colour, owing to the neutralizing power of yellowness in the grounds upon which they are laid; as well as to the general warm colour of light, and the yellow tendency of almost all vehicles and varnishes, by which the colour of purple is subdued.

208. BURNT CARMINE

is the carmine of cochineal partially charred till it resembles in colour the purple of gold, for which, in miniature and water-painting, it is substituted. It is a magnificent reddish purple of extreme richness and depth, eligible in flower-painting and the shadow of draperies. As it is generally impossible, however, to alter the nature of a pigment by merely changing its colour, burnt carmine is scarcely more permanent than the carmine from which it is produced. If used, therefore, it should be in body, and not in thin washes or as a glaze. Durable pigments are admissible in any form; but semi-stable pigments (gamboge excepted) should only be employed in body.

209. BURNT LAKE

holds the same relation to crimson lake as burnt carmine to ordinary carmine; and is hence a weaker variety of the preceding, with less richness, and likewise less permanence.

210. INDIAN PURPLE

is prepared by precipitating an extract of cochineal with sulphate of copper. It is a very deep-toned but rather cold and subdued purple, neither so red nor so brilliant as burnt carmine; and is chiefly of service in draperies. It is apt to lose its purple colour in a great measure on exposure to light and air, and assume an inky blackness; a defect which becomes less apparent when the pigment is used in bulk.

211. MARS VIOLET,

Violet de Mars, Purple Ochre, or Mineral Purple, is a dark ochre, native of the Forest of Dean in Gloucestershire. It is of a murrey or chocolate colour, and forms cool tints of a purple hue with white. It is of a darker colour than Indian red, which has also been classed among purples, but has a similar body and opacity, and generally resembles that pigment. It may be prepared artificially, and some natural red ochres burn to this colour. Being difficult and sometimes impossible to procure, Mars violet is often compounded; in which case it is liable to vary both in hue and stability. As, however, Indian red is always taken for its basis, the mixture is never wholly fugitive, nor exhibits any very glaring contrast on exposure.

212. MIXED PURPLE.

Purple being a secondary colour, composed of blue and red, it follows of course that any blue and red pigments, which are not chemically at variance, may be employed in producing mixed purples of any required hue, either by compounding or grinding them together ready for use, or by combining them in the various modes of operation in painting. In such compounding, the more perfect and permanent the original colours are, the more perfect and permanent will be the purple obtained. To produce a pure purple, neither the red nor the blue must contain or incline to yellow; while to compound a durable purple, both the red and the blue must be durable also. Ultramarine and the reds of madder yield beautiful and excellent purples, equally stable in water or oil, in glazing or tint, whether under the influence of light or impure air. Cobalt blue and madder red likewise afford good purples; and some of the finest and most delicate purples in ancient paintings appear to have been composed of ultramarine and vermilion, which furnish tints equally permanent, but less transparent than the above, and less easily compounded. Facility of use, and other advantages, are obtained at too great a sacrifice by the employment of perishable mixtures, such as the lakes of cochineal with indigo.

PERMANENT REDS. PERMANENT BLUES.
Cadmium Red. Cerulian Blue.
Liquid Rubiate. Cobalt Blue.
Madder Carmine. Genuine Ultramarine.
Rose Madder. Brilliant Ultramarine.
Mars Red. French Ultramarine.
Ochres. New Blue.
Vermilions. Permanent Blue.

It should be noted that all the above reds do not afford pure purples with blue; those which contain more or less yellow, as cadmium red and orange vermilion, furnish purples partaking more or less of olive, which is a compound of purple and green. To those reds may be added the russet Rubens Madder and the marrone Madder Brown, two pigments which are alike eligible for mixed purple and mixed orange. No purple, it will be remarked, equal in gorgeous richness to that produced from crimson lake and Prussian blue is obtainable from the colours given; just as no mixed green is of such depth and power if that blue be wanting as a constituent. But, as our compound tints are given rather as examples of durability than beauty, all semi-stable or fugitive mixtures are of necessity ignored.

213. PURPLE MADDER,

Field's Purple, or Purple Rubiate, is the only durable organic purple the palette possesses. Marked by a soft subdued richness rather than by brilliancy, it leans somewhat towards marrone, and affords the greatest depth of shadow without coldness of tint. Unfortunately, in the whole range of artistic pigments there is no colour obtainable in such small quantity as madder purple; hence its scarcity and high price cause it to be confined to water-colour painting, in which the clearness and beauty of its delicate tones render it invaluable in every stage of a drawing. With raw Sienna and indigo or Prussian blue, subdued by black, it gives beautiful shadow tints, and will be found useful in sky and other effects compounded with cobalt, rose madder, French blue and sepia, yellow ochre and cobalt, lamp black and cobalt, light red, Vandyke brown, burnt Sienna, or aureolin. With great transparency, body, and depth, it is pure and permanent in its tints, neither gives nor sustains injury on admixture, dries and glazes well in oil, works well, and is altogether most perfect and eligible. For fresco it is admirably adapted, being quite uninjured by lime.

There is a lighter and slightly brighter sort, containing less colouring matter and more base, which has all the properties of the above with less intensity of colour. For the sake of cheapness, the purple is sometimes compounded in oil, generally of brown madder and a blue. Provided the latter be stable, transparent, and mix kindly, no greater objection can be taken to this than to the neutral orange of brown madder and yellow ochre.

214. VIOLET CARMINE

is a brilliant bluish purple of much richness, employed in draperies and the like. It is prepared by precipitating an alcoholic extract of the root of the Anchusa tinctoria, commonly known as alkanet, a plant growing in the Levant, and some other warm countries. It was used by the ancients as a dye, or as a groundwork to those stuffs which were to be dyed purplish-red: the ladies in ancient times also employed it as a paint. Its colouring matter or anchusin has the character of a resin, and is dark-red, softened by heat, insoluble in water, soluble in alcohol and alkalis, and freely so in ether, fats, and volatile oils, to all of which it imparts a brilliant red hue. To obtain anchusin, all the soluble matters are first abstracted from the bruised root by water: it is then digested in a solution of carbonate of potash, from which it may be readily precipitated by an acid. Its alcoholic solution yields with different reagents crimson, flesh-coloured, blue, and violet precipitates, none of which, however, can be classed as durable. The variety under notice, violet carmine, resembles the other colours afforded by alkanet in not being able to withstand the action of light. On continued exposure, it loses its beauty and brightness, together with much of its colour, and, like Indian purple, assumes an inky blackness. Hence it is unsuited to permanently pure effects, and should only be used in body.


215. Archil Purple.

Archil may be regarded as the English, cudbear as the Scotch, and litmus as the Dutch name for one and the same substance, extracted from several species of lichens by various processes. These lichens, which are principally collected on rocks adjacent to the sea, are cleaned and ground into a pulp with water, treated from time to time with ammoniacal liquor, and exposed with frequent agitation to the action of the atmosphere. Peculiar principles existing in the lichens are, by the joint instrumentality of the air, water, and ammonia, so changed as to generate colouring matter, which, when perfect, is expressed. Soluble in water and alcohol, this colouring principle yields by precipitation with chloride of calcium a compound known as 'Solid French Purple', a pigment more stable than the archil colours generally, but all too fugitive for the palette.

216. Bismuth Purple.

A purple powder is capable of being produced from bismuth by passing chlorine gas through the hydrated oxide suspended in a saturated solution of potash. As soon as the oxide becomes brown-red, the mixture is boiled and the liquid decanted off at once, the residue being immediately washed first with alcohol and then with water. On the whole, the result is not, for an artistic pigment, worth the trouble involved in the preparation.

217. Burnt Madder

is obtained by carefully charring madder carmine until it becomes of the hue required. Bearing the same relation to madder carmine as burnt carmine to the carmine of cochineal, burnt madder is a permanent and perfectly unexceptionable pigment. By reason, probably, of its great price, it is not mentioned in trade catalogues, and must be held as commercially unknown.

218. Cobalt Purples

are obtainable ranging from the richest crimson purple to the most delicate violet. We have produced them by wet and dry methods, varying in brilliancy and beauty, but characterised generally by want of body, and frequently by a smalt-like grittiness. Chemically, good and stable colours, they are not received with favour on the palette, and certainly may be very well replaced by mixtures of cobalt blue and madder red. When a permanent compound is obtainable equal in colour to an original pigment, and superior in its physical attributes, no objection can fairly be taken to its artistic preference. There are other things to be considered in a pigment besides permanence, or even permanence and colour combined. The two together do not constitute a perfect pigment, that is, a material of practical utility and value. In the last chapter, allusion was made to a green which possesses both the one and the other, and yet is—at present, at least—quite unfitted for artistic use. Hence, with a strong partiality for simple original pigments, we are bound to confess there are cases where mixtures are justifiably preferred. All we contend for is, that each constituent of such mixtures should be stable, and neither give nor receive injury by being compounded.

219. Gold Purple,

Purple of Cassius, or Cassius's Purple Precipitate, was discovered in 1683 by Cassius of Leyden. It is a compound of tin and gold, best formed by mixing aqueous perchloride of iron with aqueous protochloride of tin, till the colour of the liquid has a shade of green, and then adding this liquid, drop by drop, to a solution of perchloride of gold, which is free from nitric acid and very dilute: after twenty-four hours the purple is deposited. When recently prepared, the colour is brightened by boiling nitric acid. Not brilliant, but rich and powerful, this purple varies in hue according to the mode of manufacture from deep crimson to murrey or dark purple: it also differs in degrees of transparency. Working well in water, it is an excellent though costly pigment, once popular in miniatures, but at present rarely, if ever used, as purple madder is cheaper, and perfectly well supplies its place. Retaining its colour at a high red heat, it is now confined to enamel and porcelain painting, and to tinging glass of a fine red. If, whilst in its hydrated state, it be washed with ammonia, a bright purple liquid results, from which a violet colour, somewhat less expensive, can be produced, by combining the gold purple with alumina, and calcining the product in the same way that is practised with cobalt. This compound may be exposed to the action of the sun's rays for a year without being sensibly affected.

220. Prussian Purple.

A prussiate of iron is obtainable of a violet hue, affording good shadow tints and clear pale washes. It has not, however, been introduced as a pigment, as ordinary Prussian blue tinged with red furnishes a similar colour.

221. Sandal Wood Purple.

Sandal wood contains about 1616 per cent. of colouring matter, soluble with difficultly in water, but readily dissolved by alcohol. From the latter solution, chloride of tin throws down a purple, and sulphate of iron a deep violet precipitate; neither of which is remarkable for permanence.

222. Tin Violet.

By heating chromate of stannic oxide to bright redness, a dark violet mass is obtained, which is better adapted to enamel painting than to the palette. It communicates in glazings a variety of tints, from rose-red to violet.


So scant is the number of good purples in common use, that there are but two which can be classed as durable, namely, purple madder and the true Mars violet.

Foremost in the second group stands burnt carmine. As there are different degrees both of permanence and fugacity, so are there different degrees of semi-stability. Burnt carmine, burnt lake, Indian purple, and violet carmine, all belong to this division; but the first certainly is more permanent than the rest.

Rich and beautiful as it is, purple madder cannot be called brilliant; while Mars violet is, of course, ochrous. Unlike green and orange, therefore, purple can point to no original pigment at once vivid and durable: as regards purple, brilliancy implies a semi-stability that borders more or less closely on fugacity. Until the advent of a perfect palette, however, brilliancy and semi-stability will doubtless hold their own. Their present popularity may be seen by a glance at the lists of artist-colours—lists compiled, be it remembered, in obedience to the law of demand and supply. If art were really so much honoured as some of its disciples pretend, none but durable colours would be employed. In our opinion, if a picture be worth painting at all, it is worth painting with permanent pigments; but many evidently think otherwise. Deploring an error neither flattering to the craft they practise nor to themselves, we would urge such to bear in mind this axiom, semi-stable pigments become fugitive when used in thin washes. Even in body they do not preserve their primitive hue, but in glazing and the like, their colour altogether flies or is wholly destroyed.

It is this semi-stability, recommended to the thoughtless and indifferent by the beauty which generally accompanies it, that is the bane of modern art. Even our greatest painters have yielded to its fascination. Who has not gazed upon one of Turner's fading pictures with still more of sadness than enjoyment, that anything so grand, so beautiful, so true, should slowly but surely be passing away? A feeling akin to pity is conjured up at the sight of the helpless wreck, abandoned amid the treacherous materials employed, and sinking deeper and deeper. Mournful, indeed, is that mighty ruin of mind amid matter; mournful the thought that in years to come, the monument sought for will not be found.

FOOTNOTES:

[A] A talent of money, i.e., a talent's weight of silver, was equal to nearly £244.


                                                                                                                                                                                                                                                                                                           

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