Gypsum.

In the previous chapter mention was made of gypsum as a compound of lime, but no reference to its action as a manure was made. In the past, gypsum was used extensively and highly valued. It was found to be of especial value for clover; and there is a story told of Benjamin Franklin which illustrates the very striking nature of its action on this crop. It is related that he once printed with gypsum the words "This has been plastered" on a field of clover, and that for a long time afterwards the legend was plainly discernible on account of the luxuriance of the clover on the parts of the field which had been thus treated.

Mode in which gypsum acts.

Despite the fact that gypsum is a most ancient manure, it is only of late years that we have come to understand the true nature of its action. For long it was believed that the reason of its striking effect in promoting clover was due to the fact that, as clover was a lime-loving plant, the action of gypsum was owing to the lime it contained. That, however, the action of gypsum is not due to the fact that it supplies lime to the plant, seems evident when it is stated that were this so, any other form of lime would have the same beneficial effect. It is well known, however, that this is not so. Besides, as we have already pointed out, lime is not a constituent which most soils lack, so far as the needs of the crop are concerned. There is a certain amount of truth in the old belief that gypsum enriches the soil in ammonia by fixing it from the air. The power that gypsum has as a fixer of ammonia has already been referred to in the chapter on Farmyard Manure; but in this case the gypsum is brought in contact with the ammonia. The origin of this old belief was due to a misconception as to the amount of ammonia in the atmosphere. No doubt gypsum greatly increases the power of a soil to absorb ammonia from the air; but the quantity of ammonia in the air is so very trifling, that its action in this respect is hardly worth considering. The true explanation of the action of gypsum is to be found in its effect on the double silicates, which it decomposes, the potash being set free. Its action is similar to that of other lime compounds, only more characteristic. As a manure, therefore, its action is indirect, and its true function is to oust the potash from its compounds. Its peculiarly favourable action on clover is due to the fact that clover specially benefits by potash, and that adding gypsum practically amounts to adding potash. Of course it should be borne in mind that the soil must contain potash compounds if gypsum is to have its full effect. Now, however, that potash salts suitable for manuring purposes are abundant, it may well be doubted whether it is not better to apply potash directly. Further, it must be borne in mind that gypsum is applied to the soil whenever it receives a dressing of superphosphate of lime, as gypsum is one of the products formed by treating insoluble phosphate of lime with sulphuric acid.

It is possible that gypsum may act as an oxidising agent in the soil, just as iron in the ferric condition does. It has a large quantity of oxygen in its composition, and under certain conditions may act as a carrier of oxygen to the lower layers of the soil. When it is used, it should be applied some months before the crop is sown.

Gypsum, therefore, although it contains two necessary plant-constituents, lime and sulphuric acid, cannot be regarded as a direct manure; and as its action comes to be more fully understood, its use, which was never very abundant in this country, will probably decrease. We have already, in the chapter on Nitrification, referred to the action of gypsum in promoting nitrification.

Salt.

The action of salt as a manure presents a problem which is at once of the highest interest and surrounded with the greatest difficulties. In view of the large quantities now used for agricultural purposes, a somewhat detailed examination of the nature of its action is not out of place in a work such as the present.

Antiquity of the Use of Salt.

The recognition of the manurial functions of salt dates back to the very earliest times. Its use among the ancients is testified by numerous allusions in the Old Testament; while, according to Pliny, it was a well-known manure in Italy. The Persians and the Chinese seem also to have used it from time immemorial, the former more especially for date-trees.

Nature of its Action.

Despite, however, the great antiquity of its use, much difference of opinion seems always to have existed as to the exact method of its action, and as to its merits as a manure in promoting vegetable growth. It furnishes, in fact, a good example of the difficulty which exists in the case of many manures, whose action is chiefly indirect, of fully understanding their influence on the soil and on the crop. In fact, the action of salt is probably more complicated than that of any other manurial substance.

Salt not a necessary Plant-food.

We have already seen that neither sodium nor chlorine—the two constituent elements of salt—are in all probability absolutely necessary plant-foods. If they are necessary, the plant only requires them in minute quantities. Despite this fact, soda is an ash-constituent of nearly every plant, and in many cases one of the most abundant. In amount it is one of the most variable of all the ash-constituents, being present in some plants only in minute quantities, while in others it occurs in large quantities. Mangel and plants of the cabbage tribe may be cited as examples of plants containing large amounts of soda in their composition. But the plants which contain it in largest quantity are those which thrive on the sea-coast, and it has been thought that for them at least salt is a necessary manure. This, however, does not seem to be the case. In fact, the amount of soda in a plant seems to be largely a matter of accident. It may be added that the succulent portions of a plant are generally richest in soda.

Can Soda replace Potash?

Again, it has been believed that soda is capable of replacing potash in the plant; but this does not seem to be the case to any extent. The view that soda is able to replace potash, it has been thought, is supported by the variation which exists in the proportion of soda and potash in different plants. It must be remembered, however, that it is highly probable that most plants contain a larger quantity of ash-constituents than is absolutely necessary for their healthy growth. Especially is this the case with such a necessary plant-food as potash, of which there is generally present, in all likelihood, an excess. The variation in the quantity of potash and soda present in many plants under different circumstances can scarcely, therefore, be regarded as furnishing a proof of the replacement of potash by soda. Incidentally we may mention, as a fact worthy of notice, that cultivated plants have more potash and less soda in their composition than wild plants. What has been said of soda may be held to apply equally to chlorine, as it seems to be chiefly in the form of common salt that soda enters the plant. The amount of salt, therefore, present in plants must be regarded as largely accidental and dependent on external circumstances, such as the nature of the soil, &c.

Salt of universal Occurrence.

But even were salt a necessary plant-food, its occurrence in the soil is already of sufficient abundance to obviate any necessity for its application. It may be said to be of almost universal occurrence. Even the air contains it in traces. That this is the case in the neighbourhood of the sea-coast is well known; but even in air far inland, accurate analysis of the air would probably demonstrate its presence in greater quantity than is commonly believed. It is a wise provision that plants absorb salt, for it increases their efficiency as food,—the function of salt as a constituent of animal food being of the very highest importance. It is an indispensable food-ingredient for animal life. With regard to ordinary farm-stock, the amount of salt which naturally occurs in their food is quite sufficient. In the case, however, of pastures in countries far removed from the sea, the custom of specially supplying stock with salt is common. This is done by placing a piece of rock-salt in the fields.

Special Sources of Salt.

The salt of commerce is obtained from various sources. Besides the sea, we have ample sources of salt in the large saline deposits found in many parts of Europe, especially in Austria, and in England in Cheshire.

The Action of Salt indirect.

From what has been said above, it is clear that the action of salt as a manure is indirect and not direct. What the nature of that indirect action is we shall now proceed to discuss.

In considering the evidence of the manurial value of salt, we are at once brought face to face with the fact that the experience of its action in the past has as often been unfavourable as favourable. Salt, it is well known, is both an antiseptic and a germicide. It is, indeed, one of the most commonly used of preservatives. When applied in large quantities to the soil, it has a most deleterious action on vegetation. This hurtful action of salt has long been known; and it is as often mentioned in the writings of antiquity on account of its unfavourable as on account of its favourable action. Thus, for example, among the ancient Jews it was customary, after the conquest of a hostile town, to strew salt on the enemy's fields, for the purpose of rendering them barren and unfertile. And again, among the Romans, for the same purpose, salt was often spread on a spot where some great crime had been committed.

While, therefore, its unfavourable action has long been known, the fact that there are circumstances under which its action is, on the contrary, favourable for promoting vegetable growth has also been long recognised. The difficulty for the agricultural student is to reconcile these two seemingly contradictory experiences. For the English agriculturist the subject possesses especial interest, since in England it has been in the past most generally used and its action most discussed since the time of Lord Bacon, who discusses in his writings the action of solutions of it on different plants.

The true explanation of salt being so different in its action is to be found in the quantity applied, the nature of the soil, the crop to which it is applied, and the conditions under which it is applied—i.e., whether it is applied alone or along with other manures.

Mechanical Action on Soils.

In the first place, it must be noted that salt exerts a mechanical action on the soil of a very similar kind to that exercised by lime. When applied to clay soils it causes a flocculation or coagulation of the fine clay-particles, and thus prevents the soil from puddling to the same extent as would otherwise be the case. In fact, an example of this action of salt when in solution causing the precipitation of fine suspended clayey matter, is afforded by the formation of deltas at the mouths of rivers. The power of clarifying muddy water is common indeed to saline solutions. Schloesing attributes the clarifying power of a soil to the presence of the saline matters it contains; and from this point of view it would appear that manures containing any saline substance may exert an important mechanical influence on the soil.

Solvent Action.

But a much more important property of salt is its solvent action on the plant-food present in the soil. Its action in decomposing the minerals containing lime, magnesia, potash, &c., is similar to the action of gypsum. By acting upon the double silicates it liberates these necessary plant-foods. It is not only on the basic substances upon which it acts, but also on the phosphoric and silicic acids, which it sets free. Its power of dissolving ammonia from the soil is considerable. Experiments with a weak solution of salt on a soil by Peters and Eichhorn to test its solvent power, showed that the salt solution dissolved more than twice as much potash and nearly thirty times as much ammonia as an equal quantity of pure water did. When applied to the soil, it seems chiefly to liberate lime and magnesia. The exact nature of the chemical action taking place is a point of some dubiety. According to some, it is changed into nitrate of soda; according to others, into carbonate of soda. The latter theory seems to be the more probable one. Its action on the lime and magnesia compounds is to convert them into chlorides; and this chemical reaction explains the action that salt has in increasing the water-retaining and water-absorbing power of the soil; for the chlorides of magnesia and lime are salts which have a great power of attracting water from the air.

Again, the very fact that salt acts as an antiseptic may serve to explain its beneficial action in certain cases where it prevents rankness of growth. No doubt this was its function when applied along with Peruvian guano. This it might do by preventing too rapid fermentation (nitrification) of the manure, or by actually weakening the plant. Its action when applied with farmyard manure may also be similar. But while its effect in many cases may be towards retarding fermentation, on the other hand its action, when applied along with lime to compost-heaps, is towards promoting more rapid decomposition. Probably a reaction takes place between the lime and the salt, the result of which is the formation of caustic soda.

Such are some of the ways in which salt may act. It must at once be seen how its action in one case will be favourable and in another case unfavourable. There must be fertilising matter present in the soil if it is to act favourably. Again, it will only be under such circumstances, where rankness of growth is likely to ensue, that its antiseptic properties will act favourably and not unfavourably.

Best used in small Quantities along with Manures.

Probably it is for these reasons that its action has been found to be most favourable when applied along with other manures and not alone. Applied along with nitrate of soda, as is commonly done, it doubtless increases the efficiency of the nitrate. Some plants seem to be undoubtedly benefited by salt: of these flax may be mentioned. The application of salt to plants of the cabbage tribe seems also to be highly beneficial. On mangels, along with other manures, it has also been found to have a very favourable effect. But with many crops its action has been proved to be less favourable.

Affects Quality of Crop.

Although salt has often been found to increase the quantity of a crop, the quality of the crop has been made to suffer. Its action on beetroot has been more especially studied. The effect of its application is to lessen the total quantity of dry matter and sugar in the plant. This has been found to be the case both when the salt was applied alone and along with nitrate of soda and other manures. On potatoes, again, its action has been found to be deleterious, lessening their percentage of starch. The deleterious action of chlorides on the quality of potatoes is also seen when potassium chloride is applied. It is for this reason that potash should never be applied to the potato crop in the form of chloride.

In the late Dr Voelcker's opinion, the conditions under which salt had the most favourable action on the mangel crop was in the case of a light sandy soil, and applied at the rate of 4 to 5 cwt. per acre. Its action when applied to clay soils was not so favourable.

Rate of Application.

Lastly, the rate at which it may be applied will naturally vary. From 1 cwt. and even less, up to 6 cwt. or even more, has been the rate at which it has been commonly applied in the past. From what has been said, it will be seen that it is more likely to exert a favourable influence when applied only in small quantities.